Abstract: The environmental performance of rapeseed oil (RO)
and rapeseed methyl ester(RME) from winter rape as fuels produced
in Romanian agroclimate is analyzed in this paper. The proposed
methodology is life cycle assessment (LCA) and takes into
consideration the influence of grain production and agroclimatic
conditions. This study shows favorable results first for RO and then
for RME. When compared to diesel fuel, both studied biofuels show
better results in the following impact categories: Abiotic depletion
potential (ADP), Ozone layer depletion (ODP) and Photochemical
ozone creation potential (POCP).Furthermore, the environmental
performance of the two biofuels studied can be improved by
changing the type of fertilizer used and also by using biofuels instead
of diesel in the field works.
Abstract: The shelf life of fish was extended using disinfection
properties of ozone. For this purpose, Trout specimens were exposed
to ozone in the aqueous media for two hours and their microbial
growth and biochemical properties were measured over time.
Microbial growth of ozone treated fish was significantly slower than
control sample, resulting in lower counts of bacteria. According to
the biochemical tests; ozone treatment had no negative effects on fat,
protein and humidity of fish. Peroxide and TVN (Total Volatile
Nitrogen) measurements showed that treatment by ozone increased
the trout shelf life from 4 days to 6 days. According to the sensory
analysis, no changes were observed in color or flavor of the ozone
treated trout.
Abstract: This study investigates the in-situ regeneration of deactivated Pt-Pd catalyst in a laboratory-scale catalysis reactor. Different regeneration conditions are tested and the activity and characteristics of regenerated catalysts are analyzed. Experimental results show that the conversion efficiencies of C3H6 by different regenerated Pt-Pd catalysts were significantly improved from 77%, 55% and 41% to 86%, 98% and 99%, respectively. The best regeneration conditions was 52ppm ozone, 500oC, and 10min. Regeneration temperature has more influences than ozone concentration and regeneration time. With the comparisons of characteristics of deactivated catalyst and regenerated catalyst, the major poison species (carbon, metals, chloride, and sulfate) on the spent catalysts can be effectively removed by ozone regeneration.
Abstract: Four phenylurea herbicides (isoproturon, chlortoluron, diuron and linuron) were dissolved in different water matrices in order to study their chemical degradation by using UV radiation, ozone and some advanced oxidation processes (UV/H2O2, O3/H2O2, Fenton reagent and the photo- Fenton system). The waters used were: ultra-pure water, a commercial mineral water, a groundwater and a surface water taken from a reservoir. Elimination levels were established for each herbicide and for several global quality parameters, and a kinetic study was performed in order to determine basic kinetic parameters of each reaction between the target phenylureas and these oxidizing systems.
Abstract: Ozone (O3) is considered as one of the most
phytotoxic pollutants with deleterious effects on living and non living
components of Ecosystems. It reduces growth and yield of many
crops as well as alters the physiology and crop quality. The present
study described series of experiments to investigate the effects of
ambient O3 at different locations with different ambient levels of O3
depending on proximity to pollutant source and ranged between 17
ppb/h in control experiment to 112 ppb/h in industrial area
respectively. The ambient levels in other three locations (King Saud
University botanical garden, King Fahd Rd, and Almanakh Garden)
were 61,61,77 ppb/h respectively. Tow legume crops species (vicia
vaba L ; and Pisum sativum) differ in their phenology and sensitivity
were used. The results showed a significant negative effect to ozone
on morphology, number of injured leaves, growth and productivity
with a difference in the degree of response depending on the plant
type. Visia Faba showed sensitivity to ozone to number and leaf area
and the degree of injury leaves 3, pisum sativum show higher
sensitivity for the gas for degree of injury 1,The relative growth rate
and seed weight, it turns out there is no significant difference
between the two plants in plant height and number of seeds.
Abstract: Cu-mesoporous TiO2 is developed for removal acid
odor cooperated with ozone assistance and online- regeneration
system with/without UV irradiation (all weather) in study. The results
showed that Cu-mesoporous TiO2 present the desirable adsorption
efficiency of acid odor without UV irradiation, due to the larger
surface area, pore sizeand the additional absorption ability provided by
Cu. In the photocatalysis process, the material structure also benefits
Cu-mesoporous TiO2 to perform the more outstanding efficiency on
degrading acid odor. Cu also postponed the recombination of
electron-hole pairs excited from TiO2 to enhance photodegradation
ability. Cu-mesoporous TiO2 could gain the conspicuous increase on
photocatalysis ability from ozone assistance, but without any benefit
on adsorption. In addition, the online regeneration procedure could
process the used Cu-mesoporous TiO2 to reinstate the adsorption
ability and maintain the photodegradtion performance, depended on
scrubbing, desorping acid odor and reducing Cu to metal state.
