Abstract: Constructed Wetland (CW) is a reasonable method to
treat wastewater. Current study was carried out to co-treat landfill
leachate and domestic wastewater using a CW system. Typha
domingensis was transplanted to CW, which encloses two substrate
layers of adsorbents named ZELIAC and zeolite. Response surface
methodology and central composite design were employed to
evaluate experimental data. Contact time (h) and leachate-towastewater
mixing ratio (%; v/v) were selected as independent
factors. Phenols and manganese removal were selected as dependent
responses. At optimum contact time (48.7 h) and leachate-towastewater
mixing ratio (20.0%), removal efficiencies of phenols and
manganese removal efficiencies were 90.5%, and 89.4%,
respectively.
Abstract: This paper presents thermal annealing de-wetting
technique for the preparation of porous metal membrane for Thin
Film Encapsulation (TFE) application. Thermal annealing de-wetting
experimental results reveal that pore size formation in porous metal
membrane depend upon i.e. 1. The substrate at which metal is
deposited, 2. Melting point of metal used for porous metal cap layer
membrane formation, 3. Thickness of metal used for cap layer, 4.
Temperature used for formation of porous metal membrane. In order
to demonstrate this technique, Silver (Ag) was used as a metal for
preparation of porous metal membrane on amorphous silicon (a-Si)
and silicon oxide. The annealing of the silver thin film of various
thicknesses was performed at different temperature. Pores in porous
silver film were analyzed using Scanning Electron Microscope
(SEM). In order to check the usefulness of porous metal film for TFE
application, the porous silver film prepared on amorphous silicon (a-
Si) and silicon oxide was released using XeF2 and VHF, respectively.
Finally, guide line and structures are suggested to use this porous
membrane for robust TFE application.
Abstract: The main parameters affecting the workability are the
water content, particle size, and the total surface of the grains, as long
as the mixing water begins by wetting the surface of the grains and
then fills the voids between the grains to form entrapped water, the
quantity of water remaining is called free water. The aim of this study is to undertake a fractal approach through
the relationship between the concrete formulation parameters and
workability. To develop this approach a series of concrete taken from
the literature was investigated by varying formulation parameters
such as G/S, the quantity of cement C and the quantity of water W. We also call another model as the model of water layer thickness
and model of paste layer thickness to judge their relevance, hence the
following results: the relevance of the water layer thickness model is
considered as a relevant when there is a variation in the water
quantity. The model of the paste layer thickness is only applicable if
we considered that the paste is made with the grain value Dmax =
2.85: value from which we see a stability of the model.
Abstract: In present global scenario, aluminum alloys are
coining the attention of many innovators as competing structural
materials for automotive and space applications. Comparing to other
challenging alloys, especially, 7xxx series aluminum alloys have
been studied seriously because of benefits such as moderate strength;
better deforming characteristics and affordable cost. It is expected
that substitution of aluminum alloys for steels will result in great
improvements in energy economy, durability and recyclability.
However, it is necessary to improve the strength and the formability
levels at low temperatures in aluminum alloys for still better
applications. Aluminum–Zinc–Magnesium with or without other
wetting agent denoted as 7XXX series alloys are medium strength
heat treatable alloys. In addition to Zn, Mg as major alloying
additions, Cu, Mn and Si are the other solute elements which
contribute for the improvement in mechanical properties by suitable
heat treatment process. Subjecting to suitable treatments like age
hardening or cold deformation assisted heat treatments; known as low
temperature thermomechanical treatments (LTMT) the challenging
properties might be incorporated. T6 is the age hardening or
precipitation hardening process with artificial aging cycle whereas T8
comprises of LTMT treatment aged artificially with X% cold
deformation. When the cold deformation is provided after solution
treatment, there is increase in hardness related properties such as
wear resistance, yield and ultimate strength, toughness with the
expense of ductility. During precipitation hardening both hardness
and strength of the samples are increasing. The hardness value may
further improve when room temperature deformation is positively
supported with age hardening known as thermomechanical treatment.
It is intended to perform heat treatment and evaluate hardness, tensile
strength, wear resistance and distribution pattern of reinforcement in
the matrix. 2 to 2.5 and 3 to 3.5 times increase in hardness is reported
in age hardening and LTMT treatments respectively as compared to
as-cast composite. There was better distribution of reinforcements in
the matrix, nearly two fold increase in strength levels and up to 5
times increase in wear resistance are also observed in the present
study.
