Abstract: Sisal leaves were subjected to enzymatic retting
method to extract the sisal fibre. A portion of the fibre was pretreated
with alkali (NaOH), and further treated with benzoyl chloride
and silane treatment reagents. Both the treated and untreated Sisal
fibre composites were used to fabricate the composite by hand lay-up
technique using unsaturated polyester resin. Tensile, flexural, water
absorption, density, thickness swelling and chemical resistant tests
were conducted and evaluated on the composites. Results obtained
for all the parameters showed an increase in the treated fibre
compared to untreated fibre. FT-IR spectra results ascertained the
inclusion of benzoyl and silane groups on the fibre surface. Scanning
electron microscopy (SEM) result obtained showed variation in the
morphology of the treated and untreated fibre. Chemical modification
was found to improve adhesion of the fibre to the matrix, as well as
physico-mechanical properties of the composites.
Abstract: Green chemistry for plant extraction of active principles is the main interest of many researchers concerned with climate change. While classical organic solvents are detrimental to our environment, greener alternatives to ionic liquids are very promising for sustainable organic chemistry. This study focused on the determination of functional groups observed in the main constituents from the ionic liquid extracts of Coleus aromaticus Benth leaves using FT-IR Spectroscopy. Moreover, this research aimed to determine the best ionic liquid that can separate functionalized plant constituents from the leaves Coleus aromaticus Benth using Fourier Transform Infrared Spectroscopy. Coleus aromaticus Benth leaf extract in different ionic liquids, elucidated pharmacologically important functional groups present in major constituents of the plant, namely, rosmarinic acid, caffeic acid and chlorogenic acid. In connection to distinctive appearance of functional groups in the spectrum and highest % transmittance, potassium chloride-glycerol is the best ionic liquid for green extraction.
Abstract: Smart metering and demand response are gaining
ground in industrial and residential applications. Smart Appliances
have been given concern towards achieving Smart home. The success
of Smart grid development relies on the successful implementation of
Information and Communication Technology (ICT) in power sector.
Smart Appliances have been the technology under development and
many new contributions to its realization have been reported in the
last few years. The role of ICT here is to capture data in real time,
thereby allowing bi-directional flow of information/data between
producing and utilization point; that lead a way for the attainment of
Smart appliances where home appliances can communicate between
themselves and provide a self-control (switch on and off) using the
signal (information) obtained from the grid. This paper depicts the
background on ICT for smart appliances paying a particular attention
to the current technology and identifying the future ICT trends for
load monitoring through which smart appliances can be achieved to
facilitate an efficient smart home system which promote demand
response program. This paper grouped and reviewed the recent
contributions, in order to establish the current state of the art and
trends of the technology, so that the reader can be provided with a
comprehensive and insightful review of where ICT for smart
appliances stands and is heading to. The paper also presents a brief
overview of communication types, and then narrowed the discussion
to the load monitoring (Non-intrusive Appliances Load Monitoring
‘NALM’). Finally, some future trends and challenges in the further
development of the ICT framework are discussed to motivate future
contributions that address open problems and explore new
possibilities.
Abstract: Intellectual capital is one of the most valuable and
important parts of the intangible assets of enterprises especially in
knowledge-based enterprises. With respect to increasing gap between
the market value and the book value of the companies, intellectual
capital is one of the components that can be placed in this gap. This
paper uses the value added efficiency of the three components,
capital employed, human capital and structural capital, to measure the
intellectual capital efficiency of Iranian industries groups, listed in
the Tehran Stock Exchange (TSE), using a 8 years period data set
from 2005 to 2012. In order to analyze the effect of intellectual
capital on the market-to-book value ratio of the companies, the data
set was divided into 10 industries, Banking, Pharmaceutical, Metals
& Mineral Nonmetallic, Food, Computer, Building, Investments,
Chemical, Cement and Automotive, and the panel data method was
applied to estimating pooled OLS. The results exhibited that value
added of capital employed has a positive significant relation with
increasing market value in the industries, Banking, Metals & Mineral
Nonmetallic, Food, Computer, Chemical and Cement, and also,
showed that value added efficiency of structural capital has a positive
significant relation with increasing market value in the Banking,
Pharmaceutical and Computer industries groups. The results of the
value added showed a negative relation with the Banking and
Pharmaceutical industries groups and a positive relation with
computer and Automotive industries groups. Among the studied
industries, computer industry has placed the widest gap between the
market value and book value in its intellectual capital.
