Abstract: There are various sources of energies available
worldwide and among them, crude oil plays a vital role. Oil recovery
is achieved using conventional primary and secondary recovery
methods. In-order to recover the remaining residual oil, technologies
like Enhanced Oil Recovery (EOR) are utilized which is also known
as tertiary recovery. Among EOR, Microbial enhanced oil recovery
(MEOR) is a technique which enables the improvement of oil
recovery by injection of bio-surfactant produced by microorganisms.
Bio-surfactant can retrieve unrecoverable oil from the cap rock which
is held by high capillary force. Bio-surfactant is a surface active agent
which can reduce the interfacial tension and reduce viscosity of oil
and thereby oil can be recovered to the surface as the mobility of the
oil is increased. Research in this area has shown promising results
besides the method is echo-friendly and cost effective compared with
other EOR techniques. In our research, on laboratory scale we
produced bio-surfactant using the strain Pseudomonas putida (MTCC
2467) and injected into designed simple sand packed column which
resembles actual petroleum reservoir. The experiment was conducted
in order to determine the efficiency of produced bio-surfactant in oil
recovery. The column was made of plastic material with 10 cm in
length. The diameter was 2.5 cm. The column was packed with fine
sand material. Sand was saturated with brine initially followed by oil
saturation. Water flooding followed by bio-surfactant injection was
done to determine the amount of oil recovered. Further, the injection
of bio-surfactant volume was varied and checked how effectively oil
recovery can be achieved. A comparative study was also done by
injecting Triton X 100 which is one of the chemical surfactant. Since,
bio-surfactant reduced surface and interfacial tension oil can be easily
recovered from the porous sand packed column.
Abstract: Protein hydrolysates prepared from a number of medicinal plants are promising sources of various bioactive peptides. In this work, proteins from dried whole plant of Euphorbia hirta Linn. were extracted and digested with pepsin for 12h. The hydrolysates of lesser than 3 KDa were fractionated by a cut-off membrane. The peptide hydrolysate was then purified by an anion-exchange chromatography on DEAE-Sephacel™ column and reverse-phase chromatography on Sep-pak C18 column, respectively. The cytotoxic effect of each peptide fraction against a gastric carcinoma cell line (KATO-III, ATCC No. HTB103) was investigated using colorimetric MTT viability assay. A human liver cell line (Chang Liver, CLS No. 300139) was used as a control normal cell line. Two purified peptide peaks, peak l and peak ll at 100µg peptides mL-1 affected cell viability of the gastric cancer cell lines to 63.85±4.94 and 66.92±6.46%, respectively. Our result showed for the first time that the peptide fractions derived from protein hydrolysate of Euphorbia hirta Linn. have anti-gastric cancer activity, which offers a potential novel and natural anti-gastric cancer remedy.
Abstract: Aerosols are small particles suspended in air that have wide varying spatial and temporal distributions. The concentration of aerosol in total columnar atmosphere is normally measured using aerosol optical depth (AOD). In long-term monitoring stations, accurate AOD retrieval is often difficult due to the lack of frequent calibration. To overcome this problem, a near-sea-level Langley calibration algorithm is developed using the combination of clear-sky detection model and statistical filter. It attempts to produce a dataset that consists of only homogenous and stable atmospheric condition for the Langley calibration purposes. In this paper, a radiance-based validation method is performed to further investigate the feasibility and consistency of the proposed algorithm at different location, day, and time. The algorithm is validated using SMARTS model based n DNI value. The overall results confirmed that the proposed calibration algorithm feasible and consistent for measurements taken at different sites and weather conditions.
Abstract: The removal of chromium by living yeast biomass immobilized onto pozzolana was studied. The results obtained in batch experiments indicate that the immobilized yeast on to pozzolana is a excellent biosorbent of Cr(V) with a good removal rates of 85–90%. The initial concentration solution and agitation speed affected Cr(V) removal. The batch studies data were described using the Freundlich and Langmuir models, but the best fit was obtained with Langmuir model. The breakthrough curve from the continuous flow studies shows that immobilized yeast in the fixed-bed column is capable of decreasing Cr(VI) concentration from 15mg/l to a adequate level.
Abstract: In the present study, two distinctly different approaches are followed for modeling of reactive distillation column, the equilibrium stage model and the nonequilibrium stage model. These models are simulated with a computer code developed in the present
study using MATLAB programming. In the equilibrium stage models, the vapor and liquid phases are assumed to be in equilibrium and allowance is made for finite reaction rates, where as in the nonequilibrium stage models simultaneous mass transfer and reaction rates are considered. These simulated model results are validated from the experimental data reported in the literature. The simulated results of equilibrium and nonequilibrium models are compared for concentration, temperature and reaction rate profiles in a reactive distillation column for Methyl Tert Butyle Ether (MTBE) production. Both the models show similar trend for the concentration, temperature and reaction rate profiles but the nonequilibrium model predictions are higher and closer to the experimental values reported in the literature.
