Abstract: The conventional production of biodiesel from crude
palm oil which contains large amounts of free fatty acids in the
presence of a homogeneous base catalyst confronts the problems of
soap formation and very low yield of biodiesel. To overcome these
problems, free fatty acids must be esterified to their esters in the
presence of an acid catalyst prior to alkaline-catalyzed
transesterification. Sulfated metal oxides are a promising group of
catalysts due to their very high acidity. In this research, aluminadoped
sulfated tin oxide (SO4
2-/Al2O3-SnO2) catalysts were prepared
and used for esterification of free fatty acids in crude palm oil in a
batch reactor. The SO4
2-/Al2O3-SnO2 catalysts were prepared from
different Al precursors. The results showed that different Al
precursors gave different activities of the SO4
2-/Al2O3-SnO2 catalysts.
The esterification of free fatty acids in crude palm oil with methanol
in the presence of SO4
2-/Al2O3-SnO2 catalysts followed first-order
kinetics.
Abstract: Resistive switching of aluminum nitride (AlNx) thin film was demonstrated in a TaN/AlNx/TiN memory cell that was prepared by sputter deposition techniques. The memory cell showed bipolar switching of resistance between +3.5 V and –3.5 V. The resistance ratio of high resistance state (HRS) to low resistance state (HRS), RHRS/RLRS, was about 2 over 100 cycles of endurance test. Both the LRS and HRS of the memory cell exhibited ohmic conduction at low voltages and Poole-Frenkel emission at high voltages. The electrical conduction in the TaN/AlNx/TiN memory cell was possibly attributed to the interactions between charges and defects in the AlNx film.
Abstract: Low silica type X (LSX) Zeolite is one of useful
material in many manufacturing due to the advantage properties
including high surface area, stability, microporous crystalline
aluminosilicates and positive ion in an extra–framework. The LSX
was used rice husk silica source which obtained by leaching with
hydrochloric acid and calcination at 500 C. To improve the
synthesis method, the LSX was crystallizated in Teflon–lined
autoclave will expedite deceasing of the amorphous particles. The
mixed gel with composition of 5.5 Na2O : 1.65 K2O : Al2O3 : 2.2
SiO2 : 122 H2O was crystallized in different container
(Polypropylene bottom and Teflon–lined autoclave). The obtained
powder was characterized by X–ray diffraction (XRD), X–ray
fluorescence spectrometry, N2 adsorption-desorption analysis BET
surface area Scanning electron microscopy (SEM) and Fourier
transform infrared spectroscopy to justify the quality of zeolite. The
results showed the crystallized zeolite in Teflon lined autoclave has
102.8 nm of crystal size, 286 m2/g of surface area and fewer amounts
of round amorphous particles when compared with the crystallized
zeolite in Polypropylene.
Abstract: The aluminum bronze matrix alumina composites using hot press and resin infiltration were investigated to study their porosities, hardness, bending strengths, and microstructures. The experiment results show that the hardness of the sintered composites with the decrease of porosity increases. The composites without and with resin infiltration have about HRF 42-61 of about 34-40% of porosity and about HRF 62-83 of about 30-36% of porosity, respectively. Besides, the alumina composites contain a more amount of iron and nickel powders would cause a lower bending strength due to forming some weaker bonding among the iron, nickel, copper, aluminum under this hot pressing of shorter time.
Abstract: Recycling of aluminum alloys often decrease fluidity,
consequently influence the castability of the alloy. In this study, the
fluidity of Al-Zn alloys, such as the standard A713 alloy with and
without scrap addition has been investigated. The scrap added was
comprised of contaminated alloy turning chips. Fluidity
measurements were performed with double spiral fluidity test
consisting of gravity casting of double spirals in green sand moulds
with good reproducibility. The influence of recycled alloy on fluidity
has been compared with that of the virgin alloy and the results
showed that the fluidity decreased with the increase in recycled alloy
at minimum pouring temperatures. Interestingly, an appreciable
improvement in the fluidity was observed at maximum pouring
temperature, especially for coated spirals.
Abstract: Removal of a reactive dye (Reactive blue 4) by
adsorption utilizing waste aluminium hydroxide sludge as an
adsorbent was investigated. The removal of the dye was optimized
using response surface methodology (RSM). In the RSM
experiments; initial dye concentration, adsorbent concentration and
contact time were critical parameters. RSM experiments were
performed at the range of initial dye concentration 31.82-368.18
mg/L, adsorbent concentration 3.18-36.82 g/L, contact time 15.82-
56.18 h. Optimum initial dye concentration, adsorbent concentration
and contact time were obtained as 108.83 mg/L, 29.36 g/L and 33.57
h respectively. At these conditions, maximum removal of the dye was
obtained as 95%. The experiments were performed at the optimum
conditions to verify these results and the same results were obtained.