Abstract: Acoustic properties of polymeric liquids are high
sensitive to free gas traces in the form of fine bubbles. Their presence
is typical for such liquids because of chemical reactions, small
wettability of solid boundaries, trapping of air in technological
operations, etc. Liquid temperature influences essentially its
rheological properties, which may have an impact on the bubble
pulsations and sound propagation in the system. The target of the
paper is modeling of the liquid temperature effect on single bubble
dynamics and sound dispersion and attenuation in polymeric solution
with spherical gas bubbles. The basic sources of attenuation (heat
exchange between gas in microbubbles and surrounding liquid,
rheological and acoustic losses) are taken into account. It is supposed
that in the studied temperature range the interface mass transfer has a
minor effect on bubble dynamics. The results of the study indicate
that temperature raise yields enhancement of bubble pulsations and
increase in sound attenuation in the near-resonance range and may
have a strong impact on sound dispersion in the liquid-bubble
mixture at frequencies close to the resonance frequency of bubbles.
Abstract: In this paper air quality conditions in Makkah and
Leeds are compared. These two cities have totally different climatic
conditions. Makkah climate is characterised as hot and dry (arid)
whereas that of Leeds is characterised as cold and wet (temperate).
This study uses air quality data from 2012 collected in Makkah,
Saudi Arabia and Leeds, UK. The concentrations of all pollutants,
except NO are higher in Makkah. Most notable, the concentrations of
PM10 are much higher in Makkah than in Leeds. This is probably due
to the arid nature of climatic conditions in Makkah and not solely due
to anthropogenic emission sources, otherwise like PM10 some of the
other pollutants, such as CO, NO, and SO2 would have shown much
greater difference between Leeds and Makkah. Correlation analysis is
performed between different pollutants at the same site and the same
pollutants at different sites. In Leeds the correlation between PM10
and other pollutants is significantly stronger than in Makkah. Weaker
correlation in Makkah is probably due to the fact that in Makkah
most of the gaseous pollutants are emitted by combustion processes,
whereas most of the PM10 is generated by other sources, such as
windblown dust, re-suspension, and construction activities. This is in
contrast to Leeds where all pollutants including PM10 are
predominantly emitted by combustions, such as road traffic.
Furthermore, in Leeds frequent rains wash out most of the
atmospheric particulate matter and suppress re-suspension of dust.
Temporal trends of various pollutants are compared and discussed.
This study emphasises the role of climatic conditions in managing air
quality, and hence the need for region-specific controlling strategies
according to the local climatic and meteorological conditions.
Abstract: In this work, the Ictalurus punctatus species estimated
available physical habitat is compared with the estimated physical
habitat for the same but modified river reach, with the aim of creating
a linear park, along a length of 5 500 m.
To determine the effect of ecological park construction, on
physical habitat of the Lerma river stretch of study, first, the available
habitat for the Ictalurus punctatus species was estimated through the
simulation of the physical habitat, by using surveying, hydraulics,
and habitat information gotten at the river reach in its actual situation.
Second, it was estimated the available habitat for the above species,
upon the simulation of the physical habitat through the proposed
modification for the ecological park creation. Third, it is presented a
comparison between both scenarios in terms of available habitat
estimated for Ictalurus punctatus species, concluding that in cases of
adult and spawning life stages, changes in the channel to create an
ecological park would produce a considerable loss of potentially
usable habitat (PUH), while in the case of the juvenile life stage PUH
remains virtually unchanged, and in the case of life stage fry the PUH
would increase due to the presence of velocities and depths of lesser
magnitude, due to the presence of minor flow rates and lower volume
of the wet channel.
It is expected that habitat modification for linear park construction
may produce the lack of Ictalurus punktatus species conservation at
the river reach of the study.
Abstract: Steady three-dimensional and two free surface waves
generated by moving bodies are presented, the flow problem to be
simulated is rich in complexity and poses many modeling challenges
because of the existence of breaking waves around the ship hull, and
because of the interaction of the two-phase flow with the turbulent
boundary layer. The results of several simulations are reported. The
first study was performed for NACA0012 of hydrofoil with different
meshes, this section is analyzed at h/c= 1, 0345 for 2D. In the second
simulation a mathematically defined Wigley hull form is used to
investigate the application of a commercial CFD code in prediction of
the total resistance and its components from tangential and normal
forces on the hull wetted surface. The computed resistance and wave
profiles are used to estimate the coefficient of the total resistance for
Wigley hull advancing in calm water under steady conditions. The
commercial CFD software FLUENT version 12 is used for the
computations in the present study. The calculated grid is established
using the code computer GAMBIT 2.3.26. The shear stress k-ωSST
model is used for turbulence modeling and the volume of fluid
technique is employed to simulate the free-surface motion. The
second order upwind scheme is used for discretizing the convection
terms in the momentum transport equations, the Modified HRIC
scheme for VOF discretization. The results obtained compare well
with the experimental data.
