Abstract: High purity hydrogen and the valuable by-product of carbon nanotubes (CNTs) can be produced by the methane catalytic decomposition. The methane conversion and the performance of CNTs were determined by the choices of catalysts and the condition of decomposition reaction. In this paper, Ni/MgO and Ni/O-D (oxidized diamond) catalysts were prepared by wetness impregnation method. The effects of reaction temperature and space velocity of methane on the methane conversion were investigated in a fixed-bed. The surface area, structure and micrography were characterized with BET, XPS, SEM, EDS technology. The results showed that the conversion of methane was above 8% within 150 min (T=500) for 33Ni/O-D catalyst and higher than 25% within 120 min (T=650) for 41Ni/MgO catalyst. The initial conversion increased with the increasing temperature of the decomposition reaction, but their catalytic activities decreased rapidly while at too higher temperature. To decrease the space velocity of methane was propitious to promote the methane conversion, but not favor of the hydrogen yields. The appearance of carbon resulted from the methane decomposition lied on the support type and the condition of catalytic reaction. It presented as fiber shape on the surface of Ni/O-D at the relatively lower temperature such as 500 and 550, but as grain shape stacked on and overlayed on the surface of the metal nickel while at 650. The carbon fiber can form on the Ni/MgO surface at 650 and the diameter of the carbon fiber increased with the decreasing space velocity.
Abstract: The purpose of this study is to investigate the capacity
of natural Turkish zeolite for NH4-N removal from landfill leachate.
The effects of modification and initial concentration on the removal
of NH4-N from leachate were also investigated. The kinetics of
adsorption of NH4-N has been discussed using three kinetic models,
i.e., the pseudo-second order model, the Elovich equation, the
intraparticle diffuion model. Kinetic parameters and correlation
coefficients were determined. Equilibrium isotherms for the
adsorption of NH4-N were analyzed by Langmuir, Freundlich and
Tempkin isotherm models. Langmuir isotherm model was found to
best represent the data for NH4-N.
Abstract: Megalopolis is a group of densely populated metropolitan areas that combine to form an urban complex. Since China introduced the economic reforms in late 1970s, the Chinese urban system has experienced unprecedented growth. The process of urbanisation prevailed in the 1980s, and the process of predominantly large city growth appeared to continue through 1990s and 2000s. In this study, the magnitude and pattern of urbanisation in China during 1990s were examined using remotely sensed imagery acquired by TM/ETM+ sensor onboard the Landsat satellites. The development of megalopolis areas in China was also studied based on the GIS analysis of the increases of urban and built-up area from 1990 to 2000. The analysis suggests that in the traditional agricultural zones in China, e.g., Huang-Huai-Hai Plains, Changjiang River Delta, Pearl River Delta and Sichuan Basin, the urban and built-up areas increased by 1.76 million hectares, of which 0.82 million hectares are expansion of urban areas, an increase of 24.78% compared with 1990 at the national scale. The Yellow River Delta, Changjiang River Delta and Pearl River Delta also saw an increase of urban and built-up area by 63.9%, 66.2% and 83.0% respectively. As a result, three major megalopolises were developed in China: the Guangzhou-Shenzhen-Hong Kong- Macau (Pearl River Delta: PRD) megalopolis area, the Shanghai- Nanjing-Hangzhou (Changjiang River Delta: CRD) megalopolis area and the Beijing-Tianjing-Tangshan-Qinhuangdao (Yellow River Delta-Bohai Sea Ring: YRD) megalopolis area. The relationship between the processed of megalopolisation and the inter-provincial population flow was also explored in the context of social-economic and transport infrastructure development in Post-reform China.
Abstract: The toxicity of aqueous extracts of two plants,
Nicotiana tobacum and Eucalyptus globulus were investigated against second instar larvae of Lycoriella auripila, one of the most
important pests of button mushroom, using agar dilution technique.
