Abstract: In the present work, Electrochemical Impedance
Spectrocopy (EIS) is applied to study the transport of different metal
cations through a cation-exchange membrane. This technique enables
the identification of the ionic-transport characteristics and to
distinguish between different transport mechanisms occurring at
different current density ranges. The impedance spectra are
dependent on the applied dc current density, on the type of cation and
on the concentration.
When the applied dc current density increases, the diameter of the
impedance spectra loops increases because all the components of
membrane system resistance increase. The diameter of the impedance
plots decreases in the order of Na(I), Ni(II) and Cr(III) due to the
increased interactions between the negatively charged sulfonic
groups of the membrane and the cations with greater charge. Nyquist
plots are shifted towards lower values of the real impedance, and its
diameter decreases with the increase of concentration due to the
decrease of the solution resistance.
Abstract: One of the crucial parameters of digital cryptographic
systems is the selection of the keys used and their distribution. The
randomness of the keys has a strong impact on the system’s security
strength being difficult to be predicted, guessed, reproduced, or
discovered by a cryptanalyst. Therefore, adequate key randomness
generation is still sought for the benefit of stronger cryptosystems.
This paper suggests an algorithm designed to generate and test
pseudo random number sequences intended for cryptographic
applications. This algorithm is based on mathematically manipulating
a publically agreed upon information between sender and receiver
over a public channel. This information is used as a seed for
performing some mathematical functions in order to generate a
sequence of pseudorandom numbers that will be used for
encryption/decryption purposes. This manipulation involves
permutations and substitutions that fulfill Shannon’s principle of
“confusion and diffusion”. ASCII code characters were utilized in the
generation process instead of using bit strings initially, which adds
more flexibility in testing different seed values. Finally, the obtained
results would indicate sound difficulty of guessing keys by attackers.
Abstract: The first part of the paper analyzes the dynamics of
the total fertility rate both at the national and regional level, pointing
out the regional disparities in the distribution of this indicator. At the
same time, we also focus on the collapse of the number of live births,
on the changes in the fertility rate by birth rank, as well as on the
failure of acquiring the desired number of children. The second part
of the study centres upon a survey applied to urban families with 3
and more than 3 offspring. The preliminary analysis highlights the
fact that an increased fertility (more than 3rd rank) is triggered by the
parents’ above the average material condition and superior education.
The current situation of Romania, which is still passing through a
period of relatively rapid demographic changes, marked by numerous
convulsions, requires a new approach, in compliance with the recent
interpretations appropriate to a new post-transitional demographic
regime.
Abstract: We proposed a Hyperbolic Gompertz Growth Model
(HGGM), which was developed by introducing a shape parameter
(allometric). This was achieved by convoluting hyperbolic sine
function on the intrinsic rate of growth in the classical gompertz
growth equation. The resulting integral solution obtained
deterministically was reprogrammed into a statistical model and used
in modeling the height and diameter of Pines (Pinus caribaea). Its
ability in model prediction was compared with the classical gompertz
growth model, an approach which mimicked the natural variability of
height/diameter increment with respect to age and therefore provides
a more realistic height/diameter predictions using goodness of fit
tests and model selection criteria. The Kolmogorov Smirnov test and
Shapiro-Wilk test was also used to test the compliance of the error
term to normality assumptions while the independence of the error
term was confirmed using the runs test. The mean function of top
height/Dbh over age using the two models under study predicted
closely the observed values of top height/Dbh in the hyperbolic
gompertz growth models better than the source model (classical
gompertz growth model) while the results of R2, Adj. R2, MSE and
AIC confirmed the predictive power of the Hyperbolic Gompertz
growth models over its source model.
Abstract: We report the microstructural and magnetic properties
of Ni50Mn39Sn11 and Ni50Mn36Sn14 ribbon Heusler alloys.
Experimental results were obtained by differential scanning
calorymetry, X-ray diffraction and vibrating sample magnetometry
techniques. The Ni-Mn-Sn system undergoes a martensitic structural
transformation in a wide temperature range. For example, for
Ni50Mn39Sn11 the start and finish temperatures of the martensitic and
austenite phase transformation for ribbon alloy were Ms=336K,
Mf=328K, As=335K and Af=343K whereas no structural
transformation is observed for Ni50Mn36Sn14 alloys. Magnetic
measurements show the typical ferromagnetic behavior with Curie
temperature 207 K at low applied field of 50 Oe. The complex
behavior exhibited by these Heusler alloys should be ascribed to the
strong coupling between magnetism and structure, being their
magnetic behavior determined by the distance between Mn atoms.
