Abstract: This first-attempt study revealed that decolorized
intermediates of azo dyes could act as redox mediators to assist
wastewater (WW) decolorization due to enhancement of
electron-transport phenomena. Electrochemical impedance spectra
indicated that hydroxyl and amino-substituent(s) were functional
group(s) as redox-mediator(s). As azo dyes are usually multiple
benzene-rings structured, their derived decolorized intermediates are
likely to play roles of electron shuttles due to lower barrier of energy
gap for electron shuttling. According to cyclic voltammetric profiles,
redox mediating characteristics of decolorized intermediates of azo
dyes (e.g., RBu171, RR198, RR141, RBk5) were clearly disclosed.
With supplementation of biodecolorized metabolites of RR141 and
198, decolorization performance of could be evidently augmented.
This study also suggested the optimal modes of microbial fuel cell
(MFC)-assisted WW decolorization would be plug-flow or batch
mode of operation with no mix. Single chamber-MFCs would be more
favourable than double chamber MFCs due to non-mixing contacting
reactor scheme for operation.
Abstract: Fluctuations of Schottky diode parameters in a
structure of the mixer are investigated. These fluctuations are
manifested in two ways. At the first, they lead to fluctuations in the
transfer factor that is lead to the amplitude fluctuations in the signal
of intermediate frequency. On the basis of the measurement data of
1/f noise of the diode at forward current, the estimation of a spectrum
of relative fluctuations in transfer factor of the mixer is executed.
Current dependence of the spectrum of relative fluctuations in
transfer factor of the mixer and dependence of the spectrum of
relative fluctuations in transfer factor of the mixer on the amplitude
of the heterodyne signal are investigated. At the second, fluctuations
in parameters of the diode lead to occurrence of 1/f noise in the
output signal of the mixer. This noise limits the sensitivity of the
mixer to the value of received signal.
Abstract: The aim of this paper is to introduce the notion of
intuitionistic fuzzy positive implicative ideals with thresholds (λ, μ) of
BCI-algebras and to investigate its properties and characterizations.
Abstract: Online measurement of the product quality is a
challenging task in cement production, especially in the production of
Celitement, a novel environmentally friendly hydraulic binder. The
mineralogy and chemical composition of clinker in ordinary Portland
cement production is measured by X-ray diffraction (XRD) and
X-ray fluorescence (XRF), where only crystalline constituents can be
detected. But only a small part of the Celitement components can be
measured via XRD, because most constituents have an amorphous
structure. This paper describes the development of algorithms
suitable for an on-line monitoring of the final processing step of
Celitement based on NIR-data. For calibration intermediate products
were dried at different temperatures and ground for variable
durations. The products were analyzed using XRD and
thermogravimetric analyses together with NIR-spectroscopy to
investigate the dependency between the drying and the milling
processes on one and the NIR-signal on the other side. As a result,
different characteristic parameters have been defined. A short
overview of the Celitement process and the challenging tasks of the
online measurement and evaluation of the product quality will be
presented. Subsequently, methods for systematic development of
near-infrared calibration models and the determination of the final
calibration model will be introduced. The application of the model on
experimental data illustrates that NIR-spectroscopy allows for a quick
and sufficiently exact determination of crucial process parameters.
Abstract: This paper describes the development of new class of
epoxy based rice husk filled jute reinforced composites. Rice husk
flour is added in 0%, 1%, 3%, 5% by weight. Epoxy resin and
triethylenetetramine (T.E.T.A) is used as matrix and hardener
respectively. It investigates the mechanical properties of the
composites and a comparison is done for monolithic jute composite
and the filled ones. The specimens are prepared according to the
ASTM standards and experimentation is carried out using INSTRON
8801. The result shows that with the increase of filler percentage the
tensile properties increases but compressive and flexural properties
decreases.
Abstract: In this work, a framework to model the Supply Chain
(SC) Collaborative Planning (CP) process is proposed. The main
contributions of this framework concern 1) the presentation of the
decision view, the most important one due to the characteristics of the
process, jointly within the physical, organisation and information
views, and 2) the simultaneous consideration of the spatial and
temporal integration among the different supply chain decision
centres. This framework provides the basis for a realistic and
integrated perspective of the supply chain collaborative planning
process and also the analytical modeling of each of its decisional
activities.
