Abstract: A simple, accurate and precise direct spectrophotometric method has been developed for the determination of cefixime in tablets and capsules. The method is based on the reaction of cefixime with a mixture of potassium iodide and potassium iodate to form yellow coloured product in ethanol-distilled water medium at room temperature which absorbed maximally at 352 nm. The factors affecting the reaction product were carefully studied and optimized. The validation parameters based on International Conference on Harmonisation (ICH, USA) guidelines were followed. The effect of common excipients used as additives has been tested and the tolerance limit was calculated for the determination of cefixime. Beer’s law is obeyed in the concentration range of 4 – 24 ug mL-1 with apparent molar absorptivity of 1.52 × 104 L mol-1cm-1 and Sandell’s sensitivity of 0.033 ug/cm2/ 0.001 absorbance unit. The limits of detection and quantitation for the proposed method are 0.32 and 1.06 ug mL-1, respectively. The proposed method has been successfully applied for the determination of cefixime in pharmaceutical formulations. The results obtained by the proposed method were statistically compared with the reference method using t- and F- values and found no significant difference between the two methods. The proposed method can be used as an alternate method for routine quality control analysis of cefixime in pharmaceutical formulations.
Abstract: Chloride resistance in Ultra High Performance
Concrete (UHPC) is determined in this paper. This work deals with
the one dimension chloride transport, which can be potentially
dangerous particularly for the durability of concrete structures. Risk
of reinforcement corrosion due to exposure to the concrete surface to
direct the action of chloride ions (mainly in the form de-icing salts or
groundwater) is dangerously increases. The measured data are
investigated depending on the depth of penetration of chloride ions
into the concrete structure. Comparative measurements with normal
strength concrete are done as well. The experimental results showed
that UHCP have improved resistance of chlorides penetration than
NSC and also chloride diffusion depth is significantly lower in
UHCP.
Abstract: In order to investigate the effect of Plant Growth
Promoting Rhizobacteria (PGPR) and rhizobium bacteria on grain
yield and some agronomic traits of mungbean (Vigna radiate L.), an
experiment was carried out based on randomized complete block
design with three replications in Malekshahi, Ilam province, Iran
during 2012-2013 cropping season. Experimental treatments
consisted of control treatment, inoculation with rhizobium bacteria,
rhizobium bacteria and Azotobacter, rhizobium bacteria and
Azospirillum, rhizobium bacteria and Pseudomonas, rhizobium
bacteria, Azotobacter and Azospirillum, rhizobium bacteria,
Azotobacter and Pseudomonas, rhizobium bacteria, Azospirillum and
Pseudomonas and rhizobium bacteria, Azotobacter, Azospirillum and
Pseudomonas. The results showed that the effect of PGPR and
rhizobium bacteria were significant affect on grain and its
components in mungbean plant. Grain yield significantly increased
by PGPR and rhizobium bacteria, so that the maximum grain yield
was obtained from rhizobium bacteria + Azospirillum +
Pseudomonas with the amount of 2287 kg.ha-1 as compared to
control treatment. Excessive application of chemical fertilizers causes
environmental and economic problems. That is, the overfertilization
of P and N leads to pollution due to soil erosion and runoff water, so
the use of PGPR and rhizobium bacteria can be justified due to
reduce input costs, increase in grain yield and environmental friendly.
Abstract: In development of floating photovoltaic generation
system, finding a suitable place of installation is as important as
development of economically feasible and stable structure. Especially
since floating photovoltaic system has its facility floating on water
surface, it is extremely important to review the effects of weather
conditions such as wind, water flow and floating matters, various
factors (such as fogs) that can reduce generation efficiency, possibility
of connection with power system, and legal restrictions. The method of
investigating suitable area and resource for development of
tracking-type floating photovoltaic generation system was proposed in
this paper, which can be used for development of floating and ocean
photovoltaic system in the future.
Abstract: In this study, a comparative analysis of the approaches
associated with the use of neural network algorithms for effective
solution of a complex inverse problem – the problem of identifying
and determining the individual concentrations of inorganic salts in
multicomponent aqueous solutions by the spectra of Raman
scattering of light – is performed. It is shown that application of
artificial neural networks provides the average accuracy of
determination of concentration of each salt no worse than 0.025 M.
The results of comparative analysis of input data compression
methods are presented. It is demonstrated that use of uniform
aggregation of input features allows decreasing the error of
determination of individual concentrations of components by 16-18%
on the average.