Abstract: Pain management is a question of quality of life and
an indicator for nursing quality. Chronic pain which is predominant
in oncology and palliative nursing situations is perceived today as a
multifactorial, individual emotional experience with specific
characteristics including the sociocultural dimension when dealing
with migrant patients. This dimension of chronic pain is of major
importance in professional nursing of migrant patients in hospices or
palliative care units. Objectives of the study are: 1. To find out more
about the sociocultural views on pain and nursing care, on customs
and nursing practices connected with pain of both Turkish Muslim
and German Christian women, 2. To improve individual and family
oriented nursing practice with view to sociocultural needs of patients
in severe pain in palliative care. In a qualitative-explorative comparative study 4 groups of women,
Turkish Muslims immigrants (4 from the first generation, 5 from the
second generation) and German Christian women of two generations
(5 of each age group) of the same age groups as the Turkish women
and with similar educational backgrounds were interviewed (semistructured
ethnographic interviews using Spradley, 1979) on their
perceptions and experiences of pain and nursing care within their
families. For both target groups the presentation will demonstrate the
following results in detail: Utterance of pain as well as “private” and
“public” pain vary within different societies and cultures. Permitted
forms of pain utterance are learned in childhood and determine
attitudes and expectations in adulthood. Language, especially when
metaphors and symbols are used, plays a major role for
misunderstandings. The sociocultural context of illness may include
specific beliefs that are important to the patients and yet seem more
than far-fetched from a biomedical perspective. Pain can be an
influential factor in family relationships where respect or hierarchies
do not allow the direct utterance of individual needs. Specific
resources are often, although not exclusively, linked to religious
convictions and are significantly helpful in reducing pain. The discussion will evaluate the results of the study with view to
the relevant literature and present nursing interventions and
instruments beyond medication that are helpful when dealing with
patients from various socio-cultural backgrounds in painful end-oflife
situations.
Abstract: The process of human resources management in the structures of corporate groups demonstrates certain specificity, resulting from the division of decision-making and executive competencies, which occurs within these structures between a parent company and its subsidiaries. The subprocess of employee assessment is considered crucial, since it provides information for the implementation of personnel function. The empirical studies conducted in corporate groups, within which at least one company is located in Poland, confirmed the critical significance of employee assessment systems in the process of human resources management in corporate groups. Parent companies, most often, retain their decision-making authority within the framework of the discussed process and introduce uniform employee assessment and personnel controlling systems to subsidiary companies. However, the instruments for employee assessment applied in corporate groups do not present such specificity.
Abstract: In this research, students’ scientific attitude, computer anxiety, educational use of the Internet, academic achievement, and problematic use of the Internet are analyzed based on different variables (gender, parents’ educational level and daily access to the Internet). The research group involves 361 students from two middle schools which are located in the center of Konya. The “general survey method” is adopted in the research. In accordance with the purpose of the study, percentage, mean, standard deviation, independent samples t--‐test, ANOVA (variance) are employed in the study. A total of four scales are implemented. These four scales include a total of 13 sub-dimensions. The scores from these scales and their subscales are studied in terms of various variables. In the research, students’ scientific attitude, computer anxiety, educational use of the Internet, the problematic Internet use and academic achievement (gender, parent educational level, and daily access to the Internet) are investigated based on various variables and some significant relations are found.
