Butene Catalytic Cracking to Propylene over Iron and Phosphorus Modified HZSM-5
HZSM-5 zeolites modified by iron and phosphorus
were applied in catalytic cracking of butene. N2 adsorption and
NH3-TPD were employed to measure the structure and acidity of
catalysts. The results indicate that increasing phosphorus loading
decreased surface area, pore volume and strong acidity of catalysts.
The addition of phosphorus significantly decreased butene conversion
and promoted propylene selectivity. The catalytic performance of
catalyst was strongly dependent on the reaction conditions.
Appropriate reaction conditions could suppress side reactions and
enhance propylene selectivity.
[1] A. Corma, F. Melo, L. Sauvanaud, F. Ortega, "Light cracked naphtha
processing: Controlling chemistry for maximum propylene production,"
Catal. Today, Vol. 107, no. pp. 699-706, 2005.
[2] Z. Wang, G. Jiang, Z. Zhao, X. Feng, A. Duan, J. Liu, C. Xu, J. Gao,
"Highly Efficient P-Modified HZSM-5 Catalyst for the Coupling
Transformation of Methanol and 1-Butene to Propene," Energy Fuels,
Vol. 24, no. 2, pp. 758-763, 2010.
[3] N. Rahimi, R. Karimzadeh, "Catalytic cracking of hydrocarbons over
modified ZSM-5 zeolites to produce light olefins: A review," Appl. Catal.
A, Vol. 398, no. 1, pp. 1-17, 2011.
[4] T.A. Nijhuis, S.J. Tinnemans, T. Visser, B.M. Weckhuysen, "Towards
real-time spectroscopic process control for the dehydrogenation of
propane over supported chromium oxide catalysts," Chem. Eng. Sci., Vol.
59, no. 22, pp. 5487-5492, 2004.
[5] G. Zhao, J. Teng, Z. Xie, W. Jin, W. Yang, Q. Chen, Y. Tang, "Effect of
phosphorus on HZSM-5 catalyst for C4-olefin cracking reactions to
produce propylene," J. Catal., Vol. 248, no. 1, pp. 29-37, 2007.
[6] Y.V. Kissin, "Chemical mechanisms of catalytic cracking over solid
acidic catalysts: Alkanes and alkenes," Catal. Rev. Sci. Eng., Vol. 43, no.
1-2, pp. 85-146, 2001.
[7] T. Blasco, A. Corma, J. Martínez-Triguero, "Hydrothermal stabilization
of ZSM-5 catalytic-cracking additives by phosphorus addition," J. Catal.,
Vol. 237, no. 2, pp. 267-277, 2006.
[8] N. Xue, X. Chen, L. Nie, X. Guo, W. Ding, Y. Chen, M. Gu, Z. Xie,
"Understanding the enhancement of catalytic performance for olefin
cracking: Hydrothermally stable acids in P/HZSM-5," J. Catal., Vol. 248,
no. 1, pp. 20-28, 2007.
[9] J. Lu, Z. Zhao, C. Xu, P. Zhang, A. Duan, "FeHZSM-5 molecular
sieves-Highly active catalysts for catalytic cracking of isobutane to
produce ethylene and propylene," Catal. Commun., Vol. 7, no. 4, pp.
199-203, 2006.
[10] K. Ramesh, C. Jie, Y.-F. Han, A. Borgna, "Synthesis, characterization,
and catalytic activity of phosphorus modified H-ZSM-5 catalysts in
selective ethanol dehydration," Ind. Eng. Chem. Res., Vol. 49, no. 9, pp.
4080-4090, 2010.
[11] G. Jiang, L. Zhang, Z. Zhao, X. Zhou, A. Duan, C. Xu, J. Gao, "Highly
effective P-modified HZSM-5 catalyst for the cracking of C4 alkanes to
produce light olefins," Appl. Catal. A, Vol. 340, no. 2, pp. 176-182, 2008.
[12] Y.-J. Lee, J.M. Kim, J.W. Bae, C.-H. Shin, K.-W. Jun, "Phosphorus
induced hydrothermal stability and enhanced catalytic activity of ZSM-5
in methanol to DME conversion," Fuel, Vol. 88, no. 10, pp. 1915-1921,
2009.
