Abstract: Fecal sterol has been proposed as a chemical indicator
of human fecal pollution even when fecal coliform populations have
diminished due to water chlorination or toxic effects of industrial
effluents. This paper describes an improved derivatization procedure
for simultaneous determination of four fecal sterols including
coprostanol, epicholestanol, cholesterol and cholestanol using gas
chromatography-mass spectrometry (GC-MS), via optimization study
on silylation procedures using N-O-bis
(trimethylsilyl)-trifluoroacetamide (BSTFA), and
N-(tert-butyldimethylsilyl)-N-methyltrifluoroacetamide
(MTBSTFA), which lead to the formation of trimethylsilyl (TMS) and
tert-butyldimethylsilyl (TBS) derivatives, respectively. Two
derivatization processes of injection-port derivatization and water bath
derivatization (60 oC, 1h) were inspected and compared. Furthermore,
the methylation procedure at 25 oC for 2h with
trimethylsilydiazomethane (TMSD) for fecal sterols analysis was also
studied. It was found that most of TMS derivatives demonstrated the
highest sensitivities, followed by methylated derivatives. For BSTFA
or MTBSTFA derivatization processes, the simple injection-port
derivatization process could achieve the same efficiency as that in the
tedious water bath derivatization procedure.
Abstract: An accurate procedure to determine free vibrations of
beams and plates is presented.
The natural frequencies are exact solutions of governing vibration
equations witch load to a nonlinear homogeny system.
The bilinear and linear structures considered simulate a bridge.
The dynamic behavior of this one is analyzed by using the theory of
the orthotropic plate simply supported on two sides and free on the
two others. The plate can be excited by a convoy of constant or
harmonic loads. The determination of the dynamic response of the
structures considered requires knowledge of the free frequencies and
the shape modes of vibrations. Our work is in this context. Indeed,
we are interested to develop a self-consistent calculation of the Eigen
frequencies.
The formulation is based on the determination of the solution of
the differential equations of vibrations. The boundary conditions
corresponding to the shape modes permit to lead to a homogeneous
system. Determination of the noncommonplace solutions of this
system led to a nonlinear problem in Eigen frequencies.
We thus, develop a computer code for the determination of the
eigenvalues. It is based on a method of bisection with interpolation
whose precision reaches 10 -12. Moreover, to determine the
corresponding modes, the calculation algorithm that we develop uses
the method of Gauss with a partial optimization of the "pivots"
combined with an inverse power procedure. The Eigen frequencies
of a plate simply supported along two opposite sides while
considering the two other free sides are thus analyzed. The results
could be generalized with the case of a beam by regarding it as a
plate with low width.
We give, in this paper, some examples of treated cases. The
comparison with results presented in the literature is completely
satisfactory.
Abstract: We propose photo-BJMOSFET (Bipolar Junction Metal-Oxide-Semiconductor Field Effect Transistor) fabricated on SOI film. ITO film is adopted in the device as gate electrode to reduce light absorption. I-V characteristics of photo-BJMOSFET obtained in dark (dark current) and under 570nm illumination (photo current) are studied furthermore to achieve high photo-to-dark-current contrast ratio. Two variables in the calculation were the channel length and the thickness of the film which were set equal to six different values, i.e., L=2, 4, 6, 8, 10, and 12μm and three different values, i.e., dsi =100, 200 and 300nm, respectively. The results indicate that the greatest photo-to-dark-current contrast ratio is achieved with L=10μm and dsi=200 nm at VGK=0.6V.
Abstract: In this study four Holstein steers with rumen fistula
fed 7 kg of dry matter (DM) of diets differing in concentrate to
alfalfa hay ratios as 60:40, 70:30, 80:20, and 90:10 in a 4 × 4 latin
square design. The pH of the ruminal fluid was measured before
the morning feeding (0.0 h) to 8 h post feeding. In this study, a
two-layered feed-forward neural network trained by the
Levenberg-Marquardt algorithm was used for modelling of ruminal
pH. The input variables of the network were time, concentrate to
alfalfa hay ratios (C/F), non fiber carbohydrate (NFC) and neutral
detergent fiber (NDF). The output variable was the ruminal pH.
The modeling results showed that there was excellent agreement
between the experimental data and predicted values, with a high
determination coefficient (R2 >0.96). Therefore, we suggest using
these model-derived biological values to summarize continuously
recorded pH data.
