Abstract: Transient simulation of the hydrogen-assisted self-ignition of propane-air mixtures were carried out in platinum-coated micro-channels from ambient cold-start conditions, using a two-dimensional model with reduced-order reaction schemes, heat conduction in the solid walls, convection and surface radiation heat transfer. The self-ignition behavior of hydrogen-propane mixed fuel is analyzed and compared with the heated feed case. Simulations indicate that hydrogen can successfully cause self-ignition of propane-air mixtures in catalytic micro-channels with a 0.2 mm gap size, eliminating the need for startup devices. The minimum hydrogen composition for propane self-ignition is found to be in the range of 0.8-2.8% (on a molar basis), and increases with increasing wall thermal conductivity, and decreasing inlet velocity or propane composition. Higher propane-air ratio results in earlier ignition. The ignition characteristics of hydrogen-assisted propane qualitatively resemble the selectively inlet feed preheating mode. Transient response of the mixed hydrogen- propane fuel reveals sequential ignition of propane followed by hydrogen. Front-end propane ignition is observed in all cases. Low wall thermal conductivities cause earlier ignition of the mixed hydrogen-propane fuel, subsequently resulting in low exit temperatures. The transient-state behavior of this micro-scale system is described, and the startup time and minimization of hydrogen usage are discussed.
Abstract: Geopolymer (cement-free) concrete is the most promising green alternative to ordinary Portland cement concrete and other cementitious materials. While a range of different geopolymer concretes have been produced, a common feature of these concretes is heat curing treatment which is essential in order to provide sufficient mechanical properties in the early age. However, there are several practical issues with the application of heat curing in large-scale structures. The purpose of this study is to develop cement-free concrete without heat curing treatment. Experimental investigations were carried out in two phases. In the first phase (Phase A), the optimum content of water, polycarboxylate based superplasticizer contents and potassium silicate activator in the mix was determined. In the second stage (Phase B), the effect of ground granulated blast furnace slag (GGBFS) incorporation on the compressive strength of fly ash (FA) and Slag based geopolymer mixtures was evaluated. Setting time and workability were also conducted alongside with compressive tests. The results showed that as the slag content was increased the setting time was reduced while the compressive strength was improved. The obtained compressive strength was in the range of 40-50 MPa for 50% slag replacement mixtures. Furthermore, the results indicated that increment of water and superplasticizer content resulted to retarding of the setting time and slight reduction of the compressive strength. The compressive strength of the examined mixes was considerably increased as potassium silicate content was increased.
Abstract: Wetting efficiency of microstructures or nanostructures patterned on Si wafers is a real challenge in integrated circuits manufacturing. In fact, bad or non-uniform wetting during wet processes limits chemical reactions and can lead to non-complete etching or cleaning inside the patterns and device defectivity. This issue is more and more important with the transistors size shrinkage and concerns mainly high aspect ratio structures. Deep Trench Isolation (DTI) structures enabling pixels’ isolation in imaging devices are subject to this phenomenon. While low-frequency acoustic reflectometry principle is a well-known method for Non Destructive Test applications, we have recently shown that it is also well suited for nanostructures wetting characterization in a higher frequency range. In this paper, we present a high-frequency acoustic reflectometry characterization of DTI wetting through a confrontation of both experimental and modeling results. The acoustic method proposed is based on the evaluation of the reflection of a longitudinal acoustic wave generated by a 100 µm diameter ZnO piezoelectric transducer sputtered on the silicon wafer backside using MEMS technologies. The transducers have been fabricated to work at 5 GHz corresponding to a wavelength of 1.7 µm in silicon. The DTI studied structures, manufactured on the wafer frontside, are crossing trenches of 200 nm wide and 4 µm deep (aspect ratio of 20) etched into a Si wafer frontside. In that case, the acoustic signal reflection occurs at the bottom and at the top of the DTI enabling its characterization by monitoring the electrical reflection coefficient of the transducer. A Finite Difference Time Domain (FDTD) model has been developed to predict the behavior of the emitted wave. The model shows that the separation of the reflected echoes (top and bottom of the DTI) from different acoustic modes is possible at 5 Ghz. A good correspondence between experimental and theoretical signals is observed. The model enables the identification of the different acoustic modes. The evaluation of DTI wetting is then performed by focusing on the first reflected echo obtained through the reflection at Si bottom interface, where wetting efficiency is crucial. The reflection coefficient is measured with different water / ethanol mixtures (tunable surface tension) deposited on the wafer frontside. Two cases are studied: with and without PFTS hydrophobic treatment. In the untreated surface case, acoustic reflection coefficient values with water show that liquid imbibition is partial. In the treated surface case, the acoustic reflection is total with water (no liquid in DTI). The impalement of the liquid occurs for a specific surface tension but it is still partial for pure ethanol. DTI bottom shape and local pattern collapse of the trenches can explain these incomplete wetting phenomena. This high-frequency acoustic method sensitivity coupled with a FDTD propagative model thus enables the local determination of the wetting state of a liquid on real structures. Partial wetting states for non-hydrophobic surfaces or low surface tension liquids are then detectable with this method.