Seven concentrations of aqueous extracts of both plants were applied
on second instar larvae and their mortality were evaluated after 24, 48 and 72 h. The obtained results revealed that aqueous extracts of N.
tabacum and E. globulus caused 77.55 and 72.5% mortality of larvae
of L. auripila at concentration of 4000 ppm after 72h, respectively. Toxicities of tobacco extract after 24, 48 and 72 h were 1.52, 1.85
and 1.70 times greather than eucalyptus, respectively. The estimated LC50 after 24, 48 and 72 h were 7316.5, 2468.5 and 2013.1 ppm for
tobacco and 64870.0, 6839.5 and 3326.4 ppm for eucalyptus, respectively. These plants merit further study as potential insecticides
for the control of L. auripila.
Abstract: This work was to study batch biosorption of Pb(II)
ions from aqueous solution by Luffa charcoal. The effect of operating
parameters such as adsorption contact time, initial pH solution and
different initial Pb(II) concentration on the sorption of Pb(II) were
investigated. The results showed that the adsorption of Pb(II) ions
was initially rapid and the equilibrium time was 10 h. Adsorption
kinetics of Pb(II) ions onto Luffa charcoal could be best described by
the pseudo-second order model. At pH 5.0 was favorable for the
adsorption and removal of Pb(II) ions. Freundlich adsorption
isotherm model was better fitted for the adsorption of Pb(II) ions than
Langmuir and Timkin isotherms, respectively. The highest monolayer
adsorption capacity obtained from Langmuir isotherm model was
51.02 mg/g. This study demonstrated that Luffa charcoal could be
used for the removal of Pb(II) ions in water treatment.
Abstract: CO2 is the primary anthropogenic greenhouse gas,
accounting for 77% of the human contribution to the greenhouse
effect in 2004. In the recent years, global concentration of CO2 in the
atmosphere is increasing rapidly. CO2 emissions have an impact on
global climate change. Anthropogenic CO2 is emitted primarily from
fossil fuel combustion. Carbon capture and storage (CCS) is one
option for reducing CO2 emissions. There are three major approaches
for CCS: post-combustion capture, pre-combustion capture and
oxyfuel process. Post-combustion capture offers some advantages as
existing combustion technologies can still be used without radical
changes on them.
There are several post combustion gas separation and capture
technologies being investigated, namely; (a) absorption, (b)
cryogenic separation, (c) membrane separation (d) micro algal biofixation
and (e) adsorption. Apart from establishing new techniques,
the exploration of capture materials with high separation performance
and low capital cost are paramount importance. However, the
application of adsorption from either technology, require easily
regenerable and durable adsorbents with a high CO2 adsorption
capacity. It has recently been reported that the cost of the CO2
capture can be reduced by using this technology. In this paper, the
research progress (from experimental results) in adsorbents for CO2
adsorption, storage, and separations were reviewed and future
research directions were suggested as well.
Abstract: This paper investigates the indices of a creative city in
Isfahan. Its main aim is to evaluate quantitative status of the creative
city indices in Isfahan city, analyze the dispersion and distribution of
these indices in Isfahan city. Concerning these, this study tries to
analyze the creative city indices in fifteen area of Isfahan through
secondary data, questionnaire, TOPSIS model, Shannon entropy and
SPSS. Based on this, the fifteen areas of Isfahan city have been
ranked with 12 factors of creative city indices. The results of studies
show that fifteen areas of Isfahan city are not equally benefiting from
creative indices and there is much difference between the areas of
Isfahan city.
Abstract: The flow filed around a flatted-roof compound has
been investigated by means of 2D and 3D numerical simulations. A
constant wind velocity profile, based both on the maximum reference
wind speed in the building site (peak gust speed worked out for a 50-
year return period) and on the local roughness coefficient, has been
simulated in order to determine the wind-induced loads on top of the
roof. After determining the influence of the incoming wind directions
on the induced roof loads, a 2D analysis of the most severe load
condition has been performed, achieving a numerical quantification
of the expected wind-induced forces on the PV panels on top of the
roof.
