Abstract: Low Temperature Matrix Isolation - Electron
Paramagnetic Resonance (LTMI-EPR) Spectroscopy was utilized to
identify the species of iron oxide nanoparticles generated during the
oxidative pyrolysis of 1-methylnaphthalene (1-MN). The otherwise
gas-phase reactions of 1--MN were impacted by a polypropylenimine
tetra-hexacontaamine dendrimer complexed with iron (III) nitrate
nonahydrate diluted in air under atmospheric conditions. The EPR
fine structure of Fe (III)2O3 nanoparticles clusters, characterized by gfactors
of 2.00, 2.28, 3.76 and 4.37 were detected on a cold finger
maintained at 77 K after accumulation over a multitude of
experiments. Additionally, a high valence Fe (IV) paramagnetic
intermediate and superoxide anion-radicals, O2•- adsorbed on
nanoparticle surfaces in the form of Fe (IV) --- O2•- were detected
from the quenching area of Zone 1 in the gas-phase.
Abstract: To evaluate the vigor of wheat seeds and stress of
premature aging effects on germination percentage, root length and
shoot length of five wheat cultivars that include Vynak, Karkheh,
Chamran, Star and Kavir which underwent a period of zero, two,
three, four days in terms of premature aging with 41°C temperature
and 100% relative humidity. Seed germination percentage, root
length and shoot length in these conditions were measured. This
experiment was conducted as a factorial completely randomized
design with four replications in laboratory conditions. The results
showed that each of aging treatments used in this experiment can be
used to detect differences in vigor of wheat varieties. Wheat cultivars
illustrated significant differences in germination percentage, root
length and shoot length in terms of premature aging. The wheat
cultivars; Astar and Vynak had maximum germination percentage
and Karkheh, respectively Kavir and Chamran had lowest percentage
of seed germination. Reactions of root and shoot length of wheat
cultivars was also different. The results showed that the seeds with a
stronger vigor affected less in premature aging condition and the
difference between the percentage of seed germination under normal
conditions and stress was significant and the seeds with the weaker
vigor were more sensitive to the premature aging stress and the
premature aging had more severe negative impact on seed vigor.
Abstract: Biodiesel production from vegetable oil will produce
glycerol as by-product about 10% of the biodiesel production. The
amount of glycerol that was produced needed alternative way to
handling immediately so as to not become the waste that polluted
environment. One of the solutions was to process glycerol to
polyglycidyl nitrate (PGN). PGN is synthesized from glycerol by
three-step reactions i.e. nitration of glycerol, cyclization of 13-
dinitroglycerine and polymerization of glycosyl nitrate. Optimum
condition of nitration of glycerol with nitric acid has not been known.
Thermodynamic feasibility should be done before run experiments in
the laboratory. The aim of this study was to determine the parameters
those affect nitration of glycerol and nitric acid and chose the
operation condition. Many parameters were simulated to verify its
possibility to experiment under conditions which would get the
highest conversion of 1, 3-dinitroglycerine and which was the ideal
condition to get it. The parameters that need to be studied to obtain
the highest conversion of 1, 3-dinitroglycerine were mol ratio of
nitric acid/glycerol, reaction temperature, mol ratio of
glycerol/dichloromethane and pressure. The highest conversion was
obtained in the range of mol ratio of nitric acid /glycerol between 2/1
– 5/1, reaction temperature of 5-25oC and pressure of 1 atm. The
parameters that need to be studied further to obtain the highest
conversion of 1.3 DNG are mol ratio of nitric acid/glycerol and
reaction temperature.
Abstract: In this paper, we explore the macroeconomic effects
of the European Single Market on Austria by simulating the
McKibbin-Sachs Global Model. Global interdependences and the
impact of long-run effects on short-run adjustments are taken into
account. We study the sensitivity of the results with respect to
different assumptions concerning monetary and fiscal policies for the
countries and regions of the world economy. The consequences of
different assumptions about budgetary policies in Austria are also
investigated. The simulation results are contrasted with ex-post
evaluations of the actual impact of Austria’s membership in the
Single Market. As a result, it can be concluded that the Austrian
participation in the European Single Market entails considerable
long-run gains for the Austrian economy with nearly no adverse sideeffects
on any macroeconomic target variable.
