Abstract: Extraction of Fe(III) from aqueous solution using Trin-
butyl Phosphate (TBP) as carrier needs a highly acidic medium
(>6N) as it favours formation of chelating complex FeCl3.TBP.
Similarly, stripping of Iron(III) from loaded organic solvents requires
neutral pH or alkaline medium to dissociate the same complex. It is
observed that TBP co-extracts acids along with metal, which causes
reversal of driving force of extraction and iron(III) is re-extracted
back from the strip phase into the feed phase during Liquid Emulsion
Membrane (LEM) pertraction. Therefore, rate of extraction of
different mineral acids (HCl, HNO3, H2SO4) using TBP with and
without presence of metal Fe(III) was examined. It is revealed that in
presence of metal acid extraction is enhanced. Determination of mass
transfer coefficient of both acid and metal extraction was performed
by using Bulk Liquid Membrane (BLM). The average mass transfer
coefficient was obtained by fitting the derived model equation with
experimentally obtained data. The mass transfer coefficient of the
mineral acid extraction is in the order of kHNO3 = 3.3x10-6m/s > kHCl =
6.05x10-7m/s > kH2SO4 = 1.85x10-7m/s. The distribution equilibria of
the above mentioned acids between aqueous feed solution and a
solution of tri-n-butyl-phosphate (TBP) in organic solvents have been
investigated. The stoichiometry of acid extraction reveals the
formation of TBP.2HCl, HNO3.2TBP, and TBP.H2SO4 complexes.
Moreover, extraction of Iron(III) by TBP in HCl aqueous solution
forms complex FeCl3.TBP.2HCl while in HNO3 medium forms
complex 3FeCl3.TBP.2HNO3
Abstract: Single crystals of Magnesium alloys such as Mg-1Al,
Mg-1Zn-0.5Y, Mg-3Li, and AZ31 alloys were successfully fabricated in this study by employing the modified Bridgman method. Single
crystals of pure Mg were also made in this study. To determine the exact orientation of crystals, Laue back-reflection method and pole figure measurement were carried out on each single crystal. Dimensions of single crystals were 10 mm in diameter and 120 mm in
length. Hardness and compression tests were conducted and the results
revealed that hardness and the strength strongly depended on the
orientation. The closer to basal one the orientation was, the higher hardness and compressive strength were. The effect of alloying was
not higher than that of orientation. After compressive deformation of single crystals, the orientation of the crystals was found to rotate and to be parallel to the basal orientation.
Abstract: This paper presents investigation effects of a sharp edged gust on aeroelastic behavior and time-domain response of a typical section model using Jones approximate aerodynamics for pure plunging motion. Flutter analysis has been done by using p and p-k methods developed for presented finite-state aerodynamic model for a typical section model (airfoil). Introduction of gust analysis as a linear set of ordinary differential equations in a simplified procedure has been carried out by using transformation into an eigenvalue problem.
Abstract: The Indian subcontinent is facing a massive challenge with regards to the energy security in member countries, i.e. providing a reliable source of electricity to facilitate development across various sectors of the economy and thereby achieve the developmental targets it has set for itself. A highly precarious situation exists in the subcontinent which is observed in the series of system failures which most of the times leads to system collapses-blackouts. To mitigate the issues related with energy security as well as keep in check the increasing supply demand gap, a possible solution that stands in front of the subcontinent is the deployment of an interconnected electricity ‘Supergrid’ designed to carry huge quanta of power across the sub continent as well as provide the infra structure for RES integration. This paper assesses the need and conditions for a Supergrid deployment and consequently proposes a meshed topology based on VSC HVDC converters for the Supergrid modeling.
Abstract: Massive use of places with strong tourist attraction
with the consequent possibility of losing place-identity produces
harmful effects on cities and their users. In order to mitigate this risk,
areas close to such places can be identified so as to widen the
visitor-s range of action and offer alternative activities integrated
with the main site. The cultural places and appropriate activities can
be identified using a method of analysis and design able to trace the
identity of the places, their characteristics and potential, and to
provide a sustainable improvement. The aim of this work is to
propose PlaceMaker as a method of urban analysis and design which
both detects elements that do not feature in traditional mapping and
which constitute the contemporary identity of the places, and
identifies appropriate project interventions. Two final complex maps
– the first of analysis and the second of design – respectively
represent the identity of places and project interventions. In order to
illustrate the method-s potential; the results of the experimentation
carried out in the Trevi-Pantheon route in Rome and the appropriate
interventions to decongest the area are illustrated.