Abstract: Steady three-dimensional and two free surface waves
generated by moving bodies are presented, the flow problem to be
simulated is rich in complexity and poses many modeling challenges
because of the existence of breaking waves around the ship hull, and
because of the interaction of the two-phase flow with the turbulent
boundary layer. The results of several simulations are reported. The
first study was performed for NACA0012 of hydrofoil with different
meshes, this section is analyzed at h/c= 1, 0345 for 2D. In the second
simulation a mathematically defined Wigley hull form is used to
investigate the application of a commercial CFD code in prediction of
the total resistance and its components from tangential and normal
forces on the hull wetted surface. The computed resistance and wave
profiles are used to estimate the coefficient of the total resistance for
Wigley hull advancing in calm water under steady conditions. The
commercial CFD software FLUENT version 12 is used for the
computations in the present study. The calculated grid is established
using the code computer GAMBIT 2.3.26. The shear stress k-ωSST
model is used for turbulence modeling and the volume of fluid
technique is employed to simulate the free-surface motion. The
second order upwind scheme is used for discretizing the convection
terms in the momentum transport equations, the Modified HRIC
scheme for VOF discretization. The results obtained compare well
with the experimental data.
Abstract: Chitosan functionalized Fe3O4-Au core shell
nanoparticles have been prepared using a two-step wet chemical
approach using NaBH4 as reducing agent for formation of Au in
ethylene glycol. X-ray diffraction studies shows individual phases of
Fe3O4 and Au in the as prepared samples with crystallite size of 5.9
and 11.4 nm respectively. The functionalization of the core-shell
nanostructure with Chitosan has been confirmed using Fourier
transform infrared spectroscopy along with signatures of octahedral
and tetrahedral sites of Fe3O4 below 600cm-1. Mössbauer
spectroscopy shows decrease in particle-particle interaction in
presence of Au shell (72% sextet) than pure oleic coated Fe3O4
nanoparticles (88% sextet) at room temperature. At 80K, oleic acid
coated Fe3O4 shows only sextets whereas the Chitosan functionalized
Fe3O4 and Chitosan functionalized Fe3O4@Au core shell show
presence of 5 and 11% doublet, respectively.
Abstract: The concentrations of heavy metals in sediments of
Qua Iboe River Estuary (QIRE) were monitored at four different
sampling locations in wet and dry seasons. A preliminary survey to
determine the four sampling stations along the river continuum
showed that the area spanned between
Abstract: This paper is aimed at proposing a rhombus shaped
wearable fractal antenna for wireless communication systems. The
geometrical descriptors of the antenna have been obtained using
bacterial foraging optimization (BFO) for wide band operation. The
method of moment based IE3D software has been used to simulate
the antenna and observed that miniaturization of 13.08% has been
achieved without degrading the resonating properties of the proposed
antenna. An analysis with different substrates has also been done in
order to evaluate the effectiveness of electrical permittivity on the
presented structure. The proposed antenna has low profile, light
weight and has successfully demonstrated wideband and multiband
characteristics for wearable electronic applications.
Abstract: The atmospheres in many cities along the coastal lines
in the world have been rapidly changed to coastal-industrial
atmosphere. Hence, it is vital to investigate the corrosion behavior of
steel exposed to this kind of environment. In this present study,
Electrochemical Impedance Spectrography (EIS) and film thickness
measurement were applied to monitor the corrosion behavior of
weathering steel covered with a thin layer of the electrolyte in a
wet-dry cyclic condition, simulating a coastal-industrial environment
at 25oC and 60% RH. The results indicate that in all cycles, the
corrosion rate increases during the drying process due to an increase in
anion concentration and an acceleration of oxygen diffusion enhanced
by the effect of the thinning out of the electrolyte. During the wet-dry
cyclic corrosion test, the long-term corrosion behavior of this steel
depends on the periods of exposure. Corrosion process is first
accelerated and then decelerated. The decelerating corrosion process is
contributed to the formation of the protective rust, favored by the
wet-dry cycle and the acid regeneration process during the rusting
process.