Abstract: This paper discusses the effect of using blast furnace iron slag as a part of fine aggregate on the mechanical performance of hot mix asphalt (HMA). The mechanical performance was evaluated based on various mechanical properties that include; Marshall/stiffness, indirect tensile strength and unconfined compressive strength. The effect of iron slag content on the mechanical properties of the mixtures was also investigated. Four HMA with various iron slag contents, namely; 0%, 5%, 10% and 15% by weight of total mixture were studied. Laboratory testing has revealed an enhancement in the compressive strength of HMA when iron slag was used. Within the tested range of iron slag content, a considerable increase in the compressive strength of the mixtures was observed with the increase of slag content. No significant improvement on Marshall/stiffness and indirect tensile strength of the mixtures was observed when slag was used. Even so, blast furnace iron slag can still be used in asphalt paving for environmental advantages.
Abstract: We investigate the performance of an integrated cascade (IC) refrigeration system which uses environment friendly zeotropic mixtures. Computational calculation has been carried out by varying pressure level at the evaporator and the condenser of the system. Effects of mass flow rate of the refrigerant on the coefficient of performance (COP) are presented. We show that the integrated cascade system produces ultra-low temperatures in the evaporator by using environment friendly zeotropic mixture.
Abstract: This paper discusses the applicability of the numerical model for a damage prediction method of the accidental hydrogen explosion occurring in a hydrogen facility. The numerical model was based on an unstructured finite volume method (FVM) code “NuFD/FrontFlowRed”. For simulating unsteady turbulent combustion of leaked hydrogen gas, a combination of Large Eddy Simulation (LES) and a combustion model were used. The combustion model was based on a two scalar flamelet approach, where a G-equation model and a conserved scalar model expressed a propagation of premixed flame surface and a diffusion combustion process, respectively. For validation of this numerical model, we have simulated the previous two types of hydrogen explosion tests. One is open-space explosion test, and the source was a prismatic 5.27 m3 volume with 30% of hydrogen-air mixture. A reinforced concrete wall was set 4 m away from the front surface of the source. The source was ignited at the bottom center by a spark. The other is vented enclosure explosion test, and the chamber was 4.6 m × 4.6 m × 3.0 m with a vent opening on one side. Vent area of 5.4 m2 was used. Test was performed with ignition at the center of the wall opposite the vent. Hydrogen-air mixtures with hydrogen concentrations close to 18% vol. were used in the tests. The results from the numerical simulations are compared with the previous experimental data for the accuracy of the numerical model, and we have verified that the simulated overpressures and flame time-of-arrival data were in good agreement with the results of the previous two explosion tests.
Abstract: The application of recycle waste tires into civil
engineering practices, namely asphalt paving mixtures and cementbased
materials has been gaining ground across the world. This
review summarizes and compares the recent achievements in the area
of plain rubberized concrete (PRC), in details. Different treatment
methods have been discussed to improve the performance of
rubberized Portland cement concrete. The review also includes the
effects of size and amount of tire rubbers on mechanical and
durability properties of PRC. The microstructure behaviour of the
rubberized concrete was detailed.
Abstract: The rheological response of blends obtained from
quaternized polysulfone and polyvinyl alcohol in N-methyl-2-
pyrrolidone as against structural peculiarity of polymers from the
blend, composition of polymer mixtures, as well as the types of
interactions were investigated. Results show that the variation of
polyvinyl alcohol composition in the studied system determines
changes of the rheological properties, suggesting that the PVA acts as
a plasticizer. Consequently, rheological behavior of complex system,
described by the nonlinear flow curve, indicates the impact of
polyvinil alcohol content to polysulfone solution, in order to facilitate
the subsequently preparation of bioactive membranes.
