Abstract: In this work, our goal is to optimize the nitriding treatment at a low-temperature of the steel 32CrMoV13 using gas mixtures of ammonia, nitrogen and hydrogen to improve the mechanical properties of the surface (good wear resistance, friction and corrosion), and of the diffusion layer of the nitrogen (good resistance to fatigue and good tenacity with heart). By limiting our work to the pure iron and to the alloys iron-chromium and iron-chromium-carbon, we have studied the various parameters which manage the nitriding: flow rate and composition of the gaseous phase, the interaction chromium-nitrogen and chromium-carbon by the help of experiments of nitriding realized in the laboratory by thermogravimetry. The acquired knowledge has been applied by the mastery of the growth of the γ' combination layer on the α diffusion layer in the case of the industrial steel 32CrMoV13.
Abstract: The study is devoted to define the optimal conditions
for the nitriding of pure iron at atmospheric pressure by using NH3-
Ar-C3H8 gas mixtures. After studying the mechanisms of phase
formation and mass transfer at the gas-solid interface, a mathematical
model is developed in order to predict the nitrogen transfer rate in the
solid, the ε-carbonitride layer growth rate and the nitrogen and
carbon concentration profiles. In order to validate the model and to
show its possibilities, it is compared with thermogravimetric
experiments, analyses and metallurgical observations (X-ray
diffraction, optical microscopy and electron microprobe analysis).
Results obtained allow us to demonstrate the sound correlation
between the experimental results and the theoretical predictions.