Abstract: All around the world pulp and paper industries are the
biggest plant production with the environmental pollution as the
biggest challenge facing the pulp manufacturing operations. The
concern among these industries is to produce a high volume of papers
with the high quality standard and of low cost without affecting the
environment. This result obtained from this bleaching study show
that the activation of peroxide was an effective method of reducing
the total applied charge of chlorine dioxide which is harmful to our
environment and also show that softwood and hardwood Kraft pulps
responded linearly to the peroxide treatments. During the bleaching
process the production plant produce chlorines. Under the trial stages
chloride dioxide has been reduced by 3 kg/ton to reduce the
brightness from 65% ISO to 60% ISO of pulp and the dosing point
returned to the E stage charges by pre-treating Kraft pulps with
hydrogen peroxide. The pulp and paper industry has developed
elemental chlorine free (ECF) and totally chlorine free (TCF)
bleaching, in their quest for being environmental friendly, they have
been looking at ways to turn their ECF process into a TCF process
while still being competitive. This prompted the research to
investigate the capability of the hydrogen peroxide as catalyst to
reduce chloride dioxide.
Abstract: Mining tailings represent a generating source of rich heavy metal material with a potential danger the public health and the environment, since these metals, under certain conditions, can leach and contaminate aqueous systems that serve like supplying potable water sources. The strategy for this work is based on the observation, experimentation and the simulation that can be obtained by binding real answers of the hydrodynamic behavior of metals leached from mining tailings, and the applied mathematics that provides the logical structure to decipher the individual effects of the general physicochemical phenomenon. The case of study presented herein focuses on mining tailings deposits located in Monte San Nicolas, Guanajuato, Mexico, an abandoned mine. This was considered the contamination source that under certain physicochemical conditions can favor the metal leaching, and its transport towards aqueous systems. In addition, the cartography, meteorology, geology and the hydrodynamics and hydrological characteristics of the place, will be helpful in determining the way and the time in which these systems can interact. Preliminary results demonstrated that arsenic presents a great mobility, since this one was identified in several superficial aqueous systems of the micro watershed, as well as in sediments in concentrations that exceed the established maximum limits in the official norms. Also variations in pH and potential oxide-reduction were registered, conditions that favor the presence of different species from this element its solubility and therefore its mobility.
Abstract: The storage of chemical fertilizers in concrete building often leads to durability problems due to chemical attack. The damage of concrete is mostly caused by certain ammonium salts. The main purpose of the research is to investigate the durability properties of concrete being exposed to ammonium nitrate solution. In this investigation, experiments are conducted on concrete type G50 and G60. The leaching process is achieved by the use of 20% concentration solution of ammonium nitrate. The durability properties investigated are water absorption, volume of permeable voids, and sorptivity. Compressive strength, pH value, and degradation depth are measured after a certain period of leaching. A decrease in compressive strength and an increase in porosity are found through the conducted experiments. Apart from that, the experimental data shows that pH value decreases with increased leaching time while the degradation depth of concrete increases with leaching time. By comparing concrete type G50 and G60, concrete type G60 is more resistant to ammonium nitrate attack.
Abstract: The recovery of metal values and safe disposal of
spent catalyst is gaining interest due to both its hazardous nature and
increased regulation associated with disposal methods. Prior to the
recovery of the valuable metals, removal of entrained deposits limit
the diffusion of lixiviate resulting in low recovery of metals must be
taken into consideration. Therefore, petroleum refinery spent catalyst
was subjected to acetone washing and roasting at 500oC. The treated
samples were investigated for metals bioleaching using
Acidithiobacillus ferrooxidans in batch reactors and the leaching
efficiencies were compared. It was found out that acetone washed
spent catalysts results in better metal recovery compare to roasted
spent. About 83% Ni, 20% Al, 50% Mo and 73% V were leached
using the acetone washed spent catalyst. In both the cases, Ni, V and
Mo was high compared to Al.
Abstract: Stormwater wetlands have been mainly designed in an
empirical approach for water quality improvement, with little
quantitative understanding of the internal microbial processes. This
study investigated into heterotrophic bacterial production rate,
heterotrophic bacterial mineralization percentage, and algal biomass
in hypertrophic and eutrophic surface flow stormwater wetlands.
Compared to a nearby wood leachate treatment wetland, the
stormwater wetlands had much higher chlorophyll-a concentrations.
The eutrophic stormwater wetland had improved water quality,
whereas the hypertrophic stormwater wetland had degraded water
quality. Heterotrophic bacterial activities in water were limited in the
stormwater wetlands due to competition of algal growth for nutrients.
The relative contribution of biofilms to the overall heterotrophic
activities was higher in the stormwater wetlands than that in the wood
leachate treatment wetland.
