Abstract: The present investigation was undertaken to explore the biogas potentiality of Jatropha (Jatropha curcas, Euphorbiaceae) Fruit Coat (JFC) alone and in combination with cattle dung (CD) in various proportions at 15 per cent total solids by batch phase anaerobic digestion for a period of ten weeks HRT (Hydraulic Retention Time) under a temperature of 35°C+1°C. The maximum biogas production was noticed in Cattle dung and Jatropha Fruit Coat in 2:1 ratio with 403.84 L/kg dry matter followed by 3:1,1:2, 1:1 and 1:3 having 329.66, 219.77, 217.79, 203.64 L /kg dm respectively as compared to 178.49 L/kg dm in CD alone. The JFC alone found to produce 91 per cent of total biogas that obtained from Cattle dung. The per cent methane content of the biogas in all the treatments was found on par with Cattle dung.
Abstract: Cerium oxide is to be recovered from monazite,
which contains about 27.35% CeO2. The principal objective
of this study is to be able to extract cerium oxide from
monazite of Moemeik Myitsone Area. The treatment of
monazite in this study involves three main steps; extraction
of cerium hydroxide from monazite, solvent extraction of
cerium hydroxide, and precipitation with oxalic acid and
calcination of cerium oxalate.
Abstract: In this study, we illustrated the performance and
microbial community of single- and two-phase systems anaerobically
co-digesting cassava pulp and pig manure. The results showed that
the volatile solid reduction and biogas productivity of two-phase
CSTR were 66 ± 4% and 2000 ± 210 ml l-1 d-1, while those of singlephase
CSTR were 59 ± 1% and 1670 ± 60 ml l-1 d-1, respectively. Codigestion
in two-phase CSTR gave higher 12% solid degradation and
25% methane production than single-phase CSTR. Phylogenetic
analysis of 16S rDNA clone library revealed that the Bacteroidetes
were the most abundant group, followed by the Clostridia in singlephase
CSTR. In hydrolysis/acidification reactor of two-phase system,
the bacteria within the phylum Firmicutes, especially Clostridium,
Eubacteriaceae and Lactobacillus were the dominant phylogenetic
groups. Among the Archaea, Methanosaeta sp. was the exclusive
predominant in both digesters while the relative abundance of
Methanosaeta sp. and Methanospirillum hungatei differed between
the two systems.
Abstract: In this study, the kinetic of biogas production was studied by performing a series laboratory experiment using rumen fluid of animal ruminant as inoculums. Cattle manure as substrate was inoculated by rumen fluid to the anaerobic biodigester. Laboratory experiments using 400 ml biodigester were performed in batch operation mode. Given 100 grams of fresh cattle manure was fed to each biodigester and mixed with rumen fluid by manure : rumen weight ratio of 1:1 (MR11). The operating temperatures were varied at room temperature and 38.5 oC. The cumulative volume of biogas produced was used to measure the biodigester performance. The research showed that the rumen fluid inoculated to biodigester gave significant effect to biogas production (P
Abstract: In this research, an anaerobic co-digestion using decanter cake from palm oil mill industry to improve the biogas production from frozen seafood wastewater is studied using Continuously Stirred Tank Reactor (CSTR) process. The experiments were conducted in laboratory-scale. The suitable Hydraulic Retention Time (HRT) was observed in CSTR experiments with 24 hours of mixing time using the mechanical mixer. The HRT of CSTR process impacts on the efficiency of biogas production. The best performance for biogas production using CSTR process was the anaerobic codigestion for 20 days of HRT with the maximum methane production rate of 1.86 l/d and the average maximum methane production of 64.6%. The result can be concluded that the decanter cake can improve biogas productivity of frozen seafood wastewater.
Abstract: In this study, aerobic digestion of tannery industry
wastewater was carried out using mixed culture obtained from
common effluent treatment plant treating tannery wastewater. The
effect of pH, temperature, inoculum concentration, agitation speed
and initial substrate concentration on the reduction of organic matters
were found. The optimum conditions for COD reduction was found
to be pH - 7 (60%), temperature - 30ÔùªC (61%), inoculum
concentration - 2% (61%), agitation speed - 150rpm (65%) and initial
substrate concentration - 1560 mg COD/L (74%). Kinetics studies
were carried by using Monod model, First order, Diffusional model
and Singh model. From the results it was found that the Monod
model suits well for the degradation of tannery wastewater using
mixed microbial consortium.
