Abstract: Different vegetable oil based biodiesel (FAMES) were prepared by alkaline transesterification using refined oils as well as waste frying oil (WFO). Methanol and sodium hydroxide are used as catalyst under similar reaction conditions. To ensure the quality of biodiesel produced, a series of different ASTM Standard tests were carried out. In this context, various testwere done including viscosity, carbon residue, specific gravity, corrosion test, flash point, cloud point and pour point. Results revealed that characteristics of biodiesel depend on the feedstock and it is far better than petroleum diesel.
Abstract: Hydrogen diffusion is the main problem for corrosion fatigue in corrosive environment. In order to analyze the phenomenon, it is needed to understand their behaviors specially the hydrogen behavior during the diffusion. So, Hydrogen embrittlement and prediction its behavior as a main corrosive part of the fractions, needed to solve combinations of different equations mathematically. The main point to obtain the equation, having knowledge about the source of causing diffusion and running the atoms into materials, called driving force. This is produced by either gradient of electrical or chemical potential. In this work, we consider the gradient of chemical potential to obtain the property equation. In diffusion of atoms, some of them may be trapped but, it could be ignorable in some conditions. According to the phenomenon of hydrogen embrittlement, the thermodynamic and chemical properties of hydrogen are considered to justify and relate them to fracture mechanics. It is very important to get a stress intensity factor by using fugacity as a property of hydrogen or other gases. Although, the diffusive behavior and embrittlement event are common and the same for other gases but, for making it more clear, we describe it for hydrogen. This considering on the definite gas and describing it helps us to understand better the importance of this relation.
Abstract: The objective of this project is to study the corrosion
behaviour and hardness based on the presence of martensite in dual
phase steel. This study was conducted on six samples of dual phase
steel which have different percentage of martensite. A total of 9
specimens were prepared by intercritical annealing process to study
the effect of temperature to the formation of martensite. The low
carbon steels specimens were heated for 25 minutes in a specified
temperature ranging from 7250C to 8250C followed by rapid cooling
in water. The measurement of corrosion rate was done by using
extrapolation tafel method, while potentiostat was used to control and
measured the current produced. This measurement is performed
through a system named CMS105. The result shows that a specimen
with higher percentage of martensite is likely to corrode faster.
Hardness test for each specimen was conducted to compare its
hardness with low carbon steel. The results obtained indicate that the
specimen hardness is proportional to the amount of martensite in dual
phase steel.
Abstract: Magnesium wastes are produced by many industrial activities. This waste problem is becoming a future problem for the world. Magnesium borates have many advantages such as; high corrosion resistance, heat resistance, high coefficient of elasticity and can also be used in the production of material against radiation. Addition, magnesium borates have great potential in sectors
including ceramic and detergents industry and superconducting materials.
In this study, using the starting materials of waste magnesium and H3BO3 the hydrothermal method was applied at a moderate
temperature of 70oC. Several mole ratios of waste magnesium to H3BO3 are selected as; 1:2, 1:4, 1:6, 1:8, 1:10. Reaction time was determined as 1 hour. After the synthesis, X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR) techniques are applied to products. As a result the forms of mcallisterite “Mg2(B6O7(OH)6)2.9(H2O)”, admontite “MgO(B2O3)3.7(H2O)” and magnesium boron hydrate (MgO(B2O3)3.6(H2O)” are obtained.
Abstract: Calcium magnesium acetate (CMA) is environmentally
benign deicing chemicals that can replace sodium chloride that is
widely used on roads and highways at present for snow and ice control
to provide safe driving conditions during winter. The price of CMA
from petroleum-derived acetic acid is quite expensive. The bamboo
vinegar is the by-product from bamboo charcoal production. The
bamboo vinegar was used to prepare calcium acetate as raw materials,
and its deicing and corrosive performances were studied in this paper.
The results show that the freezing temperature of calcium acetate is
lower than that of sodium chloride when they have same molar
concentration, the deicing performance of calcium acetate is better
than that of sodium chloride when they have same moles, while the
deicing performance of sodium chloride is better than that of calcium
acetate. The corrosion of sodium chloride on iron-nail and steel-nail is
larger than that of calcium acetate whether they have same mass
concentration or same molar concentration, and the corrosion of
sodium chloride and calcium acetate on iron-nail is larger than that on
steel-nail, and calcium acetate almost hasn't corrosion on steel-nail.
