Abstract: Dehydration of methanol to dimethyl ether (DME)
over a commercial Al2O3 catalyst was studied in an isothermal integral
fixed bed reactor. The experiments were performed on the temperature
interval 513-613 K, liquid hourly space velocity (LHSV) of 0.9-2.1h-1,
pressures between 0.1 and 1.0 MPa. The effect of different operation
conditions on the dehydration of methanol was investigated in a
laboratory scale experiment. A new intrinsic kinetics equation based
on the mechanism of Langmuir-Hinshelwood dissociation adsorption
was developed for the dehydration reaction by fitting the expressions
to the experimental data. An activation energy of 67.21 kJ/mol was
obtained for the catalyst with the best performance. Statistic test
showed that this new intrinsic kinetics equation was acceptable.
Abstract: Recently, the health of retired National Football
League players, particularly lineman has been investigated. A
number of studies have reported increased cardiometabolic risk,
premature cardiovascular disease and incidence of type 2 diabetes.
Rugby union players have somatotypes very similar to National
Football League players which suggests that rugby players may have
similar health risks. The International Golden Oldies World Rugby
Festival (GORF) provided a unique opportunity to investigate the
demographics of veteran rugby players. METHODOLOGIES: A
cross-sectional, observational study was completed using an online
web-based questionnaire that consisted of medical history and
physiological measures. Data analysis was completed using a one
sample t-test (50yrs) and Chi-square test. RESULTS:
A total of 216 veteran rugby competitors (response rate = 6.8%)
representing 10 countries, aged 35-72 yrs (mean 51.2, S.D. ±8.0),
participated in the online survey. As a group, the incidence of current
smokers was low at 8.8% (avg 72.4 cigs/wk) whilst the percentage
consuming alcohol was high (93.1% (avg 11.2 drinks/wk).
Competitors reported the following top six chronic
diseases/disorders; hypertension (18.6%), arthritis (OA/RA, 11.5%),
asthma (9.3%), hyperlipidemia (8.2%), diabetes (all types, 7.5%) and
gout (6%), there were significant differences between groups with
regard to cancer (all types) and migraines. When compared to the
Australian general population (Australian Bureau of Statistics data,
n=18,000), GORF competitors had a significantly lower incidence of
anxiety (p
Abstract: The Brazilian Agricultural Products Wholesale Market fits well as example of residues generating system, reaching 750 metric tons per month of total residues, from which 600 metric tons are organic material and 150 metric tons are recyclable materials. Organic material is basically composed of fruit, vegetables and flowers leftovers from the products commercialization. The recyclable compounds are generate from packing material employed in the commercialization process. This research work devoted efforts in carrying quantitative analysis of the residues generated in the agricultural enterprise at its final destination. Data survey followed the directions implemented by the Residues Management Program issued by the agricultural enterprise. It was noticed from that analysis the necessity of changing the logistics applied to the recyclable material collecting process. However, composting process was elected as the organic compounds destination which is considered adequate for a material composed of significant percentage of organic matter far higher than wood, cardboard and plastics contents.
Abstract: Air infiltration in mass scale industrial applications of
bio char production is inevitable. The presence of oxygen during the
carbonization process is detrimental to the production of biochar yield
and properties. The experiment was carried out on several wood
species in a fixed-bed pyrolyser under various fractions of oxygen
ranging from 0% to 11% by varying nitrogen and oxygen composition
in the pyrolysing gas mixtures at desired compositions. The bed
temperature and holding time were also varied. Process optimization
was carried out by Response Surface Methodology (RSM) by
employing Central Composite Design (CCD) using Design Expert 6.0
Software. The effect of oxygen ratio and holding time on biochar yield
within the range studied were statistically significant. From the
analysis result, optimum condition of 15.2% biochar yield of
mangrove wood was predicted at pyrolysis temperature of 403 oC,
oxygen percentage of 2.3% and holding time of two hours. This
prediction agreed well with the experiment finding of 15.1% biochar
yield.