Abstract: Nowadays, education cannot be imagined without digital technologies. It broadens the horizons of teaching learning processes. Several universities are offering online courses. For evaluation purpose, e-examination systems are being widely adopted in academic environments. Multiple-choice tests are extremely popular. Moving away from traditional examinations to e-examination, Moodle as Learning Management Systems (LMS) is being used. Moodle logs every click that students make for attempting and navigational purposes in e-examination. Data mining has been applied in various domains including retail sales, bioinformatics. In recent years, there has been increasing interest in the use of data mining in e-learning environment. It has been applied to discover, extract, and evaluate parameters related to student’s learning performance. The combination of data mining and e-learning is still in its babyhood. Log data generated by the students during online examination can be used to discover knowledge with the help of data mining techniques. In web based applications, number of right and wrong answers of the test result is not sufficient to assess and evaluate the student’s performance. So, assessment techniques must be intelligent enough. If student cannot answer the question asked by the instructor then some easier question can be asked. Otherwise, more difficult question can be post on similar topic. To do so, it is necessary to identify difficulty level of the questions. Proposed work concentrate on the same issue. Data mining techniques in specific clustering is used in this work. This method decide difficulty levels of the question and categories them as tough, easy or moderate and later this will be served to the desire students based on their performance. Proposed experiment categories the question set and also group the students based on their performance in examination. This will help the instructor to guide the students more specifically. In short mined knowledge helps to support, guide, facilitate and enhance learning as a whole.
Abstract: Thoracotomy is a great surgery that has serious pulmonary complications, so purpose of this study was to determine the response of diaphragmatic excursion to inspiratory muscle trainer post thoracotomy. Thirty patients of both sexes (16 men and 14 women) with age ranged from 20 to 40 years old had done thoracotomy participated in this study. The practical work was done in cardiothoracic department, Kasr-El-Aini hospital at faculty of medicine for individuals 3 days Post operatively. Patients were assigned into two groups: group A (study group) included 15 patients (8 men and 7 women) who received inspiratory muscle training by using inspiratory muscle trainer for 20 minutes and routine chest physiotherapy (deep breathing, cough and early ambulation) twice daily, 3 days per week for one month. Group B (control group) included 15 patients (8 men and 7 women) who received the routine chest physiotherapy only (deep breathing, cough and early ambulation) twice daily, 3 days per week for one month. Ultrasonography was used to evaluate the changes in diaphragmatic excursion before and after training program. Statistical analysis revealed a significant increase in diaphragmatic excursion in the study group (59.52%) more than control group (18.66%) after using inspiratory muscle trainer post operatively in patients post thoracotomy. It was concluded that the inspiratory muscle training device increases diaphragmatic excursion in patients post thoracotomy through improving inspiratory muscle strength and improving mechanics of breathing and using of inspiratory muscle trainer as a method of physical therapy rehabilitation to reduce post-operative pulmonary complications post thoracotomy.
Abstract: For several hundred years, the design of railway tracks
has practically remained unchanged. Traditionally, rail tracks are
placed on a ballast layer due to several reasons, including economy,
rapid drainage, and high load bearing capacity. The primary function
of ballast is to distributing dynamic track loads to sub-ballast and
subgrade layers, while also providing lateral resistance and allowing
for rapid drainage. Upon repeated trainloads, the ballast becomes
fouled due to ballast degradation and the intrusion of fines which
adversely affects the strength and deformation behaviour of ballast.
This paper presents the use of three-dimensional discrete element
method (DEM) in studying the shear behaviour of the fouled ballast
subjected to direct shear loading. Irregularly shaped particles of
ballast were modelled by grouping many spherical balls together in
appropriate sizes to simulate representative ballast aggregates. Fouled
ballast was modelled by injecting a specified number of miniature
spherical particles into the void spaces. The DEM simulation
highlights that the peak shear stress of the ballast assembly decreases
and the dilation of fouled ballast increases with an increase level of
fouling. Additionally, the distributions of contact force chain and
particle displacement vectors were captured during shearing progress,
explaining the formation of shear band and the evolutions of
volumetric change of fouled ballast.