Abstract: The Bulgarian natural expanded mineral obtained from Bentonite AD perlite (A deposit of "The Broken Mountain" for perlite mining, near by the village of Vodenicharsko, in the municipality of Djebel), was loaded with silver (as ion form - Ag+ 2 and 5 wt% by the incipient wetness impregnation method), and as atomic silver - Ag0 using Tollen-s reagent (silver mirror reaction). Some physicochemical characterization of the samples are provided via: DC arc-AES, XRD, DR-IR and UV-VIS. The aim of this work was to obtain and test the silver-loaded catalyst for ozone decomposition. So the samples loaded with atomic silver show ca. 80% conversion of ozone 20 minutes after the reaction start. Then conversion decreases to ca. 20 % but stay stable during the prolongation of time.
Abstract: The degradation of selected pharmaceuticals in some
water matrices was studied by using several chemical treatments. The
pharmaceuticals selected were the beta-blocker metoprolol, the
nonsteroidal anti-inflammatory naproxen, the antibiotic amoxicillin,
and the analgesic phenacetin; and their degradations were conducted
by using UV radiation alone, ozone, Fenton-s reagent, Fenton-like
system, photo-Fenton system, and combinations of UV radiation and
ozone with H2O2, TiO2, Fe(II), and Fe(III). The water matrices, in
addition to ultra-pure water, were a reservoir water, a groundwater,
and two secondary effluents from two municipal WWTP. The results
reveal that the presence of any second oxidant enhanced the
oxidation rates, with the systems UV/TiO2 and O3/TiO2 providing the
highest degradation rates. It is also observed in most of the
investigated oxidation systems that the degradation rate followed the
sequence: amoxicillin > naproxen > metoprolol > phenacetin. Lower
rates were obtained with the pharmaceuticals dissolved in natural
waters and secondary effluents due to the organic matter present
which consume some amounts of the oxidant agents.
Abstract: This study uses natural water and the surface properties of powdered activated carbon to acclimatize organics, forming biofilms on the surface of powdered activated carbon. To investigate the influence of different hydraulic retention times on the removal efficacy of trace organics in raw water, and to determine the optimal hydraulic retention time of a biological powdered activated carbon system, this study selects ozone-treated water processed by Feng-shan Advanced Water Purification Plant in southern Taiwan for the experiment. The evaluation indicators include assimilable organic carbon, dissolved organic carbon, and total organic carbon. The results of this study can improve the quality of drinking water treated using advanced water purification procedures.
Abstract: Ground-level tropospheric ozone is one of the air
pollutants of most concern. It is mainly produced by photochemical
processes involving nitrogen oxides and volatile organic compounds
in the lower parts of the atmosphere. Ozone levels become
particularly high in regions close to high ozone precursor emissions
and during summer, when stagnant meteorological conditions with
high insolation and high temperatures are common.
In this work, some results of a study about urban ozone
distribution patterns in the city of Badajoz, which is the largest and
most industrialized city in Extremadura region (southwest Spain) are
shown. Fourteen sampling campaigns, at least one per month, were
carried out to measure ambient air ozone concentrations, during
periods that were selected according to favourable conditions to
ozone production, using an automatic portable analyzer.
Later, to evaluate the ozone distribution at the city, the measured
ozone data were analyzed using geostatistical techniques. Thus, first,
during the exploratory analysis of data, it was revealed that they were
distributed normally, which is a desirable property for the subsequent
stages of the geostatistical study. Secondly, during the structural
analysis of data, theoretical spherical models provided the best fit for
all monthly experimental variograms. The parameters of these
variograms (sill, range and nugget) revealed that the maximum
distance of spatial dependence is between 302-790 m and the
variable, air ozone concentration, is not evenly distributed in reduced
distances. Finally, predictive ozone maps were derived for all points
of the experimental study area, by use of geostatistical algorithms
(kriging). High prediction accuracy was obtained in all cases as
cross-validation showed. Useful information for hazard assessment
was also provided when probability maps, based on kriging
interpolation and kriging standard deviation, were produced.
