Abstract: The elimimation of mefenamic acid has been carried
out by photolysis, ozonation, adsorption onto activated carbon (AC)
and combinations of the previous single systems (O3+AC and
O3+UV). The results obtained indicate that mefenamic acid is not
photo-reactive, showing a relatively low quantum yield of the order
of 6 x 10-4 mol Einstein-1. Application of ozone to mefenamic
aqueous solutions instantaneously eliminates the pharmaceutical,
achieving simultaneously a 40% of mineralization. Addition of AC to
the ozonation process does not enhance the process, moreover,
mineralization is completely inhibited if compared to results obtained
by single ozonation. The combination of ozone and UV radiation led
to the best results in terms of mineralization (60% after 120 min).
Abstract: The association between emotional inhibition strategies linked to depression has been showed inconsistent among studies. Mild emotional inhibition maybe benefit for social interaction, especially for female among East Asian cultures. The present study aimed to examine whether the inhibition–depression relationship is dependent on level of emotion inhibition and gender context, given differing value of suppressing emotional displays. We hypothesized that the negative associations between inhibition and adolescent depression would not directly, in which affected by interaction between emotion inhibition and gender. To test this hypothesis, we asked 309 junior high school students which age range from 12 to14 years old to report on their use of emotion inhibition and depression syndrome. A multiple regressions analysis revealed that significant interaction that gender as a moderator to the relationships between emotion inhibition and adolescent depression. The group with the highest level of depression was girls with high levels of emotion inhibition, whose depression score was higher than that of boys with high levels of emotion inhibition. The result highlights that the importance of context in understanding the inhibition-depression relationship.
Abstract: Five crystal modifications of water insoluble
artesunate were generated by recrystallizing it from various solvents
with improved physicochemical properties. These generated crystal
forms were characterized to select the most potent and soluble form.
SEM of all the forms showed changes in external shape leading them
to be different morphologically. DSC thermograms of Form III and
Form V showed broad endotherm peaks at 83.04oC and 76.96oC prior
to melting fusion of drug respectively. Calculated weight loss in TGA
revealed that Form III and Form V are methanol and acetone solvates
respectively. However, few additional peaks were appeared in XRPD
pattern in these two solvate forms. All forms exhibit exothermic
behavior in buffer and two solvates display maximum ease of
molecular release from the lattice. Methanol and acetone solvates
were found to be most soluble forms and exhibited higher
antimalarial efficacy showing higher survival rate (83.3%) after 30
days.
Abstract: The photocatalytic activity efficiency of TiO2 for the degradation of Toluene in photoreactor can be enhanced by nano- TiO2/LDPE composite film. Since the amount of TiO2 affected the efficiency of the photocatalytic activity, this work was mainly concentrated on the effort to embed the high amount of TiO2 in the Polyethylene matrix. The developed photocatalyst was characterized by XRD, UV-Vis spectrophotometer and SEM. The SEM images revealed the high homogeneity of the deposition of TiO2 on the polyethylene matrix. The XRD patterns interpreted that TiO2 embedded in the PE matrix exhibited mainly in anatase form. In addition, the photocatalytic results show that the toluene removal efficiencies of 30±5%, 49±4%, 68±5%, 42±6% and 33±5% were obtained when using the catalyst loading at 0%, 10%, 15%, 25% and 50% (wt. cat./wt. film), respectively.
Abstract: The two-phase flow field and the motion of the free
surface in an oscillating channel are simulated numerically to assess
the methodology for simulating nuclear reacotr thermal hydraulics
under seismic conditions. Two numerical methods are compared: one
is to model the oscillating channel directly using the moving grid of
the Arbitrary Lagrangian-Eulerian method, and the other is to simulate
the effect of channel motion using the oscillating acceleration acting
on the fluid in the stationary channel. The two-phase flow field in the
oscillating channel is simulated using the level set method in both
cases. The calculated results using the oscillating acceleration are
found to coinside with those using the moving grid, and the theoretical
back ground and the limitation of oscillating acceleration are discussed.
It is shown that the change in the interfacial area between liquid and
gas phases under seismic conditions is important for nuclear reactor
thermal hydraulics.
