Abstract: Spent petroleum catalyst from Korean petrochemical
industry contains trace amount of metals such as Ni, V and Mo.
Therefore an attempt was made to recover those trace metal using
bioleaching process. Different leaching parameters such as Fe(II)
concentration, pulp density, pH, temperature and particle size of
spent catalyst particle were studied to evaluate their effects on the
leaching efficiency. All the three metal ions like Ni, V and Mo
followed dual kinetics, i.e., initial faster followed by slower rate. The
percentage of leaching efficiency of Ni and V were higher than Mo.
The leaching process followed a diffusion controlled model and the
product layer was observed to be impervious due to formation of
ammonium jarosite (NH4)Fe3(SO4)2(OH)6. In addition, the lower
leaching efficiency of Mo was observed due to a hydrophobic coating
of elemental sulfur over Mo matrix in the spent catalyst.
Abstract: The square-lattice Ising model is the simplest system
showing phase transitions (the transition between the paramagnetic
phase and the ferromagnetic phase and the transition between the
paramagnetic phase and the antiferromagnetic phase) and critical
phenomena at finite temperatures. The exact solution of the squarelattice
Ising model with free boundary conditions is not known for
systems of arbitrary size. For the first time, the exact solution of
the Ising model on the square lattice with free boundary
conditions is obtained after classifying all )
spin configurations with the microcanonical transfer matrix. Also, the
phase transitions and critical phenomena of the square-lattice Ising
model are discussed using the exact solution on the square
lattice with free boundary conditions.
Abstract: This paper presents positive and negative full-wave
rectifier. The proposed structure is based on OTA using
commercially available ICs (LT1228). The features of the proposed
circuit are that: it can rectify and amplify voltage signal with
controllable output magnitude via input bias current: the output
voltage is free from temperature variation. The circuit description
merely consists of 1 single ended and 3 fully differential OTAs. The
performance of the proposed circuit are investigated though PSpice.
They show that the proposed circuit can function as positive/negative
full-wave rectifier, where the voltage input wide-dynamic range from
-5V to 5V. Furthermore, the output voltage is slightly dependent on
the temperature variations.
Abstract: Smith Predictor control is theoretically a good solution to the problem of controlling the time delay systems. However, it seldom gets use because it is almost impossible to find out a precise mathematical model of the practical system and very sensitive to uncertain system with variable time-delay. In this paper is concerned with a design method of smith predictor for temperature control system by Coefficient Diagram Method (CDM). The simulation results show that the control system with smith predictor design by CDM is stable and robust whilst giving the desired time domain system performance.
Abstract: To reduce the carbon dioxide emission into the
atmosphere, adsorption is believed to be one of the most attractive
methods for post-combustion treatment of flue gas. In this work,
activated carbon (AC) was modified by polyethylenimine (PEI) via
impregnation in order to enhance CO2 adsorption capacity. The
adsorbents were produced at 0.04, 0.16, 0.22, 0.25, and 0.28 wt%
PEI/AC. The adsorption was carried out at a temperature range from
30 °C to 75 °C and five different gas pressures up to 1 atm. TG-DTA,
FT-IR, UV-visible spectrometer, and BET were used to characterize
the adsorbents. Effects of PEI loading on the AC for the CO2
adsorption were investigated. Effectiveness of the adsorbents on the
CO2 adsorption including CO2 adsorption capacity and adsorption
temperature was also investigated. Adsorption capacities of CO2 were
enhanced with the increase in the amount of PEI from 0.04 to 0.22
wt% PEI before the capacities decreased onwards from0.25 wt% PEI
at 30 °C. The 0.22 wt% PEI/AC showed higher adsorption capacity
than the AC for adsorption at 50 °C to 75 °C.
Abstract: Due to the environmental and price issues of current
energy crisis, scientists and technologists around the globe are
intensively searching for new environmentally less-impact form of
clean energy that will reduce the high dependency on fossil fuel.