Abstract: Anaerobic treatment has many advantages over other
biological method particularly when used to treat complex
wastewater such as petroleum refinery wastewater. In this study two
Up-flow Anaerobic Sludge Blanket (UASB) reactors were operated
in parallel to treat six volumetric organic loads (0.58, 1.21, 0.89,
2.34, 1.47 and 4.14 kg COD/m3·d) to evaluate the chemical oxygen
demand (COD) removal efficiency. The reactors were continuously
adapting to the changing of operation condition with increase in the
removal efficiency or slight decrease until the last load which was
more than two times the load, at which the reactor stressed and the
removal efficiency decreased to 75% with effluent concentration of
1746 mg COD/L. Other parameters were also monitored such as pH,
alkalinity, volatile fatty acid and gas production rate. The UASB
reactor was suitable to treat petroleum refinery wastewater and the
highest COD removal rate was 83% at 1215 kg/m3·d with COD
concentration about 356 mg/L in the effluent.
Abstract: Study was conducted to determine the concentration of
copper, cadmium, lead and zinc in Cabomba furcata that found
abundance in Lake Chini. This aquatic plant was collected randomly
within the lake for heavy metal determination. Water quality
measurement was undertaken in situ for temperature, pH,
conductivity and dissolved oksigen using portable multi sensor probe
YSI model 556. The C. furcata was digested using wet digestion
method and heavy metal concentrations were analysed using Atomic
Absorption Spectrometer (AAS) Perkin Elmer 4100B (flame
method). Result of water quality classify Lake Chini between class II
to class III using Malaysian Water Quality Standard. According to
this standard, Lake Chini has moderate quality, which normal for
natural lake. Heavy metal concentrations in C.furcata were low and
found to be lower than the critical toxic value in aquatic plants. Oneway
ANOVA test indicated the heavy metal concentrations in
C.furcata were significantly differ between sampling location. Water
quality and heavy metal concentrations indicates that Lake Chini was
not receives anthropogenic load from nearby activities.
Abstract: Measurement of the COD of a spent caustic solution involves firstly digestion of a test sample with dichromate solution and secondly measurement of dichromate remained by titration by ferrous ammonium sulfate [FAS] to an end point. In this paper we study by a potentiometric end point with Ag/AgCl reference electrode and gold rode electrode. The potentiometric end point is sharp and easily identified especially for the samples with high turbidity and color that other methods such as colorimetric in this type of sample do not result in high precision. Because interim of titration responds quickly to potential changes within the [Cr+6/Cr+3& Fe+2/Fe+3] solution producing stable readings that is lead to accurate COD measurement. Finally results are compared with data determined using colorimetric method for standard samples. It is shown that the potentiometric end point titration with gold rode electrode can be used with equal or better facility
Abstract: In this research the level of mercury is analyzed in
muscle tissue of Otolithes ruber retailed in Hamedan, Iran were
determined by flame atomic absorption spectrometry after wet
digestion. Analysis of mercury was carried out by
spectrophotometrically. The average concentration of Hg in muscle
tissue of Otolithes ruber was 0.030±0.026 -g/g so lower than to
compare with the Maximum Allowable Concentration determined by
FAO/WHO Codex Alimentarius Commission.
Abstract: “Garbage enzyme", a fermentation product of kitchen waste, water and brown sugar, is claimed in the media as a multipurpose solution for household and agricultural uses. This study assesses the effects of dilutions (5% to 75%) of garbage enzyme in reducing pollutants in domestic wastewater. The pH of the garbage enzyme was found to be 3.5, BOD concentration about 150 mg/L. Test results showed that the garbage enzyme raised the wastewater-s BOD in proportion to its dilution due to its high organic content. For mixtures with more than 10% garbage enzyme, its pH remained acidic after the 5-day digestion period. However, it seems that ammonia nitrogen and phosphorus could be removed by the addition of the garbage enzyme. The most economic solution for removal of ammonia nitrogen and phosphorus was found to be 9%. Further tests are required to understand the removal mechanisms of the ammonia nitrogen and phosphorus.
Abstract: In this paper, a Biochemical Methane Potential (BMP)
test provides a measure of the energy production potential from codigestion
between the frozen seafood wastewater and the decanter
cake. The experiments were conducted in laboratory-scale. The
suitable ratio of the frozen seafood wastewater and the decanter cake
was observed in the BMP test. The ratio of the co-digestion between
the frozen seafood wastewater and the decanter cake has impacts on
the biogas production and energy production potential. The best
performance for energy production potential using BMP test
observed from the 180 ml of the frozen seafood wastewater and 10 g
of the decanter cake ratio. This ratio provided the maximum methane
production at 0.351 l CH4/g TCODremoval. The removal efficiencies
are 76.18%, 83.55%, 43.16% and 56.76% at TCOD, SCOD, TS and
VS, respectively. The result can be concluded that the decanter cake
can improve the energy production potential of the frozen seafood
wastewater. The energy provides from co-digestion between frozen
seafood wastewater and decanter cake approximately 19x109
MJ/year in Thailand.
