Abstract: The aim of this study was to compare the solubility of selected volatile organic compounds in water and silicon oil using the simple static headspace method. The experimental design allowed equilibrium achievement within 30 – 60 minutes. Infinite dilution activity coefficients and Henry-s law constants for various organics representing esters, ketones, alkanes, aromatics, cycloalkanes and amines were measured at 303K. The measurements were reproducible with a relative standard deviation and coefficient of variation of 1.3x10-3 and 1.3 respectively. The static determined activity coefficients using shaker flasks were reasonably comparable to those obtained using the gas liquid - chromatographic technique and those predicted using the group contribution methods mainly the UNIFAC. Silicon oil chemically known as polydimethysiloxane was found to be better absorbent for VOCs than water which quickly becomes saturated. For example the infinite dilution mole fraction based activity coefficients of hexane is 0.503 and 277 000 in silicon oil and water respectively. Thus silicon oil gives a superior factor of 550 696. Henry-s law constants and activity coefficients at infinite dilution play a significant role in the design of scrubbers for abatement of volatile organic compounds from contaminated air streams. This paper presents the phase equilibrium of volatile organic compounds in very dilute aqueous and polymeric solutions indicating the movement and fate of chemical in air and solvent. The successful comparison of the results obtained here and those obtained using other methods by the same authors and in literature, means that the results obtained here are reliable.
Abstract: Concrete strength evaluated from compression tests
on cores is affected by several factors causing differences from the
in-situ strength at the location from which the core specimen was
extracted. Among the factors, there is the damage possibly occurring
during the drilling phase that generally leads to underestimate the
actual in-situ strength. In order to quantify this effect, in this study
two wide datasets have been examined, including: (i) about 500 core
specimens extracted from Reinforced Concrete existing structures,
and (ii) about 600 cube specimens taken during the construction of
new structures in the framework of routine acceptance control. The
two experimental datasets have been compared in terms of
compression strength and specific weight values, accounting for the
main factors affecting a concrete property, that is type and amount of
cement, aggregates' grading, type and maximum size of aggregates,
water/cement ratio, placing and curing modality, concrete age. The
results show that the magnitude of the strength reduction due to
drilling damage is strongly affected by the actual properties of
concrete, being inversely proportional to its strength. Therefore, the
application of a single value of the correction coefficient, as generally
suggested in the technical literature and in structural codes, appears
inappropriate. A set of values of the drilling damage coefficient is
suggested as a function of the strength obtained from compressive
tests on cores.
Abstract: Nigerian bread is baked with vitamin A fortified wheat flour. Study aimed at determining its contribution to preschoolers- vitamin A nutriture. A cross-sectional/experimental study was carried out in four poor-urban Local Government Areas (LGAs) of Metropolitan Lagos, Nigeria. A pretested food frequency questionnaire was administered to randomly selected mothers of 1600 preschoolers (24-59 months). Retinyl Palmitate content of fourteen bread samples randomly collected from bakeries in all LGAs was analyzed at 0 and 5 days at 25oC using High Performance Liquid Chromatography. Data analysis was done at p
Abstract: This paper analytically investigates the 3D flow
pattern at the confluences of two rectangular channels having 900
angles using Navier-Stokes equations based on Reynolds Stress
Turbulence Model (RSM). The equations are solved by the Finite-
Volume Method (FVM) and the flow is analyzed in terms of steadystate
(single-phased) conditions. The Shumate experimental findings
were used to test the validity of data. Comparison of the simulation
model with the experimental ones indicated a close proximity
between the flow patterns of the two sets. Effects of the discharge
ratio on separation zone dimensions created in the main-channel
downstream of the confluence indicated an inverse relation, where a
decrease in discharge ratio, will entail an increase in the length and
width of the separation zone. The study also found the model as a
powerful analytical tool in the feasibility study of hydraulic
engineering projects.
