Abstract: Energetic and structural results for ethanol-water mixtures as a function of the mole fraction were calculated using Monte Carlo methodology. Energy partitioning results obtained for equimolar water-ethanol mixture and ether organic liquids are compared. It has been shown that at xet=0.22 the RDFs for waterethanol and ethanol-ethanol interactions indicated strong hydrophobic interactions between ethanol molecules and the local structure of solution is less structured at this concentration as at ether ones. Results obtained for ethanol-water mixture as a function of concentration are in good agreement with the experimental data.
Abstract: The organic farmers use wider range of crop varieties than the conventional farming. Bread wheat is the most favorite and the most common food crop. The organic bread wheat is usually of worse technological quality. Therefore, it is supposed to be an attractive alternative to the hulled wheat species (einkorn, emmer wheat and spelt). Twenty-five hulled bread wheat varieties and control bread wheat ones were grown on the certified organic parcel in České Budějovice (the Czech Republic) between 2009 and 2012. Their baking quality was measured and evaluated with standard methods, and in accordance with ICC. The results have shown that the grain of hulled wheat varieties contain a lot of proteins in grains (up to 18 percent); even the organic hulled bread wheat varieties are characterized by such good baking quality. Einkorn and emmer wheat are of worse technological quality of proteins (low values of gluten index and Zeleny test), which is a disadvantage of these two wheat species. On the other hand, spelt wheat is of better technological quality and is similar to the control bread wheat varieties. Mixtures consisting of bread wheat, among others, are considered good alternatives; they may contribute to wider range of use of the hulled wheat species. It is one of the possibilities which may increase the proportion of proteins in bread wheat grains; the nutrition-rich hulled wheat grains may be also used in such way at the same time.
Abstract: The paper presents a one-dimensional transient
mathematical model of compressible thermal multi-component gas
mixture flows in pipes. The set of the mass, momentum and enthalpy
conservation equations for gas phase is solved. Thermo-physical
properties of multi-component gas mixture are calculated by solving
the Equation of State (EOS) model. The Soave-Redlich-Kwong
(SRK-EOS) model is chosen. Gas mixture viscosity is calculated on
the basis of the Lee-Gonzales-Eakin (LGE) correlation. Numerical
analysis on rapid decompression in conventional dry gases is
performed by using the proposed mathematical model. The model is
validated on measured values of the decompression wave speed in
dry natural gas mixtures. All predictions show excellent agreement
with the experimental data at high and low pressure. The presented
model predicts the decompression in dry natural gas mixtures much
better than GASDECOM and OLGA codes, which are the most
frequently-used codes in oil and gas pipeline transport service.
Abstract: An artificial neural network (ANN) model is
presented for the prediction of kinematic viscosity of binary mixtures
of poly (ethylene glycol) (PEG) in water as a function of temperature,
number-average molecular weight and mass fraction. Kinematic
viscosities data of aqueous solutions for PEG (0.55419×10-6 –
9.875×10-6 m2/s) were obtained from the literature for a wide range
of temperatures (277.15 - 338.15 K), number-average molecular
weight (200 -10000), and mass fraction (0.0 – 1.0). A three layer
feed-forward artificial neural network was employed. This model
predicts the kinematic viscosity with a mean square error (MSE) of
0.281 and the coefficient of determination (R2) of 0.983. The results
show that the kinematic viscosity of binary mixture of PEG in water
could be successfully predicted using an artificial neural network
model.
Abstract: Solid dispersions (SD) of curcuminpolyvinylpyrrolidone
in the ratio of 1:2, 1:4, 1:5, 1:6, and 1:8 were
prepared in an attempt to increase the solubility and dissolution.
Solubility, dissolution, powder X-ray diffraction (XRD), differential
scanning calorimetry (DSC) and Fourier transform infrared
spectroscopy (FTIR) of solid dispersions, physical mixtures (PM)
and curcumin were evaluated. Both solubility and dissolution of
curcumin solid dispersions were significantly greater than those
observed for physical mixtures and intact curcumin. The powder
X-ray diffractograms indicated that the amorphous curcumin was
obtained from all solid dispersions. It was found that the optimum
weight ratio for curcumin:PVP K-30 is 1:6. The 1:6 solid dispersion
still in the amorphous from after storage at ambient temperature for 2
years and the dissolution profile did not significantly different from
freshly prepared.
