Abstract: In this paper effects of inclination angle on natural
convection flow in an open cavity has been analyzed with Lattice
Boltzmann Method (LBM).The angle of inclination varied from θ= -
45° to 45° with 15° intervals. Study has been conducted for Rayleigh
numbers (Ra) 104 to 106. The comparisons show that the average
Nusselt number increases with growth of Rayleigh number and the
average Nusselt number increase as inclination angles increases at
Ra=104.At Ra=105 and Ra=106 the average Nusselt number enhance
as inclination angels varied from θ= -45° to θ= 0° and decrease as
inclination angels increase in θ= 0° to θ= 45°.
Abstract: In this article, we synthesize a novel chitosan -based
superabsorbent hydrogel via graft copolymerization of mixtures
acrylic acid (AA) and N-vinyl pyrollidon onto chitosan backbones.
The polymerization reaction was carried out in an aqueous medium
and in the presence of ammonium persulfate (APS) as an initiator and
N,N'-methylene bisacrylamide (MBA) as a crosslinker.The hydrogel
structures were confirmed by FTIR spectroscopy. The swelling
behavior of these absorbent polymers was also investigated in
various salt solutions. Results indicated that the swelling capacity
decreased with an increase in the ionic strength of the swelling
medium. Furthermore, the swelling of superabsorbing hydrogels was
examined in solutions with pH values ranging between 1.0 and 13.0.
It showed a reversible pH-responsive behavior at pHs 2.0 and 8.0.
This on-off switching behavior makes the synthesized hydrogels as
an excellent candidate for controlled delivery of bioactive agents.
Abstract: In this research, the flow pattern influence on
performance of a micro PEMFC was investigated
experimentally. The investigation focused on the impacts of
bend angels and rib/channel dimensions of serpentine flow
channel pattern on the performance and investigated how they
improve the performance. The fuel cell employed for these
experiments was a micro single PEMFC with a membrane of
1.44 cm2 Nafion NRE-212. The results show that 60° and 120°
bend angles can provide the better performances at 20 and 40
sccm inlet flow rates comparing to that the conventional design.
Additionally, wider channel with narrower rib spacing gives
better performance. These results may be applied to develop
universal heuristics for the design of flow pattern of micro
PEMFC.
Abstract: There are various solutions for improving existing overhead line systems with the general purpose of increasing their limited capacity. The capacity reserve of the existing overhead lines is an important problem that must be considered from different aspects. The paper contains a comparative analysis of the mechanical and thermal limitations of an existing overhead line based on certain calculation conditions characterizing the examined variants. The methodology of the proposed estimation of the permissible conductor temperature and maximum load current is described in detail. The transmission line model consists of specific information of an existing overhead line of the Latvian power network. The main purpose of the simulation tasks is to find an additional capacity reserve by using accurate mathematical models. The results of the obtained data are presented.
Abstract: In this study, hydrogels consisted of polyvinyl alcohol,
propylene glycol and β-glucan were developed by radiation technique
for wound dressing. The prepared hydrogels were characterized by
examining of physical properties such as gel fraction and absorption
ratio. The gel fraction and absorption ratio were dependent on the
crosslinking density. On observing the wound healing of rat skin, the
resulting hydrogels accelerated the wound healing comparing to cotton
gauze. Therefore, the PVA/propylene glycol/β-glucan blended
hydrogels can greatly accelerate the healing without causing irritation.
Abstract: The aim of the present study was to evaluate the
mucoadhesion and the release of nicotinamide gel formulations using
in vitro methods. An agar plate technique was used to investigate the
adhesiveness of the gels whereas a diffusion apparatus was employed
to determine the release of nicotinamide from the gels. In this
respect, 10% w/w nicotinamide gels containing bioadhesive
polymers: Carbopol 934P (0.5-2% w/w), hydroxypropylmethyl
cellulose (HPMC) (4-10% w/w), sodium carboxymethyl cellulose
(SCMC) (4-6% w/w) and methylcellulose 4000 (MC) (3-5% w/w)
were prepared. The gel formulations had pH values in the range of
7.14 - 8.17, which were considered appropriate to oral mucosa
application. In general, the rank order of pH values appeared to be
SCMC > MC4000 > HPMC > Carbopol 934P. Types and
concentrations of polymers used somewhat affected the
adhesiveness. It was found that anionic polymers (Carbopol 934 and
SCMC) adhered more firmly to the agar plate than the neutral
polymers (HPMC and MC 4000). The formulation containing 0.5%
Carbopol 934P (F1) showed the highest release rate. With the
exception of the formulation F1, the neutral polymers tended to give
higher relate rates than the anionic polymers. For oral tissue
treatment, the optimum has to be balanced between the residence
time (adhesiveness) of the formulations and the release rate of the
drug. The formulations containing the anionic polymers: Carbopol
934P or SCMC possessed suitable physical properties (appearance,
pH and viscosity). In addition, for anionic polymer formulations,
justifiable mucoadhesive properties and reasonable release rates of
nicotinamide were achieved. Accordingly, these gel formulations
may be applied for the treatment of oral mucosal lesions.
