Abstract: The rate of nitrate adsorption by a nitrate selective ion
exchange resin was investigated in a well-stirred batch experiments.
The kinetic experimental data were simulated with diffusion models including external mass transfer, particle diffusion and chemical
adsorption. Particle pore volume diffusion and particle surface diffusion were taken into consideration separately and simultaneously
in the modeling. The model equations were solved numerically using the Crank-Nicholson scheme. An optimization technique was
employed to optimize the model parameters. All nitrate concentration
decay data were well described with the all diffusion models. The
results indicated that the kinetic process is initially controlled by external mass transfer and then by particle diffusion. The external
mass transfer coefficient and the coefficients of pore volume diffusion and surface diffusion in all experiments were close to each
other with the average value of 8.3×10-3 cm/S for external mass
transfer coefficient. In addition, the models are more sensitive to the
mass transfer coefficient in comparison with particle diffusion. Moreover, it seems that surface diffusion is the dominant particle
diffusion in comparison with pore volume diffusion.
Abstract: This work concerns the measurements of a Bulk
Acoustic Waves (BAW) emission filter S parameters and compare
with prototypes simulated types. Thanks to HP-ADS, a co-simulation
of filters- characteristics in a digital radio-communication chain is
performed. Four cases of modulation schemes are studied in order to
illustrate the impact of the spectral occupation of the modulated
signal. Results of simulations and co-simulation are given in terms of
Error Vector Measurements to be useful for a general sensibility
analysis of 4th/3rd Generation (G.) emitters (wideband QAM and
OFDM signals)
Abstract: Although, it is a long time that human know about
the importance of environment in life, but at the last decade of 20
century, the space that was full of hot scientific, collegial and
political were made in environmental challenge, So much that, this
problem not only disarrange the peace and security of life, but also it
has threatened human existence. One of the problems in last years
that are significant for authorities is unsatisfactory achieved results
against of using huge cost for magnificent environmental projects.
This subject leads thinker to this thought that for solving the
environmental problems it is needed new methods include of
sociology, ethics and philosophic, etc. methods apart of technical
affairs. Environment ethics is a new branch of philosophic ethics
discussion that discusses about the ethics relationship between
humans and universe that is around them. By notifying to the above
considered affairs, in today world, necessity of environmental ethics
for environment management is reduplicated. In the following the
article has been focused on environmental ethics role and
environmental management methods and techniques for developing
it.
Abstract: Heavy metals have bad effects on environment and
soils and it can uptake by natural HAP .natural Hap is an inexpensive
material that uptake large amounts of various heavy metals like Zn
(II) .Natural HAP (N-HAP), extracted from bovine cortical bone ash,
is a good choice for substitution of commercial HAP. Several
experiments were done to investigate the sorption capacity of Zn (II)
to N-HAP in various particles sizes, temperatures, initial
concentrations, pH and reaction times. In this study, the sorption of
Zinc ions from a Zn solution onto HAP particles with sizes of 1537.6
nm and 47.6 nm at three initial pH values of 4.50, 6.00 and 7.50 was
studied. The results showed that better performance was obtained
through a 47.6 nm particle size and higher pH values. The
experimental data were analyzed using Langmuir, Freundlich, and
Arrhenius equations for equilibrium, kinetic and thermodynamic
studies. The analysis showed a maximum adsorption capacity of NHAP
as being 1.562 mmol/g at a pH of 7.5 and small particle size.
Kinetically, the prepared N-HAP is a feasible sorbent that retains Zn
(II) ions through a favorable and spontaneous sorption process.
Abstract: This paper presents a multi-objective model for addressing two main objectives in designing rural roads networks: minimization of user operation costs and maximization of population covered. As limited budgets often exist, a reasonable trade-off must be obtained in order to account for both cost and social benefits in this type of networks. For a real-world rural road network, the model is solved, where all non-dominated solutions were obtained. Afterwards, an analysis is made on the (possibly) most interesting solutions (the ones providing better trade-offs). This analysis, coupled with the knowledge of the real world scenario (typically provided by decision makers) provides a suitable method for the evaluation of road networks in rural areas of developing countries.