Abstract: This paper proposes a Fuzzy Expert System design to
determine the wearing properties of nitrided and non nitrided steel.
The proposed Fuzzy Expert System approach helps the user and the
manufacturer to forecast the wearing properties of nitrided and non
nitrided steel under specified laboratory conditions. Surfaces of the
engineering components are often nitrided for improving wear,
corosion, fatigue specifications. A major property of nitriding
process is reducing distortion and wearing of the metalic alloys. A
Fuzzy Expert System was developed for determining the wearing and
durability properties of nitrided and non nitrided steels that were
tested under different loads and different sliding speeds in the
laboratory conditions.
Abstract: Polymer-like organic thin films were deposited on both
aluminum alloy type 6061 and glass substrates at room temperature by
Plasma Enhanced Chemical Vapor Deposition (PECVD) methodusing
benzene and hexamethyldisiloxane (HMDSO) as precursor materials.
The surface and physical properties of plasma-polymerized organic
thin films were investigated at different r.f. powers. The effects of
benzene/argon ratio on the properties of plasma polymerized benzene
films were also investigated. It is found that using benzene alone
results in a non-coherent and non-adherent powdery deposited
material. The chemical structure and surface properties of the asgrown
plasma polymerized thin films were analyzed on glass
substrates with FTIR and contact angle measurements. FTIR spectra
of benzene deposited film indicated that the benzene rings are
preserved when increasing benzene ratio and/or decreasing r.f.
powers. FTIR spectra of HMDSO deposited films indicated an
increase of the hydrogen concentration and a decrease of the oxygen
concentration with the increase of r.f. power. The contact angle (θ) of
the films prepared from benzene was found to increase by about 43%
as benzene ratio increases from 10% to 20%. θ was then found to
decrease to the original value (51°) when the benzene ratio increases
to 100%. The contact angle, θ, for both benzene and HMDSO
deposited films were found to increase with r.f. power. This signifies
that the plasma polymerized organic films have substantially low
surface energy as the r.f power increases. The corrosion resistance of
aluminum alloy substrate both bare and covered with plasma
polymerized thin films was carried out by potentiodynamic
polarization measurements in standard 3.5 wt. % NaCl solution at
room temperature. The results indicate that the benzene and HMDSO
deposited films are suitable for protection of the aluminum substrate
against corrosion. The changes in the processing parameters seem to
have a strong influence on the film protective ability. Surface
roughness of films deposited on aluminum alloy substrate was
investigated using scanning electron microscopy (SEM). The SEM
images indicate that the surface roughness of benzene deposited films
increase with decreasing the benzene ratio. SEM images of benzene
and HMDSO deposited films indicate that the surface roughness
decreases with increasing r.f. power. Studying the above parameters
indicate that the films produced are suitable for specific practical
applications.
Abstract: Chloride induced corrosion of steel reinforcement is
the main cause of deterioration of reinforced concrete marine
structures. This paper investigates the relative performance of
alternative repair options with respect to the deterioration of
reinforced concrete bridge elements in marine environments. Focus is
placed on the initiation phase of reinforcement corrosion. A
laboratory study is described which involved exposing concrete
samples to accelerated chloride-ion ingress. The study examined the
relative efficiencies of two repair methods, namely Ordinary Portland
Cement (OPC) concrete and a concrete which utilised Ground
Granulated Blastfurnace Cement (GGBS) as a partial cement
replacement. The mix designs and materials utilised were identical to
those implemented in the repair of a marine bridge on the South East
coast of Ireland in 2007. The results of this testing regime serve to
inform input variables employed in probabilistic modelling of
deterioration for subsequent reliability based analysis to compare the
relative performance of the studied repair options.
Abstract: Waste problem is becoming a future problem all over the world. Magnesium wastes which can be used in recycling processes are produced by many industrial activities. Magnesium borates which have useful properties such as; high heat resistance, corrosion resistance, supermechanical strength, superinsulation, light weight, high coefficient of elasticity and so on. Addition, magnesium borates have great potential in the development of ceramic and detergents industry, whisker-reinforced composites, antiwear, and reducing friction additives.
In this study, using the starting materials of waste magnesium and H3BO3 the hydrothermal method was applied at a moderate temperature of 70oC with different reaction times. Several reaction times of waste magnesium to H3BO3 were selected as; 30, 60, 120, 240 minutes. After the synthesis, X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR) techniques were applied to products. As a result, the forms of Admontite [MgO(B2O3)3.7(H2O)] and Mcallisterite [Mg2(B6O7(OH)6)2.9(H2O)] were synthesized.