Abstract: Many cluster based routing protocols have been
proposed in the field of wireless sensor networks, in which a group of
nodes are formed as clusters. A cluster head is selected from one
among those nodes based on residual energy, coverage area, number
of hops and that cluster-head will perform data gathering from
various sensor nodes and forwards aggregated data to the base station
or to a relay node (another cluster-head), which will forward the
packet along with its own data packet to the base station. Here a
Game Theory based Diligent Energy Utilization Algorithm (GTDEA)
for routing is proposed. In GTDEA, the cluster head selection is done
with the help of game theory, a decision making process, that selects
a cluster-head based on three parameters such as residual energy
(RE), Received Signal Strength Index (RSSI) and Packet Reception
Rate (PRR). Finding a feasible path to the destination with minimum
utilization of available energy improves the network lifetime and is
achieved by the proposed approach. In GTDEA, the packets are
forwarded to the base station using inter-cluster routing technique,
which will further forward it to the base station. Simulation results
reveal that GTDEA improves the network performance in terms of
throughput, lifetime, and power consumption.
Abstract: In language learning, second language learners as well
as Native speakers commit errors in their attempt to achieve
competence in the target language. The realm of collocation has to do
with meaning relation between lexical items. In all human language,
there is a kind of ‘natural order’ in which words are arranged or relate
to one another in sentences so much so that when a word occurs in a
given context, the related or naturally co-occurring word will
automatically come to the mind. It becomes an error, therefore, if
students inappropriately pair or arrange such ‘naturally’ co–occurring
lexical items in a text. It has been observed that most of the second
language learners in this research group commit collocation errors. A
study of this kind is very significant as it gives insight into the kinds
of errors committed by learners. This will help the language teacher
to be able to identify the sources and causes of such errors as well as
correct them thereby guiding, helping and leading the learners
towards achieving some level of competence in the language. The
aim of the study is to understand the nature of these errors as
stumbling blocks to effective essay writing. The objective of the
study is to identify the errors, analyze their structural compositions so
as to determine whether there are similarities between students in this
regard and to find out whether there are patterns to these kinds of
errors which will enable the researcher to understand their sources
and causes. As a descriptive research, the researcher samples some
nine hundred essays collected from three hundred undergraduate
learners of English as a second language in the Federal College of
Education, Kano, North- West Nigeria, i.e. three essays per each
student. The essays which were given on three different lecture times
were of similar thematic preoccupations (i.e. same topics) and length
(i.e. same number of words). The essays were written during the
lecture hour at three different lecture occasions. The errors were
identified in a systematic manner whereby errors so identified were
recorded only once even if they occur severally in students’ essays.
The data was collated using percentages in which the identified
numbers of occurrences were converted accordingly in percentages.
The findings from the study indicate that there are similarities as well
as regular and repeated errors which provided a pattern. Based on the
pattern identified, the conclusion is that students’ collocation errors
are attributable to poor teaching and learning which resulted in wrong
generalization of rules.
Abstract: The study assessed the effectiveness of Pawpaw
(Carica papaya) wood in reducing the concentrations of heavy
metals in wastewater acting as a bio-sorbent. The following heavy
metals were considered; Zinc, Cadmium, Lead, Copper, Iron,
Selenium, Nickel and Manganese. The physiochemical properties of
Carica papaya stem were studied. The experimental sample was
sourced from the trunk of a felled matured pawpaw tree. Wastewater
for experimental use was prepared by dissolving soil samples
collected from a dump site at Owerri, Imo state of Nigeria in water.
The concentration of each metal remaining in solution as residual
metal after bio-sorption was determined using Atomic absorption
Spectrometer. The effects of pH and initial heavy metal concentration
were studied in a batch reactor. The results of Spectrometer test
showed that there were different functional groups detected in the
Carica papaya stem biomass. There was increase in metal removal as
the pH increased for all the metals considered except for Nickel and
Manganese. Optimum bio-sorption occurred at pH 5.9 with 5g/100ml
solution of bio-sorbent. The results of the study showed that the
treated wastewater is fit for irrigation purpose based on Canada
wastewater quality guideline for the protection of Agricultural
standard. This approach thus provides a cost effective and
environmentally friendly option for treating wastewater.
