Abstract: Polyurethanes (PURs) are very versatile polymeric
materials with a wide range of physical and chemical properties.
PURs have desirable properties such as high abrasion resistance, tear
strength, shock absorption, flexibility and elasticity. Although they
have relatively poor thermal stability, this can be improved by using
treated clay. Polyurethane/clay nanocomposites have been
synthesized from renewable sources. A polyol for the production of
polyurethane by reaction with an isocyanate was obtained by the
synthesis of palm oil-based oleic acid with glycerol. Dodecylbenzene
sulfonic acid (DBSA) was used as catalyst and emulsifier. The
unmodified clay (kunipia-F) was treated with cetyltrimethyl
ammonium bromide (CTAB-mont) and octadodecylamine (ODAmont).
The d-spacing in CTAB-mont and ODA-mont were 1.571 nm
and 1.798 nm respectively and larger than that of the pure-mont
(1.142 nm). The organoclay was completely intercalated in the
polyurethane, as confirmed by a wide angle x-ray diffraction
(WAXD) pattern.
The results showed that adding clay demonstrated better thermal
stability in comparison with the virgin polyurethane. Onset
degradation of pure PU is at 200oC, and is lower than that of the
CTAB-mont PU and ODA-mont PU which takes place at about
318oC and 330oC, respectively. The mechanical properties (including
the dynamic mechanical properties) of pure polyurethane (PU) and
PU/clay nanocomposites, were measured. The modified organoclay
had a remarkably beneficial effect on the strength and elongation at
break of the nanocomposites, which both increased with increasing
clay content with the increase of the tensile strength of more than
214% and 267% by the addition of only 5 wt% of the
montmorillonite CTAB-mont PU and ODA-mont PU, respectively.
Abstract: In the Lost Foam Casting process, melting point
temperature of metal, as well as volume and rate of the foam
degradation have significant effect on the mold filling pattern.
Therefore, gas generation capacity and gas gap length are two
important parameters for modeling of mold filling time of the lost
foam casting processes. In this paper, the gas gap length at the liquidfoam
interface for a low melting point (aluminum) alloy and a high
melting point (Carbon-steel) alloy are investigated by the
photography technique. Results of the photography technique
indicated, that the gas gap length and the mold filling time are
increased with increased coating thickness and density of the foam.
The Gas gap lengths measured in aluminum and Carbon-steel,
depend on the foam density, and were approximately 4-5 and 25-60
mm, respectively. By using a new system, the gas generation
capacity for the aluminum and steel was measured. The gas
generation capacity measurements indicated that gas generation in
the Aluminum and Carbon-steel lost foam casting was about 50 CC/g
and 3200 CC/g polystyrene, respectively.
Abstract: This paper presents a novel method for data hiding based on neighborhood pixels information to calculate the number of bits that can be used for substitution and modified Least Significant Bits technique for data embedding. The modified solution is independent of the nature of the data to be hidden and gives correct results along with un-noticeable image degradation. The technique, to find the number of bits that can be used for data hiding, uses the green component of the image as it is less sensitive to human eye and thus it is totally impossible for human eye to predict whether the image is encrypted or not. The application further encrypts the data using a custom designed algorithm before embedding bits into image for further security. The overall process consists of three main modules namely embedding, encryption and extraction cm.
Abstract: Pentachlorophenol (PCP) is a polychlorinated
aromatic compound that is widespread in industrial effluents and is
considered to be a serious pollutant. Among the variety of industrial
effluents encountered, effluents from tanning industry are very
important and have a serious pollution potential. PCP is also formed
unintentionally in effluents of paper and pulp industries. It is highly
persistent in soils and is lethal to a wide variety of beneficial
microorganisms and insects, human beings and animals. The natural
processes that breakdown toxic chemicals in the environment have
become the focus of much attention to develop safe and environmentfriendly
deactivation technologies. Microbes and plants are among
the most important biological agents that remove and degrade waste
materials to enable their recycling in the environment. The present
investigation was carried out with the aim of developing a microbial
system for bioremediation of PCP polluted soils. A number of plant
species were evaluated for their ability to tolerate different
concentrations of pentachlorophenol (PCP) in the soil. The
experiment was conducted for 30 days under pot culture conditions.