Abstract: Non-saturated soils that while saturation greatly
decrease their volume, have sudden settlement due to increasing
humidity, fracture and structural crack are called loess soils. Whereas
importance of civil projects including: dams, canals and
constructions bearing this type of soil and thereof problems, it is
required for carrying out more research and study in relation to loess
soils. This research studies shear strength parameters by using
grading test, Atterberg limit, compression, direct shear and
consolidation and then effect of using cement and lime additives on
stability of loess soils is studied. In related tests, lime and cement are
separately added to mixed ratios under different percentages of soil
and for different times the stabilized samples are processed and effect
of aforesaid additives on shear strength parameters of soil is studied.
Results show that upon passing time the effect of additives and
collapsible potential is greatly decreased and upon increasing
percentage of cement and lime the maximum dry density is
decreased; however, optimum humidity is increased. In addition,
liquid limit and plastic index is decreased; however, plastic index
limit is increased. It is to be noted that results of direct shear test
reveal increasing shear strength of soil due to increasing cohesion
parameter and soil friction angle.
Abstract: The paper presents the potential of fuzzy logic (FL-I)
and neural network techniques (ANN-I) for predicting the
compressive strength, for SCC mixtures. Six input parameters that is
contents of cement, sand, coarse aggregate, fly ash, superplasticizer
percentage and water-to-binder ratio and an output parameter i.e. 28-
day compressive strength for ANN-I and FL-I are used for modeling.
The fuzzy logic model showed better performance than neural
network model.
Abstract: Application of synthetic antioxidants such as tertbutylhydroquinon
(TBHQ), in spite of their efficiency, is questioned
because of their possible carcinogenic effect. The purpose of this
study was application of mixtures of natural antioxidants that provide
the best oxidative stability for margarine. Antioxidant treatments
included 10 various mixtures (F1- F10) containing 100-500ppm
tocopherol mixture (Toc), 100-200ppm ascorbyl palmitate (AP), 100-
200ppm rosemary extract (Ros) and 1000ppm lecithin(Lec) along
with a control or F0 (with no antioxidant) and F11 with 120ppm
TBHQ. The effect of antioxidant mixtures on the stability of
margarine samples during oven test (60°C), rancimat test at 110°C
and storage at 4°C was evaluated. Final ranking of natural antioxidant
mixtures was as follows: F2,F10>F5,F9>F8>F1,F3,F4>F6, F7.
Considering the results of this research and ranking criteria,
F2(200ppmAp + 200ppmRos) and F10(200ppmRos + 200ppmToc
+1000ppmLec) were recommended as substitutes for TBHQ to
maintain the quality and increase the shelf-life of margarine.
Abstract: The use of amine mixtures employing
methyldiethanolamine (MDEA), monoethanolamine (MEA), and diethanolamine (DEA) have been investigated for a variety of cases
using a process simulation program called HYSYS. The results show that, at high pressures, amine mixtures have little or no advantage in the cases studied. As the pressure is lowered, it becomes more difficult for MDEA to meet residual gas requirements and mixtures can usually improve plant performance. Since the CO2 reaction rate
with the primary and secondary amines is much faster than with
MDEA, the addition of small amounts of primary or secondary amines to an MDEA based solution should greatly improve the overall reaction rate of CO2 with the amine solution. The addition of MEA caused the CO2 to be absorbed more strongly in the upper portion of the column than for MDEA along. On the other hand,
raising the concentration for MEA to 11%wt, CO2 is almost
completely absorbed in the lower portion of the column. The addition of MEA would be most advantageous.
Thus, in areas where MDEA cannot meet the residual gas
requirements, the use of amine mixtures can usually improve the plant
performance.
Abstract: Laser soldering is based on applying some soldering material (albumin) onto the approximated edges of the cut and heating the solder (and the underlying tissues) by a laser beam. Endogenous and exogenous materials such as indocyanine green (ICG) are often added to solders to enhance light absorption. Gold nanoshells are new materials which have an optical response dictated by the plasmon resonance. The wavelength at which the resonance occurs depends on the core and shell sizes, allowing nanoshells to be tailored for particular applications. The purposes of this study was use combination of ICG and different concentration of gold nanoshells for skin tissue soldering and also to examine the effect of laser soldering parameters on the properties of repaired skin. Two mixtures of albumin solder and different combinations of ICG and gold nanoshells were prepared. A full thickness incision of 2×20 mm2 was made on the surface and after addition of mixtures it was irradiated by an 810nm diode laser at different power densities. The changes of tensile strength σt due to temperature rise, number of scan (Ns), and scan velocity (Vs) were investigated. The results showed at constant laser power density (I), σt of repaired incisions increases by increasing the concentration of gold nanoshells in solder, Ns and decreasing Vs. It is therefore important to consider the tradeoff between the scan velocity and the surface temperature for achieving an optimum operating condition. In our case this corresponds to σt =1800 gr/cm2 at I~ 47 Wcm-2, T ~ 85ºC, Ns =10 and Vs=0.3mms-1.
