Abstract: The textile industry produces highly coloured
effluents containing polar and non-polar compounds. The textile mill
run by the Assam Polyester Co-operative Society Limited (APOL) is
situated at Rangia, about 55 km from Guwahati (26011' N, 91047' E)
in the northern bank of the river Brahmaputra, Assam (India). This
unit was commissioned in June 1988 and started commercial
production in November 1988. The installed capacity of the weaving
unit was 8000 m/day and that of the processing unit was 20,000
m/day. The mill has its own dyeing unit with a capacity of 1500-2000
kg/day. The western side of the mill consists of vast agricultural land
and the far northern and southern side of the mill has scattered human
population. The eastern side of the mill has a major road for
thoroughfare. The mill releases its effluents into the agricultural land
in the western side of the mill. The present study was undertaken to
assess the impact of the textile mill on surface soil quality in and
around the mill with particular reference to Cr, Mn, Ni and Zn.
Surface soil samples, collected along different directions at 200, 500
and 1000 m were digested and the metals were estimated with
Atomic Absorption Spectrophotometer. The metals were found in the
range of: Cr 50.9 – 105.0 mg kg-1, Mn 19.2- 78.6 mg kg-1, Ni 41.9 –
50.6 mg kg-1 and Zn 187.8 – 1095.8 mg kg-1. The study reveals
enrichment of Cr, Mn, Ni and Zn in the soil near the textile mill.
Abstract: A Laboratory-scale packed bed reactor with microbial
cellulose as the biofilm carrier was used to investigate the
denitrification of high-strength nitrate wastewater with specific
emphasis on the effect the nitrogen loading rate and hydraulic
retention time. Ethanol was added as a carbon source for
denitrification. As a result of this investigation, it was found that up
to 500 mg/l feed nitrate concentration the present system is able to
produce an effluent with nitrate content below 10 ppm at 3 h
hydraulic retention time. The highest observed denitrification rate
was 4.57 kg NO3-N/ (m3 .d) at a nitrate load of 5.64 kg NO3-
N/(m3 .d), and removal efficiencies higher than 90% were obtained
for loads up to 4.2 kg NO3-N/(m3 .d). A mass relation between COD
consumed and NO3-N removed around 2.82 was observed. This
continuous-flow bioreactor proved an efficient denitrification system
with a relatively low retention time.
Abstract: The response of King Abdulla Canal (KAC) water to the upgrade of As Samra Wastewater Treatment Plant which discharges its effluent to the Zarqa River is investigated. Time series quality data that extends between October 2005 and December 2009 obtained by a state of the art telemetric monitoring system were analyzed for COD, EC, TP and TN at two monitoring stations located upstream and downstream of the confluence of the Zarqa River with KAC. The samples- means and the t-test showed that there has been significant improvement in the quality of the KAC water for COD, and TP. However, the improvement in the TN was found statistically insignificant, whereas the EC of the KAC was unaffected by the upgrade. Comparing the selected parameters with the standards and guidelines for using treated wastewater in irrigation showed that the KAC water has improved towards meeting the required standards and guidelines for treated wastewater reuse in irrigation.
Abstract: The pulp and paper mill effluent is one of the high
polluting effluent amongst the effluents obtained from polluting
industries. All the available methods for treatment of pulp and paper
mill effluent have certain drawbacks. The coagulation is one of the
cheapest process for treatment of various organic effluents. Thus, the
removal of chemical oxygen demand (COD) and colour of paper mill
effluent is studied using coagulation process. The batch coagulation
process was performed using various coagulants like: aluminium
chloride, poly aluminium chloride and copper sulphate. The initial
pH of the effluent (Coagulation pH) has tremendous effect on COD
and colour removal. Poly aluminium chloride (PAC) as coagulant
reduced COD to 84 % and 92 % of colour was removed at an
optimum pH 5 and coagulant dose of 8 ml l-1. With aluminium
chloride at an optimum pH = 4 and coagulant dose of 5 g l-1, 74 %
COD and 86 % colour removal were observed. The results using
copper sulphate as coagulant (a less commercial coagulant) were
encouraging. At an optimum pH 6 and mass loading of 5 g l-1, 76 %
COD reduction and 78 % colour reduction were obtained. It was also
observed that after addition of coagulant, the pH of the effluent
decreases. The decrease in pH was highest for AlCl3, which was
followed by PAC and CuSO4. Significant amount of COD reductions
was obtained by coagulation process. Since the coagulation process
is the first stage for treatment of effluent and some of the coagulant
cations usually remain in the treated effluents. Thus, cation like
copper may be one of the good catalyst for second stage of treatment
process like wet oxidation. The copper has been found to be good
oxidation catalyst then iron and aluminum.