[13] J. Caro, M. Bülow, M. Derewinski, J. Haber, M. Hunger, J. Kärger, H.
Pfeifer, W. Storek, B. Zibrowius, "NMR and IR studies of zeolite
H-ZSM-5 modified with orthophosphoric acid," J. Catal., Vol. 124, no. 2,
pp. 367-375, 1990.
[14] X. Zhu, S. Liu, Y. Song, L. Xu, "Catalytic cracking of C4 alkenes to
propene and ethene: Influences of zeolites pore structures and Si/Al2
ratios," Appl. Catal. A, Vol. 288, no. 1, pp. 134-142, 2005.
[15] L. Li, J. Gao, C. Xu, X. Meng, "Reaction behaviors and mechanisms of
catalytic pyrolysis of C4 hydrocarbons," Chem. Eng. J., Vol. 116, no. 3,
pp. 155-161, 2006.
[16] P. Sazama, J. Dědeček, V. Gabova, B. Wichterlova, G. Spoto, S. Bordiga,
"Effect of aluminium distribution in the framework of ZSM-5 on
hydrocarbon transformation. Cracking of 1-butene," J. Catal., Vol. 254,
no. 2, pp. 180-189, 2008.
[17] N. Xue, L. Nie, D. Fang, X. Guo, J. Shen, W. Ding, Y. Chen, "Synergistic
effects of tungsten and phosphorus on catalytic cracking of butene to propene over HZSM-5," Appl. Catal. A, Vol. 352, no. 1–2, pp. 87-94,
2009.
[18] X. Zhu, S. Liu, Y. Song, S. Xie, L. Xu, "Catalytic cracking of 1-butene to
propene and ethene on MCM-22 zeolite," Appl. Catal. A, Vol. 290, no. 1,
pp. 191-199, 2005.
[1] A. Corma, F. Melo, L. Sauvanaud, F. Ortega, "Light cracked naphtha
processing: Controlling chemistry for maximum propylene production,"
Catal. Today, Vol. 107, no. pp. 699-706, 2005.
[2] Z. Wang, G. Jiang, Z. Zhao, X. Feng, A. Duan, J. Liu, C. Xu, J. Gao,
"Highly Efficient P-Modified HZSM-5 Catalyst for the Coupling
Transformation of Methanol and 1-Butene to Propene," Energy Fuels,
Vol. 24, no. 2, pp. 758-763, 2010.
[3] N. Rahimi, R. Karimzadeh, "Catalytic cracking of hydrocarbons over
modified ZSM-5 zeolites to produce light olefins: A review," Appl. Catal.
A, Vol. 398, no. 1, pp. 1-17, 2011.
[4] T.A. Nijhuis, S.J. Tinnemans, T. Visser, B.M. Weckhuysen, "Towards
real-time spectroscopic process control for the dehydrogenation of
propane over supported chromium oxide catalysts," Chem. Eng. Sci., Vol.
59, no. 22, pp. 5487-5492, 2004.
[5] G. Zhao, J. Teng, Z. Xie, W. Jin, W. Yang, Q. Chen, Y. Tang, "Effect of
phosphorus on HZSM-5 catalyst for C4-olefin cracking reactions to
produce propylene," J. Catal., Vol. 248, no. 1, pp. 29-37, 2007.
[6] Y.V. Kissin, "Chemical mechanisms of catalytic cracking over solid
acidic catalysts: Alkanes and alkenes," Catal. Rev. Sci. Eng., Vol. 43, no.
1-2, pp. 85-146, 2001.
[7] T. Blasco, A. Corma, J. Martínez-Triguero, "Hydrothermal stabilization
of ZSM-5 catalytic-cracking additives by phosphorus addition," J. Catal.,
Vol. 237, no. 2, pp. 267-277, 2006.
[8] N. Xue, X. Chen, L. Nie, X. Guo, W. Ding, Y. Chen, M. Gu, Z. Xie,
"Understanding the enhancement of catalytic performance for olefin
cracking: Hydrothermally stable acids in P/HZSM-5," J. Catal., Vol. 248,
no. 1, pp. 20-28, 2007.