Abstract: In many data mining applications, it is a priori known
that the target function should satisfy certain constraints imposed
by, for example, economic theory or a human-decision maker. In this
paper we consider partially monotone prediction problems, where the
target variable depends monotonically on some of the input variables
but not on all. We propose a novel method to construct prediction
models, where monotone dependences with respect to some of
the input variables are preserved by virtue of construction. Our
method belongs to the class of mixture models. The basic idea is to
convolute monotone neural networks with weight (kernel) functions
to make predictions. By using simulation and real case studies,
we demonstrate the application of our method. To obtain sound
assessment for the performance of our approach, we use standard
neural networks with weight decay and partially monotone linear
models as benchmark methods for comparison. The results show that
our approach outperforms partially monotone linear models in terms
of accuracy. Furthermore, the incorporation of partial monotonicity
constraints not only leads to models that are in accordance with the
decision maker's expertise, but also reduces considerably the model
variance in comparison to standard neural networks with weight
decay.
Abstract: Effect of viscosity of media on kinetic parameters of the coupled enzyme system NADH:FMN-oxidoreductase–luciferase was investigated with addition of organic solvents (glycerol and sucrose), because bioluminescent enzyme systems based on bacterial luciferases offer a unique and general tool for analysis of the many analytes and enzymes in the environment, research and clinical laboratories and other fields. The possibility of stabilization and increase of activity of the coupled enzyme system NADH:FMN-oxidoreductase–luciferase activity in vicious aqueous-organic mixtures have been shown.
Abstract: This work deals with modeling and simulation of SO2 removal in a ceramic membrane by means of FEM. A mass transfer model was developed to predict the performance of SO2 absorption in a chemical solvent. The model was based on solving conservation equations for gas component in the membrane. Computational fluid dynamics (CFD) of mass and momentum were used to solve the model equations. The simulations aimed to obtain the distribution of gas concentration in the absorption process. The effect of the operating parameters on the efficiency of the ceramic membrane was evaluated. The modeling findings showed that the gas phase velocity has significant effect on the removal of gas whereas the liquid phase does not affect the SO2 removal significantly. It is also indicated that the main mass transfer resistance is placed in the membrane and gas phase because of high tortuosity of the ceramic membrane.
Abstract: In this paper, study on carbonation process of several types of advanced plasters on lime basis is presented. The movement of carbonation head was measured by colorimetric method using phenolphtalein. The rate of carbonation was accessed also by gravimetric method. Samples of studied materials were placed into the climatic chamber for simulation of environment with high concentration of CO2. The particular samples were on all lateral sides and on the bottom side provided by epoxy resin in order to arrange 1-D transport of CO2 into the studied samples. The carbonation rates of particular materials pointed to the time dependence of diffusion process of CO2 for all the studied plasters. From the quantitative point of view, the carbonation of advanced modified plasters was much faster than for the reference lime plaster, what is beneficial for the practical application of the tested newly developed materials.
Abstract: High strength concrete has been used in situations
where it may be exposed to elevated temperatures. Numerous authors
have shown the significant contribution of polypropylene fiber to the
spalling resistance of high strength concrete.
When cement-based composite that reinforced by polypropylene
fibers heated up to 170 °C, polypropylene fibers readily melt and
volatilize, creating additional porosity and small channels in to the
matrix that cause the poor structure and low strength.
This investigation develops on the mechanical properties of mortar
incorporating polypropylene fibers exposed to high temperature.
Also effects of different pozzolans on strength behaviour of samples
at elevated temperature have been studied.
To reach this purpose, the specimens were produced by partial
replacement of cement with finely ground glass, silica fume and rice
husk ash as high reactive pozzolans. The amount of this replacement
was 10% by weight of cement to find the effects of pozzolans as a
partial replacement of cement on the mechanical properties of
mortars. In this way, lots of mixtures with 0%, 0.5%, 1% and 1.5% of
polypropylene fibers were cast and tested for compressive and
flexural strength, accordance to ASTM standard. After that
specimens being heated to temperatures of 300, 600 °C, respectively,
the mechanical properties of heated samples were tested.