Abstract: In modern agriculture, polymeric hydrogels are
known as a component able to hold an amount of water due to their
3-dimensional network structure and their tendency to absorb water
in humid environments. In addition, these hydrogels are able to
controllably release the fertilisers and pesticides loaded in them.
Therefore, they deliver these materials to the plants' roots and help
them with growing. These hydrogels also reduce the pollution of
underground water sources by preventing the active components
from leaching. In this study, sIPN acrylamide based hydrogels are
synthesised by using acrylamide free radical, potassium acrylate, and
linear polyvinyl alcohol. Ammonium nitrate is loaded in the hydrogel
as the fertiliser. The effect of various amounts of monomers and
linear polymer, measured in molar ratio, on the swelling rate,
equilibrium swelling, and release of ammonium nitrate is studied.
Abstract: The study investigated the hydrophilic to hydrophobic
transition of modified polyacrylamide hydrogel with the inclusion of
N-isopropylacrylamide (NIAM). The modification was done by
mimicking micellar polymerization, which resulted in better
arrangement of NIAM chains in the polyacrylamide network. The
degree of NIAM arrangement is described by NH number. The
hydrophilic to hydrophobic transition was measured through the
partition coefficient, K, of Orange II and Methylene Blue in hydrogel
and in water. These dyes were chosen as a model for solutes with
different degree of hydrophobicity. The study showed that the
hydrogel with higher NH values resulted in better solubility of both
dyes. Moreover, in temperature above the lower critical solution
temperature (LCST) of Poly(N-isopropylacrylamide) (PNIAM)also
caused the collapse of NIPAM chains which results in a more
hydrophobic environment that increases the solubility of Methylene
Blue and decreases the solubility of Orange II in the hydrogels with
NIPAM present.
Abstract: Hydrate phase equilibria for the binary CO2+water and
CH4+water mixtures in silica gel pore of nominal diameters 6, 30, and
100 nm were measured and compared with the calculated results based
on van der Waals and Platteeuw model. At a specific temperature,
three-phase hydrate-water-vapor (HLV) equilibrium curves for pore
hydrates were shifted to the higher-pressure condition depending on
pore sizes when compared with those of bulk hydrates. Notably,
hydrate phase equilibria for the case of 100 nominal nm pore size were
nearly identical with those of bulk hydrates. The activities of water in
porous silica gels were modified to account for capillary effect, and
the calculation results were generally in good agreement with the
experimental data. The structural characteristics of gas hydrates in
silica gel pores were investigated through NMR spectroscopy.
Abstract: A new strategy for oriented immobilization of proteins was proposed. The strategy contains two steps. The first step is to search for a docking site away from the active site on the protein surface. The second step is trying to find a ligand that is able to grasp the targeted site of the protein. To avoid ligand binding to the active site of protein, the targeted docking site is selected to own opposite charges to those near the active site. To enhance the ligand-protein binding, both hydrophobic and electrostatic interactions need to be included. The targeted docking site should therefore contain hydrophobic amino acids. The ligand is then selected through the help of molecular docking simulations. The enzyme α-amylase derived from Aspergillus oryzae (TAKA) was taken as an example for oriented immobilization. The active site of TAKA is surrounded by negatively charged amino acids. All the possible hydrophobic sites on the surface of TAKA were evaluated by the free energy estimation through benzene docking. A hydrophobic site on the opposite side of TAKA-s active site was found to be positive in net charges. A possible ligand, 3,3-,4,4- – Biphenyltetra- carboxylic acid (BPTA), was found to catch TAKA by the designated docking site. Then, the BPTA molecules were grafted onto silica gels and measured the affinity of TAKA adsorption and the specific activity of thereby immobilized enzymes. It was found that TAKA had a dissociation constant as low as 7.0×10-6 M toward the ligand BPTA on silica gel. The increase in ionic strength has little effect on the adsorption of TAKA, which indicated the existence of hydrophobic interaction between ligands and proteins. The specific activity of the immobilized TAKA was compared with the randomly adsorbed TAKA on primary amine containing silica gel. It was found that the orderly immobilized TAKA owns a specific activity twice as high as the one randomly adsorbed by ionic interaction.