[9] J. Lu, Z. Zhao, C. Xu, P. Zhang, A. Duan, "FeHZSM-5 molecular
sieves-Highly active catalysts for catalytic cracking of isobutane to
produce ethylene and propylene," Catal. Commun., Vol. 7, no. 4, pp.
199-203, 2006.
[10] K. Ramesh, C. Jie, Y.-F. Han, A. Borgna, "Synthesis, characterization,
and catalytic activity of phosphorus modified H-ZSM-5 catalysts in
selective ethanol dehydration," Ind. Eng. Chem. Res., Vol. 49, no. 9, pp.
4080-4090, 2010.
[11] G. Jiang, L. Zhang, Z. Zhao, X. Zhou, A. Duan, C. Xu, J. Gao, "Highly
effective P-modified HZSM-5 catalyst for the cracking of C4 alkanes to
produce light olefins," Appl. Catal. A, Vol. 340, no. 2, pp. 176-182, 2008.
[12] Y.-J. Lee, J.M. Kim, J.W. Bae, C.-H. Shin, K.-W. Jun, "Phosphorus
induced hydrothermal stability and enhanced catalytic activity of ZSM-5
in methanol to DME conversion," Fuel, Vol. 88, no. 10, pp. 1915-1921,
2009.
[13] J. Caro, M. Bülow, M. Derewinski, J. Haber, M. Hunger, J. Kärger, H.
Pfeifer, W. Storek, B. Zibrowius, "NMR and IR studies of zeolite
H-ZSM-5 modified with orthophosphoric acid," J. Catal., Vol. 124, no. 2,
pp. 367-375, 1990.
[14] X. Zhu, S. Liu, Y. Song, L. Xu, "Catalytic cracking of C4 alkenes to
propene and ethene: Influences of zeolites pore structures and Si/Al2
ratios," Appl. Catal. A, Vol. 288, no. 1, pp. 134-142, 2005.
[15] L. Li, J. Gao, C. Xu, X. Meng, "Reaction behaviors and mechanisms of
catalytic pyrolysis of C4 hydrocarbons," Chem. Eng. J., Vol. 116, no. 3,
pp. 155-161, 2006.
[16] P. Sazama, J. Dědeček, V. Gabova, B. Wichterlova, G. Spoto, S. Bordiga,
"Effect of aluminium distribution in the framework of ZSM-5 on
hydrocarbon transformation. Cracking of 1-butene," J. Catal., Vol. 254,
no. 2, pp. 180-189, 2008.
[17] N. Xue, L. Nie, D. Fang, X. Guo, J. Shen, W. Ding, Y. Chen, "Synergistic
effects of tungsten and phosphorus on catalytic cracking of butene to propene over HZSM-5," Appl. Catal. A, Vol. 352, no. 1–2, pp. 87-94,
2009.
[18] X. Zhu, S. Liu, Y. Song, S. Xie, L. Xu, "Catalytic cracking of 1-butene to
propene and ethene on MCM-22 zeolite," Appl. Catal. A, Vol. 290, no. 1,
pp. 191-199, 2005.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:70388", author = "Jianwen Li and Hongfang Ma and Haitao Zhang and Qiwen Sun and Weiyong Ying", title = "Butene Catalytic Cracking to Propylene over Iron and Phosphorus Modified HZSM-5", abstract = "HZSM-5 zeolites modified by iron and phosphorus
were applied in catalytic cracking of butene. N2 adsorption and
NH3-TPD were employed to measure the structure and acidity of
catalysts. The results indicate that increasing phosphorus loading
decreased surface area, pore volume and strong acidity of catalysts.
The addition of phosphorus significantly decreased butene conversion
and promoted propylene selectivity. The catalytic performance of
catalyst was strongly dependent on the reaction conditions.
Appropriate reaction conditions could suppress side reactions and
enhance propylene selectivity.", keywords = "Butene catalytic cracking, HZSM-5, modification,
reaction conditions.", volume = "9", number = "5", pages = "636-5", }