Abstract: This paper deals with stakeholders’ decisions within energy neutral urban redevelopment processes. The decisions of these stakeholders during the process will make or break energy neutral ambitions. An extensive form of game theory model gave insight in the behavioral differences of stakeholders regarding energy neutral ambitions and the effects of the changing legislation. The results show that new legislation regarding spatial planning slightly influences the behavior of stakeholders. An active behavior of the municipality will still result in the best outcome. Nevertheless, the municipality becomes more powerful when acting passively and can make the use of planning tools to provide governance towards energy neutral urban redevelopment. Moreover, organizational support, recognizing the necessity for energy neutrality, keeping focused and collaboration among stakeholders are crucial elements to achieve the objective of an energy neutral urban (re)development.
Abstract: Achievement motivation is believed to promote
giftedness attracting people to invest in many programs to adopt
gifted students providing them with challenging activities.
Intellectual giftedness is founded on the fluid intelligence and
extends to more specific abilities through the growth and inputs from
the achievement motivation. Acknowledging the roles played by the
motivation in the development of giftedness leads to an effective
nurturing of gifted individuals. However, no study has investigated
the direct and indirect effects of the achievement motivation and
fluid intelligence on intellectual giftedness. Thus, this study
investigated the contribution of motivation factors to giftedness
development by conducting tests of fluid intelligence using Cattell
Culture Fair Test (CCFT) and analytical abilities using culture
reduced test items covering problem solving, pattern recognition,
audio-logic, audio-matrices, and artificial language, and self report
questionnaire for the motivational factors. A number of 180 highscoring
students were selected using CCFT from a leading university
in Malaysia. Structural equation modeling was employed using Amos
V.16 to determine the direct and indirect effects of achievement
motivation factors (self confidence, success, perseverance,
competition, autonomy, responsibility, ambition, and locus of
control) on the intellectual giftedness. The findings showed that the
hypothesized model fitted the data, supporting the model postulates
and showed significant and strong direct and indirect effects of the
motivation and fluid intelligence on the intellectual giftedness.
Abstract: NFκB is a transcription factor regulating many
function of the vessel wall. In the normal condition , NFκB is
revealed diffuse cytoplasmic expressionsuggesting that the system is
inactive. The presence of activation NFκB provide a potential
pathway for the rapid transcriptional of a variety of genes encoding
cytokines, growth factors, adhesion molecules and procoagulatory
factors. It is likely to play an important role in chronic inflamatory
disease involved atherosclerosis. There are many stimuli with the
potential to active NFκB, including hyperlipidemia. We used 24 mice
which was divided in 6 groups. The HFD given by et libitum
procedure during 2, 4, and 6 months. The parameters in this study
were the amount of NFKB activation ,H2O2 as ROS and VCAM-1 as
a product of NFKB activation. H2O2 colorimetryc assay performed
directly using Anti Rat H2O2 ELISA Kit. The NFKB and VCAM-1
detection obtained from aorta mice, measured by ELISA kit and
imunohistochemistry. There was a significant difference activation of
H2O2, NFKB and VCAM-1 level at induce HFD after 2, 4 and 6
months. It suggest that HFD induce ROS formation and increase the
activation of NFKB as one of atherosclerosis marker that caused by
hyperlipidemia as classical atheroschlerosis risk factor.
Abstract: Dual phase steels (DPS)s have a microstructure
consisting of a hard second phase called Martensite in the soft Ferrite
matrix. In recent years, there has been interest in dual-phase steels,
because the application of these materials has made significant usage;
particularly in the automotive sector Composite microstructure of
(DPS)s exhibit interesting characteristic mechanical properties such
as continuous yielding, low yield stress to tensile strength
ratios(YS/UTS), and relatively high formability; which offer
advantages compared with conventional high strength low alloy
steels(HSLAS). The research dealt with the characterization of
damage in (DPS)s. In this study by review the mechanisms of failure
due to volume fraction of martensite second phase; a new method is
introduced to identifying the mechanisms of failure in the various
phases of these types of steels. In this method the acoustic emission
(AE) technique was used to detect damage progression. These failure
mechanisms consist of Ferrite-Martensite interface decohesion and/or
martensite phase fracture. For this aim, dual phase steels with
different volume fraction of martensite second phase has provided by
various heat treatment methods on a low carbon steel (0.1% C), and
then AE monitoring is used during tensile test of these DPSs. From
AE measurements and an energy ratio curve elaborated from the
value of AE energy (it was obtained as the ratio between the strain
energy to the acoustic energy), that allows detecting important
events, corresponding to the sudden drops. These AE signals events
associated with various failure mechanisms are classified for ferrite
and (DPS)s with various amount of Vm and different martensite
morphology. It is found that AE energy increase with increasing Vm.
