Abstract: The selective wet-etching of amorphous and
crystalline region of Sb20Se80 thin films was carried out using organic
based solution e.g. amines. We report the development of an in situ
real-time method to study the wet chemical etching process of thin
films. Characterization of the structure and surface of films studied
by X-ray diffraction, SEM and EBSD methods has been done and
potential application suggested.
Abstract: Thirty three re-wetting tests were conducted at
different combinations of temperatures (5.7- 46.30C) and relative
humidites (48.2-88.6%) with barley. Two most commonly used thinlayer
drying and rewetting models i.e. Page and Diffusion were
compared for their ability to the fit the experimental re-wetting data
based on the standard error of estimate (SEE) of the measured and
simulated moisture contents. The comparison shows both the Page
and Diffusion models fit the re-wetting experimental data of barley
well. The average SEE values for the Page and Diffusion models
were 0.176 % d.b. and 0.199 % d.b., respectively. The Page and
Diffusion models were found to be most suitable equations, to
describe the thin-layer re-wetting characteristics of barley over a
typically five day re-wetting. These two models can be used for the
simulation of deep-bed re-wetting of barley occurring during
ventilated storage and deep bed drying.
Abstract: Sulphur dioxide is a harmful gaseous product that
needs to be minimized in the atmosphere. This research work
investigates the use of zeolite as a possible additive that can improve
the sulphur dioxide capture in wet flue gas desulphurisation
dissolution process. This work determines the effect of temperature,
solid to liquid ratio, acid concentration and stirring speed on the
leaching of zeolite using a pH stat apparatus. The atomic absorption
spectrometer was used to measure the calcium ions from the solution.
It was found that the dissolution rate of zeolite decreased with
increase in solid to liquid ratio and increases with increase in
temperature, stirring speed and acid concentration. The activation
energy for the dissolution rate of zeolite in hydrochloric acid was
found to be 9.29kJ/mol. and therefore the product layer diffusion was
the rate limiting step.
Abstract: The current practice of determination of moisture diffusivity of building materials under laboratory conditions is predominantly aimed at the absorption phase. The main reason is the simplicity of the inverse analysis of measured moisture profiles. However, the liquid moisture transport may exhibit significant hysteresis. Thus, the moisture diffusivity should be different in the absorption (wetting) and desorption (drying) phase. In order to bring computer simulations of hygrothermal performance of building materials closer to the reality, it is then necessary to find new methods for inverse analysis which could be used in the desorption phase as well. In this paper we present genetic algorithm as a possible method of solution of the inverse problem of moisture transport in desorption phase. Its application is demonstrated for AAC as a typical building material.
Abstract: In this study, an experimental investigation was carried
out to fix CO2 into the electronic arc furnace (EAF) reducing slag from
stainless steelmaking process under wet grinding. The slag was ground
by the vibrating ball mill with the CO2 and pure water. The reaction
behavior was monitored with constant pressure method, and the
change of CO2 volume in the experimental system with grinding time
was measured. It was found that the CO2 absorption occurred as soon
as the grinding started. The CO2 absorption under wet grinding was
significantly larger than that under dry grinding. Generally, the
amount of CO2 absorption increased as the amount of water, the
amount of slag, the diameter of alumina ball and the initial pressure of
CO2 increased. However, the initial absorption rate was scarcely
influenced by the experimental conditions except for the initial CO2
pressure. According to this research, the CO2 reacted with the CaO
inside the slag to form CaCO3.
Abstract: Snow cover is an important phenomenon in
hydrology, hence modeling the snow accumulation and melting is an
important issue in places where snowmelt significantly contributes to
runoff and has significant effect on water balance. The physics-based
models are invariably distributed, with the basin disaggregated into
zones or grid cells. Satellites images provide valuable data to verify
the accuracy of spatially distributed model outputs. In this study a
spatially distributed physically based model (WetSpa) was applied to
predict snow cover and melting in the Latyan dam watershed in Iran.
Snowmelt is simulated based on an energy balance approach. The
model is applied and calibrated with one year of observed daily
precipitation, air temperature, windspeed, and daily potential
evaporation. The predicted snow-covered area is compared with
remotely sensed images (MODIS). The results show that simulated
snow cover area SCA has a good agreement with satellite image
snow cover area SCA from MODIS images. The model performance
is also tested by statistical and graphical comparison of simulated and
measured discharges entering the Latyan dam reservoir.
Abstract: This paper presents the climatic range calculations for
comfort evaporative cooling for Tehran. In this study the minimum
climatic conditions required to achieve an appropriate comfort zone
will be presented.
Physiologically uncomfortable conditions in arid climates are
mainly caused by the extreme heat and dryness. Direct evaporative
cooling adds moisture to the air stream until the air stream is close to
saturation. The dry bulb temperature is reduced, while the wet bulb
temperature stays the same. Evaporative cooling is economical,
effective, environmentally friendly, and healthy.
Comfort cooling by direct evaporative cooling (passive or fan
forced) in the 35. 41 N (such as Tehran) latitude requires design
wet-bulb temperature not over 25.4 C. Evaporative cooling outside
this limit cannot achieve the required 26.7 ET, and is recommended
for relief cooling only.