The toxic effect of PCP on plants was studied by monitoring seed
germination, plant growth and biomass. As the concentration of PCP
was increased to 50 ppm, the inhibition of seed germination, plant
growth and biomass was also increased. Although PCP had a
negative effect on all plant species tested, maize and groundnut
showed the maximum tolerance to PCP. Other tolerating crops
included wheat, safflower, sunflower, and soybean. From the
rhizosphere soil of the tolerant seedlings, as many as twenty seven
PCP tolerant bacteria were isolated. From soybean, 8; sunflower, 3;
safflower 8; maize 2; groundnut and wheat, 3 each isolates were
made. They were screened for their PCP degradation potentials.
HPLC analyses of PCP degradation revealed that the isolate MAZ-2
degraded PCP completely. The isolate MAZ-1 was the next best
isolate with 90 per cent PCP degradation. These strains hold promise
to be used in the bioremediation of PCP polluted soils.
Abstract: In this paper, a novel feature-based image
watermarking scheme is proposed. Zernike moments which have
invariance properties are adopted in the scheme. In the proposed
scheme, feature points are first extracted from host image and several
circular patches centered on these points are generated. The patches
are used as carriers of watermark information because they can be
regenerated to locate watermark embedding positions even when
watermarked images are severely distorted. Zernike transform is then
applied to the patches to calculate local Zernike moments. Dither
modulation is adopted to quantize the magnitudes of the Zernike
moments followed by false alarm analysis. Experimental results show
that quality degradation of watermarked image is visually
transparent. The proposed scheme is very robust against image
processing operations and geometric attacks.
Abstract: techniques are examined to overcome the
performance degradation caused by the channel dispersion using
slow frequency hopping (SFH) with dynamic frequency hopping
(DFH) pattern adaptation. In DFH systems, the frequency slots are
selected by continuous quality monitoring of all frequencies available
in a system and modification of hopping patterns for each individual
link based on replacing slots which its signal to interference ratio
(SIR) measurement is below a required threshold. Simulation results
will show the improvements in BER obtained by DFH in comparison
with matched frequency hopping (MFH), random frequency hopping
(RFH) and multi-carrier code division multiple access (MC-CDMA)
in multipath slowly fading dispersive channels using a generalized
bandpass two-path transfer function model, and will show the
improvement obtained according to the threshold selection.
Abstract: Pabdeh shaly formation (Paleocene-Oligomiocene)
has been expanded in Fars, Khozestan and Lorestan. The lower
lithostratigraphic limit of this formation in Shiraz area is
distinguished from Gurpi formation by purple shale. Its upper limit is
gradational and conformable with Asmari formation. In order to
study sequence stratigraphy and microfacies of Pabdeh formation in
Shiraz area, one stratigraphic section have been chosen (Zanjiran
section). Petrographic studies resulted in the identification of 9
pelagic and calciturbidite microfacies. The calciturbidite microfacies
have been formed when the sea level was high, the rate of carbonate
deposition was high and it slumped into the deep marine. Sequence
stratigraphy studies show that Pabdeh formation in the studied zone
consists of two depositional sequences (DS) that the lower contact is
erosional (purple shale - type one, SBI or type two, SB2) and the
upper contact is correlative conformity (type two, SB2).
Abstract: Power transformer consists of components which are
under consistent thermal and electrical stresses. The major
component which degrades under these stresses is the paper
insulation of the power transformer. At site, lightning impulses and
cable faults may cause the winding deformation. In addition, the
winding may deform due to impact during transportation. A
deformed winding will excite more stress to its insulating paper thus
will degrade it. Insulation degradation will shorten the life-span of
the transformer. Currently there are two methods of detecting the
winding deformation which are Sweep Frequency Response
Analysis (SFRA) and Low Voltage Impulse Test (LVI). The latter
injects current pulses to the winding and capture the admittance
plot. In this paper, a transformer which experienced overheating and
arcing was identified, and both SFRA and LVI were performed.
Next, the transformer was brought to the factory for untanking. The
untanking results revealed that the LVI is more accurate than the
SFRA method for this case study.
Abstract: Digital watermarking has become an important technique for copyright protection but its robustness against attacks remains a major problem. In this paper, we propose a normalizationbased robust image watermarking scheme. In the proposed scheme, original host image is first normalized to a standard form. Zernike transform is then applied to the normalized image to calculate Zernike moments. Dither modulation is adopted to quantize the magnitudes of Zernike moments according to the watermark bit stream. The watermark extracting method is a blind method. Security analysis and false alarm analysis are then performed. The quality degradation of watermarked image caused by the embedded watermark is visually transparent. Experimental results show that the proposed scheme has very high robustness against various image processing operations and geometric attacks.
