Abstract: Synthesis of gold nanoparticles has attracted much
attention since the pioneering discovery of the high catalytic activity
of supported gold nanoparticles in the reaction of CO oxidation at
low temperature. In this research field, we used Na-montmorillonite
for gold nanoparticles stabilization; various gold loading percentage
1, 2 and 5% were used for gold nanoparticles preparation. The gold
nanoparticles were obtained using chemical reduction method using
NaBH4 as reductant agent. The obtained gold nanoparticles stabilized
in Na-montmorillonite were used as catalysts for the reduction of 4-
nitrophenol to aminophenol with sodium borohydride at room
temperature. The UV-Vis results confirmed directly the gold
nanoparticles formation. The XRD and N2 adsorption results showed
the formation of gold nanoparticles in the pores of montmorillonite
with an average size of 5 nm obtained on samples with 2% gold
loading percentage. The gold particles size increased with the
increase of gold loading percentage. The reduction reaction of 4-
nitrophenol into 4-aminophenol with NaBH4 catalyzed by Au-Namontmorillonite
catalyst exhibits remarkably a high activity; the
reaction was completed within 9 min for 1%Au-Na-montmorillonite
and within 3 min for 2%Au-Na-montmorillonite.
Abstract: Public space is essential to strengthen the social and
urban fabric and the social cohesion; there lies the importance of its
study. Hence, the aim of this paper is to analyze the quality of public
space in the XXI century in both quantitative and qualitative terms. In
this article, the concept of public space includes open spaces such as
parks, public squares and walking areas. To make this analysis, we
take Mexico City as the case study. It has a population of nearly 9
million inhabitants and is composed of sixteen boroughs. For this
analysis, we consider both existing public spaces and the government
intervention for building and improving new and existent public
spaces. Results show that on the one hand, quantitatively there is not
an equitable distribution of public spaces due to both the growth of
the city itself as well as due to the absence of political will to create
public spaces. Another factor is the evolution of this city, which has
been growing merely in a “patched pattern”, where public space has
played no role at all with a total absence of urban design. On the
other hand, qualitatively, even the boroughs with the most public
spaces have not shown interest in making these spaces qualitatively
inclusive and open to the general population aiming for integration.
Therefore, urban projects that privatize public space seem to be the
rule, rather than a rehabilitation effort of the existent public spaces.
Hence, state intervention should reinforce its role as an agent of
social change acting in benefit of the majority of the inhabitants with
the promotion of more inclusive public spaces.
Abstract: In this communication, a low-cost circularly
polarized wire antenna exhibiting improved gain performance for
Dedicated Short Range Communications (DSRC), vehicle-to-vehicle
(V2V) and vehicle-to-infrastructure (V2I) communications is
presented. The proposed antenna comprises a Y-shaped quarterwavelength
monopole antenna surrounded by two iterations of eight
conductive arched walls acting as parasitic elements to enhance the
overall antenna gain and to shape the radiation pattern in the H-plane.
A hemispherical radome shell is added to protect the antenna
structure and its effect on the antenna performance is discussed. The
designed antenna demonstrates antenna gain of 8.2 dB with
omnidirectional far-field radiation pattern in the H-plane. The gain of
the proposed antenna is also compared with the characteristic of the
stand-alone Y-shaped monopole to highlight the advantages of the
proposed approach.
Abstract: Propagation of arbitrary amplitude nonlinear Alfven
waves has been investigated in low but finite β electron-positron-ion
plasma including full ion dynamics. Using Sagdeev pseudopotential
method an energy integral equation has been derived. The Sagdeev
potential has been calculated for different plasma parameters and it
has been shown that inclusion of ion parallel motion along the
magnetic field changes the nature of slow shear Alfven wave solitons
from dip type to hump type. The effects of positron concentration,
plasma-β and obliqueness of the wave propagation on the solitary
wave structure have also been examined.
Abstract: A solution methodology without using integral
transformation is proposed to develop analytical solutions for
transient heat conduction in nonuniform hollow cylinders with
time-dependent boundary condition at the outer surface. It is shown
that if the thermal conductivity and the specific heat of the medium
are in arbitrary polynomial function forms, the closed solutions of the
system can be developed. The influence of physical properties on the
temperature distribution of the system is studied. A numerical
example is given to illustrate the efficiency and the accuracy of the
solution methodology.
