Abstract: Fuller’s earth is a fine-grained, naturally occurring substance that has a substantial ability to adsorb impurities. In the present study Fuller’s earth has been characterized and used for the removal of Pb(II) from aqueous solution. The effect of various physicochemical parameters such as pH, adsorbent dosage and shaking time on adsorption were studied. The result of the equilibrium studies showed that the solution pH was the key factor affecting the adsorption. The optimum pH for adsorption was 5. Kinetics data for the adsorption of Pb(II) was best described by pseudo-second order model. The effective diffusion co-efficient for Pb(II) adsorption was of the order of 10-8 m2/s. The adsorption data for metal adsorption can be well described by Langmuir adsorption isotherm. The maximum uptake of metal was 103.3 mg/g of adsorbent. Mass transfer analysis was also carried out for the adsorption process. The values of mass transfer coefficients obtained from the study indicate that the velocity of the adsorbate transport from bulk to the solid phase was quite fast. The mean sorption energy calculated from Dubinin-Radushkevich isotherm indicated that the metal adsorption process was chemical in nature.
Abstract: The present work was conducted for the synthesis of
nano size zerovalent iron (nZVI) and hexavalent chromium (Cr(VI))
removal as a highly toxic pollutant by using this nanoparticles. Batch
experiments were performed to investigate the effects of Cr(VI),
nZVI concentration, pH of solution and contact time variation on
the removal efficiency of Cr(VI). nZVI was synthesized by
reduction of ferric chloride using sodium borohydrid. SEM and
XRD examinations applied for determination of particle size and
characterization of produced nanoparticles. The results showed that
the removal efficiency decreased with Cr(VI) concentration and pH
of solution and increased with adsorbent dosage and contact time.
The Langmuir and Freundlich isotherm models were used for the
adsorption equilibrium data and the Langmuir isotherm model was
well fitted. Nanoparticle ZVI presented an outstanding ability to
remove Cr(VI) due to high surface area, low particle size and high
inherent activity.
Abstract: Boron minerals are very useful for various industrial
activities, such as glass industry and detergent industry, due to its
mechanical and chemical properties. During the production of boron
compounds, many of these are introduced into the environment in the
form of waste. Boron is also an important micro nutrient for the
plants to vegetate but if it exists in high concentrations, it could have
toxic effects. The maximum boron level in drinking water for human
health is given as 0.3 mg/L in World Health Organization (WHO)
standards. The toxic effects of boron should be noted especially for
dry regions, thus, in recent years, increasing attention has been paid
to remove the boron from waste waters. In this study, boron removal
is implemented by ion exchange process using Amberlite IRA-743
resin. Amberlite IRA-743 resin is a boron specific resin and it
belongs to the polymerizate sorbent group within the aminopolyol
functional group. Batch studies were performed to investigate the
effects of various experimental parameters, such as adsorbent dose,
initial concentration and pH, on the removal of boron. It is found
that, when the adsorbent dose increases removal of boron from the
liquid phase increases. However, an increase in the initial
concentration decreases the removal of boron. The effective pH
values for removal of boron are determined between 8.5 and 9.
Equilibrium isotherms were also analyzed by Langmuir and
Freundlich isotherm models. The Langmuir isotherm is obeyed better
than the Freundlich isotherm.
Abstract: The purpose of this study is to investigate the capacity
of natural Turkish zeolite for NH4-N removal from landfill leachate.
The effects of modification and initial concentration on the removal
of NH4-N from leachate were also investigated. The kinetics of
adsorption of NH4-N has been discussed using three kinetic models,
i.e., the pseudo-second order model, the Elovich equation, the
intraparticle diffuion model. Kinetic parameters and correlation
coefficients were determined. Equilibrium isotherms for the
adsorption of NH4-N were analyzed by Langmuir, Freundlich and
Tempkin isotherm models. Langmuir isotherm model was found to
best represent the data for NH4-N.
