Abstract: Hydrothermally synthesized high silica borosilicates
with the MFI structure was subjected to several characterization
techniques. The effect of boron on the structure and acidity of
HZSM-5 catalyst were studied by XRD, SEM, N2 adsorption, solid
state NMR, NH3-TPD. It was confirmed that boron had entered the
framework in the boron samples. The results also revealed that strong
acidity was weakened and weak acidity was strengthened by the
boron added zeolite framework compared with parent catalyst. The
catalytic performance was carried out in a fixed bed at 460°C for
methanol to propylene (MTP) reaction. The results of MTP reaction
showed a great increment of the propylene selectivity and excellent
stability for the B-HZSM-5. The catalyst exhibited about 81%
selectivity to C2
= - C4
= olefins with 40% selectivity of propylene as
major component at near 100% methanol conversion, and the stable
performance in the studied period was 100h.
Abstract: The design of Automatic Generation Control (AGC) system plays a vital role in automation of power system. This paper proposes Hybrid Neuro Fuzzy (HNF) approach for AGC of two-area interconnected reheat thermal power system with the consideration of Generation Rate Constraint (GRC). The advantage of proposed controller is that it can handle the system non-linearities and at the same time the proposed approach is faster than conventional controllers. The performance of HNF controller has been compared with that of both conventional Proportional Integral (PI) controller as well as Fuzzy Logic Controller (FLC) both in the absence and presence of Generation Rate Constraint (GRC). System performance is examined considering disturbance in each area of interconnected power system.
Abstract: PCCI engines can reduce NOx and PM emissions
simultaneously without sacrificing thermal efficiency, but a low
combustion temperature resulting from early fuel injection, and
ignition occurring prior to TDC, can cause higher THC and CO
emissions and fuel consumption. In conclusion, it was found that the
PCCI combustion achieved by the 2-stage injection strategy with
optimized calibration factors (e.g. EGR rate, injection pressure, swirl
ratio, intake pressure, injection timing) can reduce NOx and PM
emissions simultaneously. This research works are expected to
provide valuable information conducive to a development of an
innovative combustion engine that can fulfill upcoming stringent
emission standards.
Abstract: Inorganic nanoparticles filled polymer composites
have extended their multiple functionalities to various applications,
including mechanical reinforcement, gas barrier, dimensional
stability, heat distortion temperature, flame-retardant, and thermal
conductivity. Sodium stearate-modified calcium carbonate (CaCO3)
nanoparticles were prepared using surface modification method. The
results showed that sodium stearate attached to the surface of CaCO3
nanoparticles with the chemical bond. The effect of modified CaCO3
nanoparticles on thermal properties of polypropylene (PP) was
studied by means of differential scanning calorimetry (DSC) and
Thermogravimetric analysis (TGA). It was found that CaCO3
significantly affected the crystallization temperature and
crystallization degree of PP. Effect of the modified CaCO3 content on
mechanical properties of PP/CaCO3 nanocomposites was also
studied. The results showed that the modified CaCO3 can effectively
improve the mechanical properties of PP. In comparison with PP, the
impact strength of PP/CaCO3 nanocomposites increased by about
65% and the hardness increased by about 5%.
Abstract: Conjugate natural convection in a differentially heated
square enclosure containing a polygon shaped object is studied numerically in this article. The effect of various polygon types on the
fluid flow and thermal performance of the enclosure is addressed for
different thermal conductivities. The governing equations are modeled
and solved numerically using the built-in finite element method of COMSOL software. It is found that the heat transfer rate remains
stable by varying the polygon types.
Abstract: We have devised a thermal carpet cloak theoretically
and implemented in silicon using layered metamaterial. The layered
metamaterial is composed of single crystalline silicon and its phononic
crystal. The design is based on a coordinate transformation. We
demonstrate the result with numerical simulation. Great cloaking
performance is achieved as a thermal insulator is well hidden under the
thermal carpet cloak. We also show that the thermal carpet cloak can
even the temperature on irregular surface. Using thermal carpet cloak
to manipulate the heat conduction is effective because of its low
complexity.
