Abstract: Nanoemulsions are a class of emulsions with a droplet
size in the range of 50–500 nm and have attracted a great deal of
attention in recent years because it is unique characteristics. The
physicochemical properties of nanoemulsion suggests that it can be
successfully used to recover the residual oil which is trapped in the
fine pore of reservoir rock by capillary forces after primary and
secondary recovery. Oil-in-water nanoemulsion which can be formed
by high-energy emulsification techniques using specific surfactants
can reduce oil-water interfacial tension (IFT) by 3-4 orders of
magnitude. The present work is aimed on characterization of oil-inwater
nanoemulsion in terms of its phase behavior, morphological
studies; interfacial energy; ability to reduce the interfacial tension and
understanding the mechanisms of mobilization and displacement of
entrapped oil blobs by lowering interfacial tension both at the
macroscopic and microscopic level. In order to investigate the
efficiency of oil-water nanoemulsion in enhanced oil recovery
(EOR), experiments were performed to characterize the emulsion in
terms of their physicochemical properties and size distribution of the
dispersed oil droplet in water phase. Synthetic mineral oil and a series
of surfactants were used to prepare oil-in-water emulsions.
Characterization of emulsion shows that it follows pseudo-plastic
behaviour and drop size of dispersed oil phase follows lognormal
distribution. Flooding experiments were also carried out in a
sandpack system to evaluate the effectiveness of the nanoemulsion as
displacing fluid for enhanced oil recovery. Substantial additional
recoveries (more than 25% of original oil in place) over conventional
water flooding were obtained in the present investigation.
Abstract: A simultaneous study on indoor and outdoor particulate matter concentrations was done in five elementary schools in central parts of Tehran, Iran. Three sizes of particles including PM10, PM2.5 and PM1.0 were measured in 13 classrooms within this schools during winter (January, February and March) 2009. A laserbased portable aerosol spectrometer Model Grimm-1.108, was used for the continuous measurement of particles. The average indoor concentration of PM10, PM2.5 and PM1.0 in studied schools were 274 μg/m3, 42 μg/m3 and 19 μg/m3 respectively; and average outdoor concentrations of PM10, PM2.5 and PM1.0 were evaluated to be 22 μg/m3, 38 μg/m3 and 140 μg/m3 respectively.
Abstract: In the present work homogeneous silica film on
silicon was fabricated by colloidal silica sol. The silica sol precursor
with uniformly granular particle was derived by the alkaline
hydrolysis of tetraethoxyorthosilicate (TEOS) in presence of glycerol
template. The film was prepared by dip coating process. The
templated hetero-structured silica film was annealed at elevated
temperatures to generate nano- and meso porosity in the film. The
film was subsequently annealed at different temperatures to make it
defect free and abrasion resistant. The sol and the film were
characterized by the measurement of particle size distribution,
scanning electron microscopy, XRD, FTIR spectroscopy,
transmission electron microscopy, atomic force microscopy,
measurement of the refractive index, thermal conductivity and
abrasion resistance. The porosity of the films decreased whereas
refractive index and dielectric constant of it `increased with the
increase in the annealing temperature. The thermal conductivity of
the films increased with the increase in the film thickness. The
developed porous silica film holds strong potential for use in
different areas.
Abstract: We have developed a microfluidic device system for the continuous producting of nanoparticles, and we have clarified the relationship between the mixing performance of reactors and the particle size. First, we evaluated the mixing performance of reactors by carring out the Villermaux–Dushman reaction and determined the experimental conditions for producing AgCl nanoparticles. Next, we produced AgCl nanoparticles and evaluated the mixing performance and the particle size. We found that as the mixing performance improves the size of produced particles decreases and the particle size distribution becomes sharper. We produced AgCl nanoparticles with a size of 86 nm using the microfluidic device that had the best mixing performance among the three reactors we tested in this study; the coefficient of variation (Cv) of the size distribution of the produced nanoparticles was 26.1%.
Abstract: The present study is aim to prepare and evaluate the selfnanoemulsifying drug delivery (SNEDDS) system of a poorly water soluble drug valsartan in order to achieve a better dissolution rate which would further help in enhancing oral bioavailability. The present research work describes a SNEDDS of valsartan using labrafil M 1944 CS, Tween 80 and Transcutol HP. The pseudoternary phase diagrams with presence and absence of drug were plotted to check for the emulsification range and also to evaluate the effect of valsartan on the emulsification behavior of the phases. The mixtures consisting of oil (labrafil M 1944 CS) with surfactant (tween 80), co-surfactant (Transcutol HP) were found to be optimum formulations. Prepared formulations were evaluated for its particle size distribution, nanoemulsifying properties, robustness to dilution, self emulsication time, turbidity measurement, drug content and invitro dissolution. The optimized formulations are further evaluated for heating cooling cycle, centrifugation studies, freeze thaw cycling, particle size distribution and zeta potential were carried out to confirm the stability of the formed SNEDDS formulations. The prepared formulation revealed t a significant improvement in terms of the drug solubility as compared with marketed tablet and pure drug.