Abstract: Land degradation is of concern in many countries. People more and more must address the problems associated with the degradation of soil properties due to man. Increasingly, organic soil amendments, such as compost are being examined for their potential use in soil restoration and for preventing soil erosion. In the Czech Republic, compost is the most used to improve soil structure and increase the content of soil organic matter. Land reclamation / restoration is one of the ways to evaluate industrially produced compost because Czech farmers are not willing to use compost as organic fertilizer. The most common use of reclamation substrates in the Czech Republic is for the rehabilitation of landfills and contaminated sites.
This paper deals with the influence of reclamation substrates (RS) with different proportions of compost and sand on selected soil properties–chemical characteristics, nitrogen bioavailability, leaching of mineral nitrogen, respiration activity and plant biomass production. Chemical properties vary proportionally with addition of compost and sand to the control variant (topsoil). The highest differences between the variants were recorded in leaching of mineral nitrogen (varies from 1.36mg dm-3 in C to 9.09mg dm-3). Addition of compost to soil improves conditions for plant growth in comparison with soil alone. However, too high addition of compost may have adverse effects on plant growth. In addition, high proportion of compost increases leaching of mineral N. Therefore, mixture of 70% of soil with 10% of compost and 20% of sand may be recommended as optimal composition of RS.
Abstract: The aim of this study was to screen for
microorganism that able to utilize 3-N-trimethylamino-1-propanol
(homocholine) as a sole source of carbon and nitrogen. The aerobic
degradation of homocholine has been found by a gram-positive
Rhodococcus sp. bacterium isolated from soil. The isolate was
identified as Rhodococcus sp. strain A4 based on the phenotypic
features, physiologic and biochemical characteristics, and
phylogenetic analysis. The cells of the isolated strain grown on both
basal-TMAP and nutrient agar medium displayed elementary
branching mycelia fragmented into irregular rod and coccoid
elements. Comparative 16S rDNA sequencing studies indicated that
the strain A4 falls into the Rhodococcus erythropolis subclade and
forms a monophyletic group with the type-strains of R. opacus, and
R. wratislaviensis. Metabolites analysis by capillary electrophoresis,
fast atom bombardment-mass spectrometry, and gas
chromatography- mass spectrometry, showed trimethylamine (TMA)
as the major metabolite beside β-alanine betaine and
trimethylaminopropionaldehyde. Therefore, the possible degradation
pathway of trimethylamino propanol in the isolated strain is through
consequence oxidation of alcohol group (-OH) to aldehyde (-CHO)
and acid (-COOH), and thereafter the cleavage of β-alanine betaine
C-N bonds yielded trimethylamine and alkyl chain.
Abstract: Distant-talking voice-based HCI system suffers from
performance degradation due to mismatch between the acoustic
speech (runtime) and the acoustic model (training). Mismatch is
caused by the change in the power of the speech signal as observed at
the microphones. This change is greatly influenced by the change in
distance, affecting speech dynamics inside the room before reaching
the microphones. Moreover, as the speech signal is reflected, its
acoustical characteristic is also altered by the room properties. In
general, power mismatch due to distance is a complex problem. This
paper presents a novel approach in dealing with distance-induced
mismatch by intelligently sensing instantaneous voice power variation
and compensating model parameters. First, the distant-talking speech
signal is processed through microphone array processing, and the
corresponding distance information is extracted. Distance-sensitive
Gaussian Mixture Models (GMMs), pre-trained to capture both
speech power and room property are used to predict the optimal
distance of the speech source. Consequently, pre-computed statistic
priors corresponding to the optimal distance is selected to correct
the statistics of the generic model which was frozen during training.
Thus, model combinatorics are post-conditioned to match the power
of instantaneous speech acoustics at runtime. This results to an
improved likelihood in predicting the correct speech command at
farther distances. We experiment using real data recorded inside two
rooms. Experimental evaluation shows voice recognition performance
using our method is more robust to the change in distance compared
to the conventional approach. In our experiment, under the most
acoustically challenging environment (i.e., Room 2: 2.5 meters), our
method achieved 24.2% improvement in recognition performance
against the best-performing conventional method.