Abstract: 115 samples of Labeo calbasu ranged 8.0-17.9cm
length with mean11.90±1.96 and 4.9-68.5g weight with mean
22.25±12.54 from the River Chenab, Southern Punjab, Pakistan were
analyzed to investigate length-weight relationships (LWR) of fish in
relation to condition factor (K). Standard length (SL), fork length
(FL), head length (HL) head width (HW), body girth (BG), dorsal fin
length (DFL), dorsal fin base (DFB), pectoral fin length (PcFL),
pelvic fin length (PvFL) and anal fin length (AFL) are found to be
highly correlated with increasing total length and wet body weight (r
> 0.500). Wet body weight has positive (r=0.540) and total length
has no correlation (r=0.344) with calculated Condition factor (K).
The slope “b" in the relationship is 3.27 and intercepts -2.2258.
Abstract: This study investigated the seasonal prevalence of
Aedes aegypti and Ae. albopictus larvae in three topographical areas
(i.e. mangrove, rice paddy and mountainous areas). Samples were
collected from 300 households in both wet and dry seasons in nine
districts in Nakhon Si Thammarat province. Ae. aegypti and Ae.
albopictus were found in 21 out of 29 types of water containers in
mangrove, rice paddy and mountainous areas. Ae. aegypti and Ae.
albopictus laid eggs in different container types depending on season
and topographical areas. Ae. aegypti larvae were found most in metal
box in mangrove and mountainous areas in wet season. Ae.
albopictus larvae were also found most in metal box in mangrove and
mountainous areas in both wet and dry seasons. All Ae. albopictus
larval indices were higher than Ae. aegypti larval indices in all three
topographical areas and both seasons. HI and BI did not differ in
three topographical areas but differed between Aedes sp. HI for both
Ae. aegypti and Ae. albopictus in all three topographical areas in both
seasons were greater than 10 %, except Aedes aegypti in rice paddy
area in wet season. This indicated high risks of DHF transmission in
these areas.
Abstract: Auckland has a temperate climate with comfortable warm, dry summers and mild, wet winters. Auckland house design not only focus on winter thermal performance and indoor thermal condition, but also indoor moisture control, which is closely related to indirect health effects such as dust mites, fungi, etc. Most Auckland houses are designed to use temporary heating for winter indoor thermal comfort. Based on field study data of indoor microclimate conditions of two Auckland townhouses with a whole home mechanical ventilation system or a passive wind directional skylight vent, this study is to evaluate and compare indoor moisture conditions of two insulated townhouses only using temporary heating with different ventilation systems.
Abstract: The Niger Delta Region of Nigeria is home to about
20 million people and 40 different ethnic groups. The region has an
area of seventy thousand square kilometers (70,000 KM2) of
wetlands, formed primarily by sediments deposition and makes up
7.5 percent of Nigeria's total landmass. The notable ecological zones
in this region includes: coastal barrier islands; mangrove swamp
forests; fresh water swamps; and lowland rainforests. This incredibly
naturally-endowed ecosystem region, which contains one of the
highest concentrations of biodiversity on the planet, in addition to
supporting abundant flora and fauna, is threatened by the inhuman act
known as gas flaring. Gas flaring is the combustion of natural gas
that is associated with crude oil when it is pumped up from the
ground. In petroleum-producing areas such as the Niger Delta region
of Nigeria where insufficient investment was made in infrastructure
to utilize natural gas, flaring is employed to dispose of this associated
gas. This practice has impoverished the communities where it is
practiced, with attendant environmental, economic and health
challenges. This paper discusses the adverse environmental and
health implication associated with the practice, the role of
Government, Policy makers, Oil companies and the Local
communities aimed at bring this inhuman practice to a prompt end.
Abstract: Decentralized eco-sanitation system is a promising and sustainable mode comparing to the century-old centralized conventional sanitation system. The decentralized concept relies on an environmentally and economically sound management of water, nutrient and energy fluxes. Source-separation systems for urban waste management collect different solid waste and wastewater streams separately to facilitate the recovery of valuable resources from wastewater (energy, nutrients). A resource recovery centre constituted for 20,000 people will act as the functional unit for the treatment of urban waste of a high-density population community, like Singapore. The decentralized system includes urine treatment, faeces and food waste co-digestion, and horticultural waste and organic fraction of municipal solid waste treatment in composting plants. A design model is developed to estimate the input and output in terms of materials and energy. The inputs of urine (yellow water, YW) and faeces (brown water, BW) are calculated by considering the daily mean production of urine and faeces by humans and the water consumption of no-mix vacuum toilet (0.2 and 1 L flushing water for urine and faeces, respectively). The food waste (FW) production is estimated to be 150 g wet weight/person/day. The YW is collected and discharged by gravity into tank. It was found that two days are required for urine hydrolysis and struvite precipitation. The maximum nitrogen (N) and phosphorus (P) recovery are 150-266 kg/day and 20-70 kg/day, respectively. In contrast, BW and FW are mixed for co-digestion in a thermophilic acidification tank and later a decentralized/centralized methanogenic reactor is used for biogas production. It is determined that 6.16-15.67 m3/h methane is produced which is equivalent to 0.07-0.19 kWh/ca/day. The digestion residues are treated with horticultural waste and organic fraction of municipal waste in co-composting plants.
