Abstract: Diffusion stills have been effective in water
desalination. The present work represents a model of the distillation
process by using vertical single-effect diffusion stills. A semianalytical
model has been developed to model the process. A
software computer code using Engineering Equation Solver EES
software has been developed to solve the equations of the developed
model. An experimental setup has been constructed, and used for the
validation of the model. The model is also validated against former
literature results. The results obtained from the present experimental
test rig, and the data from the literature, have been compared with the
results of the code to find its best range of validity. In addition, a
parametric analysis of the system has been developed using the
model to determine the effect of operating conditions on the system's
performance. The dominant parameters that affect the productivity of
the still are the hot plate temperature that ranges from (55- 90°C) and
feed flow rate in range of (0.00694-0.0211 kg/m2-s).
Abstract: The study examined the effect of Bonny Light whole
crude oil (WC) and its water soluble fraction (WSF) on the activities
of antioxidant enzymes (catalase (CAT) and superoxide dismutase
(SOD)) and crude mitochondria ATPases in the radicle of
germinating bean (Vigna unguiculata). The percentage germination,
level of lipid peroxidation, antioxidant enzyme and mitochondria
Ca2+ and Mg2+ ATPase activities were measured in the radicle of
bean after 7, 14 and 21 days post germination. Viable bean seeds
were planted in soils contaminated with 10ml, 25ml and 50ml of
whole crude oil (WC) and its water soluble fraction (WSF) to obtain
2, 5 and 10% v/w crude oil contamination. There was dose dependent
reduction of the number of bean seeds that germinated in the
contaminated soils compared with control (p
Abstract: Thin ZnO films are deposited on glass substrates via
sol–gel method and dip-coating. The films are prepared from zinc
acetate dehydrate as a starting reagent. After that the as-prepared
ZnO sol is aged for different periods (0, 1, 3, 5, 10, 15 and 30 days).
Nanocrystalline thin films are deposited from various sols. The
effect ZnO sols aging time on the structural and photocatalytic
properties of the films is studied. The films surface is studied by
Scanning Electron Microscopy. The effect of the aging time of the
starting solution is studied in the photocatalytic degradation of
Reactive Black 5 (RB5) by UV-vis spectroscopy. The experiments
are conducted upon UV-light illumination and in complete darkness.
The variation of the absorption spectra shows the degradation of RB5
dissolved in water, as a result of the reaction, occurring on the surface
of the films and promoted by UV irradiation. The initial
concentrations of dye (5, 10 and 20 ppm) and the effect of the aging
time are varied during the experiments. The results show, that the
increasing aging time of starting solution with respect to ZnO
generally promotes photocatalytic activity. The thin films obtained
from ZnO sol, which is aged 30 days have best photocatalytic
degradation of the dye (97,22%) in comparison with the freshly
prepared ones (65,92%). The samples and photocatalytic
experimental results are reproducible. Nevertheless, all films exhibit
a substantial activity in both UV light and darkness, which is
promising for the development of new ZnO photocatalysts by sol-gel
method.
Abstract: Currently, there is excessively growing information
about places on Facebook, which is the largest social network but
such information is not explicitly organized and ranked. Therefore
users cannot exploit such data to recommend places conveniently and
quickly. This paper proposes a Facebook application and an Android
application that recommend places based on the number of check-ins
of those places, the distance of those places from the current location,
the number of people who like Facebook page of those places, and
the number of talking about of those places. Related Facebook data is
gathered via Facebook API requests. The experimental results of the
developed applications show that the applications can recommend
places and rank interesting places from the most to the least. We have
found that the average satisfied score of the proposed Facebook
application is 4.8 out of 5. The users’ satisfaction can increase by
adding the app features that support personalization in terms of
interests and preferences.
Abstract: The present study was undertaken to investigate the
effect of aging parameters (time and temperature) on the mechanical
properties of Be-and/or Zr- treated Al-Mg-Zn (7075) alloys. Ultimate
tensile strength, 0.5% offset yield strength and % elongation
measurements were carried out on specimens prepared from cast and
heat treated 7075 alloys containing Be and/or Zr. Different aging
treatment were carried out for the as solution treated (SHT)
specimens (after quenching in warm water). The specimens were
aged at different conditions; Natural and artificial aging was carried
out at room temperature, 120C, 150C, 180C and 220C for different
periods of time. Duplex aging was performed for SHT conditions
(pre-aged at different time and temperature followed by high
temperature aging). Ultimate tensile strength, yield strength and %
elongation data results as a function of different aging parameters are
analysed. A statistical design of experiments (DOE) approach using
fractional factorial design is applied to acquire an understanding of
the effects of these variables and their interactions on the mechanical
properties of Be- and/or Zr- treated 7075 alloys. Mathematical
models are developed to relate the alloy mechanical properties with
the different aging parameters.