Abstract: Cs-type nanocomposite zeolite membrane was successfully synthesized on an alumina ceramic hollow fibre with a mean outer diameter of 1.7 mm; cesium cationic exchange test was carried out inside test module with mean wall thickness of 230 μm and an average crossing pore size smaller than 0.2 μm. Separation factor of n-butane/H2 obtained indicate that a relatively high quality closed to 20. Maxwell-Stefan modeling provides an equivalent thickness lower than 1 µm. To compare the difference an application to CO2/N2 separation has been achieved, reaching separation factors close to (4,18) before and after cation exchange on H-zeolite membrane formed within the pores of a ceramic alumina substrate.
Abstract: The main aim of this work is to develop a model of hydrogen sulfide (H2S) separation from natural gas by using membrane separation technology. The model is developed by incorporating three diffusion mechanisms which are Knudsen, viscous and surface diffusion towards membrane selectivity and permeability. The findings from the simulation result shows that the permeability of the gas is dependent toward the pore size of the membrane, operating pressure, operating temperature as well as feed composition. The permeability of methane has the highest value for Poly (1-trimethylsilyl-1-propyne ) PTMSP membrane at pore size of 0.1nm and decreasing toward a minimum peak at pore range 1 to 1.5 nm as pore size increased before it increase again for pore size is greater than 1.5 nm. On the other hand, the permeability of hydrogen sulfide is found to increase almost proportionally with the increase of membrane pore size. Generally, the increase of pressure will increase the permeability of gas since more driving force is provided to the system while increasing of temperature would decrease the permeability due to the surface diffusion drop off effect. A corroboration of the simulation result also showed a good agreement with the experimental data.
Abstract: For relatively small particles of aluminum (5%) is observed to
corrode before passivation occurs at moderate temperatures (>50oC)
in de-ionized water within one hour. Physical contact with alumina
powder results in a significant increase in both the rate of corrosion
and the extent of corrosion before passivation. Whereas the resulting
release of hydrogen gas could be of commercial interest for portable
hydrogen supply systems, the fundamental aspects of Al corrosion
acceleration in presence of dispersed alumina particles are equally
important. This paper investigates the effects of various amounts of
alumina on the corrosion rate of aluminum powders in water and the
effect of multiple additions of aluminum into a single reactor.
Abstract: Solar energy is the most “available", ecological and clean energy. This energy can be used in active or passive mode. The active mode implies the transformation of solar energy into a useful energy. The solar energy can be transformed into thermal energy, using solar collectors. In these collectors, the active and the most important element is the absorber, material which performs the absorption of solar radiation and, in at the same time, limits its reflection. The paper presents some aspects regarding the IR absorbing material – a type of cermets, used as absorber in the solar collectors, by X Ray Diffraction Technique (XRD) characterization.
Abstract: The present paper deals with the experimental and
computational study of axial collapse of the aluminum metallic shells
having combined tube-frusta geometry between two parallel plates.
Shells were having bottom two third lengths as frusta and remaining
top one third lengths as tube. Shells were compressed to recognize
their modes of collapse and associated energy absorption capability.
An axisymmetric Finite Element computational model of collapse
process is presented and analysed, using a non-linear FE code
FORGE2. Six noded isoparametric triangular elements were used to
discretize the deforming shell. The material of the shells was
idealized as rigid visco-plastic. To validate the computational model
experimental and computed results of the deformed shapes and their
corresponding load-compression and energy-compression curves
were compared. With the help of the obtained results progress of the
axisymmetric mode of collapse has been presented, analysed and
discussed.
Abstract: Curriculum is one of the most important inputs in higher education system and for knowing the strong and weak spots of it we need evaluation. The main purpose of this study was to survey of the curriculum quality of Insurance Management field. Case: University of Allameh Taba Tabaee(according to view point of students,alumni,employer and faculty members).Descriptive statistics (mean, tables, percentages, frequency distribution) and inferential statistics (CHI SQUARE) were used to analyze the data. Six criterions considered for the Quality of curriculum: objectives, content, teaching and learning methods, space and facilities, Time, assessment of learning. objectives, teaching and learning methods criterions was desirable level, content criteria was undesirable level, space and facilities, time and assessment of learning were rather desirable level. The quality of curriculum of insurance management field was relatively desirable level.