Particularly hydrogen can be produced from biomass via thermochemical
processes including pyrolysis and gasification due to the
economic advantage and can be further enhanced through in-situ
carbon dioxide removal using calcium oxide. This work focuses on
the synthesis and development of the flowsheet for the enhanced
biomass gasification process in PETRONAS-s iCON process
simulation software. This hydrogen prediction model is conducted at
operating temperature between 600 to 1000oC at atmospheric
pressure. Effects of temperature, steam-to-biomass ratio and
adsorbent-to-biomass ratio were studied and 0.85 mol fraction of
hydrogen is predicted in the product gas. Comparisons of the results
are also made with experimental data from literature. The
preliminary economic potential of developed system is RM 12.57 x
106 which equivalent to USD 3.77 x 106 annually shows economic
viability of this process.
Abstract: Fixed-bed slow pyrolysis experiments of rice husk
have been conducted to determine the effect of pyrolysis
temperature, heating rate, particle size and reactor length on the
pyrolysis product yields. Pyrolysis experiments were performed at
pyrolysis temperature between 400 and 600°C with a constant
heating rate of 60°C/min and particle sizes of 0.60-1.18 mm. The
optimum process conditions for maximum liquid yield from the rice
husk pyrolysis in a fixed bed reactor were also identified. The highest
liquid yield was obtained at a pyrolysis temperature of 500°C,
particle size of
1.18-1.80 mm, with a heating rate of 60°C/min in a 300 mm length
reactor. The obtained yield of, liquid, gas and solid were found be in
the range of 22.57-31.78 %, 27.75-42.26 % and 34.17-42.52 % (all
weight basics) respectively at different pyrolysis conditions. The
results indicate that the effects of pyrolysis temperature and particle
size on the pyrolysis yield are more significant than that of heating
rate and reactor length. The functional groups and chemical
compositions present in the liquid obtained at optimum conditions
were identified by Fourier Transform-Infrared (FT-IR) spectroscopy
and Gas Chromatography/ Mass Spectroscopy (GC/MS) analysis
respectively.
Abstract: We have investigated the effect of piezoelectric (PZ)
polarization property in binary as well as in ternary wurtzite nitrides.
It is found that with the presence of PZ polarization property, the
phonon group velocity is modified. The change in phonon group
velocity due to PZ polarization effect directly depends on
piezoelectric tensor value. Using different piezoelectric tensor values
recommended by different workers in the literature, percent change in
group velocities of phonons has been estimated. The Debye
temperatures and frequencies of binary nitrides GaN, AlN and InN
are also calculated using the modified group velocities. For ternary
nitrides AlxGa(1-x)N, InxGa(1-x)N and InxAl(1-x)N, the phonon group
velocities have been calculated as a functions of composition. A
small positive bowing is observed in phonon group velocities of
ternary alloys. Percent variations in phonon group velocities are also
calculated for a straightforward comparison among ternary nitrides.
The results are expected to show a change in phonon relaxation rates
and thermal conductivity of III-nitrides when piezoelectric
polarization property is taken into consideration.
Abstract: Direct conversion of methane to methanol by partial oxidation in a thermal reactor has a poor yield of about 2% which is less than the expected economical yield of about 10%. Conventional thermal catalytic reactors have been proposed to be superseded by plasma reactors as a promising approach, due to strength of the electrical energy which can break C-H bonds of methane. Among the plasma techniques, non-thermal dielectric barrier discharge (DBD) plasma chemical process is one of the most future promising technologies in synthesizing methanol. The purpose of this paper is presenting a brief review of CH4 oxidation with O2 in DBD plasma reactors based on the recent investigations. For this reason, the effect of various parameters of reactor configuration, feed ratio, applied voltage, residence time (gas flow rate), type of applied catalyst, pressure and reactor wall temperature on methane conversion and methanol selectivity are discussed.
Abstract: Solutions for the temperature profile around a moving
heat source are obtained using both analytic and finite element
(FEM) methods. Analytic and FEM solutions are applied to study the
temperature profile in welding. A moving heat source is represented
using both point heat source and uniform distributed disc heat source
models. Analytic solutions are obtained by solving the partial
differential equation for energy conservation in a solid, and FEM
results are provided by simulating welding using the ANSYS
software. Comparison is made for quasi steady state conditions. The
results provided by the analytic solutions are in good agreement with
results obtained by FEM.