Abstract: At highly congested reinforcement regions, which is common at beam-column joint area, clear spacing between parallel bars becomes less than maximum normal aggregate size (20mm) which has not been addressed in any design code and specifications. Limited clear spacing between parallel bars (herein after thin cover) is one of the causes which affect anchorage performance. In this study, an experimental investigation was carried out to understand anchorage performance of reinforcement in Self-Compacting Concrete (SCC) and Normal Concrete (NC) at highly congested regions under uni-axial tensile loading. Column bar was pullout whereas; beam bars were offset from column reinforcement creating thin cover as per site condition. Two different sizes of coarse aggregate were used for NC (20mm and 10mm). Strain gauges were also installed along the bar in some specimens to understand the internal stress mechanism. Test results reveal that anchorage performance is affected at highly congested reinforcement region in NC with maximum aggregate size 20mm whereas; SCC and Small Aggregate (10mm) gives better structural performance.
Abstract: This paper describes fast and efficient method for page segmentation of document containing nonrectangular block. The segmentation is based on edge following algorithm using small window of 16 by 32 pixels. This segmentation is very fast since only border pixels of paragraph are used without scanning the whole page. Still, the segmentation may contain error if the space between them is smaller than the window used in edge following. Consequently, this paper reduce this error by first identify the missed segmentation point using direction information in edge following then, using X-Y cut at the missed segmentation point to separate the connected columns. The advantage of the proposed method is the fast identification of missed segmentation point. This methodology is faster with fewer overheads than other algorithms that need to access much more pixel of a document.
Abstract: Robust stability and performance are the two most
basic features of feedback control systems. The harmonic balance
analysis technique enables to analyze the stability of limit cycles
arising from a neural network control based system operating over
nonlinear plants. In this work a robust stability analysis based on the
harmonic balance is presented and applied to a neural based control
of a non-linear binary distillation column with unstructured
uncertainty. We develop ways to describe uncertainty in the form of
neglected nonlinear dynamics and high harmonics for the plant and
controller respectively. Finally, conclusions about the performance of
the neural control system are discussed using the Nyquist stability
margin together with the structured singular values of the uncertainty
as a robustness measure.
Abstract: The porous silicon (PS), formed from the anodization
of a p+ type substrate silicon, consists of a network organized in a
pseudo-column as structure of multiple side ramifications. Structural
micro-topology can be interpreted as the fraction of the interconnected
solid phase contributing to thermal transport. The
reduction of dimensions of silicon of each nanocristallite during the
oxidation induced a reduction in thermal conductivity. Integration of
thermal sensors in the Microsystems silicon requires an effective
insulation of the sensor element. Indeed, the low thermal conductivity
of PS consists in a very promising way in the fabrication of integrated
thermal Microsystems.In this work we are interesting in the
measurements of thermal conductivity (on the surface and in depth)
of PS by the micro-Raman spectroscopy. The thermal conductivity is
studied according to the parameters of anodization (initial doping and
current density. We also, determine porosity of samples by
spectroellipsometry.
Abstract: A new and cost effective RP-HPLC method was
developed and validated for simultaneous analysis of non steroidal
anti inflammatory dugs Diclofenac sodium (DFS), Flurbiprofen
(FLP) and an opioid analgesic Tramadol (TMD) in advanced drug
delivery systems (Liposome and Microcapsules), marketed brands
and human plasma. Isocratic system was employed for the flow of
mobile phase consisting of 10 mM sodium dihydrogen phosphate
buffer and acetonitrile in molar ratio of 67: 33 with adjusted pH of
3.2. The stationary phase was hypersil ODS column (C18, 250×4.6
mm i.d., 5 μm) with controlled temperature of 30 C°. DFS in
liposomes, microcapsules and marketed drug products was
determined in range of 99.76-99.84%. FLP and TMD in
microcapsules and brands formulation were 99.78 - 99.94 % and
99.80 - 99.82 %, respectively. Single step liquid-liquid extraction
procedure using combination of acetonitrile and trichloroacetic acid
(TCA) as protein precipitating agent was employed. The detection
limits (at S/N ratio 3) of quality control solutions and plasma samples
were 10, 20, and 20 ng/ml for DFS, FLP and TMD, respectively.
The Assay was acceptable in linear dynamic range. All other
validation parameters were found in limits of FDA and ICH method
validation guidelines. The proposed method is sensitive, accurate and
precise and could be applicable for routine analysis in
pharmaceutical industry as well as in human plasma samples for
bioequivalence and pharmacokinetics studies.