Abstract: During last decades, developing multi-objective
evolutionary algorithms for optimization problems has found
considerable attention. Flexible job shop scheduling problem, as an
important scheduling optimization problem, has found this attention
too. However, most of the multi-objective algorithms that are
developed for this problem use nonprofessional approaches. In
another words, most of them combine their objectives and then solve
multi-objective problem through single objective approaches. Of
course, except some scarce researches that uses Pareto-based
algorithms. Therefore, in this paper, a new Pareto-based algorithm
called controlled elitism non-dominated sorting genetic algorithm
(CENSGA) is proposed for the multi-objective FJSP (MOFJSP). Our
considered objectives are makespan, critical machine work load, and
total work load of machines. The proposed algorithm is also
compared with one the best Pareto-based algorithms of the literature
on some multi-objective criteria, statistically.
Abstract: The influence of copper promoters and reaction
conditions on the formation of alcohols byproducts of a common
Fischer-Tropsch synthesis used iron-based catalysts were investigated.
A good compromise of 28%Cu/FeKLaSiO2 can lead to the
optimization of an improved Fischer-Tropsch catalyst. The product
distribution shifts towards hydrocarbons with increasing the reaction
temperature, while pressure promotes the formation of alcohols. It was
found that the production of either alcohols or hydrocarbons followed
A-S-F distributions, and their α parameters were essentially different
which indicated a competition in the growing chain between the two
species. TPD after acetaldehyde adsorption gave strong evidence of
the insertion of a C1 oxygen-containing species into an alkyl chain.
Abstract: Among the technologies available to reduce methane
emitted from the pig industry, biofiltration seems to be an effective
and inexpensive solution. In methane (CH4) biofiltration, nitrogen is
an important macronutrient for the microorganisms growth. The
objective of this research project was to study the effect of
ammonium (NH4
+) on the performance, the biomass production and
the nitrogen conversion of a biofilter treating methane. For NH4
+
concentrations ranging from 0.05 to 0.5 gN-NH4
+/L, the CH4 removal
efficiency and the dioxide carbon production rate decreased linearly
from 68 to 11.8 % and from 7.1 to 0.5 g/(m3-h), respectively. The dry
biomass content varied from 4.1 to 5.8 kg/(m3 filter bed). For the
same range of concentrations, the ammonium conversion decreased
while the specific nitrate production rate increased. The specific
nitrate production rate presented negative values indicating
denitrification in the biofilter.
Abstract: This study evaluated the microbiological quality
and the sensory characteristics of carp fillets processed by the
sousvide method when stored at 2 and 10 °C. Four different
combinations of sauced–storage were studied then stored at 2 or 10
°C was evaluate periodically sensory, microbiological and
chemical quality. Batches stored at 2 °C had lower growth rates of
mesophiles and psychrotrophs. Moreover, these counts decreased
by increasing the heating temperature and time. Staphylococcus
aureus, Bacillus cereus, Clostridium perfringens and Listeria
monocytogenes were not found in any of the samples. The heat
treatment of 90 °C for 15 min and sauced was the most effective to
ensure the safety and extend the shelf-life of sousvide carp
preserving its sensory characteristics. This study establishes the
microbiological quality of sous vide carp and emphasizes the
relevance of the raw materials, heat treatment and storage
temperature to ensure the safety of the product.
Abstract: In this study the integration of an absorption heat
pump (AHP) with the concentration section of an industrial pulp and
paper process is investigated using pinch technology. The optimum
design of the proposed water-lithium bromide AHP is then achieved
by minimizing the total annual cost. A comprehensive optimization is
carried out by relaxation of all stream pressure drops as well as heat
exchanger areas involving in AHP structure. It is shown that by
applying genetic algorithm optimizer, the total annual cost of the
proposed AHP is decreased by 18% compared to one resulted from
simulation.
Abstract: Magnetic carbon nanotubes composites were obtained
by filling carbon nanotubes with paramagnetic iron oxide particles.
Detailed investigation of magnetic behaviour of resulting composites
was done at different temperatures. Measurements indicate that these
functionalized nanotubes are superparamagnetic at room temperature;
however, no superparamagnetism was observed at 125 K and 80 K.
The blocking temperature TB was estimated at 145 K. These magnetic
carbon nanotubes have the potential of being used in a wide range of
applications, in particular, the production of nanofluids, which can be
controlled and steered by appropriate magnetic fields.
Abstract: In this paper, enhanced ground proximity warning simulation and validation system is designed and implemented. First, based on square grid and sub-grid structure, the global digital terrain database is designed and constructed. Terrain data searching is implemented through querying the latitude and longitude bands and separated zones of global terrain database with the current aircraft position. A combination of dynamic scheduling and hierarchical scheduling is adopted to schedule the terrain data, and the terrain data can be read and delete dynamically in the memory. Secondly, according to the scope, distance, approach speed information etc. to the dangerous terrain in front, and using security profiles calculating method, collision threat detection is executed in real-time, and provides caution and warning alarm. According to this scheme, the implementation of the enhanced ground proximity warning simulation system is realized. Simulations are carried out to verify a good real-time in terrain display and alarm trigger, and the results show simulation system is realized correctly, reasonably and stable.