Abstract: An attempt has been made to determine the strength
and impact properties of Cr-Mo steel weld and base materials by
varying the current during manual metal arc welding. Toughness over
a temperature range from -32 to 100°C of base, heat affected zone
(HAZ) and weld zones at three current settings are made. It is
observed that the deterioration in notch toughness at any zone with
the temperature decreases. The values of notch toughness for all
zones at -32°C are almost same for any current settings. The values
of notch toughness at HAZ area are higher than that of weld area due
to the coarsening of ferrite grain of HAZ occurs with higher heat
input. From microhardness and microstructure result, it can be
concluded that large inclusion content in weld deposit is the cause of
lower notch toughness value.
Abstract: Tungsten trioxide has been prepared by using P-PTA
as a precursor on alumina substrates by spin coating method.
Palladium introduced on WO3 film via electrolysis deposition by
using palladium chloride as catalytic precursor. The catalytic
precursor was introduced on the series of films with different
morphologies. X-ray diffractometry (XRD), Scanning electron
microscopy (SEM) and XPS were applied to analyze structure and
morphology of the fabricated thin films. Then we measured variation
of samples- electrical conductivity of pure and Pd added films in air
and diluted hydrogen. Addition of Pd resulted in a remarkable
improvement of the hydrogen sensing properties of WO3 by detection
of Hydrogen below 1% at room temperature. Also variation of the
electrical conductivity in the presence of diluted hydrogen revealed
that response of samples depends rather strongly on the palladium
configuration on the surface.
Abstract: Semiconductor materials with coatings have a wide range of applications in MEMS and NEMS. This work uses transfermatrix method for calculating the radiative properties. Dopped silicon is used and the coherent formulation is applied. The Drude model for the optical constants of doped silicon is employed. Results showed that for the visible wavelengths, more emittance occurs in greater concentrations and the reflectance decreases as the concentration increases. In these wavelengths, transmittance is negligible. Donars and acceptors act similar in visible wavelengths. The effect of wave interference can be understood by plotting the spectral properties such as reflectance or transmittance of a thin dielectric film versus the film thickness and analyzing the oscillations of properties due to constructive and destructive interferences. But this effect has not been shown at visible wavelengths. At room temperature, the scattering process is dominated by lattice scattering for lightly doped silicon, and the impurity scattering becomes important for heavily doped silicon when the dopant concentration exceeds1018cm-3 .
Abstract: In recent years, many researches to mine the exploding Web world, especially User Generated Content (UGC) such as
weblogs, for knowledge about various phenomena and events in the physical world have been done actively, and also Web services
with the Web-mined knowledge have begun to be developed for
the public. However, there are few detailed investigations on how accurately Web-mined data reflect physical-world data. It must be
problematic to idolatrously utilize the Web-mined data in public Web services without ensuring their accuracy sufficiently. Therefore,
this paper introduces the simplest Web Sensor and spatiotemporallynormalized
Web Sensor to extract spatiotemporal data about a target
phenomenon from weblogs searched by keyword(s) representing the
target phenomenon, and tries to validate the potential and reliability of the Web-sensed spatiotemporal data by four kinds of granularity
analyses of coefficient correlation with temperature, rainfall, snowfall,
and earthquake statistics per day by region of Japan Meteorological
Agency as physical-world data: spatial granularity (region-s population
density), temporal granularity (time period, e.g., per day vs. per week), representation granularity (e.g., “rain" vs. “heavy rain"), and
media granularity (weblogs vs. microblogs such as Tweets).
Abstract: As global industry developed rapidly, the energy
demand also rises simultaneously. In the production process, there’s a
lot of energy consumed in the process. Formally, the energy used in
generating the heat in the production process. In the total energy
consumption, 40% of the heat was used in process heat, mechanical
work, chemical energy and electricity. The remaining 50% were
released into the environment. It will cause energy waste and
environment pollution. There are many ways for recovering the waste
heat in factory. Organic Rankine Cycle (ORC) system can produce
electricity and reduce energy costs by recovering the waste of low
temperature heat in the factory. In addition, ORC is the technology
with the highest power generating efficiency in low-temperature heat
recycling. However, most of factories executives are still hesitated
because of the high implementation cost of the ORC system, even a lot
of heat are wasted. Therefore, this study constructs a nonlinear
mathematical model of waste heat recovery equipment configuration
to maximize profits. A particle swarm optimization algorithm is
developed to generate the optimal facility installation plan for the ORC
system.