Abstract: Cadmium oxide (CdO) nanoparticles have been
prepared by chemical coprecipitation method. The synthesized
nanoparticles were characterized by X-ray diffraction analysis
(XRD), scanning electron microscopy (SEM), transmission electron
microscopy (TEM), UV analysis, and dielectric studies. The
crystalline nature and particle size of the CdO nanoparticles were
characterized by Powder X-ray diffraction analysis (XRD). The
morphology of prepared CdO nanoparticles was studied by scanning
electron microscopy. The particle size was studied using the
transmission electron microscopy (TEM).The optical properties were
obtained from UV-Vis absorption spectrum. The dielectric properties
of CdO nanoparticles were studied in the frequency range of 50 Hz–5
MHz at different temperatures. The frequency dependence of the
dielectric constant and dielectric loss is found to decrease with an
increase in the frequency at different temperatures. The ac
conductivity of CdO nanoparticle has been studied.
Abstract: The increase in electric power demand in face of
environmental issues has intensified the participation of renewable
energy sources such as photovoltaics, in the energy matrix of various
countries. Due to their operational characteristics, they can generate
time-varying harmonic and inter-harmonic distortions. For this
reason, the application of methods of measurement based on
traditional Fourier analysis, as proposed by IEC 61000-4-7, can
provide inaccurate results. Considering the aspects mentioned herein,
came the idea of the development of this work which aims to present
the results of a comparative evaluation between a methodology
arising from the combination of the Prony method with the Kalman
filter and another method based on the IEC 61000-4-30 and IEC
61000-4-7 standards. Employed in this study were synthetic signals
and data acquired through measurements in a 50kWp photovoltaic
installation.
Abstract: The quality of concrete is usually defined by compressive strength, but flexural strength is the most important characteristic of concrete in a pavement which control the mix design of concrete instead of compressive strength. Therefore, the aggregates which are selected for the pavements are affected by higher flexural strength. Roller Compacting Concrete Pavement (RCCP) is not a new construction method. The other characteristic of this method is no bleeding and less shrinkage due to the lower amount of water. For this purpose, a roller is needed for placing and compacting. The surface of RCCP is not smooth; therefore, the most common use of this pavement is in an industrial zone with slower traffic speed which requires durable and tough pavement. For preparing a smoother surface, it can be achieved by asphalt paver. RCCP decrease the finishing cost because there are no bars, formwork, and the lesser labor need for placing the concrete. In this paper, different aspect of RCCP such as mix design, flexural, compressive strength and focus on the different part of RCCP on detail have been investigated.
Abstract: Highly stable and homogeneously dispersed amino
acid coated silver nanoparticles (ANP) of ≈ 10 nm diameter, ranging
from 420 to 430 nm are prepared on AgNO3 solution addition to gum
of Azadirachta indica solution at 373.15 K. The amino acids were
selected based on their polarity. The synthesized nanoparticles were
characterized by UV-Vis, FTIR spectroscopy, HR-TEM, XRD, SEM
and 1H-NMR. The coated nanoparticles were used as catalyst for the
reduction of methylene blue dye in presence of Sn(II) in aqueous,
anionic and cationic micellar media. The rate of reduction of dye was
determined by measuring the absorbance at 660 nm,
spectrophotometrically and followed the order: Kcationic > Kanionic >
Kwater. After 12 min and in absence of the ANP, only 2%, 3% and 6%
of the dye reduction was completed in aqueous, anionic and cationic
micellar media respectively while, in presence of ANP coated by
polar neutral amino acid with non-polar -R group, the reduction
completed to 84%, 95% and 98% respectively. The ANP coated with
polar neutral amino acid having non-polar -R group, increased the
rate of reduction of the dye by 94, 3205 and 6370 folds in aqueous,
anionic and cationic micellar media respectively. Also, the rate of
reduction of the dye increased by three folds when the micellar media
was changed from anionic to cationic when the ANP is coated by a
polar neutral amino acid having a non-polar -R group.
Abstract: A broadband wire monopole antenna loaded by inhomogeneous stack of annular dielectric ring resonators (DRRs) is proposed. The proposed antenna exhibits a broad impedance bandwidth from 3 to 30 GHz. This is achieved by adding an external step matching network at the antenna feed point. The matching network is comprised of three annular DRRs possessing different permittivity values and sharing the same axial over a finite ground plane. The antenna performance is characterized using full-wave EM simulation. Compared to previous-reported wire antennas with improved bandwidth achieved by DRRs, the proposed topology provides relatively compact realization and superior broadband performance.
Abstract: A myriad of environmental issues face the Nigerian
industrial region, resulting from; oil and gas production, mining,
manufacturing and domestic wastes. Amidst these, much effort has
been directed by stakeholders in the Nigerian oil producing regions,
because of the impacts of the region on the wider Nigerian economy.