Abstract: The following paper presents the results of a study
aimed at achieving a better understanding of the psychological
readiness for mobile learning (m-learning) among Saudi students,
while also evaluating m-learning readiness as a whole in Saudi
Arabia - a topic that has not yet received adequate attention from
researchers. Data was acquired via a questionnaire administered to
131 Saudi students at UK universities, in July 2013. The study
confirmed that students are confident about using mobile devices in
their daily lives, and that they would welcome more opportunities for
mobile learning. The findings also indicated that Saudi higher
education students are very familiar with, and psychologically ready
for, m-learning.
Abstract: 600 schools going adolescents and 100 teachers from
16 schools of Dhemaji and Lakhimpur district of Assam, India were
surveyed to assess and compare their awareness regarding AIDS and
AIDS Education. An awareness test was administered containing 38
items for adolescents and 40 items for teachers in the test.
Observations revealed that the majority of school-going adolescents
are poor in their HIV/AIDS and AIDS education awareness. It shows
that the school going adolescents of Dhemaji district are better in
HIV/AIDS and AIDS education awareness than the school going
adolescents of Lakhimpur district while comparing the gender,
settlement, steam and district wise variables.
Abstract: In this study, ultrasonic assisted machining (UAM) technique is applied in side-surface milling experiment for glass-ceramic workpiece material. The tungsten carbide cutting-tool with diamond coating is used in conjunction with two kinds of cooling/lubrication mediums such as water-soluble (WS) cutting fluid and minimum quantity lubricant (MQL). Full factorial process parameter combinations on the milling experiments are planned to investigate the effect of process parameters on cutting performance. From the experimental results, it tries to search for the better process parameter combination which the edge-indentation and the surface roughness are acceptable. In the machining experiments, ultrasonic oscillator was used to excite a cutting-tool along the radial direction producing a very small amplitude of vibration frequency of 20KHz to assist the machining process. After processing, toolmaker microscope was used to detect the side-surface morphology, edge-indentation and cutting tool wear under different combination of cutting parameters, and analysis and discussion were also conducted for experimental results. The results show that the main leading parameters to edge-indentation of glass ceramic are cutting depth and feed rate. In order to reduce edge-indentation, it needs to use lower cutting depth and feed rate. Water-soluble cutting fluid provides a better cooling effect in the primary cutting area; it may effectively reduce the edge-indentation and improve the surface morphology of the glass ceramic. The use of ultrasonic assisted technique can effectively enhance the surface finish cleanness and reduce cutting tool wear and edge-indentation.
Abstract: Investigations on the accumulation of heavy metals in
water and sediments of river Ogbese were carried out between
December 2010 and February 2011 using Atomic Absorption
Spectrophotometer. Etheria elliptica a sessile organism was also used
to determine the concentration of heavy metal in the aquatic
environmental. In water, Cu had the highest concentration (0.55 –
0.13 mg/l ±0.1) while in sediments, the highest value obtained was in
Fe (1.46-3.89mg/l±0.27). The minimum concentrations recorded
were in Pb; which was below detectable level. The result also
revealed that the shell accumulate more heavy metals than the flesh
of the mussel with Cu in the shell exhibiting a negative correlation
with all the metals in the flesh. However, the condition factor (K)
value is 6.44, an indication of good health. The length-weight
relationship is expressed as W = -0.48 x L 1.94 (r2 = 0.29) showing the
growth pattern to be negatively allometric.
Abstract: Lignocellolusic material is a substance that is resistant to be degraded by microorganisms or hydrolysis enzymes. To be used as materials for biofuel production, it needs pretreatment process to improve efficiency of hydrolysis. In this work, chemical pretreatments on rice straw using three diluted organic acids, including acetic acid, citric acid, oxalic acid, were optimized. Using Response Surface Methodology (RSM), the effect of three pretreatment parameters, acid concentration, treatment time, and reaction temperature, on pretreatment efficiency were statistically evaluated. The results indicated that dilute oxalic acid pretreatment led to the highest enhancement of enzymatic saccharification by commercial cellulase and yielded sugar up to 10.67 mg/ml when using 5.04% oxalic acid at 137.11 oC for 30.01 min. Compared to other acid pretreatment by acetic acid, citric acid, and hydrochloric acid, the maximum sugar yields are 7.07, 6.30, and 8.53 mg/ml, respectively. Here, it was demonstrated that organic acids can be used for pretreatment of lignocellulosic materials to enhance of hydrolysis process, which could be integrated to other applications for various biorefinery processes.