Abstract: A thirty Rahmani weaned male lambs of average body weight (27.28±1.40 kg) were randomly allotted to three similar groups, ten lambs in each, to study the benefit of commercial feed additives Tonilisat (Saccharomyces cerevisiae) and Roemin W2 (Lactobacillus acidophilus, Lactobacillus thermophilus, Bifidobacterium and Lactose) as growth promoters on lambs performance, digestibility, rumen activity and some blood constituents. The experiment lasted about 107 days. Three experimental groups were allotted as control group: received the basal ration, T1 group: received the basal ration supplemented with Tonilisat as (0.5kg/ ton concentrate feed mixture) and T2 group: received the basal ration supplemented with Roemin W2 (1kg/ ton concentrate feed mixture). Our study revealed that addition of Tonilisat significantly increased digestion coefficient of crude protein than that of the control group, Furthermore, the supplementation of Tonilisat or Roemin W2 increased (p
Abstract: One of the main challenges for one phase anaerobic digestion processes is the high concentration of NH4+ and PO4 3- ions
in the digested sludge supernatant. This project focuses on enhancing the removal of nutrients during the anaerobic digestion process through fixing both NH4+ and PO4 3- ions in the form of struvite (magnesium ammonium phosphate, MAP, MgNH4PO4.6H2O) within the anaerobic sludge. Batch anaerobic digestion tests showed that Mg2+ concentration in the range 279 – 812 mg/L had insignificant effect on CGP but incurred a slight increase in COD removal. The reactor that had soluble Mg2+:NH4+:PO43- at a molar ratio of 1.28:1:00:1:00 achieved the best performance enhancement of 8% increase in COD removal and 32% reduction in NH4+ in the reactor supernatant. Overall, the results show that there is a potential to optimise conventional anaerobic digestion such that supernatant lean in P and N, and sludge rich in nutrients are obtained.
Abstract: The quantitative determination of several trace
elements (Cr, As, Se, Cd, Hg, Pb) existing as inorganic impurities in
some oriental herb-products such as Lingzhi Mushroom capsules,
Philamin powder, etc using ICP-MS has been studied. Various
instrumental parameters such as power, gas flow rate, sample depth, as
well as the concentration of nitric acid and thick background due to
high concentration of possible interferences on the determination of
these above-mentioned elements was investigated and the optimum
working conditions of the sample measurement on ICP-MS
(Agilent-7500a) were reported. Appropriate isotope internal standards
were also used to improve the accuracy of mercury determination.
Optimal parameters for sampling digestion were also investigated. The
recovery of analytical procedure was examined by using a Certified
Reference Material (IAEA-CRM 359). The recommended procedure
was then applied for the quantitative determination of Cr, As, Se, Cd,
Hg, Pb in Lingzhi Mushroom capsule, and Philamine powder samples.
The reproducibility of sample measurement (average value between
94 and 102%) and the uncertainty of analytical data (less than 20%)
are acceptable.
Abstract: BioEnergy is an archetypal appropriate technology
and alternate source of energy in rural areas of China, and can meet
the basic need for cooking fuel in rural areas. The paper introduces
with an alternate mean of research that can accelerate the biogas
energy production. Tithonia diversifolia or the Tree marigold can be
hailed as mesophillic anaerobic digestion to increase the production
of more Bioenergy. Tithonia diversifolia is very native to Mexico and
Central America, which can be served as ornamental plants- green
manure and can prevent soil erosion. Tithonia diversifolia is widely
grown and known to Asia, Africa, America and Australia as well.
Nowadays, Considering China’s geographical condition it is found
that Tithonia diversifolia is widely growing plant in the many tropical
and subtropical regions of southern Yunnan- which can have great
usage in accelerating and increasing the Bioenergy production
technology. The paper discussed aiming at proving possibility that
Tithonia diversifolia can be applied in biogas fermentation and its
biogas production potential, the research carried experiment on
Tithonia diversifolia biogas fermentation under the mesophilic
condition (35 Celsius Degree). The result revealed that Tithonia
diversifolia can be used as biogas fermentative material, and 6%
concentration can get the best biogas production, with the TS biogas
production rate 656mL/g and VS biogas production rate 801mL/g. It
is well addressed that Tithonia diversifolia grows wildly in 53
Counties and 9 cities of Yunnan Province, which mainly grows in
form of the road side plants, the edge of the field, countryside, forest
edge, open space; of which demersum-natures can form dense
monospecific beds -causing serious harm to agricultural production
landforms threatening the ecological system as a potentially harmful
exotic plant. There are also found the three types of invasive daisy
alien plants -Eupatorium adenophorum, Eupatorium Odorata and
Tithonia diversifolia in Yunnan Province of China-among them the
Tithonia diversifolia is responsible for causing serious harm to
agricultural production. In this paper we have designed the
experimental explanation of Biogas energy production that requires
anaerobic environment and some microbes; Tithonia diversifolia
plant has been taken into consideration while carrying experiments
and with successful resulting of generating more BioEnergy
emphasizing on the practical applications of Tithonia diversifolia.