Abstract: Fermentation is well known as an essential process to
develop chocolate flavor in dried cocoa beans. Besides developing
the precursor of cocoa flavor, it also induces the color changes in the
beans. The fermentation process is influenced by various factors such
as planting material, preconditioning of cocoa pod and fermentation
technique. Therefore, this study was conducted to evaluate color of
Malaysian cocoa beans and how the duration of pods storage and
fermentation technique using shallow box will effect on its color
characteristics. There are two factors being studied i.e. duration of
cocoa pod storage (0, 2, 4 and 6 days) and duration of cocoa
fermentation (0, 1, 2, 3, 4 and 5 days). The experiment is arranged in
4 x 6 factorial designs with 24 treatments and arrangement is in a
Completely Randomised Design (CRD). The produced beans are
inspected for color changes under artificial light during cut test and
divided into four groups of color namely fully brown, purple brown,
fully purple and slaty. Cut tests indicated that cocoa beans which are
directly dried without undergone fermentation has the highest slaty
percentage. However, application of pods storage before fermentation
process is found to decrease the slaty percentage. In contrast, the
percentages of fully brown beans start to dominate after two days of
fermentation, especially from four and six days of pods storage batch.
Whereas, almost all batches of cocoa beans have a percentage of fully
purple less than 20%. Interestingly, the percentage of purple brown
beans are scattered in the entire beans batch regardless any specific
trend. Meanwhile, statistical analysis using General Linear Model
showed that the pods storage has a significant effect on the color
characteristic of the Malaysian dried beans compared to fermentation
duration.
Abstract: Dietary cholesterol has elicited the most public
interest as it relates with coronary heart disease. Thus, humans have
been paying more attention to health, thereby reducing consumption
of cholesterol enriched food. Egg is considered as one of the major
sources of human dietary cholesterol. However, an alternative way to
reduce the potential cholesterolemic effect of eggs is to modify the
fatty acid composition of the yolk. The effect of palm oil (PO),
soybean oil (SO), sesame seed oil (SSO) and fish oil (FO)
supplementation in the diets of layers on egg yolk fatty acid,
cholesterol, egg production and egg quality parameters were
evaluated in a 42-day feeding trial. One hundred and five Isa Brown
laying hens of 34 weeks of age were randomly distributed into seven
groups of five replicates and three birds per replicate in a completely
randomized design. Seven corn-soybean basal diets (BD) were
formulated: BD+No oil (T1), BD+1.5% PO (T2), BD+1.5% SO (T3),
BD+1.5% SSO (T4), BD+1.5% FO (T5), BD+0.75% SO+0.75% FO
(T6) and BD+0.75% SSO+0.75% FO (T7). Five eggs were randomly
sampled at day 42 from each replicate to assay for the cholesterol,
fatty acid profile of egg yolk and egg quality assessment. Results
showed that there were no significant (P>0.05) differences observed
in production performance, egg cholesterol and egg quality
parameters except for yolk height, albumen height, yolk index, egg
shape index, haugh unit, and yolk colour. There were no significant
differences (P>0.05) observed in total cholesterol, high density
lipoprotein and low density lipoprotein levels of egg yolk across the
treatments. However, diets had effect (P
Abstract: In this paper, an approach for the liver tumor detection
in computed tomography (CT) images is represented. The detection
process is based on classifying the features of target liver cell to
either tumor or non-tumor. Fractional differential (FD) is applied for
enhancement of Liver CT images, with the aim of enhancing texture
and edge features. Later on, a fusion method is applied to merge
between the various enhanced images and produce a variety of
feature improvement, which will increase the accuracy of
classification. Each image is divided into NxN non-overlapping
blocks, to extract the desired features. Support vector machines
(SVM) classifier is trained later on a supplied dataset different from
the tested one. Finally, the block cells are identified whether they are
classified as tumor or not. Our approach is validated on a group of
patients’ CT liver tumor datasets. The experiment results
demonstrated the efficiency of detection in the proposed technique.