Abstract: The purpose of this project is to propose a quick and
environmentally friendly alternative to measure the quality of oils
used in food industry. There is evidence that repeated and
indiscriminate use of oils in food processing cause physicochemical
changes with formation of potentially toxic compounds that can
affect the health of consumers and cause organoleptic changes. In
order to assess the quality of oils, non-destructive optical techniques
such as Interferometry offer a rapid alternative to the use of reagents,
using only the interaction of light on the oil. Through this project, we
used interferograms of samples of oil placed under different heating
conditions to establish the changes in their quality. These
interferograms were obtained by means of a Mach-Zehnder
Interferometer using a beam of light from a HeNe laser of 10mW at
632.8nm. Each interferogram was captured, analyzed and measured
full width at half-maximum (FWHM) using the software from
Amcap and ImageJ. The total of FWHMs was organized in three
groups. It was observed that the average obtained from each of the
FWHMs of group A shows a behavior that is almost linear, therefore
it is probable that the exposure time is not relevant when the oil is
kept under constant temperature. Group B exhibits a slight
exponential model when temperature raises between 373 K and 393
K. Results of the t-Student show a probability of 95% (0.05) of the
existence of variation in the molecular composition of both samples.
Furthermore, we found a correlation between the Iodine Indexes
(Physicochemical Analysis) and the Interferograms (Optical
Analysis) of group C. Based on these results, this project highlights
the importance of the quality of the oils used in food industry and
shows how Interferometry can be a useful tool for this purpose.
Abstract: Currently, green rating systems are mainly utilized for
correctly sizing mechanical and electrical systems, which have short
lifetime expectancies. In these systems, passive solar and bio-climatic
architecture, which have long lifetime expectancies, are neglected.
Urban rating systems consider buildings and services in addition to
neighborhoods and public transportation as integral parts of the built
environment. The main goal of this study was to develop a more
consistent point allocation system for urban building standards by
using six different lifetime shearing layers: Site, Structure, Skin,
Services, Space, and Stuff, each reflecting distinct environmental
damages. This shearing-layer concept was applied to internationally
well-known rating systems: Leadership in Energy and Environmental
Design (LEED) for Neighborhood Development, BRE
Environmental Assessment Method (BREEAM) for Communities
and Comprehensive Assessment System for Building Environmental
Efficiency (CASBEE) for Urban Development. The results showed
that LEED for Neighborhood Development and BREEAM for
Communities focused on long-lifetime-expectancy building designs,
whereas CASBEE for Urban Development gave equal importance to
the Building and Service Layers. Moreover, although this rating
system was applied using a building-scale assessment, “Urban Area +
Buildings” focuses on a short-lifetime-expectancy system design,
neglecting to improve the architectural design by considering bioclimatic
and passive solar aspects.
Abstract: Nowadays, several research studies point up that an
active lifestyle is essential for physical and mental health benefits.
Mobile phones have greatly influenced people’s habits and attitudes
also in the way they exercise. Our research work is mainly focused on
investigating how to exploit mobile technologies to favour people’s
exertion experience. To this end, we developed an exertion framework
users can exploit through a real world mobile application, called
EverywhereSport Run (EWRun), designed to act as a virtual personal
trainer to support runners during their trainings. In this work, inspired
by both previous findings in the field of interaction design for people
with visual impairments, feedback gathered from real users of our
framework, and positive results obtained from two experimentations,
we present some new interaction facilities we designed to enhance
the interaction experience during a training. The positive obtained
results helped us to derive some interaction design recommendations
we believe will be a valid support for designers of future mobile
systems conceived to be used in circumstances where there are limited
possibilities of interaction.
Abstract: The use of engineered nanomaterials has increased as
a result of their positive impact on many sectors of the economy,
including agriculture. Silver nanoparticles (AgNPs) are now used to
enhance seed germination, plant growth, and photosynthetic quantum
efficiency and as antimicrobial agents to control plant diseases. In
this study, we examined the effect of AgNP dosage on the seed
germination of three plant species: corn (Zea mays L.), watermelon
(Citrullus lanatus [Thunb.] Matsum. & Nakai) and zucchini
(Cucurbita pepo L.). This experiment was designed to study the
effect of AgNPs on germination percentage, germination rate, mean
germination time, root length and fresh and dry weight of seedlings
for the three species. Seven concentrations (0.05, 0.1, 0.5, 1, 1.5, 2
and 2.5 mg/ml) of AgNPs were examined at the seed germination
stage. The three species had different dose responses to AgNPs in
terms of germination parameters and the measured growth
characteristics. The germination rates of the three plants were
enhanced in response to AgNPs. Significant enhancement of the
germination percentage values was observed after treatment of the
watermelon and zucchini plants with AgNPs in comparison with
untreated seeds. AgNPs showed a toxic effect on corn root
elongation, whereas watermelon and zucchini seedling growth were
positively affected by certain concentrations of AgNPs. This study
showed that exposure to AgNPs caused both positive and negative
effects on plant growth and germination.