Abstract: The western Tombolo of the Giens peninsula in
southern France, known as Almanarre beach, is subject to coastal
erosion. We are trying to use computer simulation in order to propose
solutions to stop this erosion. Our aim was first to determine the main
factors for this erosion and successfully apply a coupled hydrosedimentological
numerical model based on observations and
measurements that have been performed on the site for decades.
We have gathered all available information and data about waves,
winds, currents, tides, bathymetry, coastal line, and sediments
concerning the site. These have been divided into two sets: one
devoted to calibrating a numerical model using Mike 21 software, the
other to serve as a reference in order to numerically compare the
present situation to what it could be if we implemented different
types of underwater constructions.
This paper presents the first part of the study: selecting and
melting different sources into a coherent data basis, identifying the
main erosion factors, and calibrating the coupled software model
against the selected reference period.
Our results bring calibration of the numerical model with good
fitting coefficients. They also show that the winter South-Western
storm events conjugated to depressive weather conditions constitute a
major factor of erosion, mainly due to wave impact in the northern
part of the Almanarre beach. Together, current and wind impact is
shown negligible.
Abstract: The tombolo of Giens is located in the town of Hyères
(France). We recall the history of coastal erosion, and prominent
factors affecting the evolution of the western tombolo. We then
discuss the possibility of stabilizing the western tombolo. Our
argumentation relies on a coupled model integrating swells, currents,
water levels and sediment transport. We present the conclusions of
the simulations of various scenarios, including pre-existing
propositions from coastal engineering offices. We conclude that
beach replenishment seems to be necessary but not sufficient for the
stabilization of the beach. Breakwaters reveal effective particularly in
the most exposed northern area. Some solutions fulfill conditions so
as to be elected as satisfactory. We give a comparative analysis of the
efficiency of 14 alternatives for the protection of the tombolo.
Abstract: The present paper summarizes the analysis of the
request for consultation of information and data on industrial
emissions made publicly available on the web site of the Ministry of
Environment, Land and Sea on integrated pollution prevention and
control from large industrial installations, the so called “AIA Portal”.
As a matter of fact, a huge amount of information on national
industrial plants is already available on internet, although it is usually
proposed as textual documentation or images.
Thus, it is not possible to access all the relevant information
through interoperability systems and also to retrieval relevant
information for decision making purposes as well as rising of
awareness on environmental issue.
Moreover, since in Italy the number of institutional and private
subjects involved in the management of the public information on
industrial emissions is substantial, the access to the information is
provided on internet web sites according to different criteria; thus, at
present it is not structurally homogeneous and comparable.
To overcome the mentioned difficulties in the case of the
Coordinating Committee for the implementation of the Agreement
for the industrial area in Taranto and Statte, operating before the
IPPC permit granting procedures of the relevant installation located
in the area, a big effort was devoted to elaborate and to validate data
and information on characterization of soil, ground water aquifer and
coastal sea at disposal of different subjects to derive a global
perspective for decision making purposes. Thus, the present paper
also focuses on main outcomes matured during such experience.
Abstract: Polysulfone (PSU) is a specialty engineering polymer
having various industrial applications. PSU is especially used in
waste water treatment membranes due to its good mechanical
properties, structural and chemical stability. But it is a hydrophobic
material and therefore its surface aim to pollute easily. In order to
resolve this problem and extend the properties of membrane, PSU
surface is rendered hydrophilic by addition of the sepiolite
nanofibers. Sepiolite is one of the natural clays, which is a hydrate
magnesium silicate fiber, also one of the well known layered clays of
the montmorillonites where has several unique channels and pores
within. It has also moisture durability, strength and low price.
Sepiolite channels give great capacity of absorption and good surface
properties. In this study, nanocomposites of commercial PSU and
Sepiolite were prepared by solvent mixing method. Different organic
solvents and their mixtures were used. Rheological characteristics of
PSU-Sepiolite solvent mixtures were analyzed, the solubility of
nanocomposite content in those mixtures were studied.