This increasing of AE energy is because of more contribution of
martensite fracture in the failure of samples with higher Vm. Final
results show a good relationship between the AE signals and the
mechanisms of failure.
Abstract: This paper fist examines three set of bivariate cointegrations between any two of current accounts, stock markets, and currency exchange markets in ten Asian countries. Furthermore, we examined the effect of country characters on this bivariate cointegration. Our findings suggest that for three sets of cointegration test, each sample country at least exists one cointegration. India consistently exhibited a bi-directional causal relationship between any two of three indicators. Unlike Pan et al. (2007) and Phylaktis and Ravazzolo (2005), we found that such cointegration is influenced by three characteristics: capital control; flexibility in foreign exchange rates; and the ratio of trade to GDP. These characteristics are the result of liberalization in each Asian country. This implies that liberalization policies are effective on improving the cointegration between any two of financial markets and current account for ten Asian countries.
Abstract: The flow and heat transfer mechanism in convex
corrugated tubes have been investigated through numerical
simulations in this paper. Two kinds of tube types named as symmetric
corrugated tube (SCT) and asymmetric corrugated tube (ACT) are
modeled and studied numerically based on the RST model. The
predictive capability of RST model is examined in the corrugation wall
in order to check the reliability of RST model under the corrugation
wall condition. We propose a comparison between the RST modelling
the corrugation wall with existing direct numerical simulation of Maaß
C and Schumann U [14]. The numerical results pressure coefficient at
different profiles between RST and DNS are well matched. The
influences of large corrugation tough radii to heat transfer and flow
characteristic had been considered. Flow and heat transfer comparison
between SCT and ACT had been discussed. The numerical results
show that ACT exhibits higher overall heat transfer performance than
SCT.
Abstract: Article devoted to the development of technologies
for medicine and agroecology by using plant organelle – spherosome.
Technological method of purification and isolation of this organelle
by using novel nanostructured carbon sorbent – “nanocarbosorb"
ARK type are presented. Also the methods of preparation of
nanocontainers based on using of spherosome with loaded isosorbide
dinitrate, piroxicam or diclofenak are exhibited. We found that the
spherosome could be applied for ecological aims as bioregulator and
also as biosensor for determination of ammonia ions in water
reservoirs at concentration range 1mM to 100mM.
Abstract: This paper analyzes the extent to which the justices of
the U.S. Supreme Court cast votes that support the positions of the
president, or more generally the Executive Branch. Can presidents
count on such deference from those justices they nominate or those
whom are nominated by other presidents of the same party? Or, do
the justices demonstrate judicial independence and impartiality such
that they are not so predisposed to vote in favor of arguments of their
nominating president-s party? The results suggest that while in
general the justices do not exhibit any marked tendency to partisan
support of presidents, more recent and conservative Supreme Court
justices are significantly more likely to support Republican
presidents.
Abstract: We study the typical domain size and configuration
character of a randomly perturbed system exhibiting continuous
symmetry breaking. As a model system we use rod-like objects
within a cubic lattice interacting via a Lebwohl–Lasher-type
interaction. We describe their local direction with a headless unit
director field. An example of such systems represents nematic LC or
nanotubes. We further introduce impurities of concentration p, which
impose the random anisotropy field-type disorder to directors. We
study the domain-type pattern of molecules as a function of p,
anchoring strength w between a neighboring director and impurity,
temperature, history of samples. In simulations we quenched the
directors either from the random or homogeneous initial
configuration. Our results show that a history of system strongly
influences: i) the average domain coherence length; and ii) the range
of ordering in the system. In the random case the obtained order is
always short ranged (SR). On the contrary, in the homogeneous case,
SR is obtained only for strong enough anchoring and large enough
concentration p. In other cases, the ordering is either of quasi long
range (QLR) or of long range (LR). We further studied memory
effects for the random initial configuration. With increasing external
ordering field B either QLR or LR is realized.