Abstract: Multiple User Interference (MUI) considers the
primary problem in Optical Code-Division Multiple Access
(OCDMA), which resulting from the overlapping among the users. In
this article we aim to mitigate this problem by studying an
interference cancellation scheme called successive interference
cancellation (SIC) scheme. This scheme will be tested on two
different detection schemes, spectral amplitude coding (SAC) and
direct detection systems (DS), using partial modified prime (PMP) as
the signature codes. It was found that SIC scheme based on both SAC
and DS methods had a potential to suppress the intensity noise, that is
to say it can mitigate MUI noise. Furthermore, SIC/DS scheme
showed much lower bit error rate (BER) performance relative to
SIC/SAC scheme for different magnitude of effective power. Hence,
many more users can be supported by SIC/DS receiver system.
Abstract: In this paper, the specific sound Transmission Loss
(TL) of the Laminated Composite Plate (LCP) with different material
properties in each layer is investigated. The numerical method to
obtain the TL of the LCP is proposed by using elastic plate theory. The
transfer matrix approach is novelty presented for computational
efficiency in solving the numerous layers of dynamic stiffness matrix
(D-matrix) of the LCP. Besides the numerical simulations for
calculating the TL of the LCP, the material properties inverse method
is presented for the design of a laminated composite plate analogous to
a metallic plate with a specified TL. As a result, it demonstrates that
the proposed computational algorithm exhibits high efficiency with a
small number of iterations for achieving the goal. This method can be
effectively employed to design and develop tailor-made materials for
various applications.
Abstract: In this study, nuclear magnetic resonance
spectroscopy and nuclear quadrupole resonance spectroscopy
parameters of 14N (Nitrogen in imidazole ring) in N–H…O hydrogen
bonding for Histidine hydrochloride monohydrate were calculated via
density functional theory. We considered a five-molecule model
system of Histidine hydrochloride monohydrate. Also we examined
the trends of environmental effect on hydrogen bonds as well as
cooperativity. The functional used in this research is M06-2X which
is a good functional and the obtained results has shown good
agreement with experimental data. This functional was applied to
calculate the NMR and NQR parameters. Some correlations among
NBO parameters, NMR and NQR parameters have been studied
which have shown the existence of strong correlations among them.
Furthermore, the geometry optimization has been performed using
M062X/6-31++G(d,p) method. In addition, in order to study
cooperativity and changes in structural parameters, along with
increase in cluster size, natural bond orbitals have been employed.
Abstract: In the cooperative transmission scheme, both the
cellular system and broadcasting system are composed. Two cellular
base stations (CBSs) communicating with a user in the cell edge use
cooperative transmission scheme in the conventional scheme. In the
case that the distance between two CBSs and the user is distant, the
conventional scheme does not guarantee the quality of the
communication because the channel condition is bad. Therefore, if the
distance between CBSs and a user is distant, the performance of the
conventional scheme is decreased. Also, the bad channel condition has
bad effects on the performance. The proposed scheme uses two relays
to communicate well with CBSs when the channel condition between
CBSs and the user is poor. Using the relay in the high attenuation
environment can obtain both advantages of the high bit error rate
(BER) and throughput performance.
Abstract: In this paper, influence of harmonics on medium
voltage distribution system of Bogazici Electricity Distribution Inc.
(BEDAS) which takes place at Istanbul/Turkey is investigated. A ring
network consisting of residential loads is taken into account for this
study. Real system parameters and measurement results are used for
simulations. Also, probable working conditions of the system are
analyzed for 50%, 75%, and 100% loading of transformers with
similar harmonic contents. Results of the study are exhibited the
influence of nonlinear loads on %THDV, P.F. and technical losses of
the medium voltage distribution system.