Mechanical tests showed significant reduction in compressive
strength which could be due to polypropylene fiber melting. Also
pozzolans improve the mechanical properties of sampels.
Abstract: Sunflower stalks were analysed for chemical
compositions: pentosan 15.84%, holocellulose 70.69%,
alphacellulose 45.74%, glucose 27.10% and xylose 7.69% based on
dry weight of 100-g raw material. The most optimum condition for
steam explosion pretreatment was as follows. Sunflower stalks were
cut into small pieces and soaked in 0.02 M H2SO4 for overnight.
After that, they were steam exploded at 207 C and 21 kg/cm2 for 3
minutes to fractionate cellulose, hemicellulose and lignin. The
resulting hydrolysate, containing hemicellulose, and cellulose pulp
contained xylose sugar at 2.53% and 7.00%, respectively.The pulp
was further subjected to enzymatic saccharification at 50 C, pH 4.8 citrate buffer) with pulp/buffer 6% (w/w)and Celluclast 1.5L/pulp
2.67% (w/w) to obtain single glucose with maximum yield 11.97%.
After fixed-bed fermentation under optimum condition using
conventional yeast mixtures to produce bioethanol, it indicated
maximum ethanol yield of 0.028 g/100 g sunflower stalk.
Abstract: An experiment of vented gas explosions involving two
different cylinder vessel volumes (0.2 and 0.0065 m3) was reported,
with equivalence ratio (Φ) ranged from 0.3 to 1.6. Both vessels were
closed at the rear end and fitted at the other side with a circular
orifice plate that gives a constant vent coefficient (K =Av/V2/3) of
16.4. It was shown that end ignition gives higher overpressures than
central ignition, even though most of the published work on venting
uses central ignition. For propane and ethylene, it is found that rich
mixtures gave the highest overpressures and these mixtures are not
considered in current vent design guidance; which the guideline is
based on mixtures giving the maximum flame temperature. A strong
influence of the vessel volume at constant K was found for methane,
propane, ethylene and hydrogen-air explosions. It can be concluded
that self- acceleration of the flame, which is dependent on the
distance of a flame from the ignition and the ‘suction’ at the vent
opening are significant factors affecting the vent flow during
explosion development in vented gas explosion. This additional
volume influence on vented explosions is not taken into account in
the current vent design guidance.
Abstract: Fatigue cracking continues to be the main challenges in
improving the performance of bituminous mixture pavements. The
purpose of this paper is to look at some aspects of the effects of fine
aggregate properties on the fatigue behaviour of hot mixture asphalt.
Two types of sand (quarry and mining sand) with two conventional
bitumen (PEN 50/60 & PEN 80/100) and four polymers modified
bitumen PMB (PM1_82, PM1_76, PM2_82 and PM2_76) were used.
Physical, chemical and mechanical tests were performed on the sands
to determine their effect when incorporated with a bituminous
mixture. According to the beam fatigue results, quarry sand that has
more angularity, rougher, higher shear strength and a higher
percentage of Aluminium oxide presented higher resistance to
fatigue. Also a PMB mixture gives better fatigue results than
conventional mixtures, this is due to the PMB having better viscosity
property than that of the conventional bitumen.
Abstract: There is a acute water problem especially in the dry
season in and around Perundurai (Erode district, Tamil Nadu, India)
where there are more number of tannery units. Hence an attempt was
made to use the waste water from tannery industry for construction
purpose. The mechanical properties such as compressive strength,
tensile strength, flexural strength etc were studied by casting various
concrete specimens in form of cube, cylinders and beams etc and
were found to be satisfactory. Hence some special properties such as
chloride attack, sulphate attack and chemical attack are considered
and comparatively studied with the conventional potable water. In
this experimental study the results of specimens prepared by using
treated and untreated tannery effluent were compared with the
concrete specimens prepared by using potable water. It was observed
that the concrete had some reduction in strength while subjected to
chloride attack, sulphate attack and chemical attack. So admixtures
were selected and optimized in suitable proportion to counter act the
adverse effects and the results were found to be satisfactory.
Abstract: This paper studies questions of continuous data dependence and uniqueness for solutions of initial boundary value problems in linear micropolar thermoelastic mixtures. Logarithmic convexity arguments are used to establish results with no definiteness assumptions upon the internal energy.