Abstract: The square-lattice Ising model is the simplest system
showing phase transitions (the transition between the paramagnetic
phase and the ferromagnetic phase and the transition between the
paramagnetic phase and the antiferromagnetic phase) and critical
phenomena at finite temperatures. The exact solution of the squarelattice
Ising model with free boundary conditions is not known for
systems of arbitrary size. For the first time, the exact solution of
the Ising model on the square lattice with free boundary
conditions is obtained after classifying all )
spin configurations with the microcanonical transfer matrix. Also, the
phase transitions and critical phenomena of the square-lattice Ising
model are discussed using the exact solution on the square
lattice with free boundary conditions.