Abstract: Accident in spent fuel pool (SFP) of Fukushima
Daiichi Unit 4 showed the importance of continuous monitoring of the
key environmental parameters such as water temperature, water level,
and radiation level in the SFP at accident conditions. Because the SFP
water temperature is one of the key parameters indicating SFP
conditions, its behavior at accident conditions shall be understood to
prepare appropriate measures. This study estimated temporal change
in the SFP water temperature at Kori Unit 1 with 587 MWe for 1 hour
after initiation of a loss-of-pool-cooling accident. For the estimation,
ANSYS CFX 13.0 code was used. The estimation showed that the
increasing rate of the water temperature was 3.90C per hour and the
SFP water temperature could reach 1000C in 25.6 hours after the
initiation of loss-of-pool-cooling accident.
Abstract: Radial flow reactor was focused for large scale
methanol synthesis and in which the heat transfer type was cross-flow.
The effects of operating conditions including the reactor inlet air
temperature, the heating pipe temperature and the air flow rate on the
cross-flow heat transfer was investigated and the results showed that
the temperature profile of the area in front of the heating pipe was
slightly affected by all the operating conditions. The main area whose
temperature profile was influenced was the area behind the heating
pipe. The heat transfer direction according to the air flow directions. In
order to provide the basis for radial flow reactor design calculation, the
dimensionless number group method was used for data fitting of the
bed effective thermal conductivity and the wall heat transfer
coefficient which was calculated by the mathematical model with the
product of Reynolds number and Prandtl number. The comparison of
experimental data and calculated value showed that the calculated
value fit the experimental data very well and the formulas could be
used for reactor designing calculation.
Abstract: A glider is in essence an unpowered vehicle and in this project we designed and built an oceanic glider, designed to operate underwater. This Glider was designed to collect ocean data such as temperature, pressure and (in future measures physical dimensions of the operating environment) and output this data to an external source. Development of the Oceanic Glider required research into various actuation systems that control buoyancy, pitch and yaw and the dynamics of these systems. It also involved the design and manufacture of the Glider and the design and implementation of a controller that enabled the Glider to navigate and move in an appropriate manner.
Abstract: A piston cylinder based high pressure differential
thermal analyzer system is developed to investigate phase
transformations, melting, glass transitions, crystallization behavior of
inorganic materials, glassy systems etc., at ambient to 4 GPa and at
room temperature to 1073 K. The pressure is calibrated by the phase
transition of bismuth and ytterbium and temperature is calibrated
by using thermocouple data chart. The system developed is
calibrated using benzoic acid, ammonium nitrate and it has a
pressure and temperature control of ± 8.9 x 10 -4 GPa , ± 2 K
respectively. The phase transition of Asx Te100-x chalcogenides,
ferrous oxide and strontium boride are studied using the
indigenously developed system.
Abstract: This paper proposes the concept of aerocapture with
aerodynamic-environment-adaptive variable geometry flexible
aeroshell that vehicle deploys. The flexible membrane is composed
of thin-layer film or textile as its aeroshell in order to solve some
problems obstructing realization of aerocapture technique.
Multi-objective optimization study is conducted to investigate
solutions and derive design guidelines. As a result, solutions which
can avoid aerodynamic heating and enlarge the corridor width up
to 10% are obtained successfully, so that the effectiveness of this
concept can be demonstrated. The deformation-use optimum
solution changes its drag coefficient from 1.6 to 1.1, along with the
change in dynamic pressure. Moreover, optimization results show
that deformation-use solution requires the membrane for which
upper temperature limit and strain limit are more than 700 K and
120%, respectively, and elasticity (Young-s modulus) is of order of
106 Pa.