Abstract: The removal efficiency of 4-chlorophenol with
different advanced oxidation processes have been studied. Oxidation
experiments were carried out using two 4-chlorophenol
concentrations: 100 mg L-1 and 250 mg L-1 and UV generated from a
KrCl excilamp with (molar ratio H2O2: 4-chlorophenol = 25:1) and
without H2O2, and, with Fenton process (molar ratio H2O2:4-
chlorophenol of 25:1 and Fe2+ concentration of 5 mg L-1).
The results show that there is no significant difference in the 4-
chlorophenol conversion when using one of the three assayed
methods. However, significant concentrations of the photoproductos
still remained in the media when the chosen treatment involves UV
without hydrogen peroxide. Fenton process removed all the
intermediate photoproducts except for the hydroquinone and the
1,2,4-trihydroxybenzene. In the case of UV and hydrogen peroxide
all the intermediate photoproducts are removed.
Microbial bioassays were carried out utilising the naturally
luminescent bacterium Vibrio fischeri and a genetically modified
Pseudomonas putida isolated from a waste treatment plant receiving
phenolic waste. The results using V. fischeri show that with samples
after degradation, only the UV treatment showed toxicity (IC50 =38)
whereas with H2O2 and Fenton reactions the samples exhibited no
toxicity after treatment in the range of concentrations studied. Using
the Pseudomonas putida biosensor no toxicity could be detected for
all the samples following treatment due to the higher tolerance of the
organism to phenol concentrations encountered.
Abstract: The performance of a sucrose-based H2 production in
a completely stirred tank reactor (CSTR) was modeled by neural
network back-propagation (BP) algorithm. The H2 production was
monitored over a period of 450 days at 35±1 ºC. The proposed model
predicts H2 production rates based on hydraulic retention time
(HRT), recycle ratio, sucrose concentration and degradation, biomass
concentrations, pH, alkalinity, oxidation-reduction potential (ORP),
acids and alcohols concentrations. Artificial neural networks (ANNs)
have an ability to capture non-linear information very efficiently. In
this study, a predictive controller was proposed for management and
operation of large scale H2-fermenting systems. The relevant control
strategies can be activated by this method. BP based ANNs modeling
results was very successful and an excellent match was obtained
between the measured and the predicted rates. The efficient H2
production and system control can be provided by predictive control
method combined with the robust BP based ANN modeling tool.
Abstract: Human middle-ear is the key component of the
auditory system. Its function is to transfer the sound waves through
the ear canal to provide sufficient stimulus to the fluids of the inner
ear. Degradation of the ossicles that transmit these sound waves from
the eardrum to the inner ear leads to hearing loss. This problem can
be overcome by replacing one or more of these ossicles by middleear
prosthesis. Designing such prosthesis requires a comprehensive
knowledge of the biomechanics of the middle-ear. There are many
finite element modeling approaches developed to understand the
biomechanics of the middle ear. The available models in the
literature, involve high computation time. In this paper, we propose a
simplified model which provides a reasonably accurate result with
much less computational time. Simulation results indicate a
maximum sound pressure gain of 10 dB at 5500 Hz.
Abstract: Degradation of polymeric insulation systems of
electrical equipments increases the space charge density and the
concentration of electrical dipoles. By consequence, the maximum
values and the slopes of absorption/resorption (A/R) currents can
change with insulation systems ageing. In this paper, an analysis of
the nature of the A/R currents and the importance of their
components, especially the polarization current and the current given
by the space charge, is presented. The experimental study concerns
the A/R currents measurements of plane samples (made from
CALMICAGLAS tapes), virgin and thermally accelerated aged. The
obtained results show that the ageing process produces an increase of
the values and a decrease of shapes of the A/R currents. Finally, the
possibility of estimating insulations ageing state and lifetime from
A/R currents measurements is discussed.
Abstract: This research was conducted in the Lower Namkam
Irrigation Project situated in the Namkam River Basin in Thailand.