Abstract: Long number multiplications (n ≥ 128-bit) are a
primitive in most cryptosystems. They can be performed better by
using Karatsuba-Ofman technique. This algorithm is easy to
parallelize on workstation network and on distributed memory, and
it-s known as the practical method of choice. Multiplying long
numbers using Karatsuba-Ofman algorithm is fast but is highly
recursive. In this paper, we propose different designs of
implementing Karatsuba-Ofman multiplier. A mixture of sequential
and combinational system design techniques involving pipelining is
applied to our proposed designs. Multiplying large numbers can be
adapted flexibly to time, area and power criteria. Computationally
and occupation constrained in embedded systems such as: smart
cards, mobile phones..., multiplication of finite field elements can be
achieved more efficiently. The proposed designs are compared to
other existing techniques. Mathematical models (Area (n), Delay (n))
of our proposed designs are also elaborated and evaluated on
different FPGAs devices.
Abstract: Stochastic modeling of network traffic is an area of
significant research activity for current and future broadband
communication networks. Multimedia traffic is statistically
characterized by a bursty variable bit rate (VBR) profile. In this
paper, we develop an improved model for uniform activity level
video sources in ATM using a doubly stochastic autoregressive
model driven by an underlying spatial point process. We then
examine a number of burstiness metrics such as the peak-to-average
ratio (PAR), the temporal autocovariance function (ACF) and the
traffic measurements histogram. We found that the former measure is
most suitable for capturing the burstiness of single scene video
traffic. In the last phase of this work, we analyse statistical
multiplexing of several constant scene video sources. This proved,
expectedly, to be advantageous with respect to reducing the
burstiness of the traffic, as long as the sources are statistically
independent. We observed that the burstiness was rapidly
diminishing, with the largest gain occuring when only around 5
sources are multiplexed. The novel model used in this paper for
characterizing uniform activity video was thus found to be an
accurate model.
Abstract: Bode stability analysis based on transmission line
modeling (TLM) for single wall carbon nanotube (SWCNT)
interconnects used in 3D-VLSI circuits is investigated for the first
time. In this analysis, the dependence of the degree of relative
stability for SWCNT interconnects on the geometry of each tube has
been acquired. It is shown that, increasing the length and diameter of
each tube, SWCNT interconnects become more stable.
Abstract: In the open space of decision support system the
mental impression of a manager-s decision has been the subject of
large importance than the ordinary famous one, when helped by
decision support system. Much of this study is an attempt to realize
the relation of decision support system usage and decision outcomes
that governs the system. For example, several researchers have
proposed so many different models to analyze the linkage between
decision support system processes and results of decision making.
This study draws the important relation of manager-s mental
approach with the use of decision support system. The findings of
this paper are theoretical attempts to provide Decision Support
System (DSS) in a way to exhibit and promote the learning in semi
structured area. The proposed model shows the points of one-s
learning improvements and maintains a theoretical approach in order
to explore the DSS contribution in enhancing the decision forming
and governing the system.
Abstract: In this paper a class of numerical methods to solve linear and nonlinear PDEs and also systems of PDEs is developed. The Differential Transform method associated with the Method of Lines (MoL) is used. The theory for linear problems is extended to the nonlinear case, and a recurrence relation is established. This method can achieve an arbitrary high-order accuracy in time. A variable stepsize algorithm and some numerical results are also presented.
Abstract: In this paper, we proposed a method to reduce
quantization error. In order to reduce quantization error, low pass
filtering is applied on neighboring samples of current block in
H.264/AVC. However, it has a weak point that low pass filtering is
performed regardless of prediction direction. Since it doesn-t consider
prediction direction, it may not reduce quantization error effectively.
Proposed method considers prediction direction for low pass filtering
and uses a threshold condition for reducing flag bit. We compare our
experimental result with conventional method in H.264/AVC and we
can achieve the average bit-rate reduction of 1.534% by applying the
proposed method. Bit-rate reduction between 0.580% and 3.567% are
shown for experimental results.