Abstract: This paper reviews recent studies and particularly the
effects of Climate Change in the North Tropical Atlantic by studying
atmospheric conditions that prevailed in 2005 ; Coral Bleaching
HotSpot and Hurricane Katrina. In the aim to better understand and
estimate the impact of the physical phenomenon, i.e. Thermal
Oceanic HotSpot (TOHS), isotopic studies of δ18O and δ13C on
marine animals from Guadeloupe (French Caribbean Island) were
carried out. Recorded measures show Sea Surface Temperature (SST)
up to 35°C in August which is much higher than data recorded by
NOAA satellites 32°C. After having reviewed the process that led to
the creation of Hurricane Katrina which hit New Orleans in August
29, 2005, it will be shown that the climatic conditions in the
Caribbean from August to October 2005 have influenced Katrina
evolution. This TOHS is a combined effect of various phenomenon
which represent an additional factor to estimate future climate
changes.
Abstract: Low silica type X (LSX) Zeolite is one of useful
material in many manufacturing due to the advantage properties
including high surface area, stability, microporous crystalline
aluminosilicates and positive ion in an extra–framework. The LSX
was used rice husk silica source which obtained by leaching with
hydrochloric acid and calcination at 500 C. To improve the
synthesis method, the LSX was crystallizated in Teflon–lined
autoclave will expedite deceasing of the amorphous particles. The
mixed gel with composition of 5.5 Na2O : 1.65 K2O : Al2O3 : 2.2
SiO2 : 122 H2O was crystallized in different container
(Polypropylene bottom and Teflon–lined autoclave). The obtained
powder was characterized by X–ray diffraction (XRD), X–ray
fluorescence spectrometry, N2 adsorption-desorption analysis BET
surface area Scanning electron microscopy (SEM) and Fourier
transform infrared spectroscopy to justify the quality of zeolite. The
results showed the crystallized zeolite in Teflon lined autoclave has
102.8 nm of crystal size, 286 m2/g of surface area and fewer amounts
of round amorphous particles when compared with the crystallized
zeolite in Polypropylene.
Abstract: This study aims at using multi-source data to monitor
coral biodiversity and coral bleaching. We used coral reef at Racha
Islands, Phuket as a study area. There were three sources of data:
coral diversity, sensor based data and satellite data.
Abstract: Land degradation is of concern in many countries. People more and more must address the problems associated with the degradation of soil properties due to man. Increasingly, organic soil amendments, such as compost are being examined for their potential use in soil restoration and for preventing soil erosion. In the Czech Republic, compost is the most used to improve soil structure and increase the content of soil organic matter. Land reclamation / restoration is one of the ways to evaluate industrially produced compost because Czech farmers are not willing to use compost as organic fertilizer. The most common use of reclamation substrates in the Czech Republic is for the rehabilitation of landfills and contaminated sites.
This paper deals with the influence of reclamation substrates (RS) with different proportions of compost and sand on selected soil properties–chemical characteristics, nitrogen bioavailability, leaching of mineral nitrogen, respiration activity and plant biomass production. Chemical properties vary proportionally with addition of compost and sand to the control variant (topsoil). The highest differences between the variants were recorded in leaching of mineral nitrogen (varies from 1.36mg dm-3 in C to 9.09mg dm-3). Addition of compost to soil improves conditions for plant growth in comparison with soil alone. However, too high addition of compost may have adverse effects on plant growth. In addition, high proportion of compost increases leaching of mineral N. Therefore, mixture of 70% of soil with 10% of compost and 20% of sand may be recommended as optimal composition of RS.
Abstract: Column leach test has been performed to examine the
behavior of leaching of sodium, calcium and potassium in landfills.
In the column leach apparatus, two different layers of contaminated
and uncontaminated soils of different height ratios (ratio of depth of
contaminated soil to the depth of uncontaminated soil) are taken.
Water is poured from an overhead tank at a particular flowrate to the
inlet of the soil column for a certain ponding depth over the
contaminated soil. Subsequent infiltration causes leaching and the
leachates are collected from the bottom of the column. The
concentrations of Na, Ca and K in the leachate are measured using
flame photometry. The experiments are further extended by changing
the rates of flow from the overhead tank to the inlet of the column in
achieving the same ponding depth. The experiments are performed
for different scenarios in which the height ratios are altered and the
variations of concentrations of Na, Ca, and K are observed. The study
brings an estimation of leaching in landfill sites for different heights
and precipitation intensity where a ponding depth is maintained over
the landfill. It has been observed that the leaching behavior of Na,
Ca, and K are not similar. Calcium exhibits highest amount of
leaching compared to Sodium and Potassium under similar
experimental conditions.
Abstract: This research was conducted in the Lower Namkam
Irrigation Project situated in the Namkam River Basin in Thailand.