Abstract: This paper is focused on the reference current
calculation in the compensation mode of the active DC traction
substations. The so-called p-q theory of the instantaneous reactive
power is used as theoretical foundation. The compensation goal of
total compensation is taken into consideration for the operation under
both sinusoidal and nonsinusoidal voltage conditions, through the
two objectives of unity power factor and perfect harmonic
cancelation. Four blocks of reference current generation implement
the conceived algorithms and they are included in a specific Simulink
library, which is useful in a DSP dSPACE-based platform working
under Matlab/Simulink. The simulation results validate the
correctness of the implementation and fulfillment of the
compensation tasks.
Abstract: In this paper a novel color image compression
technique for efficient storage and delivery of data is proposed. The
proposed compression technique started by RGB to YCbCr color
transformation process. Secondly, the canny edge detection method is
used to classify the blocks into the edge and non-edge blocks. Each
color component Y, Cb, and Cr compressed by discrete cosine
transform (DCT) process, quantizing and coding step by step using
adaptive arithmetic coding. Our technique is concerned with the
compression ratio, bits per pixel and peak signal to noise ratio, and
produce better results than JPEG and more recent published schemes
(like CBDCT-CABS and MHC). The provided experimental results
illustrate the proposed technique that is efficient and feasible in terms
of compression ratio, bits per pixel and peak signal to noise ratio.
Abstract: A new fast growing trend in tourism is ecotourism, in
which tourists visit natural ecosystems under low impact, nonconsumptive
and locally oriented activities. Through these activities
species and habitats are maintained and typically, underdeveloped
regions are emphasized. Ecotourism provides a great alternative,
especially for rural and undeveloped area. At the same time, despite
its many benefits, it also poses many risks for the naturally protected
areas. If ecotourism is practiced improperly degradation and
irreversible damages could be the unwanted result. In addition, the
lack of MSc programs in the field of Ecotourism in Europe makes it a
necessity to be developed. Such an MSc program is being
implemented with the lead partner the Technical University of
Madrid. The entire partnership has six Universities, seven SMEs and
one National Park from seven different countries all over Europe.
The MSc will have 10 educational modules that will be available
online and will prepare professionals that will be able to implement
ecotourism in a sustainable way. Only through awareness and
education a sustainable ecotourism will be achieved in the protected
areas of Europe.
Abstract: In this paper, improved performance scheme for
joint transmission (JT) is proposed in downlink (DL) coordinated
multi-point (CoMP) in case of the constraint transmission power.
This scheme is that a serving transmission point (TP) requests the
JT to an inter-TP and it selects a precoding technique according
to the channel state information (CSI) from user equipment (UE).
The simulation results show that the bit error rate (BER) and the
throughput performances of the proposed scheme provide the high
spectral efficiency and the reliable data at the cell edge.
Abstract: Based on Business and Consumer Survey (BCS) data,
the European Commission (EC) regularly publishes the monthly
Economic Sentiment Indicator (ESI) for each EU member state. ESI
is conceptualized as a leading indicator, aimed ad tracking the overall
economic activity. In calculating ESI, the EC employs arbitrarily
chosen weights on 15 BCS response balances. This paper raises the
predictive quality of ESI by applying nonlinear programming to find
such weights that maximize the correlation coefficient of ESI and
year-on-year GDP growth. The obtained results show that the highest
weights are assigned to the response balances of industrial sector
questions, followed by questions from the retail trade sector. This
comes as no surprise since the existing literature shows that the
industrial production is a plausible proxy for the overall Croatian
economic activity and since Croatian GDP is largely influenced by
the aggregate personal consumption.
Abstract: A comparison of activity and stability of the as-formed
Pt/C, Pt-Co and Pt-Pd/C electrocatalysts, prepared by a combined
approach of impregnation and seeding, was performed. According to
the activity test in a single Proton Exchange Membrane (PEM) fuel
cell, the Oxygen Reduction Reaction (ORR) activity of the Pt-M/C
electrocatalyst was slightly lower than that of Pt/C. The j0.9 V and
E10 mA/cm2 of the as-prepared electrocatalysts increased in the order of
Pt/C > Pt-Co/C > Pt-Pd/C. However, in the medium-to-high current
density region, Pt-Pd/C exhibited the best performance. With regard to
their stability in a 0.5 M H2SO4 electrolyte solution, the
electrochemical surface area decreased as the number of rounds of
repetitive potential cycling increased due to the dissolution of the
metals within the catalyst structure. For long-term measurement, Pt-
Pd/C was the most stable than the other three electrocatalysts.