Abstract: A considerable amount of energy is consumed during
transmission and reception of messages in a wireless mesh network
(WMN). Reducing per-node transmission power would greatly
increase the network lifetime via power conservation in addition to
increasing the network capacity via better spatial bandwidth reuse. In
this work, the problem of topology control in a hybrid WMN of
heterogeneous wireless devices with varying maximum transmission
ranges is considered. A localized distributed topology control
algorithm is presented which calculates the optimal transmission
power so that (1) network connectivity is maintained (2) node
transmission power is reduced to cover only the nearest neighbours
(3) networks lifetime is extended. Simulations and analysis of results
are carried out in the NS-2 environment to demonstrate the
correctness and effectiveness of the proposed algorithm.
Abstract: The possible therapeutic effect of cannabidiol, the major non-psychotropic Cannabis constituent, was investigated against acute hepatotoxicity induced by a single oral dose of acetaminophen (500mg/kg) in mice. Cannabidiol (two intraperitoneal injections, 5mg/kg, each) was given 1 hour and 12 hours following acetaminophen administration. Acetaminophen administration caused significant elevations of serum alanine aminotransferase, and hepatic malondialdehyde, and nitric oxide levels, and a significant decrease in hepatic reduced glutathione. Cannabidiol significantly attenuated the deterioration in the measured biochemical parameters resulted from acetaminophen administration. Also, histopathological examination showed that cannabidiol markedly attenuated ameliorated acetaminophen-induced liver tissue damage. These results emphasize that cannabidiol represents a potential therapeutic option to protect against acetaminophen hepartotoxicity which is a common clinical problem.
Abstract: The Marangoni convective instability in a horizontal
fluid layer with the insoluble surfactant and nondeformable free
surface is investigated. The surface tension at the free surface is
linearly dependent on the temperature and concentration gradients.
At the bottom surface, the temperature conditions of uniform
temperature and uniform heat flux are considered. By linear stability
theory, the exact analytical solutions for the steady Marangoni
convection are derived and the marginal curves are plotted. The
effects of surfactant or elasticity number, Lewis number and Biot
number on the marginal Marangoni instability are assessed. The
surfactant concentration gradients and the heat transfer mechanism at
the free surface have stabilizing effects while the Lewis number
destabilizes fluid system. The fluid system with uniform temperature
condition at the bottom boundary is more stable than the fluid layer
that is subjected to uniform heat flux at the bottom boundary.
Abstract: The urban transformation processes in its framework
and its general significance became a fundamental and vital subject
of consideration for both the developed and the developing societies.
It has become important to regulate the architectural systems adopted
by the city, to sustain the present development on one hand, and on
the other hand, to facilitate its future growth.
Thus, the study dealt with the phenomenon of urban
transformation of the Mediterranean cities, and the city of Alexandria
in particular, because of its significant historical and cultural legacy,
its historical architecture and its contemporary urbanization.
This article investigates the entirety of cities in the Mediterranean
region through the analysis of the relationship between inflation and
growth of these cities and the extent of the complexity of the city
barriers. We hope to analyze not only the internal transformations,
but the external relationships (both imperial and post-colonial) that
have shaped Alexandria city growth from the nineteenth century until
today.
Abstract: The aim of the paper work is to investigate and predict
the static performance of journal bearing in turbulent flow condition
considering micropolar lubrication. The Reynolds equation has been
modified considering turbulent micropolar lubrication and is solved
for steady state operations. The Constantinescu-s turbulence model is
adopted using the coefficients. The analysis has been done for a
parallel and inertia less flow. Load capacity and friction factor have
been evaluated for various operating parameters.
Abstract: In this paper, numerical simulations are performed to investigate the effect of disturbance block on flow field of the classical square lid-driven cavity. Attentions are focused on vortex formation and studying the effect of block position on its structure. Corner vortices are different upon block position and new vortices are produced because of the block. Finite volume method is used to solve Navier-Stokes equations and PISO algorithm is employed for the linkage of velocity and pressure. Verification and grid independency of results are reported. Stream lines are sketched to visualize vortex structure in different block positions.
Abstract: Pyrite (FeS2) is a promising candidate for cathode
materials in batteries because of it`s high theoretical capacity, low
cost and non-toxicity. In this study, nano size iron disulfide thin film
was prepared on graphite substrate through a new method as battery
cathode. In this way, acetylene black and poly vinylidene fluoride
were used as electron conductor and binder, respectively. Fabricated
thin films were analyzed by XRD and SEM. These results and
electrochemical data confirm improvement of battery discharge
capacity in comparison with commercial type of pyrite.