Degradation of groundwater quality in some areas is caused by saline
soil spots beneath ground surface. However, the tail regulated gate
structure on the Namkam River, a lateral stream of the Mekong
River. It is aimed for maintaining water level in the river at +137.5 to
+138.5 m (MSL) and flow to the irrigation canals based on a gravity
system since July 2009. It might leach some saline soil spots from
underground to soil surface if lack of understanding of the
conjunctive surface water and groundwater behaviors. This research
has been conducted by continuously the observing of both shallow
and deep groundwater level and quality from existing observation
wells. The simulation of surface water was carried out using a
hydrologic modeling system (HEC-HMS) to compute the ungauged
side flow catchments as the lateral flows for the river system model
(HEC-RAS). The constant water levels in the upstream of the
operated gate caused a slight rising up of shallow groundwater level
when compared to the water table. However, the groundwater levels
in the confined aquifers remained less impacted than in the shallow
aquifers but groundwater levels in late of wet season in some wells
were higher than the phreatic surface. This causes salinization of the
groundwater at the soil surface and might affect some crops. This
research aims for the balance of water stage in the river and efficient
groundwater utilization in this area.
Abstract: Sampling and analysis of leachate from Bhalaswa
landfill and groundwater samples from nearby locations, clearly
indicated the likely contamination of groundwater due to landfill
leachate. The results of simulation studies carried out for the
migration of Chloride from landfill shows that the simulation results
are in consonance with the observed concentration of Chloride in the
vicinity of landfill facility. The solid waste disposal system presently
being practiced in Delhi consists of mere dumping of wastes
generated, at three locations Bhalaswa, Ghazipur, and Okhla without
any regard to proper care for the protection of surrounding
environment. Bhalaswa landfill site in Delhi, which is being operated
as a dump site, is expected to become cause of serious groundwater
pollution in its vicinity. The leachate from Bhalaswa landfill was
found to be having a high concentration of chlorides, as well as DOC,
COD. The present study was undertaken to determine the likely
concentrations of principle contaminants in the groundwater over a
period of time due to the discharge of such contaminants from
landfill leachates to the underlying groundwater. The observed
concentration of chlorides in the groundwater within 75m of the
radius of landfill facility was found to be in consonance with the
simulated concentration of chloride in groundwater considering one
dimensional transport model, with finite mass of contaminant source.
Governing equation of contaminant transport involving advection and
diffusion-dispersion was solved in matlab7.0 using finite difference
method.
Abstract: Renewable water resources are crucial production
variables in arid and semi-arid regions where intensive agriculture is
practiced to meet ever-increasing demand for food and fiber. This is
crucial for the Dez and Moghan command areas where water delivery
problems and adverse environmental issues are widespread. This
paper aims to identify major problems areas using on-farm surveys of
200 farmers, agricultural extensionists and water suppliers which was
complemented by secondary data and field observations during 2010-
2011 cultivating season. The SPSS package was used to analyze and
synthesis data. Results indicated inappropriate canal operations in
both schemes, though there was no unanimity about the underlying
causes. Inequitable and inflexible distribution was found to be rooted
in deficient hydraulic structures particularly in the main and
secondary canals. The inadequacy and inflexibility of water
scheduling regime was the underlying causes of recurring pest and
disease spread which often led to the decline of crop yield and
quality, although these were not disputed, the water suppliers were
not prepared to link with the deficiencies in the operation of the main
and secondary canals. They rather attributed these to the prevailing
salinity; alkalinity, water table fluctuations and leaching of the
valuable agro-chemical inputs from the plants- route zone with farreaching
consequences. Examples of these include the pollution of
ground and surface resources due to over-irrigation at the farm level
which falls under the growers- own responsibility. Poor irrigation
efficiency and adverse environmental problems were attributed to
deficient and outdated farming practices that were in turn rooted in
poor extension programs and irrational water charges.
Abstract: Several different cements have been tested to evaluate
their potential to leach calcium, chromium and aluminum ions in soft
water environment. The research allows comparing some different
cements in order to the potential risk of water contamination. This
can be done only in the same environment. To reach the results in
reasonable short time intervals and to make heavy metals
measurements with high accuracy, demineralized water was used. In
this case the conditions of experiments are far away from the water
supply practice, but short time experiments and measurably high
concentrations of elements in the water solution are an important
advantage. Moreover leaching mechanisms can be recognized, our
experiments reported here refer to this kind of cements evaluation.
Abstract: Using steelmaking slag as a raw material, aragonite superstructure product had been synthesized via an indirect CO2 mineral sequestration rout. It mainly involved two separate steps, in which the element of calcium is first selectively leached from steelmaking slag by a novel leaching media consisting of organic solvent Tributyl phosphate (TBP), acetic acid, and ultra-purity water, followed by enhanced carbonation in a separate step for aragonite superstructure production as well as efficiency recovery of leaching media. Based on the different leaching medium employed in the steelmaking slag leaching process, two typical products were collected from the enhanced carbonation step. The products were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM), respectively. It reveals that the needle-like aragonite crystals self-organized into aragonite superstructure particles including aragonite microspheres as well as dumbbell-like spherical particles, can be obtained from the steelmaking slag with the purity over 99%.
