Abstract: Coal mining is well known to cause considerable environmental impacts, including trace element contamination of soil. This study aimed to assess the trace element (As, Cd, Co, Cu, Ni, Pb, Sb, and Zn) contamination of soil in the vicinity of coal mining activities, using the case study of Asam-asam River basin, South Kalimantan, Indonesia, and to assess the human health risk, incorporating total and bioavailable (water-leachable and acid-leachable) concentrations. The results show the enrichment of As and Co in soil, surpassing the background soil value. Contamination was evaluated based on the index of geo-accumulation, Igeo and the pollution index, PI. Igeo values showed that the soil was generally uncontaminated (Igeo ≤ 0), except for elevated As and Co. Mean PI for Ni and Cu indicated slight contamination. Regarding the assessment of health risks, the Hazard Index, HI showed adverse risks (HI > 1) for Ni, Co, and As. Further, Ni and As were found to pose unacceptable carcinogenic risk (risk > 1.10-5). Farming, settlement, and plantation were found to present greater risk than coal mines. These results show that coal mining activity in the study area contaminates the soils by particular elements and may pose potential human health risk in its surrounding area. This study is important for setting appropriate countermeasure actions and improving basic coal mining management in Indonesia.
Abstract: The chemical degradation of dieldrin in ferric
sulfide and iron powder aqueous suspension was investigated
in laboratory batch type experiments. To identify the reaction
mechanism, reduced copper was used as reductant. More than
90% of dieldrin was degraded using both reaction systems after
29 days. Initial degradation rate of the pesticide using ferric
sulfide was superior to that using iron powder. The reaction
schemes were completely dissimilar even though the ferric ion
plays an important role in both reaction systems. In the case of
metallic iron powder, dieldrin undergoes partial dechlorination.
This reaction proceeded by reductive hydrodechlorination with
the generation of H+, which arise by oxidation of ferric iron.
This reductive reaction was accelerated by reductant but
mono-dechlorination intermediates were accumulated. On the
other hand, oxidative degradation was observed in the reaction
with ferric sulfide, and the stable chemical structure of dieldrin
was decomposed into water-soluble intermediates. These
reaction intermediates have no chemical structure of drin class.
This dehalogenation reaction assumes to occur via the adsorbed
hydroxyl radial generated on the surface of ferric sulfide.