Abstract: Water contamination by toxic compound is one of the serious environmental problems today. These toxic compounds mostly originated from industrial effluents, agriculture, natural sources and human waste. These studies focus on modification of multiwalled carbon nanotube (MWCNTs) with nanoparticle of calixarene and explore the possibility of using this modification for the remediation of cadmium in water. The nanocomposites were prepared by dissolving calixarene in chloroform solution as solvent, followed by additional multiwalled carbon nanotube (MWCNTs) then sonication process for 3 hour and fabricated the nanocomposites on substrate by spin coating method. Finally, the nanocomposites were tested on cadmium ion (10 mg/ml). The morphology of nanocomposites was investigated by FESEM showing the formation of calixarene on the outer walls of carbon nanotube and cadmium ion also clearly seen from the micrograph. This formation was supported by using energy dispersive x-ray (EDX). The presence of cadmium ions in the films, leads to some changes in the surface potential and Fourier Transform Infrared spectroscopy (FTIR).The nanocomposites MWCNTs-calixarene have potential for development of sensor for pollutant monitoring and nanoelectronics devices applications.
Abstract: The present study was undertaken to investigate the
effect of pre-aging and aging parameters (time and temperature) on
the mechanical properties of Al-Mg-Zn (7075) alloys. Ultimate
tensile strength, 0.5% offset yield strength and % elongation
measurements were carried out on specimens prepared from cast and
heat treated 7075 alloys. Aging treatments were carried out for the as
solution treated (SHT) specimens (after quenching in warm water).
The specimens were aged at different conditions; Natural aging was
carried out at room temperature for different periods of time. Double
aging was performed for SHT conditions (pre-aged at different time
and temperature followed by high temperature aging). Ultimate
tensile strength, yield strength and % elongation as a function of
different pre-aging and aging parameters are analyzed to acquire an
understanding of the effects of these variables and their interactions
on the mechanical properties of Be-treated 7075 alloys.
Abstract: The mechanics of rip currents are complex, involving
interactions between waves, currents, water levels and the bathymetry,
that present particular challenges for numerical models. Here,
the effects of a grid-spacing dependent horizontal mixing on the
wave-current interactions are studied. Near the shore, wave rays
diverge from channels towards bar crests because of refraction by
topography and currents, in a way that depends on the rip current
intensity which is itself modulated by the horizontal mixing. At
low resolution with the grid-spacing dependent horizontal mixing,
the wave motion is the same for both coupling modes because the
wave deviation by the currents is weak. In high resolution case,
however, classical results are found with the stabilizing effect of
the flow by feedback of waves on currents. Lastly, wave-current
interactions and the horizontal mixing strongly affect the intensity
of the three-dimensional rip velocity.
Abstract: The absorption power generation cycle based on the
ammonia-water mixture has attracted much attention for efficient
recovery of low-grade energy sources. In this paper a thermodynamic
performance analysis is carried out for a Kalina cycle using
ammonia-water mixture as a working fluid for efficient conversion of
low-temperature heat source in the form of sensible energy. The
effects of the source temperature on the system performance are
extensively investigated by using the thermodynamic models. The
results show that the source temperature as well as the ammonia mass
fraction affects greatly on the thermodynamic performance of the
cycle.
Abstract: Water flow management is one of the most important
parts of river engineering. Non-uniformity distribution of rainfall and
various flow demand with unreasonable flow management will be
caused destroyed of river ecosystem. Then, it is very serious to
determine ecosystem flow requirement. In this paper, Flow duration
curve indices method which has hydrological based was used to
evaluate environmental flow in Gharasou River, Ardabil, Iran. Using
flow duration curve, Q90 and Q95 for different return periods were
calculated. Their magnitude were determined as 1-day, 3-day, 7-day
and 30 day. According the second method, hydraulic alteration
indices often had low and medium range. In order to maintain river at
an acceptable ecological condition, minimum daily discharge of
index Q95 is 0.7 m3.s-1.
Abstract: At certain depths during large diameter displacement
pile driving, rebound well over 0.25 inches was experienced,
followed by a small permanent-set during each hammer blow. High
pile rebound (HPR) soils may stop the pile driving and results in a
limited pile capacity. In some cases, rebound leads to pile damage,
delaying the construction project, and the requiring foundations
redesign. HPR was evaluated at seven Florida sites, during driving of
square precast, prestressed concrete piles driven into saturated, fine
silty to clayey sands and sandy clays. Pile Driving Analyzer (PDA)
deflection versus time data recorded during installation, was used to
develop correlations between cone penetrometer (CPT) pore-water
pressures, pile displacements and rebound. At five sites where piles
experienced excessive HPR with minimal set, the pore pressure
yielded very high positive values of greater than 20 tsf. However, at
the site where the pile rebounded, followed by an acceptable
permanent-set, the measured pore pressure ranged between 5 and 20
tsf. The pore pressure exhibited values of less than 5 tsf at the site
where no rebound was noticed. In summary, direct correlations
between CPTu pore pressure and rebound were produced, allowing
identification of soils that produce HPR.