Abstract: The springs located in urban areas are the outpouring
of surface water, which can serve as water supply, effluent receptors
and important local macro-drainage elements. With unplanned
occupation, non-compliance with environmental legislation and the
importance of these water bodies, it is vital to analyze the springs
within urban areas, considering the Brazilian forest code. This paper
submits an analysis and discussion methodology proposal of
environmental compliance functions of urban springs, by means of
G.I.S. - Geographic Information System analysis - and in situ
analysis. The case study included two springs which exhibit a history
of occupation along its length, with different degrees of impact. The
proposed method is effective and easy to apply, representing a
powerful tool for analyzing the environmental conditions of springs
in urban areas.
Abstract: Ammonia nitrogen is one of the most hazardous
water pollutants, discharging into water receptors through industrial
effluents. Negative environmental impacts of such chemical species
in hydrosphere include accelerated eutrophication, water toxicity and
harming the aquatics. Natural zeolite clinoptilolite has very high
selectivity & capacity for ammonium cation sorption. It occurs in
high abundances and rich mines of this zeolite exist in different parts
of Iran and thus are available more cheaply and with different sizing.
The aim of this study is to investigate ammonia nitrogen removal
over this natural sorbent from real samples of high polluted
wastewater discharging from a fertilizer producing plant. The
experimental results showed that this natural sorbent without even
any pre treatment system & with the same particle size available in
Iranian markets has still high capability & selectivity in ammonia
nitrogen removal both in batch and continuous tests.
Abstract: This study investigated possible ways to improve the
efficiency of the platinum precipitation process using ammonium
chloride by reducing the platinum content reporting to the effluent.
The ore treated consist of five platinum group metals namely,
ruthenium, rhodium, iridium, platinum, palladium and a precious
metal gold. Gold, ruthenium, rhodium and iridium were extracted
prior the platinum precipitation process. Temperature, reducing
agent, flow rate and potential difference were the variables controlled
to determine the operation conditions for optimum platinum
precipitation efficiency. Hydrogen peroxide was added as the
oxidizing agent at the temperature of 85-90oC and potential
difference of 700-850mV was the variable used to check the
oxidizing state of platinum. The platinum was further purified at
temperature between 60-65oC, potential difference above 700 mV,
ammonium chloride of 200 l, and at these conditions the platinum
content reporting to the effluent was reduced to less than 300ppm,
resulting in optimum platinum precipitation efficiency and purity of
99.9%.
Abstract: The use of sewage sludge and effluents from
wastewater treatment plants for irrigation of agricultural lands is on
the rise particularly in peri-urban areas of developing countries.
The reuse of nutrients and organic matter in treated wastewater
and sewage sludge via land application is a desirable goal. However,
trace or heavy metals present in sludge pose the risk of human or
phytotoxicity from land application. Long-term use of sewage
sludge, heavy metals can accumulate to phytotoxic levels and results
in reduced plants growth and/or enhanced metal concentrations in
plants, which consumed by animals then enter the food chain. In this
research, the amount of heavy metals was measured in plants
irrigated with wastewater and sludge application. For this purpose,
three pilots were made in a Shush treatment plant in south of Tehran.
Three plants species, spinach, lettuce and radish were selected and
planted in the pilots.First pilot was irrigated just with wastewater of
treatment plant and second pilot was irrigated with wastewater and
sludge application .Third pilot was irrigated with simulated heavy
metals solution equal 50 years of irrigation. The results indicate that
the average of amount of heavy metals Pb, Cd in three plant species
in first pilot were lower than permissible limits .In second pilot,
Cadmium accumulations are high in three species plants and more
than the standard limits. Concentration of Cd , Pb have exceed their
permitted limits in plants in third pilot . It was concluded that the use
of wastewater and sludge application in agricultural lands enriched
soils with heavy metals to concentrations that may pose potential
environmental and health risks in the long-term.