Abstract: This work was to study batch biosorption of Pb(II)
ions from aqueous solution by Luffa charcoal. The effect of operating
parameters such as adsorption contact time, initial pH solution and
different initial Pb(II) concentration on the sorption of Pb(II) were
investigated. The results showed that the adsorption of Pb(II) ions
was initially rapid and the equilibrium time was 10 h. Adsorption
kinetics of Pb(II) ions onto Luffa charcoal could be best described by
the pseudo-second order model. At pH 5.0 was favorable for the
adsorption and removal of Pb(II) ions. Freundlich adsorption
isotherm model was better fitted for the adsorption of Pb(II) ions than
Langmuir and Timkin isotherms, respectively. The highest monolayer
adsorption capacity obtained from Langmuir isotherm model was
51.02 mg/g. This study demonstrated that Luffa charcoal could be
used for the removal of Pb(II) ions in water treatment.
Abstract: Smoke discharging is a main reason of air pollution
problem from industrial plants. The obstacle of a building has an
affect with the air pollutant discharge. In this research, a mathematical
model of the smoke dispersion from two sources and one source with
a structural obstacle is considered. The governing equation of the
model is an isothermal mass transfer model in a viscous fluid. The
finite element method is used to approximate the solutions of the
model. The triangular linear elements have been used for discretising
the domain, and time integration has been carried out by semi-implicit
finite difference method. The simulations of smoke dispersion in
cases of one chimney and two chimneys are presented. The maximum
calculated smoke concentration of both cases are compared. It is then
used to make the decision for smoke discharging and air pollutant
control problems on industrial area.
Abstract: Dehydration of methanol to dimethyl ether (DME)
over a commercial Al2O3 catalyst was studied in an isothermal integral
fixed bed reactor. The experiments were performed on the temperature
interval 513-613 K, liquid hourly space velocity (LHSV) of 0.9-2.1h-1,
pressures between 0.1 and 1.0 MPa. The effect of different operation
conditions on the dehydration of methanol was investigated in a
laboratory scale experiment. A new intrinsic kinetics equation based
on the mechanism of Langmuir-Hinshelwood dissociation adsorption
was developed for the dehydration reaction by fitting the expressions
to the experimental data. An activation energy of 67.21 kJ/mol was
obtained for the catalyst with the best performance. Statistic test
showed that this new intrinsic kinetics equation was acceptable.
Abstract: The potential of economically cheaper cellulose
containing natural materials like rice husk was assessed for nickel
adsorption from aqueous solutions. The effects of pH, contact time,
sorbent dose, initial metal ion concentration and temperature on the
uptake of nickel were studied in batch process. The removal of nickel
was dependent on the physico-chemical characteristics of the
adsorbent, adsorbate concentration and other studied process
parameters. The sorption data has been correlated with Langmuir,
Freundlich and Dubinin-Radush kevich (D-R) adsorption models. It
was found that Freundlich and Langmuir isotherms fitted well to the
data. Maximum nickel removal was observed at pH 6.0. The
efficiency of rice husk for nickel removal was 51.8% for dilute
solutions at 20 g L-1 adsorbent dose. FTIR, SEM and EDAX were
recorded before and after adsorption to explore the number and
position of the functional groups available for nickel binding on to
the studied adsorbent and changes in surface morphology and
elemental constitution of the adsorbent. Pseudo-second order model
explains the nickel kinetics more effectively. Reusability of the
adsorbent was examined by desorption in which HCl eluted 78.93%
nickel. The results revealed that nickel is considerably adsorbed on
rice husk and it could be and economic method for the removal of
nickel from aqueous solutions.
Abstract: Since polymerase chain reaction (PCR) has been
invented, it has emerged as a powerful tool in genetic analysis. The
PCR products are closely linked with thermal cycles. Therefore, to
reduce the reaction time and make temperature distribution uniform in
the reaction chamber, a novel oscillatory thermal cycler is designed.