Abstract: There are few studies on eggshell of leatherback turtle
which is endangered species in Thailand. This study was focusing on
the ultrastructure and elemental composition of leatherback turtle
eggshells collected from Andaman Sea Shore, Thailand during the
nesting season using scanning electron microscope (SEM). Three
eggshell layers of leatherback turtle; the outer cuticle layer or
calcareous layer, the middle layer or middle multistrata layer and the
inner fibrous layer were recognized. The outer calcareous layer was
thick and porosity which consisted of loose nodular units of various
crystal shapes and sizes. The loose attachment between these units
resulted in numerous spaces and openings. The middle layer was
compact thick with several multistrata and contained numerous
openings connecting to both outer cuticle layer and inner fibrous
layer. The inner fibrous layer was compact and thin, and composed of
numerous reticular fibers. Energy dispersive X-ray microanalysis
detector revealed energy spectrum of X-rays character emitted from
all elements on each layer. The percentages of all elements were
found in the following order: carbon (C) > oxygen (O) > calcium
(Ca) > sulfur (S) > potassium (K) > aluminum (Al) > iodine (I) >
silicon (Si) > chlorine (Cl) > sodium (Na) > fluorine (F) >
phosphorus (P) > magnesium (Mg). Each layer consisted of high
percentage of CaCO3 (approximately 98%) implying that it was
essential for turtle embryonic development. A significant difference
was found in the percentages of Ca and Mo in the 3layers. Moreover,
transition metal, metal and toxic non-metal contaminations were
found in leatherback turtle eggshell samples. These were palladium
(Pd), molybdenum (Mo), copper (Cu), aluminum (Al), lead (Pb), and
bromine (Br). The contamination elements were seen in the outer
layers except for Mo. All elements were readily observed and
mapped using Smiling program. X-ray images which mapped the
location of all elements were showed. Calcium containing in the
eggshell appeared in high contents and was widely distributing in
clusters of the outer cuticle layer to form CaCO3 structure. Moreover,
the accumulation of Na and Cl was observed to form NaCl which was
widely distributing in 3 eggshell layers. The results from this study
would be valuable on assessing the emergent success in this
endangered species.
Abstract: In recent years asymmetric cross section aluminum
alloy stock has been finding increasing use in various industrial manufacturing areas such as general structures and automotive
components. In these areas, components are generally required to have
complex curved configuration and, as such, a bending process is required during manufacture. Undesirable deformation in bending
processes such as flattening or wrinkling can easily occur when thin-walled sections are bent. Hence, a thorough understanding of the
bending behavior of such sections is needed to prevent these undesirable deformations. In this study, the bending behavior of
asymmetric channel section was examined using finite element analysis (FEA). Typical methods of preventing undesirable
deformation, such as asymmetric laminated elastic mandrels were included in FEA model of draw bending. Additionally, axial tension
was applied to prevent wrinkling. By utilizing the FE simulations effect of restriction dies and axial tension on undesirable deformation during the process was clarified.
Abstract: Coagulation of water involves the use of coagulating
agents to bring the suspended matter in the raw water together for
settling and the filtration stage. Present study is aimed to examine the
effects of aluminum sulfate as coagulant in conjunction with Moringa
Oleifera Coagulant Protein as coagulant aid on turbidity, hardness,
and bacteria in turbid water. A conventional jar test apparatus was
employed for the tests. The best removal was observed at a pH of 7
to 7.5 for all turbidities. Turbidity removal efficiency was resulted
between % 80 to % 99 by Moringa Oleifera Coagulant Protein as
coagulant aid. Dosage of coagulant and coagulant aid decreased with
increasing turbidity. In addition, Moringa Oleifera Coagulant Protein
significantly has reduced the required dosage of primary coagulant.
Residual Al+3 in treated water were less than 0.2 mg/l and meets the
environmental protection agency guidelines. The results showed that
turbidity reduction of % 85.9- % 98 paralleled by a primary
Escherichia coli reduction of 1-3 log units (99.2 – 99.97%) was
obtained within the first 1 to 2 h of treatment. In conclusions,
Moringa Oleifera Coagulant Protein as coagulant aid can be used for
drinking water treatment without the risk of organic or nutrient
release. We demonstrated that optimal design method is an efficient
approach for optimization of coagulation-flocculation process and
appropriate for raw water treatment.