Degradation of groundwater quality in some areas is caused by saline
soil spots beneath ground surface. However, the tail regulated gate
structure on the Namkam River, a lateral stream of the Mekong
River. It is aimed for maintaining water level in the river at +137.5 to
+138.5 m (MSL) and flow to the irrigation canals based on a gravity
system since July 2009. It might leach some saline soil spots from
underground to soil surface if lack of understanding of the
conjunctive surface water and groundwater behaviors. This research
has been conducted by continuously the observing of both shallow
and deep groundwater level and quality from existing observation
wells. The simulation of surface water was carried out using a
hydrologic modeling system (HEC-HMS) to compute the ungauged
side flow catchments as the lateral flows for the river system model
(HEC-RAS). The constant water levels in the upstream of the
operated gate caused a slight rising up of shallow groundwater level
when compared to the water table. However, the groundwater levels
in the confined aquifers remained less impacted than in the shallow
aquifers but groundwater levels in late of wet season in some wells
were higher than the phreatic surface. This causes salinization of the
groundwater at the soil surface and might affect some crops. This
research aims for the balance of water stage in the river and efficient
groundwater utilization in this area.
Abstract: Land use change, if not based on proper scientific
investigation affects other physical, chemical, and biological
properties of soil and leading to increased destruction and erosion. It
was imperative to study the effects of changing rangelands to
farmlands on some Soil quality indexes. Undisturbed soil samples
were collected from the depths of 0-10 and 10-30 centimeter in
pasture with good vegetation cover(GP), pasture with medium
vegetation cover(MP), abandoned dry land farming(ADF) and
degraded dry land farming(DDF) land uses in Ghareh Aghaj
watershed of Isfahan province. The results revealed that organic
matter(OM), cation exchange capacity(CEC) and available
potassium(AK) decreasing in the depth of 0-10 centimeter were 66.6,
38.8 and 70 percent and in the depth of 10-30 centimeter were 58,
61.4 and 83.5 percent respectively in DDF comparison with GP.
Concerning to the results, it seems that land use change can decrease
soil quality and increase soil degradation and lead in undesirable
consequences.
Abstract: The need to evaluate and understand the natural
drainage pattern in a flood prone, and fast developing environment is
of paramount importance. This information will go a long way to
help the town planners to determine the drainage pattern, road
networks and areas where prominent structures are to be located. This
research work was carried out with the aim of studying the Bayelsa
landscape topography using digitized topographic information, and to
model the natural drainage flow pattern that will aid the
understanding and constructions of workable drainages. To achieve
this, digitize information of elevation and coordinate points were
extracted from a global imagery map. The extracted information was
modeled into 3D surfaces. The result revealed that the average
elevation for Bayelsa State is 12 m above sea level. The highest
elevation is 28 m, and the lowest elevation 0 m, along the coastline.
In Yenagoa the capital city of Bayelsa were a detail survey was
carried out showed that average elevation is 15 m, the highest
elevation is 25 m and lowest is 3 m above the mean sea level. The
regional elevation in Bayelsa, showed a gradation decrease from the
North Eastern zone to the South Western Zone. Yenagoa showed an
observed elevation lineament, were low depression is flanked by high
elevation that runs from the North East to the South west. Hence,
future drainages in Yenagoa should be directed from the high
elevation, from South East toward the North West and from the
North West toward South East, to the point of convergence which is
at the center that flows from South East toward the North West.
Bayelsa when considered on a regional Scale, the flow pattern is from
the North East to the South West, and also North South. It is
recommended that in the event of any large drainage construction at
municipal scale, it should be directed from North East to the South
West or from North to South. Secondly, detail survey should be
carried out to ascertain the local topography and the drainage pattern
before the design and construction of any drainage system in any part
of Bayelsa.
Abstract: This paper presents the results of the preliminary investigation of microwave (MW) irradiation pretreatments on the anaerobic digestion of food residues using biochemical methane potential (BMP) assays. Low solids systems with a total solids (TS) content ranging from 5.0-10.0% were analyzed. The inoculum to bulk mass of substrates to water ratio was 1:2:2 (mass basis). The experimental conditions for pretreatments were as follows: a control (no MW irradiation), two runs with MW irradiation for 15 and 30 minutes at 320 W, and another two runs with MW irradiation at 528 W for 30 and 60 minutes. The cumulative biogas production were 6.3 L and 8.7 L for 15min/320 W and 30min/320 W MW irradiation conditions, respectively, and 10.5 L and 11.4 L biogas for 30min/528 W and 60min/528 W, respectively, as compared to the control giving 5.8 L biogas. Both an increase in exposure time of irradiation and power of MW had increased the rate and yield of biogas. Singlefactor ANOVA tests (p