Abstract: Improving the reactive power and voltage profile of a
distribution substation is investigated in this paper. The purpose is to
properly determination of the shunt capacitors on/off status and
suitable tap changer (TC) position of a substation transformer. In
addition, the limitation of secondary bus voltage, the maximum
allowable number of switching operation in a day for on load tap
changer and on/off status of capacitors are taken into account. To
achieve these goals, an artificial neural network (ANN) is designed to
provide preliminary scheduling. Input of ANN is active and reactive
powers of transformer and its primary and secondary bus voltages.
The output of ANN is capacitors on/off status and TC position. The
preliminary schedule is further refined by fuzzy dynamic
programming in order to reach the final schedule. The operation of
proposed method in Q/V improving is compared with the results
obtained by operator operation in a distribution substation.
Abstract: Here we report on the utilization of Laser-Induced
Breakdown Spectroscopy (LIBS) for determination of Quantum Dots
(QDs) in liquid solution. The process of optimization of experimental
conditions from choosing the carrier medium to application of colloid
QDs is described. The main goal was to get the best possible signal to
noise ratio.
The results obtained from the measurements confirmed the capability
of LIBS technique for qualitative and afterwards quantitative
determination of QDs in liquid solution.
Abstract: Among many different methods that are used for
optimizing different engineering problems mathematical (numerical)
optimization techniques are very important because they can easily
be used and are consistent with most of engineering problems. Many
studies and researches are done on stability analysis of three
dimensional (3D) slopes and the relating probable slip surfaces and
determination of factors of safety, but in most of them force
equilibrium equations, as in simplified 2D methods, are considered
only in two directions. In other words for decreasing mathematical
calculations and also for simplifying purposes the force equilibrium
equation in 3rd direction is omitted. This point is considered in just a
few numbers of previous studies and most of them have only given a
factor of safety and they haven-t made enough effort to find the most
probable slip surface. In this study shapes of the slip surfaces are
modeled, and safety factors are calculated considering the force
equilibrium equations in all three directions, and also the moment
equilibrium equation is satisfied in the slip direction, and using
nonlinear programming techniques the shape of the most probable
slip surface is determined. The model which is used in this study is a
3D model that is composed of three upper surfaces which can cover
all defined and probable slip surfaces. In this research the meshing
process is done in a way that all elements are prismatic with
quadrilateral cross sections, and the safety factor is defined on this
quadrilateral surface in the base of the element which is a part of the
whole slip surface. The method that is used in this study to find the
most probable slip surface is the non-linear programming method in
which the objective function that must get optimized is the factor of
safety that is a function of the soil properties and the coordinates of
the nodes on the probable slip surface. The main reason for using
non-linear programming method in this research is its quick
convergence to the desired responses. The final results show a good
compatibility with the previously used classical and 2D methods and
also show a reasonable convergence speed.
Abstract: In this study, a double-sided linear switched reluctance
motor (LSRM) drive was investigated as an alternative actuator for
vertical linear transportation applications such as a linear elevator
door, hospital and subway doors which move linearly and where
accurate position control and rapid response is requested. A prototype
sliding elevator door that is focused on a home elevator with LSRMs
is designed. The motor has 6/4 poles, 3 phases, 8A, 24V, 250 W and
250 N pull forces. Air gap between rotor and translator poles of the
designed motor and phase coil-s ideal inductance profile are obtained
in compliance with the geometric dimensions. Operation and
switching sections as motor and generator has been determined from
the inductance profile.
Abstract: This paper describes WiPoD (Wireless Position
Detector) which is a pure software based location determination and
tracking (positioning) system. It uses empirical signal strength measurements from different wireless access points for mobile user
positioning. It is designed to determine the location of users having
802.11 enabled mobile devices in an 802.11 WLAN infrastructure
and track them in real time. WiPoD is the first main module in our
LBS (Location Based Services) framework. We tested K-Nearest
Neighbor and Triangulation algorithms to estimate the position of a
mobile user. We also give the analysis results of these algorithms for
real time operations. In this paper, we propose a supportable, i.e.
understandable, maintainable, scalable and portable wireless
positioning system architecture for an LBS framework. The WiPoD
software has a multithreaded structure and was designed and implemented with paying attention to supportability features and real-time constraints and using object oriented design principles. We also describe the real-time software design issues of a wireless positioning system which will be part of an LBS framework.