Abstract: In this paper, the effects of radiation, chemical
reaction and double dispersion on mixed convection heat and mass
transfer along a semi vertical plate are considered. The plate is
embedded in a Newtonian fluid saturated non - Darcy (Forchheimer
flow model) porous medium. The Forchheimer extension and first
order chemical reaction are considered in the flow equations. The
governing sets of partial differential equations are nondimensionalized
and reduced to a set of ordinary differential
equations which are then solved numerically by Fourth order Runge–
Kutta method. Numerical results for the detail of the velocity,
temperature, and concentration profiles as well as heat transfer rates
(Nusselt number) and mass transfer rates (Sherwood number) against
various parameters are presented in graphs. The obtained results are
checked against previously published work for special cases of the
problem and are found to be in good agreement.
Abstract: This work presents the experimental results obtained
at a pilot plant which works with a slow, wet and catalytic pyrolysis
process of dry fowl manure. This kind of process mainly consists in
the cracking of the organic matrix and in the following reaction of
carbon with water, which is either already contained in the organic
feed or added, to produce carbon monoxide and hydrogen. Reactions
are conducted in a rotating reactor maintained at a temperature of
500°C; the required amount of water is about 30% of the dry organic
feed. This operation yields a gas containing about 59% (on a volume
basis) of hydrogen, 17% of carbon monoxide and other products such
as light hydrocarbons (methane, ethane, propane) and carbon
monoxide in lesser amounts. The gas coming from the reactor can be
used to produce not only electricity, through internal combustion
engines, but also heat, through direct combustion in industrial
boilers. Furthermore, as the produced gas is devoid of both solid
particles and pollutant species (such as dioxins and furans), the
process (in this case applied to fowl manure) can be considered as an
optimal way for the disposal and the contemporary energetic
valorization of organic materials, in such a way that is not damaging
to the environment.
Abstract: Conventional materials like glass, wood or metals
replacement with polymer materials is still continuing. More simple
thus cheaper production is the main reason. However due to high
energy and petrochemical prices are polymer prices increasing too.
That´s why various kinds of fillers are used to make polymers
cheaper. Of course target is to maintain or improve properties of
these compounds. In this paper are solved rheology issues of
polymers compounded with vegetal origin fibers.
Abstract: ZnO nanocrystals with mean diameter size 14 nm
have been prepared by precipitation method, and examined as
photocatalyst for the UV-induced degradation of insecticide diazinon
as deputy of organic pollutant in aqueous solution. The effects of
various parameters, such as illumination time, the amount of
photocatalyst, initial pH values and initial concentration of
insecticide on the photocatalytic degradation diazinon were
investigated to find desired conditions. In this case, the desired
parameters were also tested for the treatment of real water containing
the insecticide. Photodegradation efficiency of diazinon was
compared between commercial and prepared ZnO nanocrystals. The
results indicated that UV/ZnO process applying prepared
nanocrystalline ZnO offered electrical energy efficiency and
quantum yield better than commercial ZnO. The present study, on the
base of Langmuir-Hinshelwood mechanism, illustrated a pseudo
first-order kinetic model with rate constant of surface reaction equal
to 0.209 mg l-1 min-1 and adsorption equilibrium constant of 0.124 l
mg-1.
Abstract: It was determined that woody biomass and livestock excreta can be utilized as hydrogen resources and hydrogen produced from such sources can be used to fill fuel cell vehicles (FCVs) at hydrogen stations. It was shown that the biomass transport costs for hydrogen production may be reduced the costs for co-generation. In the Tokyo Metropolitan Area, there are only a few sites capable of producing hydrogen from woody biomass in amounts greater than 200 m3/h-the scale required for a hydrogen station to be operationally practical. However, in the case of livestock excreta, it was shown that 15% of the municipalities in this area are capable of securing sufficient biomass to be operationally practical for hydrogen production. The differences in feasibility of practical operation depend on the type of biomass.
Abstract: When the results of the total element concentrations using USEPA method 3051A are compared to the sequential extraction analyses (i.e. the sum of fractions BCR1, BCR2 and BRC3), it can be calculated that the recovery values of elements varied between 56.8-% and 69.4-% in the bottom ash, and between 11.3-% and 70.9-% in the fly ash. This indicates that most of the elements in the ashes do not occur as readily soluble forms.