The sample is placed in a fixed chamber, and three constant isothermal
zones are established and lined in the system. The sample is oscillated
and contacted with three different isothermal zones to complete
thermal cycles. This study presents the design of the geometric
characteristics of the chamber. The commercial software
CFD-ACE+TM is utilized to investigate the influences of various
materials, heating times, chamber volumes, and moving speed of the
chamber on the temperature distributions inside the chamber. The
chamber moves at a specific velocity and the boundary conditions
with time variations are related to the moving speed. Whereas the
chamber moves, the boundary is specified at the conditions of the
convection or the uniform temperature. The user subroutines compiled
by the FORTRAN language are used to make the numerical results
realistically. Results show that the reaction chamber with a rectangular
prism is heated on six faces; the effects of various moving speeds of
the chamber on the temperature distributions are examined. Regarding
to the temperature profiles and the standard deviation of the
temperature at the Y-cut cross section, the non-uniform temperature
inside chamber is found as the moving speed is larger than 0.01 m/s.
By reducing the heating faces to four, the standard deviation of the
temperature of the reaction chamber is under 1.4×10-3K with the range
of velocities between 0.0001 m/s and 1 m/s. The nature convective
boundary conditions are set at all boundaries while the chamber moves
between two heaters, the effects of various moving velocities of the
chamber on the temperature distributions are negligible at the assigned
time duration.
Abstract: Protective coatings that resist oxide scale growth and
decrease chromium evaporation are necessary to make stainless steel
interconnect materials for long-term durable operation of solid oxide
fuel cells (SOFCs). In this study a layer of cobalt was electroplated
on the surface of AISI 441 ferritic stainless steel which is used in
solid oxide fuel cells for interconnect applications. The oxidation
behavior of coated substrates was studied as a function of time at
operating conditions of SOFCs. Cyclic oxidation has been also tested
at 800ºC for 100 cycles. Cobalt coating during isothermal oxidation
caused to the oxide growth resistance by limiting the outward
diffusion of Cr cation and the inward diffusion of oxygen anion.
Results of cyclic oxidation exhibited that coated substrates
demonstrate an excellent resistance against the spallation and
cracking.
Abstract: Absorptive characteristics of polyaniline synthesized
in mixture of water and acetonitrile in 50/50 volume ratio was
studied. Synthesized polyaniline in powder shape is used as an
adsorbent to remove toxic hexavalent chromium from aqueous
solutions. Experiments were conducted in batch mode with different
variables such as agitation time, solution pH and initial concentration
of hexavalent chromium. Removal mechanism is the combination of
surface adsorption and reduction. The equilibrium time for removal
of Cr(T) and Cr(VI) was about 2 and 10 minutes respectively. The
optimum pH for total chromium removal occurred at pH 7 and
maximum hexavalent chromium removal took place under acidic
condition at pH 3. Investigating the isothermal characteristics showed
that the equilibrium adsorption data fitted both Freundlich-s and
Langmuir-s isotherms. The maximum adsorption of chromium was
calculated 36.1 mg/g for polyaniline
Abstract: Cashew nut shells were converted into activated carbon powders using KOH activation plus CO2 gasification at 1027 K. The increase both of impregnation ratio and activation time, there was swiftly the development of mesoporous structure with increasing of mesopore volume ratio from 20-28% and 27-45% for activated carbon with ratio of KOH per char equal to 1 and 4, respectively. Activated carbon derived from KOH/char ratio equal to 1 and CO2 gasification time from 20 to 150 minutes were exhibited the BET surface area increasing from 222 to 627 m2.g-1. And those were derived from KOH/char ratio of 4 with activation time from 20 to 150 minutes exhibited high BET surface area from 682 to 1026 m2.g-1. The adsorption of Lead(II) and Cadmium(II) ion was investigated. This adsorbent exhibited excellent adsorption for Lead(II) and Cadmium(II) ion. Maximum adsorption presented at 99.61% at pH 6.5 and 98.87% at optimum conditions. The experimental data was calculated from Freundlich isotherm and Langmuir isotherm model. The maximum capacity of Pb2+ and Cd2+ ions was found to be 28.90 m2.g-1 and 14.29 m2.g-1, respectively.