Abstract: For collecting data from all sensor nodes, some
changes in Dynamic Source Routing (DSR) protocol is proposed. At
each hop level, route-ranking technique is used for distributing
packets to different selected routes dynamically. For calculating rank
of a route, different parameters like: delay, residual energy and
probability of packet loss are used. A hybrid topology of
DMPR(Disjoint Multi Path Routing) and MMPR(Meshed Multi Path
Routing) is formed, where braided topology is used in different
faulty zones of network. For reducing energy consumption, variant
transmission ranges is used instead of fixed transmission range. For
reducing number of packet drop, a fuzzy logic inference scheme is
used to insert different types of delays dynamically. A rule based
system infers membership function strength which is used to
calculate the final delay amount to be inserted into each of the node
at different clusters.
In braided path, a proposed 'Dual Line ACK Link'scheme is
proposed for sending ACK signal from a damaged node or link to a
parent node to ensure that any error in link or any node-failure
message may not be lost anyway. This paper tries to design the
theoretical aspects of a model which may be applied for collecting
data from any large hanging iron structure with the help of wireless
sensor network. But analyzing these data is the subject of material
science and civil structural construction technology, that part is out
of scope of this paper.
Abstract: The demand of hydrocarbons has increased the
construction of pipelines and the protection of the physical and
mechanical integrity of the already existing infrastructure. Corrosion
is the main reason of failures in the pipeline and it is mostly produced
by acid (HCOOCH3). In this basis, a CFD code was used, in order to
study the corrosion of internal wall of hydrocarbons pipeline. In this
situation, the corrosion phenomenon shows a growing deposit, which
causes defect damages (welding or fabrication) at diverse positions
along the pipeline. The solution of the pipeline corrosion is based on
the diminution of the Naphthenic acid.
Abstract: Titanium oxide films with different morphologies have for the first time been fabricated through hydrothermal reactions between a titanium substrate and iodine powder in water or ethanol. SEM revealed that iodine supported titanium (Ti-I2) surface shows different morphologies with variable treatment conditions. The mean surface roughness (Ra) was increased in the different groups. Use of surfactant has a role to increase the roughness of the film. The surface roughness was in the range of 0.15 μm-0.42 μm. Furthermore, the electrochemical examinations showed that the Ti-I2 surface fabricated in alcoholic medium has high corrosion resistance than in aqueous medium.
Abstract: Electrolytic dissolution characteristics of UO2 and
SIMFUEL electrodes were studied at several potentials in carbonate
solutions of a high concentration at several pHs. The electrolytic
uranium dissolution was much affected by a corrosion product of
UO2CO3 generated at the electrode during the dissolution in carbonate
solution. The corrosion product distorted the voltammogram at UO2
and SIMFUEL electrodes in the potential region of oxygen evolution
and increased the overpotential of oxygen evolution at the electrode.
The effective dissolution in a carbonate solution could be obtained at
an applied potential such as +4 V (vs SSE) or more which had an
overpotential of oxygen evolution high enough to rupture the
corrosion product on the electrode surface.
Abstract: The aim of this paper is to compare the effectiveness and electrochemical behavior of typical oilfield corrosion inhibitors with previous oilfield corrosion inhibitors under the same electrochemical techniques to control preferential weld corrosion of X65 pipeline steel in artificial seawater saturated with carbon dioxide at a pressure of one bar. A secondary aim is to investigate the conditions under which current reversal takes place. A flow channel apparatus was used in the laboratory to simulate the actual condition that occurs in marine pipelines. Different samples from the parent metal, the weld metal and the heat affected zone in the pipeline steel were galvanically coupled. The galvanic currents flowing between the weld regions were recorded using zero-resistance ammeters and tested under static and flowing conditions in both inhibited and uninhibited media. The results show that a current reversal took place when 30ppm of both green oilfield inhibitors were present, resulting in accelerated weld corrosion.