Abstract: This paper describes the NEAR (Navigating Exhibitions, Annotations and Resources) panel, a novel interactive visualization technique designed to help people navigate and interpret groups of resources, exhibitions and annotations by revealing hidden relations such as similarities and references. NEAR is implemented on A•VI•RE, an extended online information repository. A•VI•RE supports a semi-structured collection of exhibitions containing various resources and annotations. Users are encouraged to contribute, share, annotate and interpret resources in the system by building their own exhibitions and annotations. However, it is hard to navigate smoothly and efficiently in A•VI•RE because of its high capacity and complexity. We present a visual panel that implements new navigation and communication approaches that support discovery of implied relations. By quickly scanning and interacting with NEAR, users can see not only implied relations but also potential connections among different data elements. NEAR was tested by several users in the A•VI•RE system and shown to be a supportive navigation tool. In the paper, we further analyze the design, report the evaluation and consider its usage in other applications.
Abstract: The Euler-s equation of motion is extended to include
the viscosity stress tensor leading to the formulation of Navier–
Stokes type equation. The latter is linearized and applied to
investigate the rotational motion or vorticity in a viscous fluid.
Relations for the velocity of viscous waves and attenuation parameter
are obtained in terms of viscosity (μ) and the density (¤ü) of the fluid.
μ and ¤ü are measured experimentally as a function of temperature for
two different samples of light and heavy crude oil. These data
facilitated to determine the activation energy, velocity of viscous
wave and the attenuation parameter. Shear wave velocity in heavy oil
is found to be much larger than the light oil, whereas the attenuation
parameter in heavy oil is quite low in comparison to light one. The
activation energy of heavy oil is three times larger than light oil.
Abstract: This paper proposes an architectural and graphical
user interface (GUI) design of a traditional Thai musical instrument
application for tablet computers for practicing “Ranaad Ek" which is
a trough-resonated keyboard percussion instrument. The application
provides percussion methods for a player as real as a physical
instrument. The application consists of two playing modes. The first
mode is free playing, a player can freely multi touches on wooden bar
to produce instrument sounds. The second mode is practicing mode
that guilds the player to follow percussions and rhythms of practice
songs. The application has achieved requirements and specifications.
Abstract: This paper presents a NDT by infrared thermography with excitation CO2 Laser, wavelength of 10.6 μm. This excitation is the controllable heating beam, confirmed by a preliminary test on a wooden plate 1.2 m x 0.9 m x 1 cm. As the first practice, this method is applied to detecting the defect in CFRP heated by the Laser 300 W during 40 s. Two samples 40 cm x 40 cm x 4.5 cm are prepared, one with defect, another one without defect. The laser beam passes through the lens of a deviation device, and heats the samples placed at a determinate position and area. As a result, the absence of adhesive can be detected. This method displays prominently its application as NDT with the composite materials. This work gives a good perspective to characterize the laser beam, which is very useful for the next detection campaigns.
Abstract: In this study, some physical and mechanical properties
of jujube fruits, were measured and compared at constant moisture
content of 15.5% w.b. The results showed that the mean length, width
and thickness of jujube fruits were 18.88, 16.79 and 15.9 mm,
respectively. The mean projected areas of jujube perpendicular to
length, width, and thickness were 147.01, 224.08 and 274.60 mm2,
respectively. The mean mass and volume were 1.51 g and 2672.80
mm3, respectively. The arithmetic mean diameter, geometric mean
diameter and equivalent diameter varied from 14.53 to 20 mm, 14.5
to 19.94 mm, and 14.52 to 19.97 mm, respectively. The sphericity,
aspect ratio and surface area of jujube fruits were 0.91, 0.89 and
926.28 mm2, respectively. Whole fruit density, bulk density and
porosity of jujube fruits were measured and found to be 1.52 g/cm3,
0.3 g/cm3 and 79.3%, respectively. The angle of repose of jujube fruit
was 14.66° (±0.58°). The static coefficient of friction on galvanized
iron steel was higher than that on plywood and lower than that on
glass surface. The values of rupture force, deformation, hardness and
energy absorbed were found to be between 11.13-19.91N, 2.53-
4.82mm, 3.06-5.81N mm and 20.13-39.08 N/mm, respectively.
Abstract: Online Communities are an example of sociallyaware,
self-organising, complex adaptive computing systems.
The multi-agent systems (MAS) paradigm coordinated by
self-organisation mechanisms has been used as an effective
way for the simulation and modeling of such systems. In this
paper, we propose a model for simulating an online health
community using a situated multi-agent system approach,
governed by the co-evolution of the social and spatial
organisations of the agents.