Abstract: Nowadays, engineering ceramics have significant
applications in different industries such as; automotive, aerospace,
electrical, electronics and even martial industries due to their
attractive physical and mechanical properties like very high hardness
and strength at elevated temperatures, chemical stability, low friction
and high wear resistance. However, these interesting properties plus
low heat conductivity make their machining processes too hard,
costly and time consuming. Many attempts have been made in order
to make the grinding process of engineering ceramics easier and
many scientists have tried to find proper techniques to economize
ceramics' machining processes. This paper proposes a new diamond
plunge grinding technique using ultrasonic vibration for grinding
Alumina ceramic (Al2O3). For this purpose, a set of laboratory
equipments have been designed and simulated using Finite Element
Method (FEM) and constructed in order to be used in various
measurements. The results obtained have been compared with the
conventional plunge grinding process without ultrasonic vibration
and indicated that the surface roughness and fracture strength
improved and the grinding forces decreased.
Abstract: The distribution, enrichment, and accumulation of zinc
(Zn) in the sediments of Kaohsiung Ocean Disposal Site (KODS),
Taiwan were investigated. Sediment samples from two outer disposal
site stations and nine disposed stations in the KODS were collected per
quarterly in 2009 and characterized for Zn, aluminum, organic matter,
and grain size. Results showed that the mean Zn concentrations varied
from 48 mg/kg to 456 mg/kg. Results from the enrichment factor (EF)
and geo-accumulation index (Igeo) analyses imply that the sediments
collected from the KODS can be characterized between moderate and
moderately severe degree enrichment and between none and none to
medium accumulation of Zn, respectively. However, results of
potential ecological risk index indicate that the sediment has low
ecological potential risk. The EF, Igeo, and Zn concentrations at the
disposed stations were slightly higher than those at outer disposal site.
This indicated that the disposed area centers may be subjected to the
disposal impaction of harbor dredged sediments.
Abstract: Most CT reconstruction system x-ray computed
tomography (CT) is a well established visualization technique in
medicine and nondestructive testing. However, since CT scanning
requires sampling of radiographic projections from different viewing
angles, common CT systems with mechanically moving parts are too
slow for dynamic imaging, for instance of multiphase flows or live
animals. A large number of X-ray projections are needed to
reconstruct CT images, so the collection and calculation of the
projection data consume too much time and harmful for patient. For
the purpose of solving the problem, in this study, we proposed a
method for tomographic reconstruction of a sample from a limited
number of x-ray projections by using linear interpolation method. In
simulation, we presented reconstruction from an experimental x-ray
CT scan of a Aluminum phantom that follows to two steps: X-ray
projections will be interpolated using linear interpolation method and
using it for CT reconstruction based upon Ordered Subsets
Expectation Maximization (OSEM) method.
Abstract: Iron ore and coal are the two major important raw
materials being used in Iron making industries. Usually ore fines
containing around 5% Alumina are rejected due to higher proportion
of alumina. Therefore, a technology or process which may reduce
the alumina content by 2% by beneficiation process will be highly
attractive . In addition fine coals with ash content is used nearly 12%
is directly injected in blast furnace. Fast fluidization is a technology
by using dry beneficiation of coal and iron ore can be done. During
the fluidization process the iron ore band coal is fluidized at high
velocity in the riser of a fast fluidized bed, the heavier and coarse
particles is generally settled at the bottom in a dense zone of the riser
while the finer and lighter particle are entrained to the top dilute zone
and then via a cyclone is fed back to the bottom of the riser column.
Most of the alumina and low ash fine size coals being lighter are
expected to move up to the riser and by a natural beneficiation of
ores is expected to take place in the riser. Therefore in this study an
attempt has been made for dry beneficiation of iron ore and coal in a
fluidized bed and its hydrodynamic characterization.
Abstract: Scatter behavior of fatigue life in die-cast AM60B
alloy was investigated. For comparison, those in rolled AM60B alloy
and die-cast A365-T5 aluminum alloy were also studied. Scatter
behavior of pore size was also investigated to discuss dominant
factors for fatigue life scatter in die-cast materials. Three-parameter
Weibull function was suitable to explain the scatter behavior of both
fatigue life and pore size. The scatter of fatigue life in die-cast
AM60B alloy was almost comparable to that in die-cast A365-T5
alloy, while it was significantly large compared to that in the rolled
AM60B alloy. Scatter behavior of pore size observed at fracture
nucleation site on the fracture surface was comparable to that
observed on the specimen cross-section and also to that of fatigue
life. Therefore, the dominant factor for large scatter of fatigue life in
die-cast alloys would be the large scatter of pore size. This
speculation was confirmed by the fracture mechanics fatigue life
prediction, where the pore observed at fatigue crack nucleation site
was assumed as the pre-existing crack.