Abstract: The pollutant removal efficiency of the Intermittently
Decanted Extended Aeration (IDEA) wastewater treatment system at
Curtin University Sarawak Campus, and conventional activated
sludge wastewater treatment system at a local resort, Resort A, is
monitored. The influent and effluent characteristics are tested during
wet and dry weather conditions, and peak and off peak periods. For
the wastewater treatment systems at Curtin Sarawak and Resort A,
during dry weather and peak season, it was found that the BOD5
concentration in the influent is 121.7mg/L and 80.0mg/L
respectively, and in the effluent, 18.7mg/L and and 18.0mg/L
respectively. Analysis of the performance of the IDEA treatment
system showed that the operational costs can be minimized by 3%, by
decreasing the number of operating cycles. As for the treatment
system in Resort A, by utilizing a smaller capacity air blower, a
saving of 12% could be made in the operational costs.
Abstract: This study investigated the presence of polycyclic
aromatic hydrocarbons (PAHs) in the sediments of the Musa Bay
(around the PETZONE coastal area) from Feb 2010 to Jun 2010.
Concentrations of PAHs recorded in the Musa Bay sediments ranged
from 537.89 to 26,659.06 ng/g dry weight with a mean value of
3990.74 ng/g. the highest concentration of PAHs was observed at
station 4, which is located near the aromatic outlet of Imam
Khomeini petrochemical company (station 4: BI-PC Aromatic
effluent outlet) in which its concentration level was more than the
NOAA sediment quality guideline value (ERL= 4022 ng/g dry
weight). Owing to the concentration of PAHs in the study area, its
concentration level was still meet the NOAA sediment quality
guideline value (ERL: 4022 ng/g dry weight); however, according to
the PELq factor, slightly adverse biological effects are associated
with the exposure to PAHs levels in the study area (0.1< PELq= 0.24
> 0.5).
Abstract: Fecal sterol has been proposed as a chemical indicator
of human fecal pollution even when fecal coliform populations have
diminished due to water chlorination or toxic effects of industrial
effluents. This paper describes an improved derivatization procedure
for simultaneous determination of four fecal sterols including
coprostanol, epicholestanol, cholesterol and cholestanol using gas
chromatography-mass spectrometry (GC-MS), via optimization study
on silylation procedures using N-O-bis
(trimethylsilyl)-trifluoroacetamide (BSTFA), and
N-(tert-butyldimethylsilyl)-N-methyltrifluoroacetamide
(MTBSTFA), which lead to the formation of trimethylsilyl (TMS) and
tert-butyldimethylsilyl (TBS) derivatives, respectively. Two
derivatization processes of injection-port derivatization and water bath
derivatization (60 oC, 1h) were inspected and compared. Furthermore,
the methylation procedure at 25 oC for 2h with
trimethylsilydiazomethane (TMSD) for fecal sterols analysis was also
studied. It was found that most of TMS derivatives demonstrated the
highest sensitivities, followed by methylated derivatives. For BSTFA
or MTBSTFA derivatization processes, the simple injection-port
derivatization process could achieve the same efficiency as that in the
tedious water bath derivatization procedure.
Abstract: A study was carried out to determine the effect of water quality on flotation performance. The experimental test work comprised of batch flotation tests using Denver lab cell for a period of 10 minutes. Nine different test runs were carried out in triplicates to ensure reproducibility using different water types from different thickener overflows, return and sewage effluent water (process water) and portable water. The water sources differed in pH, total dissolved solids, total suspended solids and conductivity. Process water was found to reduce the concentrate recovery and mass pull, while portable water increased the concentrate recovery and mass pull. Portable water reduced the concentrate grade while process water increased the concentrate grade. It is proposed that a combination of process water and portable water supply be used in flotation circuits to balance the different effects that the different water types have on the flotation efficiency.
Abstract: A local wastewater treatment plant (WWTP)
experiencing poor nitrification tracked down high level of
surfactants in the plant-s influent and effluent. The aims of this project were to assess the potential inhibitory effect of surfactants on activated sludge processes. The effect of the
presence of TergitolNP-9, TrigetolNP-7, Trigetol15-S-9,
dodecylbenzene sulphonate (SDBS) and sodium dodecyl
sulfate (SDS) on activated sludge oxygen uptake rate (OUR) and nitrification were assessed. The average concentration of non-ionic and anionic
surfactants in the influent to the local WWTP were 7 and 8.7 mg/L, respectively. Removal of 67% to 90% of the non-ionic and 93-99% of the anionic surfactants tested were measured. All surfactants tested showed inhibitory effects both on OUR
and nitrification. SDS incurred the lowest inhibition whereas
SDBS and NP-9 caused severe inhibition to OUR and
Nitrification. Activated sludge flocs sizes slightly decreased
after 3 hours contact with the surfactant present in the test.