Abstract: This paper looks into detailed investigation of
thermal-hydraulic characteristics of the flow field in a fuel rod
model, especially near the spacer. The area investigate represents a
source of information on the velocity flow field, vortex, and on the
amount of heat transfer into the coolant all of which are critical for
the design and improvement of the fuel rod in nuclear power plants.
The flow field investigation uses three-dimensional Computational
Fluid Dynamics (CFD) with the Reynolds stresses turbulence model
(RSM). The fuel rod model incorporates a vertical annular channel
where three different shapes of spacers are used; each spacer shape is
addressed individually. These spacers are mutually compared in
consideration of heat transfer capabilities between the coolant and
the fuel rod model. The results are complemented with the calculated
heat transfer coefficient in the location of the spacer and along the
stainless-steel pipe.
Abstract: The malfunction of thermal protection system (TPS) caused by aerodynamic heating is a latent trouble to aircraft structure safety. Accurately predicting the structure temperature field is quite important for the TPS design of hypersonic vehicle. Since Thornton’s work in 1988, the coupled method of aerodynamic heating and heat transfer has developed rapidly. However, little attention has been paid to the influence of structural deformation on aerodynamic heating and structural temperature field. In the flight, especially the long-endurance flight, the structural deformation, caused by the aerodynamic heating and temperature rise, has a direct impact on the aerodynamic heating and structural temperature field. Thus, the coupled interaction cannot be neglected. In this paper, based on the method of static aero-thermo-elasticity, considering the influence of aero-thermo-elasticity deformation, the aerodynamic heating and heat transfer coupled results of hypersonic vehicle wing model were calculated. The results show that, for the low-curvature region, such as fuselage or center-section wing, structure deformation has little effect on temperature field. However, for the stagnation region with high curvature, the coupled effect is not negligible. Thus, it is quite important for the structure temperature prediction to take into account the effect of elastic deformation. This work has laid a solid foundation for improving the prediction accuracy of the temperature distribution of aircraft structures and the evaluation capacity of structural performance.
Abstract: Biodiesel production with used frying by
transesterification reaction with methanol, using a commercial
kaolinite thermally-activated solid acid catalyst was investigated.
The surface area, the average pore diameter and pore volume of the
kaolinite catalyst were 10 m2/g, 13.0 nm and 30 mm3/g, respectively.
The optimal conditions for the transesterification reaction were
determined to be oil/methanol, in a molar ratio 1:31, temperature 160
ºC and catalyst concentration of 3% (w/w). The yield of fatty acids
methyl esters (FAME) was 92.4% after 2 h of reaction. This method
of preparation of biodiesel can be a positive alternative for utilizing
used frying corn oil for feedstock of biodiesel combined with the
inexpensive catalyst.
Abstract: The aim of this research was to calculate the thermal
properties of Au3Ni Nanowire. The molecular dynamics (MD)
simulation technique was used to obtain the effect of radius size on
the energy, the melting temperature and the latent heat of fusion at
the isobaric-isothermal (NPT) ensemble. The Quantum Sutton-Chen
(Q-SC) many body interatomic potentials energy have been used for
Gold (Au) and Nickel (Ni) elements and a mixing rule has been
devised to obtain the parameters of these potentials for nanowire
stats. Our MD simulation results show the melting temperature and
latent heat of fusion increase upon increasing diameter of nanowire.
Moreover, the cohesive energy decreased with increasing diameter of
nanowire.
Abstract: Subgrade moisture content varies with environmental and soil conditions and has significant influence on pavement performance. Therefore, it is important to establish realistic estimates of expected subgrade moisture contents to account for the effects of this variable on predicted pavement performance during the design stage properly. The initial boundary soil suction profile for a given pavement is a critical factor in determining expected moisture variations in the subgrade for given pavement and climatic and soil conditions. Several numerical models have been developed for predicting water and solute transport in saturated and unsaturated subgrade soils. Soil hydraulic properties are required for quantitatively describing water and chemical transport processes in soils by the numerical models. The required hydraulic properties are hydraulic conductivity, water diffusivity, and specific water capacity. The objective of this paper was to determine isothermal moisture profiles in a soil fill and predict the soil moisture movement above the ground water table using a simple one-dimensional finite difference model.