Abstract: Acoustic properties of polymeric liquids are high
sensitive to free gas traces in the form of fine bubbles. Their presence
is typical for such liquids because of chemical reactions, small
wettability of solid boundaries, trapping of air in technological
operations, etc. Liquid temperature influences essentially its
rheological properties, which may have an impact on the bubble
pulsations and sound propagation in the system. The target of the
paper is modeling of the liquid temperature effect on single bubble
dynamics and sound dispersion and attenuation in polymeric solution
with spherical gas bubbles. The basic sources of attenuation (heat
exchange between gas in microbubbles and surrounding liquid,
rheological and acoustic losses) are taken into account. It is supposed
that in the studied temperature range the interface mass transfer has a
minor effect on bubble dynamics. The results of the study indicate
that temperature raise yields enhancement of bubble pulsations and
increase in sound attenuation in the near-resonance range and may
have a strong impact on sound dispersion in the liquid-bubble
mixture at frequencies close to the resonance frequency of bubbles.
Abstract: In recent research copper and manganese systems
were found to be the most active in CO and organic compounds
oxidation among the base catalysts. The mixed copper manganese
oxide has been widely studied in oxidation reactions because of their
higher activity at low temperatures in comparison with single oxide
catalysts. The results showed that the formation of spinel
CuxMn3−xO4 in the oxidized catalyst is responsible for the activity
even at room temperature. That is why the most of the investigations
are focused on the hopcalite catalyst (CuMn2O4) as the best coppermanganese
catalyst. Now it’s known that this is true only for CO
oxidation, but not for mixture of CO and VOCs. The purpose of this
study is to investigate the alumina supported copper-manganese
catalysts with different Cu/Mn molar ratio in terms of oxidation of
CO, methanol and dimethyl ether. The catalysts were prepared by impregnation of γ-Al2O3 with
copper and manganese nitrates and the catalytic activity
measurements were carried out in two stage continuous flow
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions closest possible to the industrial. Gas
mixtures on the input and output of the reactor were analyzed with a
gas chromatograph, equipped with FID and TCD detectors. The
texture characteristics were determined by low-temperature (- 196oС)
nitrogen adsorption in a Quantachrome Instruments NOVA 1200e
(USA) specific surface area & pore analyzer. Thermal, XRD and
TPR analyses were performed. It was established that the active component of the mixed Cu-
Mn/γ–alumina catalysts strongly depends on the Cu/Mn molar ratio.
Highly active alumina supported Cu-Mn catalysts for CO, methanol
and DME oxidation were synthesized. While the hopcalite is the best
catalyst for CO oxidation, the best compromise for simultaneous
oxidation of all components is the catalyst with Cu/Mn molar ratio
1:5.
Abstract: HZSM-5 zeolites modified by iron and phosphorus
were applied in catalytic cracking of butene. N2 adsorption and
NH3-TPD were employed to measure the structure and acidity of
catalysts. The results indicate that increasing phosphorus loading
decreased surface area, pore volume and strong acidity of catalysts.
The addition of phosphorus significantly decreased butene conversion
and promoted propylene selectivity. The catalytic performance of
catalyst was strongly dependent on the reaction conditions.
Appropriate reaction conditions could suppress side reactions and
enhance propylene selectivity.
Abstract: The notion of power and gender domination is one of
the inseparable aspects of themes in postmodern literature. The
reason of its importance has been discussed frequently since the rise
of Michel Foucault and his insight into the circulation of power and
the transgression of forces. Language and society operate as the basic
grounds for the study, as all human beings are bound to the set of
rules and norms which shape them in the acceptable way in the
macrocosm. How different genders in different positions behave and
show reactions to the provocation of social forces and superiority of
one another is of great interest to writers and literary critics. Mamet’s
works are noticeable for their controversial but timely themes which
illustrate human conflicts with the society and greed for power. Many
critics like Christopher Bigsby and Harold Bloom have discussed
Mamet and his ideas in recent years. This paper is the study of
Oleanna, Mamet’s masterpiece about the teacher-student relationship
and the circulation of power between a man and woman. He shows
the very breakable boundaries in the domination of a gender and the
downfall of speech as the consequence of transgression and freedom.