Abstract: The elimimation of mefenamic acid has been carried
out by photolysis, ozonation, adsorption onto activated carbon (AC)
and combinations of the previous single systems (O3+AC and
O3+UV). The results obtained indicate that mefenamic acid is not
photo-reactive, showing a relatively low quantum yield of the order
of 6 x 10-4 mol Einstein-1. Application of ozone to mefenamic
aqueous solutions instantaneously eliminates the pharmaceutical,
achieving simultaneously a 40% of mineralization. Addition of AC to
the ozonation process does not enhance the process, moreover,
mineralization is completely inhibited if compared to results obtained
by single ozonation. The combination of ozone and UV radiation led
to the best results in terms of mineralization (60% after 120 min).
Abstract: This paper reports the three-phase (gas + liquid +
hydrate) equilibrium pressure versus temperature data for a (O3 + O2 +
CO2 + H2O) system for developing the hydrate-based technology to
preserve ozone, a chemically unstable substance, for various
industrial, medical and consumer uses. These data cover the
temperature range from 272 K to 277 K, corresponding to pressures
from 1.6 MPa to 3.1 MPa, for each of the three different (O3 +
O2)-to-CO2 or O2-to-CO2 molar ratios in the gas phase, which are
approximately 4 : 6, 5 : 5, respectively. The mole fraction of ozone in
the gas phase was ~0.03 , which are the densest ozone fraction to
artificially form O3 containing hydrate ever reported in the literature.
Based on these data, the formation of hydrate containing
high-concentration ozone, as high as 1 mass %, will be expected.
Abstract: This paper focuses on sovereign credit risk meaning a
hot topic related to the current Eurozone crisis. In the light of the
recent financial crisis, market perception of the creditworthiness of
individual sovereigns has changed significantly. Before the outbreak
of the financial crisis, market participants did not differentiate
between credit risk born by individual states despite different levels
of public indebtedness. In the proceeding of the financial crisis, the
market participants became aware of the worsening fiscal situation in
the European countries and started to discriminate among
government issuers. Concerns about the increasing sovereign risk
were reflected in surging sovereign risk premium. The main of this
paper is to shed light on the characteristics of the sovereign risk with
the special attention paid to the mutual relation between credit spread
and the CDS premium as the main measures of the sovereign risk
premium.
Abstract: Chlorine is one of the most abundant elements in
nature, which undergoes a complex biogeochemical cycle. Chlorine
bound in some substances is partly responsible for atmospheric ozone
depletion and contamination of some ecosystems. As due to
international regulations anthropogenic burden of volatile
organochlorines (VOCls) in atmosphere decreases, natural sources
(plants, soil, abiotic formation) are expected to dominate VOCl
production in the near future. Examples of plant VOCl production are
methyl chloride, and bromide emission from (sub)tropical ferns,
chloroform, 1,1,1-trichloroethane and tetrachloromethane emission
from temperate forest fern and moss. Temperate forests are found to
emit in addition to the previous compounds tetrachloroethene, and
brominated volatile compounds. VOCls can be taken up and further
metabolized in plants. The aim of this work is to identify and
quantitatively analyze the formed VOCls in temperate forest
ecosystems by a cryofocusing/GC-ECD detection method, hence
filling a gap of knowledge in the biogeochemical cycle of chlorine.
Abstract: Most often the contaminants are not taken seriously into consideration, and this behavior comes out directly from the lack of monitoring and professional reporting about pollution in the printing facilities in Serbia. The goal of planned and systematic ozone measurements in ambient air of the screen printing facilities in Novi Sad is to examine of its impact on the employees health, and to track trends in concentration. In this study, ozone concentrations were determined by using discontinuous and continuous method during the automatic and manual screen printing process. Obtained results indicates that the average concentrations of ozone measured during the automatic process were almost 3 to 28 times higher for discontinuous and 10 times higher for continuous method (1.028 ppm) compared to the values prescribed by OSHA. In the manual process, average concentrations of ozone were within prescribed values for discontinuous and almost 3 times higher for continuous method (0.299 ppm).