Abstract: In this article, we synthesize a novel chitosan -based
superabsorbent hydrogel via graft copolymerization of mixtures
acrylic acid (AA) and N-vinyl pyrollidon onto chitosan backbones.
The polymerization reaction was carried out in an aqueous medium
and in the presence of ammonium persulfate (APS) as an initiator and
N,N'-methylene bisacrylamide (MBA) as a crosslinker.The hydrogel
structures were confirmed by FTIR spectroscopy. The swelling
behavior of these absorbent polymers was also investigated in
various salt solutions. Results indicated that the swelling capacity
decreased with an increase in the ionic strength of the swelling
medium. Furthermore, the swelling of superabsorbing hydrogels was
examined in solutions with pH values ranging between 1.0 and 13.0.
It showed a reversible pH-responsive behavior at pHs 2.0 and 8.0.
This on-off switching behavior makes the synthesized hydrogels as
an excellent candidate for controlled delivery of bioactive agents.
Abstract: There is inadequate information on the practice of
female genital mutilation (FGM) in the UK, and there are often
myths and perceptions within communities that influence the
effectiveness of prevention programmes. This means it is difficult to
address the trends and changes in the practice in the UK.
To this end, FORWARD undertook novel and innovative research
using the Participatory Ethnographic and Evaluative Research
(PEER) method to explore the views of women from Eritrea, Sudan,
Somalia and Ethiopia that live in London and Bristol (two UK cities).
Women-s views, taken from PEER interviews, reflected reasons for
continued practice of FGM: marriageability, the harnessing and
control of female sexuality, and upholding traditions from their
countries of origin. It was also clear that the main supporters of the
practice were believed to be older women within families and
communities.
Women described the impact FGM was having on their lives as
isolating. And although it was clearly considered a private and
personal matter, they developed a real sense of connection with their
peers within the research process.
The women were overwhelmingly positive about combating the
practice, although they believed it would probably take a while
before it ends completely. They also made concrete
recommendations on how to improve support services for women
affected by FGM: Training for professionals (particularly in
healthcare), increased engagement with, and outreach to,
communities, culturally appropriate materials and information made
available and accessible to communities, and more consequent
implementation of legislation.
Finally, the women asked for more empathy and understanding,
particularly from health professionals. Rather than presenting FGM
as a completely alien and inconceivable practice, it may help for
those looking into these women-s lives and working with them to
understand the social and economic context in which the practice
takes place.
Abstract: Stable bacterial polymorphism on a single limiting resource may appear if between the evolved strains metabolic interactions take place that allow the exchange of essential nutrients [8]. Towards an attempt to predict the possible outcome of longrunning evolution experiments, a network based on the metabolic capabilities of homogeneous populations of every single gene knockout strain (nodes) of the bacterium E. coli is reconstructed. Potential metabolic interactions (edges) are allowed only between strains of different metabolic capabilities. Bacterial communities are determined by finding cliques in this network. Growth of the emerged hypothetical bacterial communities is simulated by extending the metabolic flux balance analysis model of Varma et al [2] to embody heterogeneous cell population growth in a mutual environment. Results from aerobic growth on 10 different carbon sources are presented. The upper bounds of the diversity that can emerge from single-cloned populations of E. coli such as the number of strains that appears to metabolically differ from most strains (highly connected nodes), the maximum clique size as well as the number of all the possible communities are determined. Certain single gene deletions are identified to consistently participate in our hypothetical bacterial communities under most environmental conditions implying a pattern of growth-condition- invariant strains with similar metabolic effects. Moreover, evaluation of all the hypothetical bacterial communities under growth on pyruvate reveals heterogeneous populations that can exhibit superior growth performance when compared to the performance of the homogeneous wild-type population.
Abstract: Pressure waves and Water Hammer occur in a
pumping system when valves are closed or opened suddenly or in
the case of sudden failure of pumps. Determination of maximum
water hammer is considered one of the most important technical
and economical items of which engineers and designers of
pumping stations and conveyance pipelines should take care.
Hammer Software is a recent application used to simulate water
hammer. The present study focuses on determining significance of
each input parameter of the application relative to the maximum
amount of water hammer estimated by the software. The study
determines estimated maximum water hammer variations due to
variations of input parameters including water temperature, pipe
type, thickness and diameter, electromotor rpm and power, and
moment of inertia of electromotor and pump. In our study,
Kuhrang Pumping Station was modeled using WaterGEMS
Software. The pumping station is characterized by total discharge
of 200 liters per second, dynamic height of 194 meters and 1.5
kilometers of steel conveyance pipeline and transports water to
Cheshme Morvarid for farmland irrigation. The model was run in
steady hydraulic condition and transferred to Hammer Software.