Abstract: In India, most of the pavement is laid by bituminous
road and the consumption of binder is high for pavement construction
and also modified binders are used to satisfy any specific pavement
requirement. Since the binders are visco-elastic material which is
having the mechanical properties of binder transition from viscoelastic
solid to visco-elastic fluid. In this paper, two different
protocols were used to measure the viscosity property of binder using
a Brookfield Viscometer and there is a need to find the appropriate
mixing and compaction temperatures of various types of binders
which can result in complete aggregate coating and adequate field
density of HMA mixtures. The aim of this work is to find the
transition temperature from Non-Newtonian behavior to Newtonian
behavior of the binder by adopting a steady shear protocol and the
shear rate ramp protocol. The transition from non-Newtonian to
Newtonian can occur through an increase of temperature and shear of
the material. The test has been conducted for unmodified binder VG
30. The transition temperature was found in the unmodified binder
VG is 120oC. Therefore, the application of both modified binder and
unmodified binder in the pavement construction needs to be studied
properly by considering temperature and traffic loading factors of the
respective project site.
Abstract: Response Surface Methods (RSM) provide
statistically validated predictive models that can then be manipulated
for finding optimal process configurations. Variation transmitted to
responses from poorly controlled process factors can be accounted
for by the mathematical technique of propagation of error (POE),
which facilitates ‘finding the flats’ on the surfaces generated by
RSM. The dual response approach to RSM captures the standard
deviation of the output as well as the average. It accounts for
unknown sources of variation. Dual response plus propagation of
error (POE) provides a more useful model of overall response
variation. In our case, we implemented this technique in predicting
compressive strength of concrete of 28 days in age. Since 28 days is
quite time consuming, while it is important to ensure the quality
control process. This paper investigates the potential of using design
of experiments (DOE-RSM) to predict the compressive strength of
concrete at 28th day. Data used for this study was carried out from
experiment schemes at university of Benghazi, civil engineering
department. A total of 114 sets of data were implemented. ACI mix
design method was utilized for the mix design. No admixtures were
used, only the main concrete mix constituents such as cement, coarseaggregate,
fine aggregate and water were utilized in all mixes.
Different mix proportions of the ingredients and different water
cement ratio were used. The proposed mathematical models are
capable of predicting the required concrete compressive strength of
concrete from early ages.
Abstract: In this work, our goal is to optimize the nitriding treatment at a low-temperature of the steel 32CrMoV13 using gas mixtures of ammonia, nitrogen and hydrogen to improve the mechanical properties of the surface (good wear resistance, friction and corrosion), and of the diffusion layer of the nitrogen (good resistance to fatigue and good tenacity with heart). By limiting our work to the pure iron and to the alloys iron-chromium and iron-chromium-carbon, we have studied the various parameters which manage the nitriding: flow rate and composition of the gaseous phase, the interaction chromium-nitrogen and chromium-carbon by the help of experiments of nitriding realized in the laboratory by thermogravimetry. The acquired knowledge has been applied by the mastery of the growth of the γ' combination layer on the α diffusion layer in the case of the industrial steel 32CrMoV13.
Abstract: Within this paper, latest results on processing of energetic nanomaterials by means of the Spray Flash Evaporation technique are presented. This technology constitutes a highly effective and continuous way to prepare fascinating materials on the nano- and micro-scale. Within the process, a solution is set under high pressure and sprayed into an evacuated atomization chamber. Subsequent ultrafast evaporation of the solvent leads to an aerosol stream, which is separated by cyclones or filters. No drying gas is required, so the present technique should not be confused with spray dying. Resulting nanothermites, insensitive explosives or propellants and compositions are foreseen to replace toxic (according to REACH) and very sensitive matter in military and civil applications. Diverse examples are given in detail: nano-RDX (n-Cyclotrimethylentrinitramin) and nano-aluminum based systems, mixtures (n-RDX/n-TNT - trinitrotoluene) or even cocrystalline matter like n-CL-20/HMX (Hexanitrohexaazaisowurtzitane/ Cyclotetra-methylentetranitramin). These nanomaterials show reduced sensitivity by trend without losing effectiveness and performance. An analytical study for material characterization was performed by using Atomic Force Microscopy, X-Ray Diffraction, and combined techniques as well as spectroscopic methods. As a matter of course, sensitivity tests regarding electrostatic discharge, impact, and friction are provided.