Although collaborative environmental management has been noted as
an effective approach in managing environmental issues, little
attention has been given to the roles and practices of stakeholders in
effecting a collaborative environmental management framework for
the Nigerian oil-producing region. This paper produces a framework
to expand and deepen knowledge relating to stakeholders aspects of
collaborative roles in managing environmental issues in the Nigeria
oil-producing region. The knowledge is derived from analysis of
stakeholders’ practices – studied through multiple case studies using
document analysis. Selected documents of key stakeholders –
Nigerian government agencies, multi-national oil companies and host
communities, were analyzed. Open and selective coding was
employed manually during document analysis of data collected from
the offices and websites of the stakeholders. The findings showed
that the stakeholders have a range of roles, practices, interests, drivers
and barriers regarding their collaborative roles in managing
environmental issues. While they have interests for efficient resource
use, compliance to standards, sharing of responsibilities, generating
of new solutions, and shared objectives; there is evidence of major
barriers and these include resource allocation, disjointed policy,
ineffective monitoring, diverse socio- economic interests, lack of
stakeholders’ commitment and limited knowledge sharing. However,
host communities hold deep concerns over the collaborative roles of
stakeholders for economic interests, particularly, where government
agencies and multi-national oil companies are involved. With these
barriers and concerns, a genuine stakeholders’ collaboration is found
to be limited, and as a result, optimal environmental management
practices and policies have not been successfully implemented in the
Nigeria oil-producing region. A framework is produced that describes
practices that characterize collaborative environmental management
might be employed to satisfy the stakeholders’ interests. The
framework recommends critical factors, based on the findings, which
may guide a collaborative environmental management in the oil
producing regions. The recommendations are designed to re-define
the practices of stakeholders in managing environmental issues in the
oil producing regions, not as something wholly new, but as an
approach essential for implementing a sustainable environmental
policy. This research outcome may clarify areas for future research as
well as to contribute to industry guidance in the area of collaborative
environmental management.
Abstract: This study investigated the effects of thermal
treatment on Tualang honey sample in terms of honey colour and
heat-induced small metabolites. The heating process was carried out
in a temperature controlled water batch at 90oC for 4 hours. The
honey samples were put in cylinder tubes with the dimension of 1 cm
diameter and 10 cm length for homogenous heat transfer. The results
found that the thermal treatment produced not only
hydroxylmethylfurfural, but also other harmful substances such as
phthalic anhydride and radiolytic byproducts. The degradation of
honey protein was due to the detection of free amino acids such as
cysteine and phenylalanine in heat-treated honey samples. Sugar
dehydration was also occurred because fragmented di-galactose was
identified based on the presence of characteristic ions in the mass
fragmentation pattern. The honey colour was found getting darker as
the heating duration was increased up to 4 hours. Approximately, 60
mm PFund of increment was noticed for the honey colour with the
colour change rate of 14.8 mm PFund per hour. Based on the
principal component analysis, the score plot clearly shows that the
chemical profile of Tualang honey was significantly altered after 2
hours of heating at 90oC.
Abstract: In this paper, von Mises and Drucker-Prager yield criteria, as typical ones that consider the effect of intermediate principal stress σ2, have been selected and employed for investigating the influence of σ2 on the solution of a typical stability problem. The bearing capacity factors have been calculated under plane strain condition (strip footing) and axisymmetric condition (circular footing) using the method of stress characteristics together with the criteria mentioned. Different levels of σ2 relative to the other two principal stresses have been considered. While a higher σ2 entry in yield criterion gives a higher bearing capacity; its entry in equilibrium equations (axisymmetric) causes substantial reduction.
Abstract: In this paper, de Laval rotor system has been
characterized by a hinge model and its transient response numerically
treated for a dynamic solution. The effect of the ensuing non-linear
disturbances namely rub and breathing crack is numerically
simulated. Subsequently, three analysis methods: Orbit Analysis, Fast
Fourier Transform (FFT), and Wavelet Transform (WT) are
employed to extract features of the vibration signal of the faulty
system. An analysis of the system response orbits clearly indicates
the perturbations due to the rotor-to-stator contact. The sensitivities
of WT to the variation in system speed have been investigated by
Continuous Wavelet Transform (CWT). The analysis reveals that
features of crack, rubs and unbalance in vibration response can be
useful for condition monitoring. WT reveals its ability to detect nonlinear
signal, and obtained results provide a useful tool method for
detecting machinery faults.
Abstract: Rivers have transient storage or dead zones where
injected pollutants or solutes are entrapped for considerable period of
time, known as residence time, before being released into the main
flowing zones of rivers. In this study, a new empirical expression for
residence time, implementing genetic programming on published
dispersion data, has been derived. The proposed expression uses few
hydraulic and geometric characteristics of rivers which are normally
known to the authorities. When compared with some reported
expressions, based on various statistical indices, it can be concluded
that the proposed expression predicts the residence time of pollutants
in natural rivers more accurately.