Abstract: The objective of the article was to identify the impacts of gamification on customers' behaviour. The most important applications of games in marketing and mechanisms of gamification are presented in the article. A detailed analysis of the influence of gamification on customers using two brands, Foursquare and Nike, was also presented. Research studies using auditory survey methods were carried out among 176 young respondents, who are potential targets of gamification. The studies confirmed a huge participation of young people in customer loyalty programs with relatively low participation in other gamificationbased marketing activities. The research findings clearly indicate that gamification mechanisms are the most attractive.
Abstract: This paper presents a study the effect of nose radius
(Rz-mm) on cutting force components and temperatures during the
machining simulation in an orthogonal cutting process for titanium
alloy (Ti-6Al-4V). The cutting process was performed at various
nose radiuses (Rz-mm) while the depth of cut (d-mm), feed rate (fmm/
tooth) and cutting speed (vc-m/ min) were remained constant.
The main cutting force (Fc), feed cutting force (Ft) and temperatures
were estimated by using finite element modeling (FEM) through
ABAQUS/EXPLICIT software and the simulation was developed the
two-dimension via an orthogonal cutting process during machining
titanium alloy (Ti-6Al-4V). The results led to the conclusion that the
nose radius (Rz-mm) has affected directly on the cutting force
components. However, temperature gave no indication or has no
significant relation with nose radius during machining titanium alloy
(Ti-6Al-4V). Hence, any increase or decrease in the nose radius (Rzmm)
during machining operation led to effect on the cutting forces
and thus it will be effective on surface finish, quality, and quantity of
products.
Abstract: Reliability of long-term storage products is related to
the availability of the whole system, and the evaluation of storage life
is of great necessity. These products are usually highly reliable and
little failure information can be collected. In this paper, an analytical
method based on data from accelerated storage life test is proposed to
evaluate the reliability index of the long-term storage products. Firstly,
singularities are eliminated by data normalization and residual
analysis. Secondly, with the preprocessed data, the degradation path
model is built to obtain the pseudo life values. Then by life distribution
hypothesis, we can get the estimator of parameters in high stress levels
and verify failure mechanism consistency. Finally, the life distribution
under the normal stress level is extrapolated via the acceleration model
and evaluation of the actual average life is available. An application
example with the camera stabilization device is provided to illustrate
the methodology we proposed.
Abstract: The capability of exploiting the electronic charge and
spin properties simultaneously in a single material has made diluted
magnetic semiconductors (DMS) remarkable in the field of
spintronics. We report the designing of DMS based on zinc-blend
ZnO doped with Cr impurity. The full potential linearized augmented
plane wave plus local orbital FP-L(APW+lo) method in density
functional theory (DFT) has been adapted to carry out these
investigations. For treatment of exchange and correlation energy,
generalized gradient approximations have been used. Introducing Cr
atoms in the matrix of ZnO has induced strong magnetic moment
with ferromagnetic ordering at stable ground state. Cr:ZnO was found
to favor the short range magnetic interaction that
reflect tendency of Cr clustering. The electronic structure of ZnO is
strongly influenced in the presence of Cr impurity atoms where
impurity bands appear in the band gap.
Abstract: Although, lanthanum carbonate has not been approved
by the FDA for treatment of hyperphosphatemia, we prospectively
evaluated the efficacy of the combination of Calcium hydroxyapatite
(CHAp) and Lanthanum Carbonate (LaC) for the treatment of
hyperphosphatemia on mice. CHAp was prepared by co-precipitation
method using Ca(OH)2, H3PO4, NH4OH with calcination at 1200ºC.