Abstract: An application framework provides a reusable design
and implementation for a family of software systems. Application
developers extend the framework to build their particular
applications using hooks. Hooks are the places identified to show
how to use and customize the framework. Hooks define the
Framework Interface Classes (FICs) and the specifications of their
methods. As part of the development life cycle, it is required to test
the implementations of the FICs. Building a testing model to express
the behavior of a class is an essential step for the generation of the
class-based test cases. The testing model has to be consistent with the
specifications provided for the hooks. State-based models consisting
of states and transitions are testing models well suited to objectoriented
software. Typically, hand-construction of a state-based
model of a class behavior is expensive, error-prone, and may result in
constructing an inconsistent model with the specifications of the class
methods, which misleads verification results. In this paper, a
technique is introduced to automatically synthesize a state-based
testing model for FICs using the specifications provided for the
hooks. A tool that supports the proposed technique is introduced.
Abstract: The static stability analysis of stiffened functionally
graded cylindrical shells by isotropic rings and stringers subjected to
axial compression is presented in this paper. The Young's modulus of
the shell is taken to be function of the thickness coordinate. The
fundamental relations, the equilibrium and stability equations are
derived using the Sander's assumption. Resulting equations are
employed to obtain the closed-form solution for the critical axial
loads. The effects of material properties, geometric size and different
material coefficient on the critical axial loads are examined. The
analytical results are compared and validated using the finite element
model.
Abstract: Researchers have long had trouble in measurement of
Exchangeable Sodium Ratio (ESR) at salt-affected soils. this
parameter are often determined using laborious and time consuming
laboratory tests, but it may be more appropriate and economical to
develop a method which uses a more simple soil salinity index. The
aim of this study was to determine the relationship between
exchangeable sodium ratio (ESR) and sodium adsorption ratio (SAR)
in some salt-affected soils of Khuzestan plain. To this purpose, two
experimental areas (S1, S2) of Khuzestan province-IRAN were
selected and four treatments with three replications by series of
double rings were applied. The treatments were included 25cm,
50cm, 75cm and 100cm water application. The statistical results of
the study indicated that in order to predict soil ESR based on soil
SAR the linear regression model ESR=0.2048+0.0066 SAR
(R2=0.53) & ESR=0.0564+0.0171 SAR (R2=0.76) can be
recommended in Pilot S1 and S2 respectively.
Abstract: Because of architectural condition and structure application, sometimes mass source and stiffness source are not coincidence, and the structure is irregular. The structure is also might be asymmetric as an asymmetric bracing in plan which leads to unbalance distribution of stiffness or because of unbalance distribution of the mass. Both condition lead to eccentricity and torsion in the structure. The deficiency of ordinary code to evaluate the performance of steel structures against earthquake has been caused designing based on performance level or capacity spectrum be used. By using the mentioned methods it is possible to design a structure that its behavior against different earthquakes be predictive. In this article 5- story buildings with different percentage of asymmetric which is because of stiffness changes and kind of bracing (x and chevron bracing) have been designed. The static and dynamic nonlinear analysis under three acceleration recording has been done. Finally performance level of the structure has been evaluated.
Abstract: A DC-to-DC converter for applications involving a
source with widely varying voltage conditions with loads requiring
constant voltage from full load down to no load is presented.
The switching regulator considered is a Buck converter with Pulse
Skipping Modulation control whereby pulses applied to the switch
are blocked or released on output voltage crossing a predetermined
value. Results of the study on the performance of regulator circuit
are presented. The regulator regulates over a wide input voltage range
with slightly higher ripple content and good transient response. Input
current spectrum indicates a good EMI performance with crowding
of components at low frequency range.
Abstract: Mankind has entered into an extremely complex and
controversial stage of its development: the world is simultaneously
organized and chaoticized, globalized and localized, combined and
split. Analysts point out that globalization as a process of
strengthening economic, cultural, financial and other ties of states
cause many problems. In the economic sphere, it creates the danger
of growing gap between the states, in the sphere of politics it leads to
the weakening of political power and influence of nation-states.
Abstract: In this paper, we study the application of Extreme
Learning Machine (ELM) algorithm for single layered feedforward
neural networks to non-linear chaotic time series problems. In this
algorithm the input weights and the hidden layer bias are randomly
chosen. The ELM formulation leads to solving a system of linear
equations in terms of the unknown weights connecting the hidden
layer to the output layer. The solution of this general system of
linear equations will be obtained using Moore-Penrose generalized
pseudo inverse. For the study of the application of the method we
consider the time series generated by the Mackey Glass delay
differential equation with different time delays, Santa Fe A and
UCR heart beat rate ECG time series. For the choice of sigmoid,
sin and hardlim activation functions the optimal values for the
memory order and the number of hidden neurons which give the
best prediction performance in terms of root mean square error are
determined. It is observed that the results obtained are in close
agreement with the exact solution of the problems considered
which clearly shows that ELM is a very promising alternative
method for time series prediction.