Abstract: The highly nonlinear characteristics of drying
processes have prompted researchers to seek new nonlinear control
solutions. However, the relation between the implementation
complexity, on-line processing complexity, reliability control
structure and controller-s performance is not well established. The
present paper proposes high performance nonlinear fuzzy controllers
for a real-time operation of a drying machine, being developed under
a consistent match between those issues. A PCI-6025E data
acquisition device from National Instruments® was used, and the
control system was fully designed with MATLAB® / SIMULINK
language. Drying parameters, namely relative humidity and
temperature, were controlled through MIMOs Hybrid Bang-bang+PI
(BPI) and Four-dimensional Fuzzy Logic (FLC) real-time-based
controllers to perform drying tests on biological materials. The
performance of the drying strategies was compared through several
criteria, which are reported without controllers- retuning. Controllers-
performance analysis has showed much better performance of FLC
than BPI controller. The absolute errors were lower than 8,85 % for
Fuzzy Logic Controller, about three times lower than the
experimental results with BPI control.
Abstract: A family of improved secant-like method is proposed in this paper. Further, the analysis of the convergence shows that this method has super-linear convergence. Efficiency are demonstrated by numerical experiments when the choice of α is correct.
Abstract: In general, image-based 3D scenes can now be found in many popular vision systems, computer games and virtual reality tours. So, It is important to segment ROI (region of interest) from input scenes as a preprocessing step for geometric stricture detection in 3D scene. In this paper, we propose a method for segmenting ROI based on tensor voting and Dirichlet process mixture model. In particular, to estimate geometric structure information for 3D scene from a single outdoor image, we apply the tensor voting and Dirichlet process mixture model to a image segmentation. The tensor voting is used based on the fact that homogeneous region in an image are usually close together on a smooth region and therefore the tokens corresponding to centers of these regions have high saliency values. The proposed approach is a novel nonparametric Bayesian segmentation method using Gaussian Dirichlet process mixture model to automatically segment various natural scenes. Finally, our method can label regions of the input image into coarse categories: “ground", “sky", and “vertical" for 3D application. The experimental results show that our method successfully segments coarse regions in many complex natural scene images for 3D.
Abstract: The performance and complexity of QoS routing depends on the complex interaction between a large set of parameters. This paper investigated the scaling properties of source-directed link-state routing in large core networks. The simulation results show that the routing algorithm, network topology, and link cost function each have a significant impact on the probability of successfully routing new connections. The experiments confirm and extend the findings of other studies, and also lend new insight designing efficient quality-of-service routing policies in large networks.
Abstract: The research object was wheat bread. Experiments
were carried out at the Faculty of Food Technology of the Latvia
University of Agriculture. An active packaging in combination with
modified atmosphere (MAP, CO2 60% and N2 40%) was examined
and compared with traditional packaging in air ambiance. Polymer
Multibarrier 60, PP and OPP bags were used. Influence of iron based
oxygen absorber in sachets of 100 cc obtained from Mitsubishi Gas
Chemical Europe Ageless® was tested on the quality during the shelf
of wheat bread. Samples of 40±4 g were packaged in polymer
pouches (110 mm x 120 mm), hermetically sealed by MULTIVAC
C300 vacuum chamber machine, and stored in room temperature
+21.0±0.5 °C. The physiochemical properties – weight losses,
moisture content, hardness, pH, colour, changes of atmosphere
content (CO2 and O2) in headspace of packs, and microbial
conditions were analysed before packaging and in the 7th, 14th, 21st
and 28th days of storage.
Abstract: This paper presents an intrusion detection system of hybrid neural network model based on RBF and Elman. It is used for anomaly detection and misuse detection. This model has the memory function .It can detect discrete and related aggressive behavior effectively. RBF network is a real-time pattern classifier, and Elman network achieves the memory ability for former event. Based on the hybrid model intrusion detection system uses DARPA data set to do test evaluation. It uses ROC curve to display the test result intuitively. After the experiment it proves this hybrid model intrusion detection system can effectively improve the detection rate, and reduce the rate of false alarm and fail.