Lanthanum carbonate was prepared by chemical method using
NaHCO3 and LaCl3 at low pH environment, below 4.0. The
structures were characterized by FTIR spectra and SEM -EDX
analysis. The study group included 16 subjects-mice divided into four
groups according to the administered substance: lanthanum carbonate
(group A), CHAp (group B), lanthanum carbonate + CHAp (group C)
and salt water (group D). The results indicate a phosphate decrease
when subjects (mice) were treated with CHAp and lanthanum
carbonate (0.5% CMC), in a single dose of 1500 mg/kg. Serum
phosphate concentration decreased [(from 4.5 ± 0.8 mg/dL) to
4.05 ± 0.2 mg/dL), P < 0.01] in group A and in group C (to 3.6
± 0.2 mg/dL) at 12 hours from the administration. The combination
of CHAp and lanthanum carbonate is a suitable regimen for
hyperphosphatemia treatment because it avoids both the
hypercalcemia of CaCO3 and the adverse effects of CHAp.
Abstract: The material selection in the design of the sandwich
structures is very crucial aspect because of the positive or negative
influences of the base materials to the mechanical properties of the
entire panel. In the literature, it was presented that the selection of the
skin and core materials plays very important role on the behavior of
the sandwich. Beside this, the use of the correct adhesive can make
the whole structure to show better mechanical results and behavior.
In the present work, the static three-point bending tests were
performed on the sandwiches having an aluminum alloy foam core,
the skins made of three different types of fabrics and two different
commercial adhesives (flexible polyurethane and toughened epoxy
based) at different values of support span distances by aiming the
analyses of their flexural performance in terms of absorbed energy,
peak force values and collapse mechanisms. The main results of the
flexural loading are: force-displacement curves obtained after the
bending tests, peak force and absorbed energy values, collapse
mechanisms and adhesion quality. The experimental results presented
that the sandwiches with epoxy based toughened adhesive and the
skins made of S-Glass Woven fabrics indicated the best adhesion
quality and mechanical properties. The sandwiches with toughened
adhesive exhibited higher peak force and energy absorption values
compared to the sandwiches with flexible adhesive. The use of these
sandwich structures can lead to a weight reduction of the transport
vehicles, providing an adequate structural strength under operating
conditions.
Abstract: The textile industry plays a major role in the economy
of India and on the other side of the coin it is the major source for
water pollution. As azo dyes is the largest dye class they are
extensively used in many fields such as textile industry, leather
tanning industry, paper production, food, color photography,
pharmaceuticals and medicine, cosmetic, hair colorings, wood
staining, agricultural, biological and chemical research etc. In
addition to these, they can have acute and/or chronic effects on
organisms depending on their concentration and length of exposure
when they discharged as effluent in the environment. The aim of this
study was to assess the genotoxic and histotoxic potentials of
environmentally relevant concentrations of C. I. Reactive Red 120
(RR 120) on Catla catla, important edible freshwater fingerlings. For
this, healthy Catla catla fingerlings were procured from the
Government Fish Farm and acclimatized in 100 L capacity and
continuously aerated glass aquarium in laboratory for 15 days.
According to APHA some physic-chemical parameters were
measured and maintained such as temperature, pH, dissolve oxygen,
alkalinity, total hardness. Water along with excreta had been changed
every 24 hrs. All fingerlings were fed artificial food palates once a
day @ body weight. After 15 days fingerlings were grouped in 5 (10
in each) and exposed to various concentrations of RR 120 (Control,
10, 20, 30 and 40 mg.l-1) and samples (peripheral blood and gills,
kidney) were collected and analyzed at 96 hrs. All results were
compared with the control. Micronuclei (MN), nuclear buds (NB),
fragmented-apoptotic (FA) and bi-nucleated (BN) cells in blood
smears and in tissues (gills and kidney cells) were observed.
Prominent histopathological alterations were noticed in gills such as
aneurism, hyperplasia, degenerated central axis, lifting of gill
epithelium, curved secondary gill lamellae etc. Similarly kidney
showed some detrimental changes like shrunken glomeruli with
increased periglomerular space, degenerated renal tubules etc. Both
haematological and histopathological changes clearly reveal the toxic
potential of RR 120. This work concludes that water pollution
assessment can be done by these two biomarkers which provide
baseline to the further chromosomal or molecular work.