Abstract: The present study attempted to improve the Mercury
(Hg) sorption capacity of kanuma volcanic ash soil (KVAS) by
impregnating the cupper (Cu). Impregnation was executed by 1 and
5% Cu powder and sorption characterization of optimum Hg
removing Cu impregnated KVAS was performed under different
operational conditions, contact time, solution pH, sorbent dosage and
Hg concentration using the batch operation studies. The 1% Cu
impregnated KVAS pronounced optimum improvement (79%) in
removing Hg from water compare to control. The present
investigation determined the equilibrium state of maximum Hg
adsorption at 6 h contact period. The adsorption revealed a pH
dependent response and pH 3.5 showed maximum sorption capacity
of Hg. Freundlich isotherm model is well fitted with the experimental
data than that of Langmuir isotherm. It can be concluded that the Cu
impregnation improves the Hg sorption capacity of KVAS and 1%
Cu impregnated KVAS could be employed as cost-effective
adsorbent media for treating Hg contaminated water.
Abstract: This paper deals with the problem of thermal and
mechanical shocks, which rising during operation, mostly at
interrupted cut. Here will be solved their impact on the cutting edge
tool life, the impact of coating technology on resistance to shocks
and experimental determination of tool life in heating flame.
Resistance of removable cutting edges against thermal and
mechanical shock is an important indicator of quality as well as its
abrasion resistance. Breach of the edge or its crumble may occur due
to cyclic loading. We can observe it not only during the interrupted
cutting (milling, turning areas abandoned hole or slot), but also in
continuous cutting. This is due to the volatility of cutting force on
cutting. Frequency of the volatility in this case depends on the type
of rising chips (chip size element). For difficult-to-machine materials
such as austenitic steel particularly happened at higher cutting speeds
for the localization of plastic deformation in the shear plane and for
the inception of separate elements substantially continuous chips.
This leads to variations of cutting forces substantially greater than for
other types of steel.
Abstract: A pilot project was carried out in 2007 by the senior
students of Cyprus International University, aiming to minimize the
total cost of waste collection in Northern Cyprus. Many developed
and developing countries have cut their transportation costs – which
lies between 30-40% – down at a rate of 40% percent, by
implementing network models for their route assignments.
Accordingly, a network model was implemented at Göçmenköy
district, to optimize and standardize waste collection works. The
work environment of the employees were also redesigned to provide
maximum ergonomy and to increase productivity, efficiency and
safety. Following the collection of the required data including waste
densities, lengths of roads and population, a model was constructed
to allocate the optimal route assignment for the waste collection
trucks at Göçmenköy district.
Abstract: In this study, communities of ammonia-oxidizing
archaea (AOA) and ammonia-oxidizing bacteria (AOB) in nitrifying
activated sludge (NAS) prepared by enriching sludge from a
municipal wastewater treatment plant in three continuous-flow
reactors receiving an inorganic medium containing different
ammonium concentrations of 2, 10, and 30 mM NH4
+-N (NAS2,
NAS10, and NAS30, respectively) were investigated using molecular
analysis. Results suggested that almost all AOA clones from NAS2,
NAS10, and NAS30 fell into the same AOA cluster and AOA
communities in NAS2 and NAS10 were more diverse than those of
NAS30. In contrast to AOA, AOB communities obviously shifted
from the seed sludge to enriched NASs and in each enriched NAS,
communities of AOB varied particularly. The seed sludge contained
members of N. communis cluster and N. oligotropha cluster. After it
was enriched under various ammonium loads, members of N.
communis cluster disappeared from all enriched NASs. AOB with
high affinity to ammonia presented in NAS 2, AOB with low affinity
to ammonia presented in NAS 30, and both types of AOB survived in
NAS 10. These demonstrated that ammonium load significantly
influenced AOB communities, but not AOA communities in enriched
NASs.
Abstract: Ethanol has become more attractive in fuel industry
either as fuel itself or an additive that helps enhancing the octane
number and combustibility of gasoline. This research studied a
pressure swing adsorption using cassava-based adsorbent prepared
from mixture of cassava starch and cassava pulp for dehydration of
ethanol vapor. The apparatus used in the experiments consisted of
double adsorption columns, an evaporator, and a vacuum pump. The
feed solution contained 90-92 %wt of ethanol. Three process
variables: adsorption temperatures (110, 120 and 130°C), adsorption
pressures (1 and 2 bar gauge) and feed vapor flow rate (25, 50 and 75
% valve opening of the evaporator) were investigated. According to
the experimental results, the optimal operating condition for this
system was found to be at 2 bar gauge for adsorption pressure, 120°C
for adsorption temperature and 25% valve opening of the evaporator.