Abstract: The purpose of this study is analyzing the relationship
between trust and social capital of people with using Social Network
Analysis. In this study, two aspects of social capital will be focused:
Bonding, homophilous social capital (BoSC), and Bridging,
heterophilous social capital (BrSC). These two aspects diverge each
other regarding to the social theories. The other concept of the study
is Trust (Tr), namely interpersonal trust, willing to ascribe good
intentions to and have confidence in the words and actions of other
people. In this study, the sample group, 61 people, was selected from
a private firm from the defense industry. The relation between
BoSC/BrSC and Tr is shown by using Social Network Analysis
(SNA) and statistical analysis with Likert type-questionnaire. The
results of the analysis show the Cronbach’s alpha value is 0.756 and
social capital values (BoSC/BrSC) is not correlated with Tr values of
the people.
Abstract: This first-attempt study revealed that decolorized
intermediates of azo dyes could act as redox mediators to assist
wastewater (WW) decolorization due to enhancement of
electron-transport phenomena. Electrochemical impedance spectra
indicated that hydroxyl and amino-substituent(s) were functional
group(s) as redox-mediator(s). As azo dyes are usually multiple
benzene-rings structured, their derived decolorized intermediates are
likely to play roles of electron shuttles due to lower barrier of energy
gap for electron shuttling. According to cyclic voltammetric profiles,
redox mediating characteristics of decolorized intermediates of azo
dyes (e.g., RBu171, RR198, RR141, RBk5) were clearly disclosed.
With supplementation of biodecolorized metabolites of RR141 and
198, decolorization performance of could be evidently augmented.
This study also suggested the optimal modes of microbial fuel cell
(MFC)-assisted WW decolorization would be plug-flow or batch
mode of operation with no mix. Single chamber-MFCs would be more
favourable than double chamber MFCs due to non-mixing contacting
reactor scheme for operation.
Abstract: River Hindon is an important river catering the
demand of highly populated rural and industrial cluster of western
Uttar Pradesh, India. Water quality of river Hindon is deteriorating at
an alarming rate due to various industrial, municipal and agricultural
activities. The present study aimed at identifying the pollution
sources and quantifying the degree to which these sources are
responsible for the deteriorating water quality of the river. Various
water quality parameters, like pH, temperature, electrical
conductivity, total dissolved solids, total hardness, calcium, chloride,
nitrate, sulphate, biological oxygen demand, chemical oxygen
demand, and total alkalinity were assessed. Water quality data
obtained from eight study sites for one year has been subjected to the
two multivariate techniques, namely, principal component analysis
and cluster analysis. Principal component analysis was applied with
the aim to find out spatial variability and to identify the sources
responsible for the water quality of the river. Three Varifactors were
obtained after varimax rotation of initial principal components using
principal component analysis. Cluster analysis was carried out to
classify sampling stations of certain similarity, which grouped eight
different sites into two clusters. The study reveals that the
anthropogenic influence (municipal, industrial, waste water and
agricultural runoff) was the major source of river water pollution.
Thus, this study illustrates the utility of multivariate statistical
techniques for analysis and elucidation of multifaceted data sets,
recognition of pollution sources/factors and understanding
temporal/spatial variations in water quality for effective river water
quality management.
Abstract: This study evaluated to facilitate separation of ABS
plastics from other waste plastics by froth flotation after surface
hydrophilization of ABS with heat treatment. The mild heat treatment
at 100oC for 60s could selectively increase the hydrophilicity of the
ABS plastics surface (i.e., ABS contact angle decreased from 79o to
65.8o) among other plastics mixture. The SEM and XPS results of
plastic samples sufficiently supported the increase in hydrophilic
functional groups and decrease contact angle on ABS surface, after
heat treatment. As a result of the froth flotation (at mixing speed 150
rpm and airflow rate 0.3 L/min) after heat treatment, about 85% of
ABS was selectively separated from other heavy plastics with 100%
of purity. The effect of optimum treatment condition and detailed
mechanism onto separation efficiency in the froth floatation was also
investigated. This research is successful in giving a simple, effective,
and inexpensive method for ABS separation from waste plastics.