Abstract: Thermal behavior of fuel channel under loss of coolant accident (LOCA) is a major concern for nuclear reactor safety. LOCA along with failure of emergency cooling water system (ECC) may leads to mechanical deformations like sagging and ballooning. In order to understand the phenomenon an experiment has been carried out using 19 pin fuel element simulator. Main purpose of the experiment was to trace temperature profiles over the pressure tube, calandria tube and clad tubes of Indian Pressurized Heavy Water Reactor (IPHWR) under symmetrical and asymmetrical heat-up conditions. For simulating the fully voided scenario, symmetrical heating of pressure was carried out by injecting 13.2 KW (2 % of nominal power) to all the 19 pins and the temperatures of pressure tube, calandria tube and clad tubes were measured. During symmetrical heating the sagging of fuel channel was initiated at 460 °C and the highest temperature attained by PT was 650 °C . The decay heat from clad tubes was dissipated to moderator mainly by radiation and natural convection. The highest temperature of 680 °C was observed over the outer ring of clad tubes of fuel simulator. Again, to simulate partially voided condition, asymmetrical heating of pressure was carried out by supplying 8.0 kW power to upper 8 pins of fuel simulator and temperature profiles were measured. Along the circumference of pressure tube (PT) the highest temperature difference of 320 °C was observed, which highlights the magnitude of thermal stresses under partially voided conditions.
Abstract: In this paper a three dimensional thermal model of a
sliding contact system is proposed for both steady-state or transient
conditions. The influence of contact force, electric current and
ambient temperature on the temperature distribution, has been
investigated. A thermal analysis of the different type of the graphite
material of fixed electric contact and its influence on contact system
temperature rise, has been performed. To validate the three
dimensional thermal model, some experimental tests have been done.
There is a good correlation between experimental and simulation
results.
Abstract: The mechanism behind the electromigration and
thermomigration failure in flip-chip solder joints with Cu-pillar bumps
was investigated in this paper through using finite element method.
Hot spot and the current crowding occurrs in the upper corner of
copper column instead of solders of the common solder ball. The
simulation results show that the change in thermal gradient is
noticeable, which might greatly affect the reliability of solder joints
with Cu-pillar bumps under current stressing. When the average
applied current density is increased from 1×104 A/cm2 to 3×104 A/cm2
in solders, the thermal gradient would increase from 74 K/cm to 901
K/cm at an ambient temperature of 25°C. The force from thermal
gradient of 901 K/cm can nearly induce thermomigration by itself.
With the increase in applied current, the thermal gradient is growing. It
is proposed that thermomigration likely causes a serious reliability
issue for Cu column based interconnects.
Abstract: Aluminum alloy has an extensive range of industrial application due to its consistent mechanical properties and structural integrity. The heat treatment by precipitation technique affected the Magnesium, Silicon Manganese and copper crystals dissolved in the Aluminum alloy. The crystals dislocated to precipitate on the crystal’s boundaries of the Aluminum alloy when given a thermal energy increased its hardness. In this project various times and temperature were varied to find out the best combination of these variables to increase the precipitation of the metals on the Aluminum crystal’s boundaries which will lead to get the highest hardness. These specimens are then tested for their hardness and tensile strength. It is noticed that when the temperature increases, the precipitation increases and consequently the hardness increases. A threshold temperature value (264C0) of Aluminum alloy should not be reached due to the occurrence of recrystalization which causes the crystal to grow. This recrystalization process affected the ductility of the alloy and decrease hardness. In addition, and while increasing the temperature the alloy’s mechanical properties will decrease. The mechanical properties, namely tensile and hardness properties are investigated according to standard procedures. In this research, different temperature and time have been applied to increase hardening.The highest hardness at 100°c in 6 hours equals to 207.31 HBR, while at the same temperature and time the lowest elongation equals to 146.5.