The results obtained indicated that high concentrations of
surfactants are likely to have an adverse effect on the
performance of WWTPs utilizing activated sludge processes.
Abstract: Laboratory experiments have been performed to investigate photocatalytic detoxification by using TiO2 photocatalyst for treating dairy effluent. Various operational parameters such as catalyst concentration, initial concentration, angle of tilt of solar flat plate reactor and flow rate were investigated. Results indicated that the photocatalytic detoxification process can efficiently treat dairy effluent. Experimental runs with dairy wastewater can be used to identify the optimum operational parameters to perform wastewater degradation on large scale for recycling purpose. Also effect of two different types of reactors on degradation process was analyzed.
Abstract: The degradation of selected pharmaceuticals in some
water matrices was studied by using several chemical treatments. The
pharmaceuticals selected were the beta-blocker metoprolol, the
nonsteroidal anti-inflammatory naproxen, the antibiotic amoxicillin,
and the analgesic phenacetin; and their degradations were conducted
by using UV radiation alone, ozone, Fenton-s reagent, Fenton-like
system, photo-Fenton system, and combinations of UV radiation and
ozone with H2O2, TiO2, Fe(II), and Fe(III). The water matrices, in
addition to ultra-pure water, were a reservoir water, a groundwater,
and two secondary effluents from two municipal WWTP. The results
reveal that the presence of any second oxidant enhanced the
oxidation rates, with the systems UV/TiO2 and O3/TiO2 providing the
highest degradation rates. It is also observed in most of the
investigated oxidation systems that the degradation rate followed the
sequence: amoxicillin > naproxen > metoprolol > phenacetin. Lower
rates were obtained with the pharmaceuticals dissolved in natural
waters and secondary effluents due to the organic matter present
which consume some amounts of the oxidant agents.
Abstract: The effects of irrigation with dairy factory wastewater
on soil properties were investigated at two sites that had received
irrigation for > 60 years. Two adjoining paired sites that had never
received DFE were also sampled as well as another seven fields from
a wider area around the factory. In comparison with paired sites that
had not received effluent, long-term wastewater irrigation resulted in
an increase in pH, EC, extractable P, exchangeable Na and K and
ESP. These changes were related to the use of phosphoric acid,
NaOH and KOH as cleaning agents in the factory. Soil organic C
content was unaffected by DFE irrigation but the size (microbial
biomass C and N) and activity (basal respiration) of the soil
microbial community were increased. These increases were
attributed to regular inputs of soluble C (e.g. lactose) present as milk
residues in the wastewater. Principal component analysis (PCA) of
the soils data from all 11sites confirmed that the main effects of DFE
irrigation were an increase in exchangeable Na, extractable P and
microbial biomass C, an accumulation of soluble salts and a liming
effect. PCA analysis of soil bacterial community structure, using
PCR-DGGE of 16S rDNA fragments, generally separated individual
sites from one another but did not group them according to irrigation
history. Thus, whilst the size and activity of the soil microbial
community were increased, the structure and diversity of the
bacterial community remained unaffected.
Abstract: An HPLC-UV analytical method was developed to
determine ethylenediaminetetraacetic acid (EDTA) in dairy
wastewater and surface water. The optimizing separation was achieved
by reversed–phase ion-pair liquid chromatography on a C18 column
using methanol as mobile phase solvent, tetrabutylammonium bromide
as the ion-pair reagent in pH 3.3 formate buffer solution at a flow rate
of 0.9 mL min-1 with a UV detector at 265 nm. No interference of Ca,
Mg or NO3
- was detected. Method performance was evaluated in terms
of linearity, repeatability and reproducibility. The method detection
limit was 5 μg L-1. The contents of EDTA in dairy effluents were 72 ~
261 μg L-1 at a large dairy site. A change of EDTA concentration was
observed downstream of the dairy effluent discharge, but this was well
under the predicted no effect concentration for aquatic ecosystem.