This paper aims at- to find a new mechanism to provide a more
scientific basis for the development of this plant herbicides in Biogas
energy and to improve the utilization throughout the world as well.
Abstract: The aim of this study was to investigate the
effectiveness of anaerobic digestion for the treatment of wool
scouring wastes. The experiments design comprised three ratios of
waste (W) to seed(S) (W:S) of 25:75, 50:50 and 75:25, corresponding
to 1.9. 1.7 and 1.5g tCOD/g TS, respectively, with or without
chemicals addition. NH4Cl was added to the reactors as a source for
nitrogen to achieve C:N:P of 420:14:3. A cationic flocculent was
added at 0.5 and 0.75% to enhance flocculation of sludge. The results
showed that the reactors that received W:S at a ratio of 25:75
produced the largest volume of biogas. The final soluble COD
(sCOD) was below the limits for discharge to the sewer system.
Abstract: Carbon nanotubes (CNTs) possess unique structural,
mechanical, thermal and electronic properties, and have been
proposed to be used for applications in many fields. However, to
reach the full potential of the CNTs, many problems still need to be
solved, including the development of an easy and effective
purification procedure, since synthesized CNTs contain impurities,
such as amorphous carbon, carbon nanoparticles and metal particles.
Different purification methods yield different CNT characteristics
and may be suitable for the production of different types of CNTs. In
this study, the effect of different purification chemicals on carbon
nanotube quality was investigated. CNTs were firstly synthesized by
chemical vapor deposition (CVD) of acetylene (C2H2) on a
magnesium oxide (MgO) powder impregnated with an iron nitrate
(Fe(NO3)3·9H2O) solution. The synthesis parameters were selected
as: the synthesis temperature of 800°C, the iron content in the
precursor of 5% and the synthesis time of 30 min. The liquid phase
oxidation method was applied for the purification of the synthesized
CNT materials. Three different acid chemicals (HNO3, H2SO4, and
HCl) were used in the removal of the metal catalysts from the
synthesized CNT material to investigate the possible effects of each
acid solution to the purification step. Purification experiments were
carried out at two different temperatures (75 and 120 °C), two
different acid concentrations (3 and 6 M) and for three different time
intervals (6, 8 and 15 h). A 30% H2O2 : 3M HCl (1:1 v%) solution
was also used in the purification step to remove both the metal
catalysts and the amorphous carbon. The purifications using this
solution were performed at the temperature of 75°C for 8 hours.
Purification efficiencies at different conditions were evaluated by
thermogravimetric analysis. Thermal and electrical properties of
CNTs were also determined. It was found that the obtained electrical
conductivity values for the carbon nanotubes were typical for organic
semiconductor materials and thermal stabilities were changed
depending on the purification chemicals.
Abstract: The enthusiasm for gluten avoidance in a growing
market is met by improvements in sensitive detection methods for
analysing gluten content. Paradoxically, manufacturers employ no
such systems in the production process but continue to market their
product as gluten free, a significant risk posed to an undetermined
coeliac population. This paper resonates with an immunological
response that causes gastrointestinal scarring and villous atrophy with
the conventional description of personal injury. This thesis divulges
into evaluating potential inadequacies of gluten labelling laws which
not only present a diagnostic challenge for general practitioners in the
UK but it also exposes a less than adequate form of available legal
protection to those who suffer adverse reactions as a result of gluten
digestion. Central to this discussion is whether a claim brought in
misrepresentation, negligence and/or under the Consumer Protection
Act 1987 could be sustained. An interesting comparison is then made
with the legal regimes of neighboring jurisdictions furthering the
theme of a legally un-catered for gluten kingdom.
Abstract: Anaerobic Digestion has become a promising
technology for biological transformation of organic fraction of the
municipal solid wastes (MSW). In order to represent the kinetic
behavior of such biological process and thereby to design a reactor
system, development of a mathematical model is essential.
Addressing this issue, a simplistic mathematical model has been
developed for anaerobic digestion of MSW in a continuous flow
reactor unit under homogeneous steady state condition. Upon
simulated hydrolysis, the kinetics of biomass growth and substrate
utilization rate are assumed to follow first order reaction kinetics.
Simulation of this model has been conducted by studying sensitivity
of various process variables. The model was simulated using typical
kinetic data of anaerobic digestion MSW and typical MSW
characteristics of Kolkata. The hydraulic retention time (HRT) and
solid retention time (SRT) time were mainly estimated by varying
different model parameters like efficiency of reactor, influent
substrate concentration and biomass concentration. Consequently,
design table and charts have also been prepared for ready use in the
actual plant operation.