Abstract: Nanocrystalline thin film of Na0.1V2O5.nH2O xerogel
obtained by sol gel synthesis was used as gas sensor. Gas sensing
properties of different gases such as hydrogen, petroleum and
humidity were investigated. Applying XRD and TEM the size of the
nanocrystals is found to be 7.5 nm. SEM shows a highly porous
structure with submicron meter-sized voids present throughout the
sample. FTIR measurement shows different chemical groups
identifying the obtained series of gels. The sample was n-type
semiconductor according to the thermoelectric power and electrical
conductivity. It can be seen that the sensor response curves from
130oC to 150oC show a rapid increase in sensitivity for all types of
gas injection, low response values for heating period and the rapid
high response values for cooling period. This result may suggest that
this material is able to act as gas sensor during the heating and
cooling process.
Abstract: In this paper, we have focused on study of swelling kinetics and salt-sensitivity behavior of a superabsorbing hydrogel based on carboxymethylcellulose (CMC) and acrylic acid and 2- Buthyl methacrylate. The swelling kinetics of the hydrogels with various particle sizes was preliminary investigated as well. The swelling of the hydrogel showed a second order kinetics of swelling in water. In addition, swelling measurements of the synthesized hydrogels in various chloride salt solutions was measured. Results indicated that a swelling-loss with an increase in the ionic strength of the salt solutions.
Abstract: A novel thermo-sensitive superabsorbent hydrogel
with salt- and pH-responsiveness properties was obtained by grafting
of mixtures of acrylic acid (AA) and N-isopropylacrylamide
(NIPAM) monomers onto kappa-carrageenan, kC, using ammonium
persulfate (APS) as a free radical initiator in the presence of
methylene bisacrylamide (MBA) as a crosslinker. Infrared
spectroscopy was carried out to confirm the chemical structure of the
hydrogel. Moreover, morphology of the samples was examined by
scanning electron microscopy (SEM). The effect of MBA
concentration and AA/NIPAM weight ratio on the water absorbency
capacity has been investigated. The swelling variations of hydrogels
were explained according to swelling theory based on the hydrogel
chemical structure. The hydrogels exhibited salt-sensitivity and
cation exchange properties. The temperature- and pH-reversibility
properties of the hydrogels make the intelligent polymers as good
candidates for considering as potential carriers for bioactive agents,
e.g. drugs.
Abstract: Titanium gels doped with water-soluble cationic porphyrin were synthesized by the sol–gel polymerization of Ti (OC4H9)4. In this work we investigate the spectroscopic properties along with SEM images of tetra carboxyl phenyl porphyrin when incorporated into porous matrix produced by the sol–gel technique.
Abstract: When acid is pumped into damaged reservoirs for
damage removal/stimulation, distorted inflow of acid into the
formation occurs caused by acid preferentially traveling into highly
permeable regions over low permeable regions, or (in general) into
the path of least resistance. This can lead to poor zonal coverage and
hence warrants diversion to carry out an effective placement of acid.
Diversion is desirably a reversible technique of temporarily reducing
the permeability of high perm zones, thereby forcing the acid into
lower perm zones.
The uniqueness of each reservoir can pose several challenges to
engineers attempting to devise optimum and effective diversion
strategies. Diversion techniques include mechanical placement and/or
chemical diversion of treatment fluids, further sub-classified into ball
sealers, bridge plugs, packers, particulate diverters, viscous gels,
crosslinked gels, relative permeability modifiers (RPMs), foams,
and/or the use of placement techniques, such as coiled tubing (CT)
and the maximum pressure difference and injection rate (MAPDIR)
methodology.