Abstract: The Yasuj city stream named the Beshar supply
water for different usages such as aquaculture farms , drinking,
agricultural and industrial usages. Fish processing plants
,Agricultural farms, waste water of industrial zones and hospitals
waste water which they are generate by human activity produce a
considerable volume of effluent and when they are released in to the
stream they can effect on the water quality and down stream aquatic
systems. This study was conducted to evaluate the effects of outflow
effluent from different human activity and point and non point
pollution sources on the water quality and health of the Beshar
river next to Yasuj. Yasuj is the biggest and most important city in
the Kohkiloye and Boyerahmad province . The Beshar River is one
of the most important aquatic ecosystems in the upstream of the
Karun watershed in south of Iran which is affected by point and non
point pollutant sources . This study was done in order to evaluate the
effects of human activities on the water quality and health of the
Beshar river. This river is approximately 190 km in length and
situated at the geographical positions of 51° 20' to 51° 48' E and 30°
18' to 30° 52' N it is one of the most important aquatic ecosystems of
Kohkiloye and Boyerahmad province in south-west Iran. In this
research project, five study stations were selected to examine water
pollution in the Beshar River systems. Human activity is now one of
the most important factors affecting on hydrology and water quality
of the Beshar river. Humans use large amounts of resources to sustain
various standards of living, although measures of sustainability are
highly variable depending on how sustainability is defined. The
Beshar river ecosystems are particularly sensitive and vulnerable to
human activities. The water samples were analyzed, then some
important water quality parameters such as pH, dissolve oxygen
(DO), Biochemical Oxygen Demand (BOD5), Chemical Oxygen
Demand (COD), Total Suspended Solids (TDS),Turbidity,
Temperature, Nitrates (NO3) and Phosphates (PO4) were estimated
at the two stations. The results show a downward trend in the water
quality at the down stream of the city. The amounts of
BOD5,COD,TSS,T,Turbidity, NO3 and PO4 in the down stream
stations were considerably more than the station 1. By contrast the
amounts of DO in the down stream stations were less than to the
station 1. However when effluent discharge consequence of human
activities are released into the Beshar river near the city, the quality
of river are decreases and the environmental problems of the river
during the next years are predicted to rise.
Abstract: Multiport diffusers are the effective engineering
devices installed at the modern marine outfalls for the steady
discharge of effluent streams from the coastal plants, such as
municipal sewage treatment, thermal power generation and seawater
desalination. A mathematical model using a two-dimensional
advection-diffusion equation based on a flat seabed and incorporating
the effect of a coastal tidal current is developed to calculate the
compounded concentration following discharges of desalination
brine from a sea outfall with multiport diffusers. The analytical
solutions are computed graphically to illustrate the merging of
multiple brine plumes in shallow coastal waters, and further
approximation will be made to the maximum shoreline's
concentration to formulate dilution of a multiport diffuser discharge.
Abstract: The presence of toxic heavy metals in industrial
effluents is one of the serious threats to the environment. Heavy
metals such as Cadmium, Chromium, Lead, Nickel, Zinc, Mercury,
Copper, Arsenic are found in the effluents of industries such as
foundries, electroplating, petrochemical, battery manufacturing,
tanneries, fertilizer, dying, textiles, metallurgical and metal finishing.
Tremendous increase of industrial copper usage and its presence in
industrial effluents has lead to a growing concern about the fate and
effects of Copper in the environment. Percolation of industrial
effluents through soils leads to contamination of ground water and
soils. The transport of heavy metals and their diffusion into the soils
has therefore, drawn the attention of the researchers.
In this study, an attempt has been made to delineate the
mechanisms of transport and fate of copper in terrestrial
environment. Column studies were conducted using perplex glass
square column of dimension side 15 cm and 1.35 m long. The soil
samples were collected from a natural drain near Mohali (India). The
soil was characterized to be poorly graded sandy loam. The soil was
compacted to the field dry density level of about 1.6 g/cm3. Break
through curves for different depths of the column were plotted. The
results of the column study indicated that the copper has high
tendency to flow in the soils and fewer tendencies to get absorbed on
the soil particles. The t1/2 estimates obtained from the studies can be
used for design copper laden wastewater disposal systems.