Abstract: Transient shape variation of a rotating liquid dropletis
simulated numerically. The three dimensional Navier-Stokes
equations were solved by using the level set method. The shape
variation from the sphere to the rotating ellipsoid, and to the two-robed
shapeare simulated, and the elongation of the two-robed droplet is
discussed. The two-robed shape after the initial transient is found to be
stable and the elongation is almost the same for the cases with different
initial rotation rate. The relationship between the elongation and the
rotation rate is obtained by averaging the transient shape variation. It is
shown that the elongation of two-robed shape is in good agreement
with the existing experimental data. It is found that the transient
numerical simulation is necessary for analyzing the largely elongated
two-robed shape of rotating droplet.
Abstract: In this paper, a watermarking algorithm that uses the wavelet transform with Multiple Description Coding (MDC) and Quantization Index Modulation (QIM) concepts is introduced. Also, the paper investigates the role of Contourlet Transform (CT) versus Wavelet Transform (WT) in providing robust image watermarking. Two measures are utilized in the comparison between the waveletbased and the contourlet-based methods; Peak Signal to Noise Ratio (PSNR) and Normalized Cross-Correlation (NCC). Experimental results reveal that the introduced algorithm is robust against different attacks and has good results compared to the contourlet-based algorithm.
Abstract: The use of hard and brittle material has become
increasingly more extensive in recent years. Therefore processing of
these materials for the parts fabrication has become a challenging
problem. However, it is time-consuming to machine the hard brittle
materials with the traditional metal-cutting technique that uses
abrasive wheels. In addition, the tool would suffer excessive wear as
well. However, if ultrasonic energy is applied to the machining
process and coupled with the use of hard abrasive grits, hard and
brittle materials can be effectively machined. Ultrasonic machining
process is mostly used for the brittle materials. The present research
work has developed models using finite element approach to predict
the mechanical stresses sand strains produced in the tool during
ultrasonic machining process. Also the flow behavior of abrasive
slurry coming out of the nozzle has been studied for simulation using
ANSYS CFX module. The different abrasives of different grit sizes
have been used for the experimentation work.
Abstract: Text categorization (the assignment of texts in natural language into predefined categories) is an important and extensively studied problem in Machine Learning. Currently, popular techniques developed to deal with this task include many preprocessing and learning algorithms, many of which in turn require tuning nontrivial internal parameters. Although partial studies are available, many authors fail to report values of the parameters they use in their experiments, or reasons why these values were used instead of others. The goal of this work then is to create a more thorough comparison of preprocessing parameters and their mutual influence, and report interesting observations and results.
Abstract: Rule Discovery is an important technique for mining knowledge from large databases. Use of objective measures for discovering interesting rules lead to another data mining problem, although of reduced complexity. Data mining researchers have studied subjective measures of interestingness to reduce the volume of discovered rules to ultimately improve the overall efficiency of KDD process. In this paper we study novelty of the discovered rules as a subjective measure of interestingness. We propose a hybrid approach that uses objective and subjective measures to quantify novelty of the discovered rules in terms of their deviations from the known rules. We analyze the types of deviation that can arise between two rules and categorize the discovered rules according to the user specified threshold. We implement the proposed framework and experiment with some public datasets. The experimental results are quite promising.
Abstract: Color Image quantization (CQ) is an important
problem in computer graphics, image and processing. The aim of
quantization is to reduce colors in an image with minimum distortion.
Clustering is a widely used technique for color quantization; all
colors in an image are grouped to small clusters. In this paper, we
proposed a new hybrid approach for color quantization using firefly
algorithm (FA) and K-means algorithm. Firefly algorithm is a swarmbased
algorithm that can be used for solving optimization problems.