Abstract: Depositional environment and source potential of the
different organic-rich levels of Devonian age (up to 990m thick) from
the onshore EC-1 well (Southern Tunisia) were investigated based on
the analysis of more than 130 cutting samples by different
geochemical techniques (Rock-Eval pyrolysis, GC-MS). The
obtained results including Rock Eval Pyrolysis data and biomarker
distribution (terpanes, steranes and aromatics) have been used to
describe the depositional environment and to assess the thermal
maturity of the Devonian organic matter. These results show that the
Emsian deposits exhibit poor to fair TOC contents. The associated
organic matter is composed of mixed kerogen (type II/III), as
indicated by the predominance of C29 steranes over C27 and C28
homologous, that was deposited in a slightly reduced environment
favoring organic matter preservation. Thermal maturity assessed from
Tmax, TNR and MPI-1 values shows a mature stage of organic
matter. The Middle Devonian (Eifelian) shales are rich in type II
organic matter that was deposited in an open marine depositional
environment. The TOC values are high and vary between 2 and 7%
indicating good to excellent source rock. The relatively high HI
values (reaching 547 mg HC/g TOC) and the low values of t19/t23
tricyclic terpane ratio (< 0.2) confirm the marine origin of the organic
matter (type II). During the Upper Devonian, the organic matter was
deposited under variable redox conditions, oxic to suboxic which is
clearly indicated by the low C35/C34 hopanes ratio, immature to
marginally mature with the vitrinite reflectance ranging from 0.5 to
0.7 Ro and Tmax value of 426°C-436 °C and the TOC values range
between 0.8% to 4%.
Abstract: Taking into account the significance of measuring the
daily use of the study space in the libraries in order to develop and
reorganize the space for enhancing the efficiency of the study space,
the current study aimed to apply GIS in analyzing the study halls of
the Central Library and Document Center of Tehran University in
order to determine how study desks and chairs were used by the
students. The study used a combination of survey-descriptive and
system design method. In order to gather the required data, surveydescriptive
method was used. For implementing and entering data
into ArcGIS and analyzing the data and displaying the results on the
maps of the study halls of the library, system design method was
utilized. The design of the spatial database of the use of the study
halls was measured through the extent of occupancy of the space by
the library users and the maps of the study halls of the central library
of Tehran University as the case study. The results showed that
Abooreyhan hall had the highest rate of occupancy of the desks and
chairs compared to the other halls. The Hall of Science and
Technology, with an average occupancy rate of 0.39 for the tables
represented the lowest number of users and Rashid al-Dins hall, and
Science and Technology hall with an average occupancy rate (0.40)
had the lowest number of users for seats. In this study, the
comparison of the space occupied at different periods in the morning,
evenings, afternoons, and several months was performed through
GIS. This system analyzed the space relationships effectively and
efficiently. The output of this study would be used by administrators
and librarians to determine the exact extent of use of the equipment
of the study halls and librarians can use the output map to design the
space more efficiently at the library.
Abstract: The mechanisms underlying the association between
obesity and asthma may be related to a decreased immunological
tolerance induced by a defective function of regulatory T cells
(Tregs). The aim of this study is to establish the potential link
between these diseases and CD4+, CD25+ FoxP3+ Tregs as well as T
helper cells (Ths) in children. This is a prospective case control
study. Obese (n:40), asthmatic (n:40), asthmatic obese (n:40) and
healthy children (n:40), who don't have any acute or chronic diseases,
were included in this study. Obese children were evaluated according
to WHO criteria. Asthmatic patients were chosen based on GINA
criteria. Parents were asked to fill up the questionnaire. Informed
consent forms were taken. Blood samples were marked with CD4+,
CD25+ and FoxP3+ in order to determine Tregs and Ths by flow
cytometric method. Statistical analyses were performed. p≤0.05 was
chosen as meaningful threshold. Tregs exhibiting anti-inflammatory
nature were significantly lower in obese (0,16%; p≤0,001), asthmatic
(0,25%; p≤0,01) and asthmatic obese (0,29%; p≤0,05) groups than
the control group (0,38%). Ths were counted higher in asthma group
than the control (p≤0,01) and obese (p≤0,001) groups. T cell
immunity plays important roles in obesity and asthma pathogeneses.
Decreased numbers of Tregs found in obese, asthmatic and asthmatic
obese children may help to elucidate some questions in
pathophysiology of these diseases. For HOMA-IR levels, any
significant difference was not noted between control and obese
groups, but statistically higher values were found for obese
asthmatics. The values obtained in all groups were found to be below
the critical cut off points. This finding has made the statistically
significant difference observed between Tregs of obese, asthmatic,
obese asthmatic and control groups much more valuable. These
findings will be useful in diagnosis and treatment of these disorders
and future studies are needed. The production and propagation of
Tregs may be promising in alternative asthma and obesity treatments.