Then, the model was run in several unsteady hydraulic conditions
and sensitivity of maximum water hammer to each input parameter
was calculated. It is shown that parameters to which maximum
water hammer is most sensitive are moment of inertia of pump and
electromotor, diameter, type and thickness of pipe and water
temperature, respectively.
Abstract: The aim of this study is to develop mathematical
relationships for the performance parameter brake thermal efficiency
(BTE) and emission parameter nitrogen oxides (NOx) for the various
esters of vegetable oils used as CI engine fuel. The BTE is an
important performance parameter defining the ability of engine to
utilize the energy supplied and power developed similarly it is
indication of efficiency of fuels used. The esters of cottonseed oil,
soybean oil, jatropha oil and hingan oil are prepared using
transesterification process and characterized for their physical and
main fuel properties including viscosity, density, flash point and
higher heating value using standard test methods. These esters are
tried as CI engine fuel to analyze the performance and emission
parameters in comparison to diesel. The results of the study indicate
that esters as a fuel does not differ greatly with that of diesel in
properties. The CI engine performance with esters as fuel is in line
with the diesel where as the emission parameters are reduced with the
use of esters.
The correlation developed between BTE and brake power(BP),
gross calorific value(CV), air-fuel ratio(A/F), heat carried away by
cooling water(HCW). Another equation is developed between the
NOx emission and CO, HC, smoke density (SD), exhaust gas
temperature (EGT). The equations are verified by comparing the
observed and calculated values which gives the coefficient of
correlation of 0.99 and 0.96 for the BTE and NOx equations
respectively.
Abstract: In this paper a novel, simple and reliable digital firing
scheme has been implemented for speed control of three-phase
induction motor using ac voltage controller. The system consists of
three-phase supply connected to the three-phase induction motor via
three triacs and its control circuit. The ac voltage controller has three
modes of operation depending on the shape of supply current. The
performance of the induction motor differs in each mode where the
speed is directly proportional with firing angle in two modes and
inversely in the third one. So, the control system has to detect the
current mode of operation to choose the correct firing angle of triacs.
Three sensors are used to feed the line currents to control system to
detect the mode of operation. The control strategy is implemented
using a low cost Xilinx Spartan-3E field programmable gate array
(FPGA) device. Three PI-controllers are designed on FPGA to
control the system in the three-modes. Simulation of the system is
carried out using PSIM computer program. The simulation results
show stable operation for different loading conditions especially in
mode 2/3. The simulation results have been compared with the
experimental results from laboratory prototype.
Abstract: Pyritisation halos are identified in weathering crusts and unconsolidated formations at five locations within large fault structure of the Urals’ eastern slope. Electron microscopy reveals the presence of inclusions and growths on pyrite faces – normally on cubic pyrite with striations, or combinations of cubes and other forms. Following neogenesis types are established: native elements and intermetallic compounds (including gold and silver), halogenides, sulphides, sulfosalts, tellurides, sulphotellurides,
selenides, tungstates, sulphates, phosphates, carbon-based substances. Direct relationship is noted between amount and diversity of such mineral phases, and proximity to and scale of ore-grade mineralization. Gold and silver, both in native form and within tellurides, presence of lead (galena, native lead), native tungsten, and, possibly, molybdenite and sulfosalts can indicate gold-bearing formations. First find of native tungsten in the Urals is for the first time – in crystallised and druse-like form. Link is suggested between unusual mineralization and “reducing” hydrothermal fluids from deep-seated faults at later stages of Urals’ reactivation.
Abstract: Coal tar is a liquid by-product of the process of coal
gasification and carbonation. This liquid oil mixture contains various
kinds of useful compounds such as phenol, o-cresol, and p-cresol.
These compounds are widely used as raw material for insecticides,
dyes, medicines, perfumes, coloring matters, and many others.
This research needed to be done that given the optimum conditions
for the separation of phenol, o-cresol, and p-cresol from the coal tar
by solvent extraction process. The aim of the present work was to
study the effect of two kinds of aqueous were used as solvents:
methanol and acetone solutions, the effect of temperature (298, 306,
and 313K) and mixing (30, 35, and 40rpm) for the separation of
phenol, o-cresol, and p-cresol from coal tar by solvent extraction.
Results indicated that phenol, o-cresol, and p-cresol in coal tar
were selectivity extracted into the solvent phase and these
components could be separated by solvent extraction. The aqueous
solution of methanol, mass ratio of solvent to feed, Eo/Ro=1,
extraction temperature 306K and mixing 35 rpm were the most
efficient for extraction of phenol, o-cresol, and p-cresol from coal tar.