Abstract: This study was carried out to investigate the adverse
effect of industrial wastewater on surface water quality in Gebeng
industrial estate, Pahang, Malaysia. Surface water was collected from
six sampling stations. Physicochemical parameters were
characterized based on in-situ and ex-situ analysis according to
standard methods by American Public Health Association (APHA).
Selected heavy metals were determined by using Inductively Coupled
Plasma Mass Spectrometry (ICP MS). The results revealed that the
concentration of heavy metals such as Pb, Cu, Cd, Cr and Hg were
high in samples. The results also showed that the value of Pb and Hg
were higher in the wet season in comparison to dry season.
According to Malaysia National Water Quality Standard (NWQS)
and Water Quality Index (WQI) all the sampling station were
categorized as class IV (highly polluted). The present study revealed
that the adverse effects of careless disposal of wastes and directly
discharge of effluents affected on surface water quality. Therefore,
the authorities should implement the laws to ensure the proper
practices of wastewater management for environmental sustainability
around the study area.
Abstract: Scrubbing by a liquid spraying is one of the most
effective processes used for removal of fine particles and soluble
gas pollutants (such as SO2, HCl, HF) from the flue gas. There are
many configurations of scrubbers designed to provide contact
between the liquid and gas stream for effectively capturing
particles or soluble gas pollutants, such as spray plates, packed bed
towers, jet scrubbers, cyclones, vortex and venturi scrubbers. The
primary function of venturi scrubber is the capture of fine particles
as well as HCl, HF or SO2 removal with effect of the flue gas
temperature decrease before input to the absorption column. In this
paper, sulfur dioxide (SO2) from flue gas was captured using new
design replacing venturi scrubber (1st degree of wet scrubbing).
The flue gas was prepared by the combustion of the carbon
disulfide solution in toluene (1:1 vol.) in the flame in the reactor.
Such prepared flue gas with temperature around 150°C was
processed in designed laboratory O-element scrubber. Water was
used as absorbent liquid. The efficiency of SO2 removal, pressure
drop and temperature drop were measured on our experimental
device. The dependence of these variables on liquid-gas ratio was
observed. The average temperature drop was in the range from
150°C to 40°C. The pressure drop was increased with increasing of
a liquid-gas ratio, but no too much as for the common venturi
scrubber designs. The efficiency of SO2 removal was up to 70 %.
The pressure drop of our new designed wet scrubber is similar to
commonly used venturi scrubbers; nevertheless the influence of
amount of the liquid on pressure drop is not so significant.
Abstract: Propylene self-metathesis to ethylene and butene was
studied over WOx/SiO2 catalysts at 450oC and atmospheric pressure.
The WOx/SiO2 catalysts were prepared by incipient wetness
impregnation of ammonium metatungstate aqueous solution. It was
found that, adding nano-sized extra supports (SiO2 and TiO2) by
physical mixing with the WOx/SiO2 enhanced propylene conversion.
The UV-Vis and FT-Raman results revealed that WOx could migrate
from the original silica support to the extra support, leading to a
better dispersion of WOx. The ICP-OES results also indicate that
WOx existed on the extra support. Coke formation was investigated
on the catalysts after 10 h time-on-stream by TPO. However, adding
nano-sized extra supports led to higher coke formation which may be
related to acidity as characterized by NH3-TPD.
Abstract: Catalytic combustion of methane is imperative due to
stability of methane at low temperature. Methane (CH4), therefore,
remains unconverted in vehicle exhausts thereby causing greenhouse
gas GHG emission problem. In this study, heterogeneous catalysts of
palladium with bio-char (2 wt% Pd/Bc) and Al2O3 (2wt% Pd/ Al2O3)
supports were prepared by incipient wetness impregnation and then
subsequently tested for catalytic combustion of CH4. Support-porous
heterogeneous catalytic combustion (HCC) material were selected
based on factors such as surface area, porosity, thermal stability,
thermal conductivity, reactivity with reactants or products, chemical
stability, catalytic activity, and catalyst life. Sustainable and
renewable support-material of bio-mass char derived from palm shell
waste material was compared with those from the conventional
support-porous materials. Kinetic rate of reaction was determined for
combustion of methane on Palladium (Pd) based catalyst with Al2O3
support and bio-char (Bc). Material characterization was done using
TGA, SEM, and BET surface area. The performance test was
accomplished using tubular quartz reactor with gas mixture ratio of
3% methane and 97% air. The methane porous-HCC conversion was
carried out using online gas analyzer connected to the reactor that
performed porous-HCC. BET surface area for prepared 2 wt% Pd/Bc
is smaller than prepared 2wt% Pd/ Al2O3 due to its low porosity
between particles. The order of catalyst activity based on kinetic rate
on reaction of catalysts in low temperature was 2wt%
Pd/Bc>calcined 2wt% Pd/ Al2O3> 2wt% Pd/ Al2O3>calcined 2wt%
Pd/Bc. Hence agro waste material can successfully be utilized as an
inexpensive catalyst support material for enhanced CH4 catalytic
combustion.