Abstract: Properties of cement pastes with fine-ground ceramics
used as an alternative binder replacing Portland cement up to 20% of
its mass are investigated. At first, the particle size distribution of
cement and fine-ground ceramics is measured using laser analyser.
Then, the material properties are studied in the early hardening
period up to 28 days. The hydration process of studied materials is
monitored by electrical conductivity measurement using TDR
sensors. The changes of materials- structures within the hardening are
observed using pore size distribution measurement. The compressive
strength measurements are done as well. Experimental results show
that the replacement of Portland cement by fine-ground ceramics in
the amount of up to 20% by mass is acceptable solution from the
mechanical point of view. One can also assume similar physical
properties of designed materials to the reference material with only
Portland cement as binder.
Abstract: Zeolite A and MCM-41 have extensive applications in basic science, petrochemical science, energy conservation/storage, medicine, chemical sensor, air purification, environmentally benign composite structure and waste remediation. However, the use of zeolite A and MCM-41 in these areas, especially environmental remediation, are restricted due to prohibitive production cost. Efficient recycling of and resource recovery from coal fly ash has been a major topic of current international research interest, aimed at achieving sustainable development of human society from the viewpoints of energy, economy, and environmental strategy. This project reported an original, novel, green and fast methods to produce nano-porous zeolite A and MCM-41 materials from coal fly ash. For zeolite A, this novel production method allows a reduction by half of the total production time while maintaining a high degree of crystallinity of zeolite A which exists in a narrower particle size distribution. For MCM-41, this remarkably green approach, being an environmentally friendly process and reducing generation of toxic waste, can produce pure and long-range ordered MCM-41 materials from coal fly ash. This approach took 24 h at 25 oC to produce 9 g of MCM-41 materials from 30 g of the coal fly ash, which is the shortest time and lowest reaction temperature required to produce pure and ordered MCM-41 materials (having the largest internal surface area) compared to the values reported in the literature. Performance evaluation of the produced zeolite A and MCM-41 materials in wastewater treatment and air pollution control were reported. The residual fly ash was also converted to zeolite Na-P1 which showed good performance in removal of multi-metal ions in wastewater. In wastewater treatment, compared to commercial-grade zeolite A, adsorbents produced from coal fly ash were effective in removing multi heavy metal ions in water and could be an alternative material for treatment of wastewater. In methane emission abatement, the zeolite A (produced from coal fly ash) achieved similar methane removal efficiency compared to the zeolite A prepared from pure chemicals. This report provides the guidance for production of zeolite A and MCM-41 from coal fly ash by a cost-effective approach which opens potential applications of these materials in environmental industry. Finally, environmental and economic aspects of production of zeolite A and MCM-41 from coal fly ash were discussed.
Abstract: The present work compares the performance of three
turbulence modeling approach (based on the two-equation k -ε
model) in predicting erosive wear in multi-size dense slurry flow
through rotating channel. All three turbulence models include
rotation modification to the production term in the turbulent kineticenergy
equation. The two-phase flow field obtained numerically
using Galerkin finite element methodology relates the local flow
velocity and concentration to the wear rate via a suitable wear model.
The wear models for both sliding wear and impact wear mechanisms
account for the particle size dependence. Results of predicted wear
rates using the three turbulence models are compared for a large
number of cases spanning such operating parameters as rotation rate,
solids concentration, flow rate, particle size distribution and so forth.
The root-mean-square error between FE-generated data and the
correlation between maximum wear rate and the operating
parameters is found less than 2.5% for all the three models.
Abstract: The mechanical properties of granular solids are
dependent on the flow of stresses from one particle to another
through inter-particle contact. Although some experimental methods
have been used to study the inter-particle contacts in the past,
preliminary work with these techniques indicated that they do not
have the necessary resolution to distinguish between those contacts
that transmit the load and those that do not, especially for systems
with a wide distribution of particle sizes. In this research, computer
simulations are used to study the nature and distribution of contacts
in a compact with wide particle size distribution, representative of
aggregate size distribution used in asphalt pavement construction.
The packing fraction, the mean number of contacts and the
distribution of contacts were studied for different scenarios. A
methodology to distinguish and compute the fraction of load-bearing
particles and the fraction of space-filling particles (particles that do
not transmit any force) is needed for further investigation.
Abstract: This paper presents a review on published literature
and experimental works on local sands for possible use as proppant,
specifically those from Terengganu coastal area. This includes
examination on characteristics of sand samples and selection of
experiments for proppant testing. Sand samples from identified areas
were tested according to particle size distribution, density, roundness
and sphericity, turbidity and mineralogy. Results from sand samples
were compared against proppant specifications set by API RP 56 and
selected commercial proppants. The present study found that the size
distribution, sphericity, turbidity and bulk density of Terengganu
sands are at par with some of commercial proppants. Nevertheless,
Terengganu sand samples do not completely surpass the required
roundness for use as proppant.