Abstract: Ferroresonance is an electrical phenomenon in
nonlinear character, which frequently occurs in power system due to
transmission line faults and single or more-phase switching on the
lines as well as usage of the saturable transformers. In this study, the
ferroresonance phenomena are investigated under the modeling of the
West Anatolian Electric Power Network of 380 kV in Turkey. The
ferroresonance event is observed as a result of removing the loads at
the end of the lines. In this sense, two different cases are considered.
At first, the switching is applied at 2nd second and the ferroresonance
affects are observed between 2nd and 4th seconds in the voltage
variations of the phase-R. Hence the ferroresonance and nonferroresonance
parts of the overall data are compared with each
others using the Fourier transform techniques to show the
ferroresonance affects.
Abstract: The plastic forming process of sheet plate takes an
important place in forming metals. The traditional techniques of tool
design for sheet forming operations used in industry are experimental
and expensive methods. Prediction of the forming results,
determination of the punching force, blank holder forces and the
thickness distribution of the sheet metal will decrease the production
cost and time of the material to be formed. In this paper, multi-stage
deep drawing simulation of an Industrial Part has been presented
with finite element method. The entire production steps with
additional operations such as intermediate annealing and springback
has been simulated by ABAQUS software under axisymmetric
conditions. The simulation results such as sheet thickness
distribution, Punch force and residual stresses have been extracted in
any stages and sheet thickness distribution was compared with
experimental results. It was found through comparison of results, the
FE model have proven to be in close agreement with those of
experiment.
Abstract: The present work was conducted for the synthesis of
nano size zerovalent iron (nZVI) and hexavalent chromium (Cr(VI))
removal as a highly toxic pollutant by using this nanoparticles. Batch
experiments were performed to investigate the effects of Cr(VI),
nZVI concentration, pH of solution and contact time variation on
the removal efficiency of Cr(VI). nZVI was synthesized by
reduction of ferric chloride using sodium borohydrid. SEM and
XRD examinations applied for determination of particle size and
characterization of produced nanoparticles. The results showed that
the removal efficiency decreased with Cr(VI) concentration and pH
of solution and increased with adsorbent dosage and contact time.
The Langmuir and Freundlich isotherm models were used for the
adsorption equilibrium data and the Langmuir isotherm model was
well fitted. Nanoparticle ZVI presented an outstanding ability to
remove Cr(VI) due to high surface area, low particle size and high
inherent activity.
Abstract: The aim of this work is to analyze a viscous flow in
the axisymmetric nozzle taken into account the mesh size both in the
free stream and into the boundary layer. The resolution of the Navier-
Stokes equations is realized by using the finite volume method to
determine the supersonic flow parameters at the exit of convergingdiverging
nozzle. The numerical technique uses the Flux Vector
Splitting method of Van Leer. Here, adequate time stepping
parameter, along with CFL coefficient and mesh size level is selected
to ensure numerical convergence. The effect of the boundary layer
thickness is significant at the exit of the nozzle. The best solution is
obtained with using a very fine grid, especially near the wall, where
we have a strong variation of velocity, temperature and shear stress.
This study enabled us to confirm that the determination of boundary
layer thickness can be obtained only if the size of the mesh is lower
than a certain value limits given by our calculations.
Abstract: Graph rewriting-based visual model processing is a
widely used technique for model transformation. Visual model
transformations often need to follow an algorithm that requires a
strict control over the execution sequence of the transformation steps.
Therefore, in Visual Model Processors (VMPs) the execution order
of the transformation steps is crucial. This paper presents the visual
control flow support of Visual Modeling and Transformation System
(VMTS), which facilitates composing complex model
transformations of simple transformation steps and executing them.
The VMTS Visual Control Flow Language (VCFL) uses stereotyped
activity diagrams to specify control flow structures and OCL
constraints to choose between different control flow branches. This
paper introduces VCFL, discusses its termination properties and
provides an algorithm to support the termination analysis of VCFL
transformations.