The failure of the language the teacher uses and the abuse of his own
words by a student who seeks superiority and knowledge are the
main subjects of the discussion. Supported by the ideas of Foucault,
the language Mamet uses to present his characters becomes the
fundamental premise in this study. As a result, language becomes
both the means of achievement and downfall.
Abstract: Auditory hallucinations among the most invalidating
and distressing experiences reported by patients diagnosed with
schizophrenia, leading to feelings of powerlessness and helplessness
towards their illness. In more severe cases, these auditory
hallucinations can take the form of commanding voices, which are
often related to high suicidality rates in these patients. Several
authors propose that the meanings attributed to the hallucinatory
experience, rather than characteristics like form and content, can be
determinant in patients’ reactions to hallucinatory activity,
particularly in the case of voice-hearing experiences. In this study, 48
patients diagnosed with paranoid schizophrenia presenting auditory
hallucinations were studied. Multiple regression analyses were
computed to study the influence of several developmental aspects,
such as family and social dynamics, bullying, depression, and sociocognitive
variables on the auditory hallucinations, on patients’
attributions and relationships with their voices, and on the resulting
invalidation of hallucinatory experience. Overall, results showed how
relationships with voices can mirror several aspects of interpersonal
relationship with others, and how self-schemas, depression and actual
social relationships help shaping the voice-hearing experience. Early
experiences of victimization and submission help predict the
attributions of omnipotence of the voices, and increased hostility
from parents seems to increase the malevolence of the voices,
suggesting that socio-cognitive factors can significantly contribute to
the etiology and maintenance of auditory hallucinations. The
understanding of the characteristics of auditory hallucinations and the
relationships patients established with their voices can allow the
development of more promising therapeutic interventions that can be
more effective in decreasing invalidation caused by this devastating
mental illness.
Abstract: The aim of the current study was to develop and
validate a Response to Stressful Situations Scale (RSSS) for the
Portuguese population. This scale assesses the degree of stress
experienced in scenarios that can constitute positive, negative and
more neutral stressors, and also describes the physiological,
emotional and behavioral reactions to those events according to their
intensity. These scenarios include typical stressor scenarios relevant
to patients with schizophrenia, which are currently absent from most
scales, assessing specific risks that these stressors may bring on
subjects, which may prove useful in non-clinical and clinical
populations (i.e. Patients with mood or anxiety disorders,
schizophrenia). Results from Principal Components Analysis and
Confirmatory Factor Analysis of two adult samples from general
population allowed to confirm a three-factor model with good fit
indices: χ2 (144)= 370.211, p = 0.000; GFI = 0.928; CFI = 0.927; TLI =
0.914, RMSEA = 0.055, P(rmsea ≤0.005) = .096; PCFI = .781.
Further data analysis of the scale revealed that RSSS is an adequate
assessment tool of stress response in adults to be used in further
research and clinical settings, with good psychometric characteristics,
adequate divergent and convergent validity, good temporal stability
and high internal consistency.
Abstract: Microscopic simulation tool kits allow for
consideration of the two processes of railway operations and the
previous timetable production. Block occupation conflicts on both
process levels are often solved by using defined train priorities. These
conflict resolutions (dispatching decisions) generate reactionary
delays to the involved trains. The sum of reactionary delays is
commonly used to evaluate the quality of railway operations, which
describes the timetable robustness. It is either compared to an
acceptable train performance or the delays are appraised
economically by linear monetary functions. It is impossible to
adequately evaluate dispatching decisions without a well-founded
objective function. This paper presents a new approach for the
evaluation of dispatching decisions. The approach uses mode choice
models and considers the behaviour of the end-customers. These
models evaluate the reactionary delays in more detail and consider
other competing modes of transport. The new approach pursues the
coupling of a microscopic model of railway operations with the
macroscopic choice mode model. At first, it will be implemented for
railway operations process but it can also be used for timetable
production. The evaluation considers the possibility for the customer
to interchange to other transport modes. The new approach starts to
look at rail and road, but it can also be extended to air travel. The
result of mode choice models is the modal split. The reactions by the
end-customers have an impact on the revenue of the train operating
companies. Different purposes of travel have different payment
reserves and tolerances towards late running. Aside from changes to
revenues, longer journey times can also generate additional costs.