Production of 1.48 grams of ethanol with concentration higher than
99.5 wt% per gram of adsorbent was obtained. PSA with cassavabased
adsorbent reported in this study could be an alternative method
for production of nearly anhydrous ethanol. Dehydration of ethanol
vapor achieved in this study is due to an interaction between free
hydroxyl group on the glucose units of the starch and the water
molecules.
Abstract: An accurate procedure to determine free vibrations of
beams and plates is presented.
The natural frequencies are exact solutions of governing vibration
equations witch load to a nonlinear homogeny system.
The bilinear and linear structures considered simulate a bridge.
The dynamic behavior of this one is analyzed by using the theory of
the orthotropic plate simply supported on two sides and free on the
two others. The plate can be excited by a convoy of constant or
harmonic loads. The determination of the dynamic response of the
structures considered requires knowledge of the free frequencies and
the shape modes of vibrations. Our work is in this context. Indeed,
we are interested to develop a self-consistent calculation of the Eigen
frequencies.
The formulation is based on the determination of the solution of
the differential equations of vibrations. The boundary conditions
corresponding to the shape modes permit to lead to a homogeneous
system. Determination of the noncommonplace solutions of this
system led to a nonlinear problem in Eigen frequencies.
We thus, develop a computer code for the determination of the
eigenvalues. It is based on a method of bisection with interpolation
whose precision reaches 10 -12. Moreover, to determine the
corresponding modes, the calculation algorithm that we develop uses
the method of Gauss with a partial optimization of the "pivots"
combined with an inverse power procedure. The Eigen frequencies
of a plate simply supported along two opposite sides while
considering the two other free sides are thus analyzed. The results
could be generalized with the case of a beam by regarding it as a
plate with low width.
We give, in this paper, some examples of treated cases. The
comparison with results presented in the literature is completely
satisfactory.
Abstract: Nowadays there are many methods for representing
knowledge such as semantic network, neural network, and conceptual
graphs. Nonetheless, these methods are not sufficiently efficient
when applied to perform and deduce on knowledge domains about
supporting in general education such as algebra, analysis or plane
geometry. This leads to the introduction of computational network
which is a useful tool for representation knowledge base, especially
for computational knowledge, especially knowledge domain about
general education. However, when dealing with a practical problem,
we often do not immediately find a new solution, but we search
related problems which have been solved before and then proposing
an appropriate solution for the problem. Besides that, when finding
related problems, we have to determine whether the result of them
can be used to solve the practical problem or not. In this paper, the
extension model of computational network has been presented. In this
model, Sample Problems, which are related problems, will be used
like the experience of human about practical problem, simulate the
way of human thinking, and give the good solution for the practical
problem faster and more effectively. This extension model is applied
to construct an automatic system for solving algebraic problems in
middle school.
Abstract: In this paper, four carbazole-based D-D-π-A organic
dyes code as CCT2A, CCT3A, CCT1PA and CCT2PA were reported.
A series of these organic dyes containing identical donor and
acceptor group but different π-system. The effect of replacing of
thiophene by phenyl thiophene as π-system on the physical
properties has been focused. The structural, energetic properties and
absorption spectra were theoretically investigated by means of
Density Functional Theory (DFT) and Time-Dependent Density
Functional Theory (TD-DFT). The results show that nonplanar
conformation due to steric hindrance in donor part (cabazolecarbazole
unit) of dye molecule can prevent unfavorable dye
aggregation. By means of the TD-DFT method, the absorption
spectra were calculated by B3LYP and BHandHLYP to study the
affect of hybrid functional on the excitation energy (Eg). The results
revealed the increasing of thiophene units not only resulted in
decreasing of Eg, but also found the shifting of absorption spectra to
higher wavelength. TD-DFT/BHandHLYP calculated results are
more strongly agreed with the experimental data than B3LYP
functions. Furthermore, the adsorptions of CCT2A and CCT3A on the
TiO2 anatase (101) surface were carried out by mean of the chemical
periodic calculation. The result exhibit the strong adsorption energy.
The calculated results provide our new organic dyes can be
effectively used as dye for Dye Sensitized Solar Cell (DSC).