Abstract: The microbiological and physicochemical
characteristics of wetland soils in Eket Local Government Area were
studied between May 2001 and June 2003. Total heterotrophic
bacterial counts (THBC), total fungal counts (TFC), and total
actinomycetes counts (TAC) were determined from soil samples
taken from four locations at two depths in the wet and dry seasons.
Microbial isolates were characterized and identified. Particle size and
chemical parameters were also determined using standard methods.
THBC ranged from 5.2 (+0.17) x106 to 1.7 (+0.18) x107 cfu/g and
from 2.4 (+0.02) x106 to 1.4 (+0.04) x107cfu/g in the wet and dry
seasons, respectively. TFC ranged from 1.8 (+0.03) x106 to 6.6 (+
0.18) x106 cfu/g and from 1.0 (+0.04) x106 to 4.2 (+ 0.01) x106 cfu/g
in the wet and dry seasons, respectively .TAC ranged from 1.2
(+0.53) x106 to 6.0 (+0.05) x106 cfu/g and from 0.6 (+0.01) x106 to
3.2 (+ 0.12) x106 cfu/g in the wet and dry season, respectively.
Acinetobacter, Alcaligenes, Arthrobacter, Bacillus, Beijerinckja,
Enterobacter, Micrococcus, Flavobacterium, Serratia, Enterococcus,
and Pseudomonas species were predominant bacteria while
Aspergillus, Fusarium, Mucor, Penicillium, and Rhizopus were the
dominant fungal genera isolated. Streptomyces and Norcadia were
the actinomycetes genera isolated. The particle size analysis showed
high sand fraction but low silt and clay. The pH and % organic
matter were generally acidic and low, respectively at all locations.
Calcium dominated the exchangeable bases with low electrical
conductivity and micronutrients. These results provide the baseline
data of Eket wetland soils for its management for sustainable
agriculture.
Abstract: Contour filter strips planted with perennial vegetation
can be used to improve surface and ground water quality by reducing
pollutant, such as NO3-N, and sediment outflow from cropland to a
river or lake. Meanwhile, the filter strips of perennial grass with biofuel
potentials also have economic benefits of producing ethanol. In
this study, The Soil and Water Assessment Tool (SWAT) model was
applied to the Walnut Creek Watershed to examine the effectiveness
of contour strips in reducing NO3-N outflows from crop fields to the
river or lake. Required input data include watershed topography,
slope, soil type, land-use, management practices in the watershed and
climate parameters (precipitation, maximum/minimum air
temperature, solar radiation, wind speed and relative humidity).
Numerical experiments were conducted to identify potential
subbasins in the watershed that have high water quality impact, and
to examine the effects of strip size and location on NO3-N reduction
in the subbasins under various meteorological conditions (dry,
average and wet). Variable sizes of contour strips (10%, 20%, 30%
and 50%, respectively, of a subbasin area) planted with perennial
switchgrass were selected for simulating the effects of strip size and
location on stream water quality. Simulation results showed that a
filter strip having 10%-50% of the subbasin area could lead to 55%-
90% NO3-N reduction in the subbasin during an average rainfall
year. Strips occupying 10-20% of the subbasin area were found to be
more efficient in reducing NO3-N when placed along the contour
than that when placed along the river. The results of this study can
assist in cost-benefit analysis and decision-making in best water
resources management practices for environmental protection.
Abstract: Modeling and simulation of fixed bed three-phase
catalytic reactors are considered for wet air catalytic oxidation of
phenol to perform a comparative numerical analysis between tricklebed
and packed-bubble column reactors. The modeling involves
material balances both for the catalyst particle as well as for different
fluid phases. Catalyst deactivation is also considered in a transient
reactor model to investigate the effects of various parameters
including reactor temperature on catalyst deactivation. The
simulation results indicated that packed-bubble columns were
slightly superior in performance than trickle beds. It was also found
that reaction temperature was the most effective parameter in catalyst
deactivation.
Abstract: In seismic survey, the information regarding the
velocity of compression wave (Vp) as well as shear wave (Vs) are
very useful especially during the seismic interpretation. Previous
studies showed that both Vp and Vs determined by above methods
are totally different with respect to each other but offered good
approximation. In this study, both Vp and Vs of consolidated granite
rock were studied by using ultrasonic testing method and seismic
refraction method. In ultrasonic testing, two different condition of
rock are used which is dry and wet. The differences between Vp and
Vs getting by using ultrasonic testing and seismic refraction were
investigated and studied. The effect of water content in granite rock
towards the value of Vp and Vs during ultrasonic testing are also
measured. Within this work, the tolerance of the differences between
the velocity of seismic wave getting from ultrasonic testing and the
velocity of seismic wave getting from seismic refraction are also
measured and investigated.