Abstract: In a metal forming process, the friction between the
material and the tools influences the process by modifying the stress
distribution of the workpiece. This frictional behaviour is often taken
into account by using a constant coefficient of friction in the finite
element simulations of sheet metal forming processes. However,
friction coefficient varies in time and space with many parameters.
The Stribeck friction model is investigated in this study to predict
springback behaviour of AA6061-T4 sheets during V-bending
process. The coefficient of friction in Stribeck curve depends on
sliding velocity and contact pressure. The plane-strain bending
process is simulated in ABAQUS/Standard. We compared the
computed punch load-stroke curves and springback related to the
constant coefficient of friction with the defined friction model. The
results clearly showed that the new friction model provides better
agreement between experiments and results of numerical simulations.
The influence of friction models on stress distribution in the
workpiece is also studied numerically
Abstract: An attempt has been made to develop a
seminumerical model to study temperature variations in dermal
layers of human limbs. The model has been developed for two
dimensional steady state case. The human limb has been assumed to
have elliptical cross section. The dermal region has been divided
into three natural layers namely epidermis, dermis and subdermal
tissues. The model incorporates the effect of important physiological
parameters like blood mass flow rate, metabolic heat generation, and
thermal conductivity of the tissues. The outer surface of the limb is
exposed to the environment and it is assumed that heat loss takes
place at the outer surface by conduction, convection, radiation, and
evaporation. The temperature of inner core of the limb also varies at
the lower atmospheric temperature. Appropriate boundary conditions
have been framed based on the physical conditions of the problem.
Cubic splines approach has been employed along radial direction and
Fourier series along angular direction to obtain the solution. The
numerical results have been computed for different values of
eccentricity resembling with the elliptic cross section of the human
limbs. The numerical results have been used to obtain the
temperature profile and to study the relationships among the various
physiological parameters.
Abstract: The development incompatible with environment cannot be sustainable. Using renewable energy sources such as solar energy, geothermal energy and wind energy can make sustainable development in a region. Iran has a lot of renewable and nonrenewable energy resources. Since Iran has a special geographic position, it has lot of solar and wind energy resources. Both solar and wind energy are free, renewable and adaptable with environment. The study of 10 year wind data in Iranian South coastal and Islands synoptic stations shows that the production of wind power electricity and water pumping is possible in this region. In this research, we studied the local and temporal distribution of wind using three – hour statistics of windspeed in Iranian South coastal and Islands synoptic stations. This research shows that the production of wind power electricity is possible in this region all the year.
Abstract: Smoke discharging is a main reason of air pollution
problem from industrial plants. The obstacle of a building has an
affect with the air pollutant discharge. In this research, a mathematical
model of the smoke dispersion from two sources and one source with
a structural obstacle is considered. The governing equation of the
model is an isothermal mass transfer model in a viscous fluid. The
finite element method is used to approximate the solutions of the
model. The triangular linear elements have been used for discretising
the domain, and time integration has been carried out by semi-implicit
finite difference method. The simulations of smoke dispersion in
cases of one chimney and two chimneys are presented. The maximum
calculated smoke concentration of both cases are compared. It is then
used to make the decision for smoke discharging and air pollutant
control problems on industrial area.
Abstract: Later marine propeller is the main component of ship
propulsion system. For a non-series propeller, it is difficult to
indicate the open water marine propeller performance without an
experimental study to measure the marine propeller parameters.
In the present study, the open water performance of a non-series
marine propeller has been carried out experimentally. The
geometrical aspects of a commercial non-series marine propeller
have been measured for a propeller blade area ratio of 0.3985. The
measured propeller performance parameters were the thrust and
torque coefficients for different propeller rotational speed and
different water channel flow velocity, then the open water
performance for the propeller has been plotted.
In addition, a direct comparison between the obtained
experimental results and a theoretical study of a B-series marine
propeller of the same blade area ratio has been carried out. A
correction factor has been introduced to apply the operating
conditions of the experimental results to that of the theoretical study
for the studied marine propeller.