The costs are either time- or track-specific and arise from required
changes to rolling stock or train crew cycles. Only the variable values
are summarised in the contribution margin, which is the base for the
monetary evaluation of delays. The contribution margin is calculated
for different possible solutions to the same conflict. The conflict
resolution is optimised until the monetary loss becomes minimal. The
iterative process therefore determines an optimum conflict resolution
by monitoring the change to the contribution margin. Furthermore, a
monetary value of each dispatching decision can also be derived.
Abstract: OPEN_EmoRec_II is an open multimodal corpus with
experimentally induced emotions. In the first half of the experiment,
emotions were induced with standardized picture material and in the
second half during a human-computer interaction (HCI), realized
with a wizard-of-oz design. The induced emotions are based on the
dimensional theory of emotions (valence, arousal and dominance).
These emotional sequences - recorded with multimodal data (facial
reactions, speech, audio and physiological reactions) during a
naturalistic-like HCI-environment one can improve classification
methods on a multimodal level.
This database is the result of an HCI-experiment, for which 30
subjects in total agreed to a publication of their data including the
video material for research purposes*. The now available open
corpus contains sensory signal of: video, audio, physiology (SCL,
respiration, BVP, EMG Corrugator supercilii, EMG Zygomaticus
Major) and facial reactions annotations.
Abstract: OPEN_EmoRec_II is an open multimodal corpus with
experimentally induced emotions. In the first half of the experiment,
emotions were induced with standardized picture material and in the
second half during a human-computer interaction (HCI), realized
with a wizard-of-oz design. The induced emotions are based on the
dimensional theory of emotions (valence, arousal and dominance).
These emotional sequences - recorded with multimodal data (facial
reactions, speech, audio and physiological reactions) during a
naturalistic-like HCI-environment one can improve classification
methods on a multimodal level.
This database is the result of an HCI-experiment, for which 30
subjects in total agreed to a publication of their data including the
video material for research purposes*. The now available open
corpus contains sensory signal of: video, audio, physiology (SCL,
respiration, BVP, EMG Corrugator supercilii, EMG Zygomaticus
Major) and facial reactions annotations.
Abstract: The advent of social networking technologies has been
met with mixed reactions in academic and corporate circles around
the world. This study explored the influence of social network in
current era, the relation being maintained between the Social
networking site and its user by the extent of use, benefits and latest
technologies. The study followed a descriptive research design
wherein a questionnaire was used as the main research tool. The data
collected was analyzed using SPSS 16. Data was gathered from 1205
users and analyzed in accordance with the objectives of the study.
The analysis of the results seem to suggest that the majority of users
were mainly using Facebook, despite of concerns raised about the
disclosure of personal information on social network sites, users
continue to disclose huge quantity of personal information, they find
that reading privacy policy is time consuming and changes made can
result into improper settings.
Abstract: Hydrothermal liquefaction (HTL) is a technique for obtaining clean biofuel from biomass in the presence of heat and pressure in an aqueous medium which leads to a decomposition of this biomass to the formation of various products. A role of operating conditions is essential for the bio-oil and other products’ yield and also quality of the products. The effects of these parameters were investigated in regards to the composition and yield of the products. Chlorellaceae microalgae were tested under different HTL conditions to clarify suitable conditions for extracting bio-oil together with value-added co-products. Firstly, different microalgae loading rates (5-30%) were tested and found that this parameter has not much significant to product yield. Therefore, 10% microalgae loading rate was selected as a proper economical solution for conditioned schedule at 250oC and 30 min-reaction time. Next, a range of temperature (210-290oC) was applied to verify the effects of each parameter by keeping the reaction time constant at 30 min. The results showed no linkage with the increase of the reaction temperature and some reactions occurred that lead to different product yields. Moreover, some nutrients found in the aqueous product are possible to be utilized for nutrient recovery.