The proposed method can overcome the drawbacks of both
algorithms such as the local optima converge problem in K-means
and the early converge of firefly algorithm. Experiments on three
commonly used images and the comparison results shows that the
proposed algorithm surpasses both the base-line technique k-means
clustering and original firefly algorithm.
Abstract: Transesterification of candlenut (aleurites moluccana)
oil with methanol using potassium hydroxide as catalyst was
studied. The objective of the present investigation was to produce
the methyl ester for use as biodiesel. The operation variables
employed were methanol to oil molar ratio (3:1 – 9:1), catalyst
concentration (0.50 – 1.5 %) and temperature (303 – 343K). Oil
volume of 150 mL, reaction time of 75 min were fixed as common
parameters in all the experiments. The concentration of methyl ester
was evaluated by mass balance of free glycerol formed which was
analyzed by using periodic acid. The optimal triglyceride conversion
was attained by using methanol to oil ratio of 6:1, potassium
hydroxide as catalyst was of 1%, at room temperature. Methyl ester
formed was characterized by its density, viscosity, cloud and pour
points. The biodiesel properties had properties similar to those of
diesel oil, except for the viscosity that was higher.
Abstract: In the present study, fracture behavior of woven
fabric-reinforced glass/epoxy composite laminates under mode III
crack growth was experimentally investigated and numerically
modeled. Two methods were used for the calculation of the strain
energy release rate: the experimental compliance calibration (CC)
method and the Virtual Crack Closure Technique (VCCT). To
achieve this aim ECT (Edge Crack Torsion) was used to evaluate
fracture toughness in mode III loading (out of plane-shear) at
different crack lengths. Load–displacement and associated energy
release rates were obtained for various case of interest. To
calculate fracture toughness JIII, two criteria were considered
including non-linearity and maximum points in load-displacement
curve and it is observed that JIII increases with the crack length
increase. Both the experimental compliance method and the virtual
crack closure technique proved applicable for the interpretation of the
fracture mechanics data of woven glass/epoxy laminates in mode III.
Abstract: The chemical degradation of dieldrin in ferric
sulfide and iron powder aqueous suspension was investigated
in laboratory batch type experiments. To identify the reaction
mechanism, reduced copper was used as reductant. More than
90% of dieldrin was degraded using both reaction systems after
29 days. Initial degradation rate of the pesticide using ferric
sulfide was superior to that using iron powder. The reaction
schemes were completely dissimilar even though the ferric ion
plays an important role in both reaction systems. In the case of
metallic iron powder, dieldrin undergoes partial dechlorination.
This reaction proceeded by reductive hydrodechlorination with
the generation of H+, which arise by oxidation of ferric iron.
This reductive reaction was accelerated by reductant but
mono-dechlorination intermediates were accumulated. On the
other hand, oxidative degradation was observed in the reaction
with ferric sulfide, and the stable chemical structure of dieldrin
was decomposed into water-soluble intermediates. These
reaction intermediates have no chemical structure of drin class.
This dehalogenation reaction assumes to occur via the adsorbed
hydroxyl radial generated on the surface of ferric sulfide.
Abstract: Resins are used in nuclear power plants for water
ultrapurification. Two approaches are considered in this work:
column experiments and simulations. A software called OPTIPUR
was developed, tested and used. The approach simulates the onedimensional
reactive transport in porous medium with convectivedispersive
transport between particles and diffusive transport within
the boundary layer around the particles. The transfer limitation in the
boundary layer is characterized by the mass transfer coefficient
(MTC). The influences on MTC were measured experimentally. The
variation of the inlet concentration does not influence the MTC; on
the contrary of the Darcy velocity which influences. This is consistent
with results obtained using the correlation of Dwivedi&Upadhyay.
With the MTC, knowing the number of exchange site and the relative
affinity, OPTIPUR can simulate the column outlet concentration
versus time. Then, the duration of use of resins can be predicted in
conditions of a binary exchange.