Abstract: The unanticipated destruct of more of the steel moment frames in Northridge earthquake, altered class of regard to the beamto- column connections in moment frames. Panel zone is one the significant part of joints which, it-s stiffness and rigidity has an important effect on the behavior and ductility of the frame. Specifically that behavior of panel zone has a very significant effect on the special moment frames. In this paper , meanwhile the relations for modeling of panel zone in frames are expressed , special moment frames with different spans and stories were studied in the way of performance-based design. The frames designed in according with Iranian steel building code. The effect of panel zone is also considered and in the case of non-existence of performance level, by changing in intimacies and parameter of panel zone, performance level is considered.
Abstract: This work presents a theoretical investigation of the
simultaneous absorption of CO2 and H2S into aqueous solutions of
MDEA and DEA. In this process the acid components react
with the basic alkanolamine solution via an exothermic,
reversible reaction in a gas/liquid absorber. The use of amine
solvents for gas sweetening has been investigated using
process simulation programs called HYSYS and ASPEN. We
use Electrolyte NRTL and Amine Package and Amines
(experimental) equation of state. The effects of temperature and
circulation rate and amine concentration and packed column and
murphree efficiency on the rate of absorption were studied.
When lean amine flow and concentration increase, CO2 and H2S
absorption increase too. With the improvement of inlet amine
temperature in absorber, CO2 and H2S penetrate to upper stages of
absorber and absorption of acid gases in absorber decreases. The CO2
concentration in the clean gas can be greatly influenced by the
packing height, whereas for the H2S concentration in the clean gas the
packing height plays a minor role. HYSYS software can not
estimate murphree efficiency correctly and it applies the same
contributions in all diagrams for HYSYS software. By
improvement in murphree efficiency, maximum temperature
of absorber decrease and the location of reaction transfer to the
stages of bottoms absorber and the absorption of acid gases
increase.
Abstract: The technique of k-anonymization has been proposed to obfuscate private data through associating it with at least k identities. This paper investigates the basic tabular structures that
underline the notion of k-anonymization using cell suppression.
These structures are studied under idealized conditions to identify the
essential features of the k-anonymization notion. We optimize data kanonymization
through requiring a minimum number of anonymized
values that are balanced over all columns and rows. We study the
relationship between the sizes of the anonymized tables, the value k, and the number of attributes. This study has a theoretical value through contributing to develop a mathematical foundation of the kanonymization
concept. Its practical significance is still to be
investigated.
Abstract: Because of the requirement for low sulfur content of
fuel oils, it is necessary to develop alternative methods for desulfurization of heavy fuel oil. Due to the disadvantages of HDS
technologies such as costs, safety and green environment, new
methods have been developed. Among these methods is ultrasoundassisted
oxidative desulfurization. Using ultrasound-assisted
oxidative desulfurization, compounds such as benzothiophene and
dibenzothiophene can be oxidized. As an alternative method is sulfur
elimination of heavy fuel oil by using of activated carbon in a packed column in batch condition. The removal of sulfur compounds in this
case to reach about 99%. The most important property of activated carbon is ability of it for adsorption, which is due to high surface area
and pore volume of it.
Abstract: Liners are made to protect the groundwater table from
the infiltration of leachate which normally carries different kinds of
toxic materials from landfills. Although these liners are engineered to
last for long period of time; unfortunately these liners fail; therefore,
toxic materials pass to groundwater. This paper focuses on the
changes of the hydraulic conductivity of a sand-bentonite liner due to
the infiltration of biofuel and ethanol fuel. Series of laboratory tests
were conducted in 20-cm-high PVC columns. Several compositions
of sand-bentonite liners were tested: 95% sand: 5% bentonite; 90%
sand: 10% bentonite; and 100% sand (passed mesh #40). The
columns were subjected to extreme pressures of 40 kPa, and 100 kPa
to evaluate the transport of alternative fuels (biofuel and ethanol
fuel). For comparative studies, similar tests were carried out using
water. Results showed that hydraulic conductivity increased due to
the infiltration of alternative fuels through the liners. Accordingly,
the increase in the hydraulic conductivity showed significant
dependency on the type of liner mixture and the characteristics of the
liquid. The hydraulic conductivity of a liner (subjected to biofuel
infiltration) consisting of 5% bentonite: 95% sand under pressure of
40 kPa and 100 kPa had increased by one fold. In addition, the
hydraulic conductivity of a liner consisting of 10% bentonite: 90%
sand under pressure of 40 kPa and 100 kPa and infiltrated by biofuel
had increased by three folds. On the other hand, the results obtained
by water infiltration under 40 kPa showed lower hydraulic
conductivities of 1.50×10-5 and 1.37×10-9 cm/s for 5% bentonite:
95% sand, and 10% bentonite: 90% sand, respectively. Similarly,
under 100 kPa, the hydraulic conductivities were 2.30×10-5 and
1.90×10-9 cm/s for 5% bentonite: 95% sand, and 10% bentonite: 90%
sand, respectively.