Abstract: Risperidone (RISP) is an antipsychotic agent and has
low water solubility and nontargeted delivery results in numerous
side effects. Hence, an attempt was made to develop SLNs hydrogel
for intranasal delivery of RISP to achieve maximum bioavailability
and reduction of side effects. RISP loaded SLNs composed of 1.65%
(w/v) lipid mass were produced by high shear homogenization (HSH)
coupled ultrasound (US) method using glycerylmonostearate (GMS)
or Imwitor 900K (solid lipid). The particles were loaded with 0.2%
(w/v) of the RISP & surface-tailored with a 2.02% (w/v) non-ionic
surfactant Tween® 80. Optimization was done using 32 factorial
design using Design Expert® software. The prepared SLNs
dispersion incorporated into Polycarbophil AA1 hydrogel (0.5%
w/v). The final gel formulation was evaluated for entrapment
efficiency, particle size, rheological properties, X ray diffraction, in
vitro diffusion, ex vivo permeation using sheep nasal mucosa and
histopathological studies for nasocilliary toxicity. The entrapment
efficiency of optimized SLNs was found to be 76 ± 2%,
polydispersity index
Abstract: The aim of this work was to apply extractive
distillation for acetonitrile removal from water solutions, to validate
thermodynamic criterion based on excess Gibbs energy to entrainer
selection process for acetonitrile – water mixture separation and show
its potential efficiency at isothermal conditions as well as at isobaric
(conditions of real distillation process), to simulate and analyze an
extractive distillation process with chosen entrainers: optimize
amount of trays and feeds, entrainer/original mixture and reflux
ratios. Equimolar composition of the feed stream was chosen for the
process, comparison of the energy consumptions was carried out.
Glycerol was suggested as the most energetically and ecologically
suitable entrainer.
Abstract: Pipe failure and leakage is a problematic issue and the
traditional solution of replacing the pipes is costly and time
consuming. Rehabilitation by relining materials based on polymer
composites is an alternative solution towards the degradation problem
of the old piping. This paper provides a brief summary of advances in
technology, methods and materials for relining as well as a summary
of the degradation analyses of the two main composite materials used
for relining, rubber filled epoxy and reinforced polyester baltoflake
when they are exposed in deionized water and elevated temperature
up to 80°C for a duration of 2-14 months in the laboratory.
Abstract: Liver disorders are one of the major problems of the
world. Despite its frequent occurrence, high morbidity and high
mortality, its medical management is currently inadequate. This study
was designed to evaluate the hepatoprotective effect of saponin
extract of the root of Garcinia kola on the integrity of the liver of
paracetamol induced wistar albino rats. Twenty five (25) male adult
wistar albino rats were divided into five (5) groups. Group I was the
Control group that received distilled water only, group II was the
negative control that received 2 g/kg of paracetamol on the 13th day,
and group III, IV and V were pre-treated with 100, 200 and
400mg/kg of the saponin extract before inducing the liver damage on
the 13th day with 2 g/kg of paracetamol. Twenty four (24) h after
administration, the rats were sacrificed and blood samples were
collected. The serum Alanine Transaminase (ALT), Aspartate
Transaminase (AST), Alkaline Phosphatase (ALP) activities,
Bilirubin and conjugated bilirubin, glucose and protein
concentrations were evaluated. The liver was fixed immediately in
Formalin and was processed and stained in Haematoxylin and Eosin
(H&E). Administration of saponin extract from the root of Garcinia
kola significantly decreased paracetamol induced elevated enzymes
in the test group. Also histological observations showed that saponin
extract of the root of Garcinia kola exhibited a significant liver
protection against the toxicant as evident by the cells trying to return
to normal. Saponin extract from the root of Garcinia kola indicated a
protection of structural integrity of the hepatocytic cell membrane
and regeneration of the damaged liver.
Abstract: This study presents synthesis of novel block
copolymers of thienyl end capped ethoxylated nonyl phenol and
pyrrole via chemical oxidative polymerization. Ethoxylated nonyl
phenol (ENP) was reacted with 2-thiophenecarbonyl chloride in order
to synthesize a macromonomer containing thienyl end-group (ENPThC).
Then copolymers of ENP-ThC and pyrrole were synthesized
by chemical oxidative polymerization using iron (III) chloride as an
oxidant. ENP-ThC served both as a macromonomer and an emulsifier
for pyrrole with poor solubility in water.
The synthesized block copolymers (ENP-ThC-b-PPy) were
characterized by spectroscopic analysis and the electrical
conductivities were investigated with 4-point probe technique.