Abstract: Anodizing is an electrochemical process that converts the metal surface into a decorative, durable, corrosion-resistant, anodic oxide finish. Aluminum is ideally suited to anodizing, although other nonferrous metals, such as magnesium and titanium, also can be anodized. The anodic oxide structure originates from the aluminum substrate and is composed entirely of aluminum oxide. This aluminum oxide is not applied to the surface like paint or plating, but is fully integrated with the underlying aluminum substrate, so cannot chip or peel. It has a highly ordered, porous structure that allows for secondary processes such as coloring and sealing. In this experimental paper, we focus on a reliable method for fabricating nanoporous alumina with high regularity. Starting from study of nanostructure materials synthesize methods. After that, porous alumina fabricate in the laboratory by anodization of aluminum oxide. Hard anodization processes are employed to fabricate the nanoporous alumina using 0.3M oxalic acid and 90, 120 and 140 anodized voltages. The nanoporous templates were characterized by SEM and FFT. The nanoporous templates using 140 voltages have high ordered. The pore formation, influence of the experimental conditions on the pore formation, the structural characteristics of the pore and the oxide chemical reactions involved in the pore growth are discuss.
Abstract: This paper presents the results of corrosion fatigue
crack growth behaviour of a Ni-Cr-Mn steel commonly used in
marine applications. The effect of mechanical variables such as
frequency and load ratio on fatigue crack growth rate at various
stages has been studied using compact tension (C(T)) specimens
along the rolling direction of steel plate under 3.5% saturated NaCl
aqueous environment. The significance of crack closure on corrosion
fatigue, and the validity of Elber-s empirical linear crack closure
model with the ASTM compliance offset method have been
examined.
Fatigue crack growth rate is higher and threshold stress intensities
are lower in aqueous environment compared to the lab air conditions.
It is also observed that the crack growth rate increases at lower
frequencies. The higher stress ratio promotes the crack growth. The
effect of oxidization and corrosion pit formation is very less as the
stress ratio is increased. It is observed that as stress ratios are
increased, the Elber-s crack closure model agrees well with the crack
closure estimated by the ASTM compliance offset method for tests
conducted at 5Hz frequency compared to tests conducted at 1Hz in
corrosive environment.
Abstract: The current study has investigated the ageing
phenomena of silica optical fibres in relation to water activity which might be accelerated when exposed to a supplementary energy, such as microwaves. A controlled stress by winding fibres onto accurate
diameter mandrel was applied. Taking into account that normally a
decrease in fibre strength is induced in time by chemical action of water, the effects of cumulative reagents such as: water, applied stress and supplementary energy (microwave) in some cases acted in
the opposite manner. The microwave effect as a structural relaxation
catalyst appears unexpected, even if the overall gain in fibre strength is not high, but the stress corrosion factor revealed significant
increase in certain simulation conditions.
Abstract: Low carbon deep drawing steel DC 01 according to EN 10130-91 was nitrooxidized in dissociated ammonia at 580°C/45 min and consequently oxidised at 380°C/5 min in vapour of distilled water. Material after nitrooxidation had 54 % increase of yield point, 34 % increase of strength and 10-times increased resistance to atmospheric corrosion in comparison to the material before nitrooxidation. The microstructure of treated material consisted of thin ε-phase layer connected to layer containing precipitated massive needle shaped Fe4N - γ' nitrides. This layer passed to a diffusion layer consisting of fine irregular shaped Fe16N2 - α'' nitrides regularly dispersed in ferritic matrix. Fatigue properties were examined under bending load with frequency of 20 kHz and sinusoidal symmetric cycle. The results confirmed positive influence of nitrooxidation on fatigue properties as fatigue limit of treated material was double in comparison to untreated material.
Abstract: Greenhouse gases (GHG) emissions impose major
threat to global warming potential (GWP). Unfortunately
manufacturing sector is one of the major sources that contribute
towards the rapid increase in greenhouse gases (GHG) emissions. In
manufacturing sector electric power consumption is the major driver
that influences CO2 emission. Titanium alloys are widely utilized in
aerospace, automotive and petrochemical sectors because of their
high strength to weight ratio and corrosion resistance. Titanium
alloys are termed as difficult to cut materials because of their poor
machinability rating. The present study analyzes energy consumption
during cutting with reference to material removal rate (MRR).
Surface roughness was also measured in order to optimize energy
consumption.
Abstract: The localized corrosion behavior of laser surface
melted 304L austenitic stainless steel was studied by
potentiodynamic polarization test. The extent of improvement in
corrosion resistance was governed by the preferred orientation and
the percentage of delta ferrite present on the surface of the laser
melted sample. It was established by orientation imaging microscopy
that the highest pitting potential value was obtained when grains were
oriented in the most close- packed [101] direction compared to the
random distribution of the base metal and other laser surface melted
samples oriented in [001] direction. The sample with lower
percentage of ferrite had good pitting resistance.