It is not always realized that the effectiveness of diverters greatly
depends on reservoir properties, such as formation type, temperature,
reservoir permeability, heterogeneity, and physical well
characteristics (e.g., completion type, well deviation, length of
treatment interval, multiple intervals, etc.). This paper reviews the
mechanisms by which each variety of diverter functions and
discusses the effect of various reservoir properties on the efficiency
of diversion techniques. Guidelines are recommended to help
enhance productivity from zones of interest by choosing the best
methods of diversion while pumping an optimized amount of
treatment fluid. The success of an overall acid treatment often
depends on the effectiveness of the diverting agents.
Abstract: Raman spectroscopy are used to characterize the
chemical changes in normoxic polyhydroxyethylacrylate gel
dosimeter (PHEA) induced by radiation. Irradiations in the low dose
region are performed and the polymerizations of PHEA gels are
monitored by the observing the changes of Raman shift intensity of
the carbon covalent bond of PHEA originated from both monomer
and the cross-linker. The variation in peak intensities with absorbed
dose was observed. As the dose increase, the peak intensities of
covalent bond of carbon in the polymer gels decrease. This point out
that the amount of absorbed dose affect the polymerization of
polymer gels. As the absorbed dose increase, the polymerizations
also increase. Results verify that PHEA gel dosimeters are sensitive
even in lower dose region.
Abstract: In this paper we examine some properties of suborbital graphs for the congruence subgroup r 0 (N) . Then we give necessary and sufficient conditions for graphs to have triangels.
Abstract: The purpose of Grid computing is to utilize
computational power of idle resources which are distributed in
different areas. Given the grid dynamism and its decentralize
resources, there is a need for an efficient scheduler for scheduling
applications. Since task scheduling includes in the NP-hard problems
various researches have focused on invented algorithms especially
the genetic ones. But since genetic is an inherent algorithm which
searches the problem space globally and does not have the efficiency
required for local searching, therefore, its combination with local
searching algorithms can compensate for this shortcomings. The aim
of this paper is to combine the genetic algorithm and GELS (GAGELS)
as a method to solve scheduling problem by which
simultaneously pay attention to two factors of time and number of
missed tasks. Results show that the proposed algorithm can decrease
makespan while minimizing the number of missed tasks compared
with the traditional methods.
Abstract: In the paper we presented the possibility of application
collagen gels with active principle-s from marine algae extract and chlorhexidine salt in dental medicine. The hydro-alcoholic extracts
from marine algae have been used as they have been obtained. The extracts from marine algae and chlorhexidine salt (digluconate) are
incorporated in type I non-denatured fibrillar collagen matrixes. In order to obtain therapeutic effects at nanostructure level, it is important to know the rheological characteristics of the relevant mixtures of collagen gels and extracts from marine algae selected for use. In this survey we have studied mixtures made of non-denatured
fibrillar collagen hydro-gels where different concentrations of marine
algae have been incorporated. Based on the data obtained for the
shearing tensions, we have traced the rheograms – the diagrams for shearing tensions depending on the shearing speed values – from
which we have calculated the apparent viscosities as ratios between shearing tension and speed values, which have been figured in
relation to the shearing speed values, with a view to levelling
dependency.
Abstract: An experimental and numerical study has been conducted to clarify heat transfer characteristics and effectiveness of a cross-flow heat exchanger employing staggered wing-shaped tubes at different angels of attack. The water-side Rew and the air-side Rea were at 5 x 102 and at from 1.8 x 103 to 9.7 x 103, respectively. The tubes arrangements were employed with various angles of attack θ1,2,3 from 0° to 330° at the considered Rea range. Correlation of Nu, St, as well as the heat transfer per unit pumping power (ε) in terms of Rea, design parameters for the studied bundle were presented. The temperature fields around the staggered wing-shaped tubes bundle were predicted by using commercial CFD FLUENT 6.3.26 software package. Results indicated that the heat transfer was increased by increasing the angle of attack from 0° to 45°, while the opposite was true for angles of attack from 135° to 180°. The best thermal performance and hence η of studied bundle was occurred at the lowest Rea and/or zero angle of attack. Comparisons between the experimental and numerical results of the present study and those, previously, obtained for similar available studies showed good agreements.