Abstract: A clay soil classified as A-7-6 and CH soil according
to AASHTO and unified soil classification system respectively, was
stabilized using A-3 soil (AASHTO soil classification system). The
clay soil was replaced with 0%, 10%, 20%, to 100% A-3 soil,
compacted at both British Standard Light (BSL) and British Standard
Heavy (BSH) compaction energy levels and using Unconfined
Compressive Strength (UCS) as evaluation criteria. The Maximum
Dry Density (MDD) of the treated soils at both the BSL and BSH
compaction energy levels showed increase from 0% to 40% A-3 soil
replacement after which the values reduced to 100% replacement.
The trend of the Optimum Moisture Content (OMC) with varied A-3
soil replacement was similar to that of MDD but in a reversed order.
The OMC reduced from 0% to 40% A-3 soil replacement after which
the values increased to 100% replacement. This trend was attributed
to the observed reduction in void ratio from 0% to 40% replacement
after which the void ratio increased to 100% replacement. The
maximum UCS for the soil at varied A-3 soil replacement increased
from 272 and 770 kN/m2 for BSL and BSH compaction energy level
at 0% replacement to 295 and 795 kN/m2 for BSL and BSH
compaction energy level respectively at 10% replacement after which
the values reduced to 22 and 60 kN/m2 for BSL and BSH compaction
energy level respectively at 70% replacement. Beyond 70%
replacement, the mixtures could not be moulded for UCS test.
Abstract: Natural admixtures provide concrete with enhanced
properties but their processing end up making them very expensive
resulting in increase to cost of concrete. In this study the effect
of Gum from Acacia Karroo (GAK) as set-retarding admixture
in cement pastes was studied. The possibility of using GAK as
water reducing admixture both in cement mortar concrete was
also investigated. Cement pastes with different dosages of GAK
were prepared to measure the setting time using different dosages.
Compressive strength of cement mortars with 0.7, 0.8 and 0.9%
weight of cement and w/c ratio of 0.5 were compared to those with
water cement (w/c) ratio of 0.44 but same dosage of GAK. Concrete
samples were prepared using higher dosages of GAK (1, 2 and 3%
wt of cement) and a water bidder (w/b) of 0.61 were compared to
those with the same GAK dosage but with reduced w/b ratio. There
was increase in compressive strength of 9.3% at 28 days for cement
mortar samples with 0.9% dosage of GAK and reduced w/c ratio.
Abstract: Asphalt concrete pavements have a short life cycle,
failing mainly due to temperature changes, traffic loading and ageing.
Modified asphalt mixtures provide the technology to produce a
bituminous binder with improved viscoelastic properties, which
remain in balance over a wider temperature range and loading
conditions. In this research, 60/70 penetration grade asphalt binder
was modified by adding 2, 4, 6, 8 and 10 percent by weight of asphalt
binder following the wet process and the mineral aggregate was
modified by adding 1, 2, 3, 4 and 5 percent crumb rubber by volume
of the mineral aggregate following the dry process. The LDPE
modified asphalt binder rheological properties were evaluated. The
laboratory results showed an increase in viscosity, softening point
and stiffness of the binder. The modified asphalt was then used in
preparing asphalt mixtures by Marshall Mix design procedure. The
Marshall Stability values for mixes containing 2% crumb rubber and
4% LDPE were found to be 30% higher than the conventional asphalt
concrete mix.
Abstract: Thermal enhancement of a single mini channel in
Proton Exchange Membrane Fuel Cell (PEMFC) cooling plate is
numerically investigated. In this study, low concentration of Al2O3 in
Water - Ethylene Glycol mixtures is used as coolant in single channel
of carbon graphite plate to mimic the mini channels in PEMFC
cooling plate. A steady and incompressible flow with constant heat
flux is assumed in the channel of 1mm x 5mm x 100mm. Nano
particle of Al2O3 used ranges from 0.1, 0.3 and 0.5 vol %
concentration and then dispersed in 60:40 (water: Ethylene Glycol)
mixture. The effect of different flow rates to fluid flow and heat
transfer enhancement in Re number range of 20 to 140 was observed.