Abstract: Moisture is an important consideration in many
aspects ranging from irrigation, soil chemistry, golf course, corrosion
and erosion, road conditions, weather predictions, livestock feed
moisture levels, water seepage etc. Vegetation and crops always
depend more on the moisture available at the root level than on
precipitation occurrence. In this paper, design of an instrument is
discussed which tells about the variation in the moisture contents of
soil. This is done by measuring the amount of water content in soil by
finding the variation in capacitance of soil with the help of a
capacitive sensor. The greatest advantage of soil moisture sensor is
reduced water consumption. The sensor is also be used to set lower
and upper threshold to maintain optimum soil moisture saturation and
minimize water wilting, contributes to deeper plant root growth
,reduced soil run off /leaching and less favorable condition for insects
and fungal diseases. Capacitance method is preferred because, it
provides absolute amount of water content and also measures water
content at any depth.
Abstract: As wireless sensor networks are energy constraint networks
so energy efficiency of sensor nodes is the main design issue.
Clustering of nodes is an energy efficient approach. It prolongs the
lifetime of wireless sensor networks by avoiding long distance communication.
Clustering algorithms operate in rounds. Performance of
clustering algorithm depends upon the round time. A large round
time consumes more energy of cluster heads while a small round
time causes frequent re-clustering. So existing clustering algorithms
apply a trade off to round time and calculate it from the initial
parameters of networks. But it is not appropriate to use initial
parameters based round time value throughout the network lifetime
because wireless sensor networks are dynamic in nature (nodes can be
added to the network or some nodes go out of energy). In this paper
a variable round time approach is proposed that calculates round
time depending upon the number of active nodes remaining in the
field. The proposed approach makes the clustering algorithm adaptive
to network dynamics. For simulation the approach is implemented
with LEACH in NS-2 and the results show that there is 6% increase
in network lifetime, 7% increase in 50% node death time and 5%
improvement over the data units gathered at the base station.
Abstract: In the area where the high quality water is not
available, unconventional water sources are used to irrigate.
Household leachate is one of the sources which are used in dry and
semi dry areas in order to water the barer trees and plants. It meets
the plants needs and also has some effects on the soil, but at the same
time it might cause some problems as well. This study in order to
evaluate the effect of using Compost leachate on the density of soil
iron in form of a statistical pattern called ''Split Plot'' by using two
main treatments, one subsidiary treatment and three repetitions of the
pattern in a three month period. The main N treatments include:
irrigation using well water as a blank treatments and the main I
treatments include: irrigation using leachate and well water
concurrently. Some subsidiary treatments were DI (Drop Irrigation)
and SDI (Sub Drop Irrigation). Then in the established plots, 36
biannual pine and cypress shrubs were randomly grown. Two months
later the treatment begins. The results revealed that there was a
significant variation between the main treatment and the instance
regarding pH decline in the soil which was related to the amount of
leachate injected into the soil. After some time and using leachate the
pH level fell, as much as 0.46 and also increased due to the great
amounts of leachate. The underneath drop irrigation ends in better
results than sub drop irrigation since it keeps the soil texture fixed.
Abstract: Decomposition processes take place in landfill
generate leachates that can be categorized mainly of acetogenic and
methanogenic in nature. BOD:COD ratio computed in this study for a
landfill site over a 3 years duration revealed as a good indicator to
identify acetogenic leachate from methanogenic leachate. Correlation
relationships to predict pollutant level taking into consideration of
climatic condition are derived.
Abstract: In this study, the ability of Aspergillus niger and
Penicillium simplicissimum to extract heavy metals from a spent
refinery catalyst was investigated. For the first step, a spent
processing catalyst from one of the oil refineries in Iran was
physically and chemically characterized. Aspergillus niger and
Penicillium simplicissimum were used to mobilize Al/Co/Mo/Ni from
hazardous spent catalysts. The fungi were adapted to the mixture of
metals at 100-800 mg L-1 with increments in concentration of 100 mg
L-1. Bioleaching experiments were carried out in batch cultures. To
investigate the production of organic acids in sucrose medium,
analyses of the culture medium by HPLC were performed at specific
time intervals after inoculation. The results obtained from Inductive
coupled plasma-optical emission spectrometry (ICP-OES) showed
that after the one-step bioleaching process using Aspergillus niger,
maximum removal efficiencies of 27%, 66%, 62% and 38% were
achieved for Al, Co, Mo and Ni, respectively. However, the highest
removal efficiencies using Penicillium simplicissimum were of 32%,
67%, 65% and 38% for Al, Co, Mo and Ni, respectively