Abstract: Accurate and comprehensive thermodynamic properties of pure and mixture of refrigerants are in demand by both producers and users of these materials. Information about thermodynamic properties is important initially to qualify potential candidates for working fluids in refrigeration machinery. From practical point of view, Refrigerants and refrigerant mixtures are widely used as working fluids in many industrial applications, such as refrigerators, heat pumps, and power plants The present work is devoted to evaluating seven cubic equations of state (EOS) in predicting gas and liquid phase volumetric properties of nine ozone-safe refrigerants both in super and sub-critical regions. The evaluations, in sub-critical region, show that TWU and PR EOS are capable of predicting PVT properties of refrigerants R32 within 2%, R22, R134a, R152a and R143a within 1% and R123, R124, R125, TWU and PR EOS's, from literature data are 0.5% for R22, R32, R152a, R143a, and R125, 1% for R123, R134a, and R141b, and 2% for R124. Moreover, SRK EOS predicts PVT properties of R22, R125, and R123 to within aforementioned errors. The remaining EOS's predicts volumetric properties of this class of fluids with higher errors than those above mentioned which are at most 8%.In general, the results are in favor of the preference of TWU and PR EOS over other remaining EOS's in predicting densities of all mentioned refrigerants in both super and sub critical regions. Typically, this refrigerant is known to offer advantages such as ozone depleting potential equal to zero, Global warming potential equal to 140, and no toxic.
Abstract: Shortening of natural resources will impose greater
limitations of electric energy consumption in various fields including
water treatment technologies. Small water treatment installations
supplied with electric energy from solar sources are perfect example of
zero-emission technology. Possibility of solar energy application, as
one of the alternative energy resources for decontamination processes
is strongly dependent on geographical location. Various examples of
solar driven water purification systems are given and design of
solar-water treatment installation based on ozone for the geographical
conditions in Poland are presented.
Abstract: Water is the key of national development. Wherever a spring has been dried out or a river has changed its course, the area-s people have migrated and have been scattered and the area-s civilization has lost its brilliance. Today, air pollution, global warming and ozone layer damage are as the problems of countries, but certainly in the next decade the shortage and pollution of waters will be important issues of the world. The polluted waters are more dangerous in when they are used in agriculture. Because they infect plants and these plants are used in human and livestock consumption in food chain. With the increasing population growth and after that, the increase need to facilities and raw materials, human beings has started to do haste actions and wanted or unwanted destroyed his life basin. They try to overuse and capture his environment extremely, instead of having futurism approach in sustainable use of nature. This process includes Zayanderood recession, and caused its pollution after the transition from industrial and urban areas. Zayandehrood River in Isfahan is a vital artery of a living ecosystem. Now is the location of disposal waste water of many cities, villages and existing industries. The central area of the province is an important industrial place, and its environmental situation has reached a critical stage. Not only a large number of pollution-generating industries are active in the city limits, but outside of the city and adjacent districts Zayandehrood River, heavy industries like steel, Mobarakeh Steel and other tens great units pollute wild life. This article tries to study contaminant sources of Zayanderood and their severity, and determine and discuss the share of each of these resources by major industrial centers located in areas. At the end, we represent suitable strategy.
Abstract: A sequential treatment of ozonation followed by a
Fenton or photo-Fenton process, using black light lamps (365 nm) in
this latter case, has been applied to remove a mixture of
pharmaceutical compounds and the generated by-products both in
ultrapure and secondary treated wastewater. The scientifictechnological
innovation of this study stems from the in situ
generation of hydrogen peroxide from the direct ozonation of
pharmaceuticals, and can later be used in the application of Fenton
and photo-Fenton processes. The compounds selected as models
were sulfamethoxazol and acetaminophen. It should be remarked that
the use of a second process is necessary as a result of the low
mineralization yield reached by the exclusive application of ozone.
Therefore, the influence of the water matrix has been studied in terms
of hydrogen peroxide concentration, individual compound
concentration and total organic carbon removed. Moreover, the
concentration of different iron species in solution has been measured.
Abstract: It is well recognized that the green house gases such
as Chlorofluoro Carbon (CFC), CH4, CO2 etc. are responsible
directly or indirectly for the increase in the average global temperature
of the Earth. The presence of CFC is responsible for
the depletion of ozone concentration in the atmosphere due to
which the heat accompanied with the sun rays are less absorbed
causing increase in the atmospheric temperature of the Earth. The
gases like CH4 and CO2 are also responsible for the increase in
the atmospheric temperature. The increase in the temperature level
directly or indirectly affects the dynamics of interacting species
systems. Therefore, in this paper a mathematical model is proposed
and analysed using stability theory to asses the effects of increasing
temperature due to greenhouse gases on the survival or extinction of
populations in a prey-predator system. A threshold value in terms
of a stress parameter is obtained which determines the extinction or
existence of populations in the underlying system.