Abstract: The counter flow solar air heaters, with four
transverse fins and wire mesh layers are constructed and investigated
experimentally for thermal efficiency at a geographic location of
Cyprus in the city of Famagusta. The absorber plate is replaced by
sixteen steel wire mesh layers, 0.18 x 0.18cm in cross section
opening and a 0.02cm in diameter. The wire mesh layers arranged in
three groups, first and second include 6 layers, while the third include
4 layers. All layers fixed in the duct parallel to the glazing and each
group separated from the others by wood frame thickness of 0.5cm to
reduce the pressure drop. The transverse fins arranged in a way to
force the air to flow through the bed like eight letter path with flow
depth 3cm. The proposed design has increased the heat transfer rate,
but on other hand causes a high pressure drop. The obtained results
show that, for air mass flow rate range between 0.011-0.036kg/s, the
thermal efficiency increases with increasing the air mass flow. The
maximum efficiency obtained is 65.6% for the mass flow rate of
0.036kg/s. Moreover, the temperature difference between the outlet
flow and the ambient temperature, ΔT, reduces as the air mass flow
rate increase. The maximum difference between the outlet and
ambient temperature obtained was 43°C for double pass for minimum
mass flow rate of 0.011kg/s. Comparison with a conventional solar
air heater collector shows a significantly development in the thermal
efficiency.
Abstract: The characteristic bending strength (MOR) and mean
modulus of elasticity (MOE) of tropical hardwood red seraya (Shorea
spp.) plywood were determined using European Standard EN310 and
EN789. The thickness of the test specimen was 4.0mm, 7.0mm,
9.0mm, 12.0mm and 15.0mm. The experiment found that the MOR
of red seraya plywood in EN310 is about 12% to 20% and 7% to
24% higher than EN789 whereas MOE were about 28% to 41% and
30% to 36% lower than those obtained from EN 789 for test
specimens parallel and perpendicular to the grain direction. The
linear regression shows that MOR and MOE for EN789 is about 0.8
times less and 1.5 times more than EN310. The experiment also
found that the MOR and MOE of EN310 and EN789 also depend on
the wood species that used in the experiment.
Abstract: A study concerning the photocatalytic decolourization
of Congo red (CR) dye, over artificial UV irradiation is presented.
Photocatalysts based on a commercial titanium dioxide (TiO2)
modified with transition metals (Ni, Cu and Zn) were used. The
dopage method used was wet impregnation. A TiO2 sample without
salt was subjected to the same hydrothermal treatment to be used as
reference. Congo red solutions to several pH conditions (natural and
basic) were used to evaluate photocatalytic performance of each
doped catalysts. Photodecolourization percentage was measured
spectrofotrometically after 3 h of treatment to 499 nm as response
variable. Kinetics investigations of photodegradation indicated that
reactions obey to Langmuir-Hinshelwood model and pseudo–first
order law. The rate constant studies of photocatalytic decolourization
reactions for Zn–TiO2 and Cu–TiO2 photocatalysts indicated that in
all cases the rate constant of the reaction was higher than that of TiO2
undoped. These results show that nature of the metal modifying the
TiO2 influence on the efficiency of the photocatalyst evaluated in
process. Ni does not present an additional effect compared with TiO2,
while Zn enhances the photoactivity due to its electronic properties.
Abstract: Introduction: Visual performance is an important factor in sport excellence. Visual involvement in a sport varies according to environmental demands associated with that sport. These environmental demands are matched by a task specific motor response. The purpose of this study was to determine if sport specific exercises will improve the visual performance of male rugby players, in order to achieve maximal results on the sports field. Materials & Methods: Twenty six adult male rugby players, aged 16-22, were chosen as subjects. In order to evaluate the effect of sport specific exercises on visual skills, a pre-test - post-test experimental group design was adopted for the study. Results: Significant differences (p≤0.05) were seen in the focussing, tracking, vergence, sequencing, eye-hand coordination and visualisation components Discussion & Conclusions: Sport specific exercises improved visual skills in rugby players which may provide them with an advantage over their opponents. This study suggests that these training programs and participation in regular on-line EyeDrills sports vision exercises (www.eyedrills.co.za) aimed at improving the athlete-s visual coordination, concentration, focus, hand-eye co-ordination, anticipation and motor response should be incorpotated in the rugby players exercise regime.