Abstract: The change of conditions for production companies in
high-wage countries is characterized by the globalization of
competition and the transition of a supplier´s to a buyer´s market. The
companies need to face the challenges of reacting flexibly to these
changes. Due to the significant and increasing degree of automation,
assembly has become the most expensive production process.
Regarding the reduction of production cost, assembly consequently
offers a considerable rationalizing potential. Therefore, an
aerodynamic feeding system has been developed at the Institute of
Production Systems and Logistics (IFA), Leibniz Universitaet
Hannover. This system has been enabled to adjust itself by using a
genetic algorithm. The longer this genetic algorithm is executed the
better is the feeding quality. In this paper, the relation between the
system´s setting time and the feeding quality is observed and a
function which enables the user to achieve the minimum of the total
feeding time is presented.
Abstract: This study evaluated the acute toxicity and tissue
distribution of intravenously administered gold nanoparticles
(AuNPs) in male rabbits. Rabbits were exposed to single dose of
AuNPs (300 μg/ kg). Toxic effects were assessed via general
behavior, hematological parameters, serum biochemical parameters,
and histopathological examination of various rabbits’ organs.
Inductively coupled plasma–mass spectrometry (ICP-MS) was used
to determine gold concentrations in tissue samples collected at
predetermined time intervals. After one week, AuNPs exerted no
obvious acute toxicity in rabbits. However, inflammatory reactions
were observed in liver, lungs and kidneys accompanied with mild
absolute neutrophilia and significant monocytosis. The highest gold
levels were found in the spleen and liver followed by lungs, and
kidneys. These results indicated that AuNPs could be distributed
extensively to various tissues in the body, but primarily in the spleen
and liver.
Abstract: The Haussmannization plan of Cairo in 1867 formed a
regular network of roundabout spaces, though deteriorated at present.
The method of identifying the spatial structure of roundabout Cairo
for conservation matches the voronoi diagram with the space syntax
through their geometrical property of spatial convexity. In this
initiative, the primary convex hull of first-order voronoi adopts the
integral and control measurements of space syntax on Cairo’s
roundabout generators. The functional essence of royal palaces
optimizes the roundabout structure in terms of spatial measurements
and the symbolic voronoi projection of 'Tahrir Roundabout' over the
Giza Nile and Pyramids. Some roundabouts of major public and
commercial landmarks surround the pole of 'Ezbekia Garden' with a
higher control than integral measurements, which filter the new
spatial structure from the adjacent traditional town. Nevertheless, the
least integral and control measures correspond to the voronoi
contents of pollutant workshops and the plateau of old Cairo Citadel
with the visual compensation of new royal landmarks on top.
Meanwhile, the extended suburbs of infinite voronoi polygons
arrange high control generators of chateaux housing in 'garden city'
environs. The point pattern of roundabouts determines the
geometrical characteristics of voronoi polygons. The measured
lengths of voronoi edges alternate between the zoned short range at
the new poles of Cairo and the distributed structure of longer range.
Nevertheless, the shortest range of generator-vertex geometry
concentrates at 'Ezbekia Garden' where the crossways of vast Cairo
intersect, which maximizes the variety of choice at different spatial
resolutions. However, the symbolic 'Hippodrome' which is the largest
public landmark forms exclusive geometrical measurements, while
structuring a most integrative roundabout to parallel the royal syntax.
Overview of the symbolic convex hull of voronoi with space syntax
interconnects Parisian Cairo with the spatial chronology of scattered
monuments to conceive one universal Cairo structure. Accordingly,
the approached methodology of 'voronoi-syntax' prospects the future
conservation of roundabout Cairo at the inferred city-level concept.
Abstract: Ensuring of continuity of business is basic strategy of
every company. Continuity of organization activities includes
comprehensive procedures that help in solving unexpected situations
of natural and anthropogenic character (for example flood, blaze,
economic situations). Planning of continuity operations is a process
that helps identify critical processes and implement plans for the
security and recovery of key processes. The aim of this article is to
demonstrate application of system approach to managing business
continuity called business continuity management systems in military
issues. This article describes the life cycle of business continuity
management which is based on the established cycle PDCA (Plan-
Do-Check-Act). After this is carried out by activities which are
making by University of Defence during activation of forces and
means of the integrated rescue system in case of emergencies -
accidents at a nuclear power plant in Czech Republic. Activities of
various stages of deployment earmarked forces and resources are
managed and evaluated by using MCMS application (Military
Continuity Management System).