Abstract: A sensitive and specific method for quantitative
determination of aflatoxins(B1, B2, G1,G2), deoxynivalenol,
fumonisin(B1,B2), ochratoxin A, zearalenone, T-2 and HT-2 in
roasted and ground grains using liquid chromatography combined
with tandem mass spectrometry. A double extraction using a
phosphate buffer solution followed by methanol was applied to
achieve effective co extraction of 11 mycotoxins. A multitoxin
immunoaffinity column for all these mycotoxins was used to clean up
the extract. The LODs of mycotoxins were 0.1~6.1 μg/kg, LOQs were
0.3~18.4 μg/kg. Forty seven samples collected from Seoul (Korea) for
mycotoxin contamination monitoring. The results showed that the
occurrence of zearalenone and deoxynivalenol were frequent.
Zearalenone was detected in all samples and deoxynivalenol was
detected in 80.9 % samples in the range 0.626 ~ 29.264 μg/kg and N.D
~ 48.332 μg/kg respectively. Fumonisins and ochratoxin A were
detected in 46.8% samples and 17 % samples respectively, aflatoxins
and T-2/HT-2 toxins were not detected all samples.
Abstract: Broccoli has been widely recognized as a wealthy
vegetable which contains multiple nutrients with potent anti-cancer
properties. Lamb’s lettuce has been used as food for many centuries
but only recently became commercially available and literature is
therefore exiguous concerning these vegetables. The aim of this work
was to evaluate the influence of the extraction conditions on the yield
of phenolic compounds and the corresponding antioxidant capacity of
broccoli and lamb’s lettuce. The results indicate that lamb’s lettuce,
compared to broccoli, contains simultaneously a large amount of total
polyphenols as well as high antioxidant activity. It is clearly
demonstrated that extraction solvent significantly influences the
antioxidant activity. Methanol is the solvent that can globally
maximize the antioxidant extraction yield. The results presented
herein prove lamb’s lettuce as a very interesting source of
polyphenols, and thus a potential health-promoting food.
Abstract: Hidden failure in a protection system has been
recognized as one of the main reasons which may cause to a power
system instability leading to a system cascading collapse. This paper
presents a computationally systematic approach used to obtain the
estimated average probability of a system cascading collapse by
considering the effect of probability hidden failure in a protection
system. The estimated average probability of a system cascading
collapse is then used to determine the severe loading condition
contributing to the higher risk of critical system cascading collapse.
This information is essential to the system utility since it will assist
the operator to determine the highest point of increased system
loading condition prior to the event of critical system cascading
collapse.
Abstract: In this paper, the sum of squares in linear regression is
reduced to sum of squares in semi-parametric regression. We
indicated that different sums of squares in the linear regression are
similar to various deviance statements in semi-parametric regression.
In addition to, coefficient of the determination derived in linear
regression model is easily generalized to coefficient of the
determination of the semi-parametric regression model. Then, it is
made an application in order to support the theory of the linear
regression and semi-parametric regression. In this way, study is
supported with a simulated data example.
Abstract: Simultaneous determination of multicomponents of phenol, resorcinol and catechol with a chemometric technique a PCranking artificial neural network (PCranking-ANN) algorithm is reported in this study. Based on the data correlation coefficient method, 3 representative PCs are selected from the scores of original UV spectral data (35 PCs) as the original input patterns for ANN to build a neural network model. The results obtained by iterating 8000 .The RMSEP for phenol, resorcinol and catechol with PCranking- ANN were 0.6680, 0.0766 and 0.1033, respectively. Calibration matrices were 0.50-21.0, 0.50-15.1 and 0.50-20.0 μg ml-1 for phenol, resorcinol and catechol, respectively. The proposed method was successfully applied for the determination of phenol, resorcinol and catechol in synthetic and water samples.
Abstract: Metal cutting is a severe plastic deformation process
involving large strains, high strain rates, and high temperatures.
Conventional analysis of the chip formation process is based on bulk
material deformation disregarding the inhomogeneous nature of the
material microstructure. A series of orthogonal cutting tests of AISI
1045 and 1144 steel were conducted which yielded similar process
characteristics and chip formations. With similar shear angles and cut
chip thicknesses, shear strains for both chips were found to range
from 2.0 up to 2.8. The manganese-sulfide (MnS) precipitate in the
1144 steel has a very distinct and uniform shape which allows for
comparison before and after chip formation. From close observations
of MnS precipitates in the cut chips it is shown that the conventional
approach underestimates plastic strains in metal cutting.
Experimental findings revealed local shear strains around a value of
6. These findings and their implications are presented and discussed.