Batch and Continuous Packed Column Studies Biosorption by Yeast Supported onto Granular Pozzolana

The removal of chromium by living yeast biomass immobilized onto pozzolana was studied. The results obtained in batch experiments indicate that the immobilized yeast on to pozzolana is a excellent biosorbent of Cr(V) with a good removal rates of 85–90%. The initial concentration solution and agitation speed affected Cr(V) removal. The batch studies data were described using the Freundlich and Langmuir models, but the best fit was obtained with Langmuir model. The breakthrough curve from the continuous flow studies shows that immobilized yeast in the fixed-bed column is capable of decreasing Cr(VI) concentration from 15mg/l to a adequate level. 





References:
[1] A. Ozer, H. S. Altundogan, M. Erdem, F. Tumen, “A study on the Cr
(VI) removal from aqueous sol utions by steel wool.”Environ. Pollut.,
vol. 97,1997,pp. 107-112.
[2] R. Mauri, R. Shinnar, M.D. Amore,P. Giordano,A. Volpe, “. Solvent
extraction of chromium and cadmium from contaminated soils”
J.AIChE. vol.47, 2001, pp 509-512.
[3] M. Lotfi, N. Adhoum, 2002. “Modified activated carbon for the removal
ofcopper, zinc, chromium and cyanide from wastewater” Separ.
Purif.Technol. Vol.26, pp. 137-146.
[4] B. Volesky, “Detoxification of metal-bearing effluents: biosorption for
the next century Hydrometallurgy” vol.59, 2001, pp.203–216.
[5] E. W. Wilde, J.R. “Benemann Biotechnol. Wilde, E. W. and J. R.
Benemann Bioremoval of heavy metals by the use of microalgae”
Biotechnol. Adv.vol.11, 1993, pp. 781-812.
[6] C. L. Brierley, “Bioremediation of metal-contaminated surface and
ground waters” J. Geomicrobiol.vol.8, 1990, pp.201–223.
[7] A. Malik, “Metal bioremediation through growing cells”. Environ. Int.
vol.30, 2004, pp. 261 – 78.
[8] M. Uysal, I. Ar, “Removal of Cr(VI) from industrial wastewaters by
adsorption. Part I: Determination of optimum conditions” Journal of
Hazardous Materials vol.149, 2007, pp.482–491.
[9] R. S. Bai, T. E. Abraham, “Studies on chromium(VI) adsorption–
desorption using immobilized fungal biomass” Biores. Technol.vol.87,
2003, pp. 17–26.
[10] S. A., Wanees, A.M., Ahmed, M.S., Adam, M.A., Mohamed “
Adsorption Studies on the Removal of Hexavalent Chromium-
Contaminated Wastewater using Activated Carbon and Bentonite”
Chemistry J. vol. 02,2012, pp. 95-105.
[11] Y. S. Ho, G. Mckay, “Sorption of copper(II) from aqueous solution by
peat”. Water Air Soil Pollut.vol. 158, 2004, pp.77–97.
[12] Y. S. Ho, G. McKay, “Pseudo second-order model for sorption
processes” Process Biochem. vol.34, 1999, pp. 451–465.
[13] H. Doshi, C. Seth, A. Ray, L. Kothari, “Bioaccumulation of Heavy
Metals by Green Algae” Curr. Microbiol.vol.56,2008,pp.246–255
[14] E. Oguz, “Equilibrium isotherms and kinetics studies for the sorption of
fluoride on light weight concrete materials,” Colloid Surf. A.vol.295,
2007pp.258–263.
[15] A. Saeed, M. Iqbal,“ Bioremoval of cadmium from aqueous solution by
black gram husk (Cicer arientinum) ”.Water Res.,vol.37, 2003 pp.3472–
3480.
[16] Z. Aksu, T. Kutsal, “Determination of kinetic parameters in the
biosorption of copper (II) on Cladophora sp., in a packed bed column
bioreactor” Process Biochem., vol.1998,pp. 7–13.
[17] P. Kaewsarn, “Biosorption of copper(II) from aqueous solutions by pretreated
biomass of marine algae Padina sp. ”Chemosphere
j.vol.47,2002,pp. 1081–1085.