Abstract: CTMA-bentonite and BTEA-Bentonite prepared by Na-bentonite cation exchanged with cetyltrimethylammonium(CTMA) and benzyltriethylammonium (BTEA). Products were characterized by XRD and IR techniques.The d001 spacing value of CTMA-bentonite and BTEA-bentonite are 7.54Å and 3.50Å larger than that of Na-bentonite at 100% cation exchange capacity, respectively. The IR spectrum showed that the intensities of OH stretching and bending vibrations of the two organoclays decreased greatly comparing to untreated Na-bentonite. Batch experiments were carried out at 303 K, 318 K and 333 K to obtain the sorption isotherms of Crystal violet onto the two organoclays. The results show that the sorption isothermal data could be well described by Freundlich model. The dynamical data for the two organoclays fit well with pseudo-second-order kinetic model. The adsorption capacity of CTMA-bentonite was found higher than that of BTEA-Bentonite. Thermodynamic parameters such as changes in the free energy (ΔG°), the enthalpy (ΔH°) and the entropy (ΔS°) were also evaluated. The overall adsorption process of Crystal violet onto the two organoclays were spontaneous, endothermic physisorption. The CTMA-bentonite and BTEA-Bentonite could be employed as low-cost alternatives to activated carbon in wastewater treatment for the removal of color which comes from textile dyes.
Abstract: The experiments were performed in a batch set up
under different concentrations of Cu (II) (0.2 g.l-1 to 0.9 g.l-1), pH (4-
6), temperatures (20oC – 40oC) with varying teak leaves powder (as
biosorbent) dosage of 0.3 g.l-1 to 0.5 g.l-1. The kinetics of interactions
were tested with pseudo first order Lagergran equation and the value
for k1 was found to be 6.909 x 10-3 min-1. The biosorption data gave
a good fit with Langmuir and Fruendlich isotherms and the Langmuir
monolayer capacity (qm) was found to be 166.78 mg. g-1. Similarly
the Freundlich adsorption capacity (Kf) was estimated as 2.49 l g-1.
The mean values of the thermodynamic parameters ΔH, ΔS, and ΔG
were -62.42 KJ. mol-1, -0.219 KJ.mol-1 K-1 and -1.747 KJ.mol-1 at
293 K from a solution containing 0.4 g l-1 of Cu(II) showing the
biosorption to be thermodynamically favourable. These results show
good potentiality of using teak leaves as a biosorbent for the removal
of Cu(II) from aqueous solutions.
Abstract: Unsteady natural convection and heat transfer in a square cavity partially filled with porous media using a thermal
non-equilibrium model is studied in this paper. The left vertical wall is
maintained at a constant hot temperature Th and the right vertical wall
is maintained at a constant cold temperature Tc, while the horizontal
walls are adiabatic. The governing equations are obtained by applying
the Darcy model and Boussinesq approximation. COMSOL’s finite
element method is used to solve the non-dimensional governing
equations together with specified boundary conditions. The governing
parameters of this study are the Rayleigh number (Ra = 10^5, and Ra = 10^6 ), Darcy namber (Da = 10^−2, and Da = 10^−3),
the modified thermal conductivity ratio (10^−1 ≤ γ ≤ 10^4), the inter-phase heat transfer coefficien (10^−1 ≤ H ≤ 10^3) and the
time dependent (0.001 ≤ τ ≤ 0.2). The results presented for
values of the governing parameters in terms of streamlines in both
fluid/porous-layer, isotherms of fluid in fluid/porous-layer, isotherms
of solid in porous layer, and average Nusselt number.
Abstract: The paper reports on the results of experimental and
numerical study of nonstationary swirling flow in an isothermal
model of vortex burner. It has been identified that main source of the
instability is related to a precessing vortex core (PVC) phenomenon.