The result showed that heat transfer coefficient was improved by
18.11%, 9.86% and 5.37% for 0.5, 0.3 and 0.1 vol. % Al2O3 in 60:40
(water: EG) as compared to base fluid of 60:40 (water: EG). It is also
showed that the higher vol. % concentration of Al2O3 performed
better in term of thermal enhancement but at the expense of higher
pumping power required due to increase in pressure drop
experienced. Maximum additional pumping power of 0.0012W was
required for 0.5 vol % Al2O3 in 60:40 (water: EG) at Re number 140.
Abstract: This paper reports on the response of a fiber-optic
sensing probe to small concentrations of hydrogen peroxide (H2O2)
vapor at room temperature. H2O2 has extensive applications in industrial and medical
environments. Conversely, H2O2 can be a health hazard by itself. For
example, H2O2 induces cellular damage in human cells and its
presence can be used to diagnose illnesses such as asthma and human
breast cancer. Hence, development of reliable H2O2 sensor is of vital
importance to detect and measure this species. Ferric ferrocyanide, referred to as Prussian Blue (PB), was
deposited on the tip of a multimode optical fiber through the single
source precursor technique and served as an indicator of H2O2 in a
spectroscopic manner. Sensing tests were performed in H2O2-H2O
vapor mixtures with different concentrations of H2O2. The results of sensing tests show the sensor is able to detect H2O2
concentrations in the range of 50.6 ppm to 229.5 ppm. Furthermore,
the sensor response to H2O2 concentrations is linear in a log-log scale
with the adjacent R-square of 0.93. This sensing behavior allows us
to detect and quantify the concentration of H2O2 in the vapor phase.
Abstract: Ultraviolet photocatalytic oxidation (UV-PCO)
technology has been recommended as a green approach to health
indoor environment when it is integrated into mechanical ventilation
systems for inorganic and organic compounds removal as well as
energy saving due to less outdoor air intakes. Although much research
has been devoted to UV-PCO, limited information is available on the
UV-PCO behavior tested by the mixtures in literature. This project
investigated UV-PCO performance and by-product generation using a
single and a mixture of acetone and MEK at 100 ppb each in a
single-pass duct system in an effort to obtain knowledge associated
with competitive photochemical reactions involved in. The
experiments were performed at 20 % RH, 22 °C, and a gas flow rate of
128 m3/h (75 cfm). Results show that acetone and MEK mutually
reduced each other’s PCO removal efficiency, particularly negative
removal efficiency for acetone. These findings were different from
previous observation of facilitatory effects on the adsorption of
acetone and MEK on photocatalyst surfaces.
Abstract: This paper investigates the effectiveness of two
natural zeolites in reducing expansion of concrete due to alkali-silica
reaction. These natural zeolites have different reactive silica content.
Three aggregates; two natural sands and one crushed stone aggregate
were used while preparing mortar bars in accordance with accelerated
mortar bar test method, ASTM C1260. Performances of natural
zeolites are compared by examining the expansions due to alkali
silica reaction. Natural zeolites added to the mixtures at 10% and
20% replacement levels by weight of cement. Natural zeolite with
high reactive silica content had better performance on reducing
expansions due to ASR. In this research, using high reactive zeolite at
20% replacement levels was effective in mitigating expansions.
Abstract: Barley (Hordeum vulgare L.), vetch (Vicia villosa),
and grass pea (Lathyrus sativus L.) monocultures as well as mixtures
of barley with each of the above legumes, in three seeding ratios (i.e.,
barley: legume 75:25, 50:50 and 25:75, based on seed numbers) were
used to investigated forage yield and competition indices. The results
showed that intercropping reduced the dry matter yield of the three
component plants, compared with their respective monocrops. The
greatest value of total dry matter yield was obtained from barley25-
grasspea75 (5.44 t ha-1) mixture, followed by grass pea sole crop (4.99
t ha-1). The total actual yield loss (AYL) values were positive and
greater than 0 in all mixtures, indicating an advantage from
intercropping over sole crops. Intercropped barley had a higher
relative crowding coefficient (K=1.64) than intercropped legumes
(K=1.20), indicating that barley was more competitive than legumes
in mixtures. Furthermore, grass pea was more competitive than vetch
in mixtures with barley. The highest land equivalent ratio (LER),
system productivity index (SPI) and monetary advantage index
(MAI) were obtained when barley was mixed at a rate of 25% with
75% seed rate of grass pea. It is concluded that intercropping of
barley with grass pea has a good potential to improve the
performance of forage with high land-use efficiency.