Abstract: If an unsteady heat transfer or heat impulse happens in
part of the cryogenic pipeline system of large space environment
simulation equipment while running in vacuum environment, it will
lead to abnormal flow of the cryogenic fluid in the pipeline. When the
situation gets worse, the cryogenic fluid in the pipeline will have phase
change and a gas block which results in the malfunction of the
cryogenic pipeline system. Referring to the structural parameter of a
typical cryogenic pipeline system and the basic equation, an analytical
model and a calculation model for cryogenic pipeline system can be
built. The various factors which influence the thermal resistance of a
cryogenic pipeline system can be analyzed and calculated by using the
qualitative analysis relation deduced for thermal resistance of pipeline.
The research conclusion could provide theoretical support for the
design and operation of a cryogenic pipeline system
Abstract: This study describes the preparation of a novel proton
conducting membranes based on bacterial cellulose (BC) modified by
grafting of 2-acrylamido-2-methyl-1 -propanesulfonic acid (AMPS)
through UV-induced graft polymerization. These AMPS-g-BC
membranes have been characterized by various techniques including
FTIR, SEM and TGA, to find their successful grafting of AMPS on
BC, surface morphology and thermal stability, respectively. Physical
properties of AMPS-g-BC membranes have been assessed in terms of
Lamda value( λ ), ion exchange capacity(IEC) and proton
conductivity. The relationship between degree of grafting and AMPS
concentration used for grafting has been determined by weight gain
method. An optimum proton conductivity equal to 2.89x10-2 S cm-1
and IEC value equal to 1.79 mmol g-1 have been obtained when 20
wt% AMPS concentration is used for grafting (i.e. the corresponding
membrane is notated as AMPS20-g-BC).
Abstract: In recent years Malaysia has included renewable
energy as an alternative fuel to help in diversifying the country-s
energy reliance on oil, natural gas, coal and hydropower with
biomass and solar energy gaining priority. The scope of this paper is
to look at the designing procedures and analysis of a solar thermal
parabolic trough concentrator by simulation utilizing meteorological
data in several parts of Malaysia. Parameters which include the
aperture area, the diameter of the receiver and the working fluid may
be varied to optimize the design. Aperture area is determined by
considering the width and the length of the concentrator whereas the
geometric concentration ratio (CR) is obtained by considering the
width and diameter of the receiver. Three types of working fluid are
investigated. Theoretically, concentration ratios can be very high in
the range of 10 to 40 000 depending on the optical elements used and
continuous tracking of the sun. However, a thorough analysis is
essential as discussed in this paper where optical precision and
thermal analysis must be carried out to evaluate the performance of
the parabolic trough concentrator as the theoretical CR is not the only
factor that should be considered.
Abstract: In the present work homogeneous silica film on
silicon was fabricated by colloidal silica sol. The silica sol precursor
with uniformly granular particle was derived by the alkaline
hydrolysis of tetraethoxyorthosilicate (TEOS) in presence of glycerol
template. The film was prepared by dip coating process. The
templated hetero-structured silica film was annealed at elevated
temperatures to generate nano- and meso porosity in the film. The
film was subsequently annealed at different temperatures to make it
defect free and abrasion resistant. The sol and the film were
characterized by the measurement of particle size distribution,
scanning electron microscopy, XRD, FTIR spectroscopy,
transmission electron microscopy, atomic force microscopy,
measurement of the refractive index, thermal conductivity and
abrasion resistance. The porosity of the films decreased whereas
refractive index and dielectric constant of it `increased with the
increase in the annealing temperature. The thermal conductivity of
the films increased with the increase in the film thickness. The
developed porous silica film holds strong potential for use in
different areas.
Abstract: The objectif of the present work is to determinate the
potential of the solar parabolic trough collector (PTC) for use in the
design of a solar thermal power plant in Algeria. The study is based
on a mathematical modeling of the PTC. Heat balance has been
established respectively on the heat transfer fluid (HTF), the absorber
tube and the glass envelop using the principle of energy conservation
at each surface of the HCE cross-sectionn. The modified Euler
method is used to solve the obtained differential equations. At first
the results for typical days of two seasons the thermal behavior of the
HTF, the absorber and the envelope are obtained. Then to determine
the thermal performances of the heat transfer fluid, different oils are
considered and their temperature and heat gain evolutions compared.