Abstract: A new reverse phase-high performance liquid chromatography (RP-HPLC) method with fluorescent detector (FLD) was developed and optimized for Norfloxacin determination in human plasma. Mobile phase specifications, extraction method and excitation and emission wavelengths were varied for optimization. HPLC system contained a reverse phase C18 (5 μm, 4.6 mm×150 mm) column with FLD operated at excitation 330 nm and emission 440 nm. The optimized mobile phase consisted of 14% acetonitrile in buffer solution. The aqueous phase was prepared by mixing 2g of citric acid, 2g sodium acetate and 1 ml of triethylamine in 1 L of Milli-Q water was run at a flow rate of 1.2 mL/min. The standard curve was linear for the range tested (0.156–20 μg/mL) and the coefficient of determination was 0.9978. Aceclofenac sodium was used as internal standard. A detection limit of 0.078 μg/mL was achieved. Run time was set at 10 minutes because retention time of norfloxacin was 0.99 min. which shows the rapidness of this method of analysis. The present assay showed good accuracy, precision and sensitivity for Norfloxacin determination in human plasma with a new internal standard and can be applied pharmacokinetic evaluation of Norfloxacin tablets after oral administration in human.
Abstract: This paper describes the development of a fully
automated measurement software for antenna radiation pattern
measurements in a Compact Antenna Test Range (CATR). The
CATR has a frequency range from 2-40 GHz and the measurement
hardware includes a Network Analyzer for transmitting and
Receiving the microwave signal and a Positioner controller to control
the motion of the Styrofoam column. The measurement process
includes Calibration of CATR with a Standard Gain Horn (SGH)
antenna followed by Gain versus angle measurement of the Antenna
under test (AUT). The software is designed to control a variety of
microwave transmitter / receiver and two axis Positioner controllers
through the standard General Purpose interface bus (GPIB) interface.
Addition of new Network Analyzers is supported through a slight
modification of hardware control module. Time-domain gating is
implemented to remove the unwanted signals and get the isolated
response of AUT. The gated response of the AUT is compared with
the calibration data in the frequency domain to obtain the desired
results. The data acquisition and processing is implemented in
Agilent VEE and Matlab. A variety of experimental measurements
with SGH antennas were performed to validate the accuracy of
software. A comparison of results with existing commercial
softwares is presented and the measured results are found to be
within .2 dBm.
Abstract: Excessive ductility demand on shorter piers is a
common problem for irregular bridges subjected to strong ground
motion. Various techniques have been developed to reduce the
likelihood of collapse of bridge due to failure of shorter piers. This
paper presents the new approach to improve the seismic behavior of
such bridges using Nitinol shape memory alloys (SMAs).
Superelastic SMAs have the ability to remain elastic under very large
deformation due to martensitic transformation. This unique property
leads to enhanced performance of controlled bridge compared with
the performance of the reference bridge. To evaluate the effectiveness
of the devices, nonlinear time history analysis is performed on a RC
single column bent highway bridge using a suite of representative
ground motions. The results show that this method is very effective in
limiting the ductility demand of shorter pier.
Abstract: In this work, we study the problem of determining
the minimum scheduling length that can satisfy end-to-end (ETE)
traffic demand in scheduling-based multihop WSNs with cooperative
multiple-input multiple-output (MIMO) transmission scheme. Specifically,
we present a cross-layer formulation for the joint routing,
scheduling and stream control problem by incorporating various
power and rate adaptation schemes, and taking into account an
antenna beam pattern model and the signal-to-interference-and-noise
(SINR) constraint at the receiver. In the context, we also propose
column generation (CG) solutions to get rid of the complexity
requiring the enumeration of all possible sets of scheduling links.
Abstract: The paper aims at investigating influence of medium
capacity on linear adsorbed solute dispersion into chemically
heterogeneous fixed beds. A discrete chemical heterogeneity
distribution is considered in the one-dimensional advectivedispersive
equation. The partial differential equation is solved using
finite volumes method based on the Adam-Bashforth algorithm.
Increased dispersion is estimated by comparing breakthrough curves
second order moments and keeping identical hydrodynamic
properties. As a result, dispersion increase due to chemical
heterogeneity depends on the column size and surprisingly on the
solid capacity. The more intense capacity is, the more important
solute dispersion is. Medium length which is known to favour this
effect vanishing according to the linear adsorption in fixed bed seems
to create nonmonotonous variation of dispersion because of the
heterogeneity. This nonmonotonous behaviour is also favoured by
high capacities.