Abstract: Nitrogen fertilizer is the most used and often the most
mismanaged nutrient input. Nitrogen management has tremendous
implications on crop productivity, quality and environmental
stewardship. Sufficient nitrogen is needed to optimum yield and
quality. Soil and in-season plant tissue testing for nitrogen status are
a time consuming and expensive process. Real time sensing of plant
nitrogen status can be a useful tool in managing nitrogen inputs. The
objectives of this project were to assess the reliability of remotely
sensed non-destructive plant nitrogen measurements compared to wet
chemistry data from sampled plant tissue, develop in-season nitrogen
recommendations based on remotely sensed data for improved
nitrogen use efficiency and assess the potential for determining yield
and quality from remotely sensed data. Very good correlations were
observed between early-season remotely sensed crop nitrogen status
and plant nitrogen concentrations and subsequent in-season fertilizer
recommendations. The transmittance/absorbance type meters gave
the most accurate readings. Early in-season fertilizer recommendation
would be to apply 40 kg nitrogen per hectare plus 15 kg nitrogen per
hectare for each unit difference measured with the SPAD meter
between the crop and reference area or 25 kg plus 13 kg per hectare
for each unit difference measured with the CCM 200. Once the crop
was sufficiently fertilized meter readings became inconclusive and
were of no benefit for determining nitrogen status, silage yield and
quality and grain yield and protein.
Abstract: Comparing other methods of waste water treatment,
constructed wetlands are one of the most fascinating practices
because being a natural process they are eco-friendly have low
construction and maintenance cost and have considerable capability
of wastewater treatment. The current research was focused mainly on
comparison of Ranunculus muricatus and Typha latifolia as wetland
plants for domestic wastewater treatment by designing and
constructing efficient pilot scale horizontal subsurface flow
mesocosms. Parameters like chemical oxygen demand, biological
oxygen demand, phosphates, sulphates, nitrites, nitrates, and
pathogenic indicator microbes were studied continuously with
successive treatments. Treatment efficiency of the system increases
with passage of time and with increase in temperature. Efficiency of
T. latifolia planted setups in open environment was fairly good for
parameters like COD and BOD5 which was showing reduction up to
82.5% for COD and 82.6% for BOD5 while DO was increased up to
125%. Efficiency of R. muricatus vegetated setup was also good but
lowers than that of T. latifolia planted showing 80.95% removal of
COD and BOD5. Ranunculus muricatus was found effective in
reducing bacterial count in wastewater. Both macrophytes were
found promising in wastewater treatment.
Abstract: This research has been conducted to study the method
of culture and comparing growth and biomass of Gracilaria corticata
cultured on rope and net for 50 days through two treatments (first
treatment: culture of alga on net and the second treatment: culture of
alga on rope and each treatment was repeated by four cases). During
culture period, the water of aquariums was replaced once every two
days for 40-50%. Also, 0.3-0.5 grams of urea fertilizer was added to
the culture environment for fertilization. Moreover, some of the
environmental factors such as pH, salinity and temperature of the
environment were measured on a daily basis. During the culture
period, extent of longitudinal growth of the species of both treatments
was equal. The said length was reached from 8-10 cm to 10.5-13 cm
accordingly. The resulted weight in repetitions of the first treatment
was higher than that of the second treatment in such a way as in the
first treatment, its weight reached from 10 grams to 21.119 grams and
in the second treatment, its weight reached from 10 grams to 17.663
grams. On a whole, it may be stated that that kind of alga being
studied has a considerable growth with respect to its volume. The
results have revealed that the percentage of daily growth and wet
weight at the end of the first treatment was higher than that of the
second treatment and it was registered as 0.934, 6.072 and 811.432 in
the first treatment and 0.797, 4.990 and 758.071 in the second
treatment respectively. This difference is significant (P