The PVC induced flow pulsation characteristics such as precession
frequency and its variation as a function of flowrate and swirl number
have been explored making use of acoustic probes. Additionally
pressure transducers were used to measure the pressure drops on the
working chamber and across the vortex flow. The experiments have
been included also the mean velocity measurements making use of a
laser-Doppler anemometry. The features of instantaneous flowfield
generated by the PVC were analyzed employing a commercial CFD
code (Star-CCM+) based on Detached Eddy Simulation (DES)
approach. Validity of the numerical code has been checked by
comparison calculated flowfield data with the obtained experimental
results. It has been confirmed particularly that the CFD code applied
correctly reproduces the flow features.
Abstract: This paper is a numerical investigation of a laminar
isothermal plane two dimensional wall jet. Special attention has been
paid to the effect of the inlet conditions at the nozzle exit on the
hydrodynamic and thermal characteristics of the flow. The
behaviour of various fluids evolving in both forced and mixed
convection regimes near a vertical plate plane is carried out. The
system of governing equations is solved with an implicit finite
difference scheme. For numerical stability we use a staggered non
uniform grid. The obtained results show that the effect of the Prandtl
number is significant in the plume region in which the jet flow is
governed by buoyant forces. Further for ascending X values, the
buoyancy forces become dominating, and a certain agreement
between the temperature profiles are observed, which shows that the
velocity profile has no longer influence on the wall temperature
evolution in this region. Fluids with low Prandtl number warm up
more importantly, because for such fluids the effect of heat diffusion
is higher.
Abstract: Nonlinear propagation of ion-acoustic waves in a selfgravitating
dusty plasma consisting of warm positive ions,
isothermal two-temperature electrons and negatively charged dust
particles having charge fluctuations is studied using the reductive
perturbation method. It is shown that the nonlinear propagation of
ion-acoustic waves in such plasma can be described by an uncoupled
third order partial differential equation which is a modified form of
the usual Korteweg-deVries (KdV) equation. From this nonlinear
equation, a new type of solution for the ion-acoustic wave is
obtained. The effects of two-temperature electrons, gravity and dust
charge fluctuations on the ion-acoustic solitary waves are discussed
with possible applications.
Abstract: The objective of the present work is to conduct
investigations leading to a more complete explanation of single phase
natural convective heat transfer in an enclosure with fin utilizing
nano fluids. The nano fluid used, which is composed of Aluminum
oxide nano particles in suspension of Ethylene glycol, is provided at
various volume fractions. The study is carried out numerically for a
range of Rayleigh numbers, fin heights and aspect ratio. The flow and
temperature distributions are taken to be two-dimensional. Regions
with the same velocity and temperature distributions are identified as
symmetry of sections. One half of such a rectangular region is chosen
as the computational domain taking into account the symmetry about
the fin. Transport equations are modeled by a stream functionvorticity
formulation and are solved numerically by finite-difference
schemes. Comparisons with previously published works on the basis
of special cases are done. Results are presented in the form of
streamline, vector and isotherm plots as well as the variation of local
Nusselt number along the fin under different conditions.
Abstract: In the present study Schwertmannite (an iron oxide
hydroxide) is selected as an adsorbent for defluoridation of water.
The adsorbent was prepared by wet chemical process and was
characterized by SEM, XRD and BET. The fluoride adsorption
efficiency of the prepared adsorbent was determined with respect to
contact time, initial fluoride concentration, adsorbent dose and pH of
the solution. The batch adsorption data revealed that the fluoride
adsorption efficiency was highly influenced by the studied factors.
Equilibrium was attained within one hour of contact time indicating
fast kinetics and the adsorption data followed pseudo second order
kinetic model. Equilibrium isotherm data fitted to both Langmuir and
Freundlich isotherm models for a concentration range of 5-30 mg/L.
The adsorption system followed Langmuir isotherm model with
maximum adsorption capacity of 11.3 mg/g. The high adsorption
capacity of Schwertmannite points towards the potential of this
adsorbent for fluoride removal from aqueous medium.