Abstract: This article focuses on the issue of airport emergency
plans, which are documents describing reactions to events with
impact on aviation safety or aviation security. The article specifically
focuses on the use and creation of emergency plans, where could be
found a number of disagreements between different stakeholders, for
which the airport emergency plan applies. Those are the friction
surfaces of interfaces, which is necessary to identify and ensure them
smooth process to avoid dangerous situations or delay.
Abstract: Electroencephalogram (EEG) is a noninvasive
technique that registers signals originating from the firing of neurons
in the brain. The Emotiv EEG Neuroheadset is a consumer product
comprised of 14 EEG channels and was used to record the reactions
of the neurons within the brain to two forms of stimuli in 10
participants. These stimuli consisted of auditory and visual formats
that provided directions of ‘right’ or ‘left.’ Participants were
instructed to raise their right or left arm in accordance with the
instruction given. A scenario in OpenViBE was generated to both
stimulate the participants while recording their data. In OpenViBE,
the Graz Motor BCI Stimulator algorithm was configured to govern
the duration and number of visual stimuli. Utilizing EEGLAB under
the cross platform MATLAB®, the electrodes most stimulated during
the study were defined. Data outputs from EEGLAB were analyzed
using IBM SPSS Statistics® Version 20. This aided in determining
the electrodes to use in the development of a brain-machine interface
(BMI) using real-time EEG signals from the Emotiv EEG
Neuroheadset. Signal processing and feature extraction were
accomplished via the Simulink® signal processing toolbox. An
Arduino™ Duemilanove microcontroller was used to link the Emotiv
EEG Neuroheadset and the right and left Mecha TE™ Hands.
Abstract: Carbon Deposits are often occurred inside the
industrial coke oven during coking process. Accumulation of carbon
deposits may cause a big issue, which seriously influences the coking
operation. The carbon is burning off by injecting fresh air through
pipes into coke oven which is an efficient way practically operated in
industries. The burning off carbon deposition in coke oven performed
by Computational Fluid Dynamics (CFD) method has provided an
evaluation of the feasibility study. A three dimensional, transient,
turbulent reacting flow simulation has performed with three different
injecting air flow rate and another kind of injecting configuration. The
result shows that injection higher air flow rate would effectively
reduce the carbon deposits. In the meantime, the opened charging
holes would suck extra oxygen from atmosphere to participate in
reactions. In term of coke oven operating limits, the wall temperatures
are monitored to prevent over-heating of the adiabatic walls during
burn-off process.
Abstract: Epidermal Growth Factor (EGF, Mw=6,045) has been
reported to have high efficiency of wound repair and anti-wrinkle
effect. However, the half-life of EGF in the body is too short to exert
the biological activity effectively when applied in free form. Growth
Factors can be stabilized by immobilization with carbohydrates from
thermal and proteolytic degradation. Low molecular weight chitosan
(LMCS) and its derivate prepared by hydrogen peroxide has high
solubility. LM6A6DC was successfully prepared as a reactive
carbohydrate for the stabilization of EGF by the reactions of LMCS
with alkalization, tosylation, azidation and reduction. The structure of
LM6A6DC was confirmed by FT-IR, 1H NMR and elementary
analysis. For enhancing the stability of free EGF, EGF was attached
with LM6A6DC by using water-soluble carbodiimide.
EGF-LM6A6DC conjugates did not show any cytotoxicity on the
Normal Human Dermal Fibroblast (NHDF) 3T3 proliferation at least
under 100 μg/ml. In the result, it was considered that LM6A6DC is
suitable to immobilize of growth factor.
Abstract: Chitosan has been an attractive biopolymer for
decades, but its processability is lowered by its poor solubility,
especially in physiological pH values. Freeze concentrated reactions
of chitosan with several organic acids including acrylic, citraconic,
itaconic, and maleic acid revealed improved solubility and
morphological properties. Solubility traits were assessed with a
modified ninhydrin test. Chitosan derivatives were characterized by
ATR-FTIR and morphological characteristics were determined by
SEM. This study is a unique approach to chemically modify chitosan
to enhance water solubility.