Abstract: Fly ash is an important waste, produced in thermal
power plants which causes very important environmental pollutions.
For this reason the usage and evaluation the fly ash in various areas
are very important. Nearly, 15 million tons/year of fly ash is
produced in Turkey. In this study, usage of fly ash with diatomite and
molasses for heavy metal (Cd) adsorption from wastewater is
investigated. The samples of Seyitomer region fly ash were analyzed
by X-ray fluorescence (XRF) and Scanning Electron Microscope
(SEM) then diatomite (0 and 1% in terms of fly ash, w/w) and
molasses (0-0.75 mL) were pelletized under 30 MPa of pressure for
the usage of cadmium (Cd) adsorption in wastewater. After the
adsorption process, samples of Seyitomer were analyzed using
Optical Emission Spectroscopy (ICP-OES). As a result, it is seen that
the usage of Seyitomer fly ash is proper for cadmium (Cd) adsorption
and an optimum adsorption yield with 52% is found at a compound
with Seyitomer fly ash (10 g), diatomite (0.5 g) and molasses (0.75
mL) at 2.5 h of reaction time, pH:4, 20ºC of reaction temperature and
300 rpm of stirring rate.
Abstract: Recent perceived climate variability raises concerns
with unprecedented hydrological phenomena and extremes.
Distribution and circulation of the waters of the Earth become
increasingly difficult to determine because of additional uncertainty
related to anthropogenic emissions. The world wide observed
changes in the large-scale hydrological cycle have been related to an
increase in the observed temperature over several decades. Although
the effect of change in climate on hydrology provides a general
picture of possible hydrological global change, new tools and
frameworks for modelling hydrological series with nonstationary
characteristics at finer scales, are required for assessing climate
change impacts. Of the downscaling techniques, dynamic
downscaling is usually based on the use of Regional Climate Models
(RCMs), which generate finer resolution output based on atmospheric
physics over a region using General Circulation Model (GCM) fields
as boundary conditions. However, RCMs are not expected to capture
the observed spatial precipitation extremes at a fine cell scale or at a
basin scale. Statistical downscaling derives a statistical or empirical
relationship between the variables simulated by the GCMs, called
predictors, and station-scale hydrologic variables, called predictands.
The main focus of the paper is on the need for using statistical
downscaling techniques for projection of local hydrometeorological
variables under climate change scenarios. The projections can be then
served as a means of input source to various hydrologic models to
obtain streamflow, evapotranspiration, soil moisture and other
hydrological variables of interest.
Abstract: This study aimed at designing and developing a
mechanical force gauge for the square watermelon mold for the first
time. It also tried to introduce the square watermelon characteristics
and its production limitations. The mechanical force gauge
performance and the product itself were also described. There are
three main designable gauge models: a. hydraulic gauge, b. strain
gauge, and c. mechanical gauge. The advantage of the hydraulic
model is that it instantly displays the pressure and thus the force
exerted by the melon. However, considering the inability to measure
forces at all directions, complicated development, high cost, possible
hydraulic fluid leak into the fruit chamber and the possible influence
of increased ambient temperature on the fluid pressure, the
development of this gauge was overruled. The second choice was to
calculate pressure using the direct force a strain gauge. The main
advantage of these strain gauges over spring types is their high
precision in measurements; but with regard to the lack of conformity
of strain gauge working range with water melon growth, calculations
were faced with problems. Finally the mechanical pressure gauge has
advantages, including the ability to measured forces and pressures on
the mold surface during melon growth; the ability to display the peak
forces; the ability to produce melon growth graph thanks to its
continuous force measurements; the conformity of its manufacturing
materials with the required physical conditions of melon growth; high
air conditioning capability; the ability to permit sunlight reaches the
melon rind (no yellowish skin and quality loss); fast and
straightforward calibration; no damages to the product during
assembling and disassembling; visual check capability of the product
within the mold; applicable to all growth environments (field,
greenhouses, etc.); simple process; low costs and so forth.
Abstract: Web search engines are designed to retrieve and
extract the information in the web databases and to return dynamic
web pages. The Semantic Web is an extension of the current web in
which it includes semantic content in web pages. The main goal of
semantic web is to promote the quality of the current web by
changing its contents into machine understandable form. Therefore,
the milestone of semantic web is to have semantic level information
in the web. Nowadays, people use different keyword- based search
engines to find the relevant information they need from the web.
But many of the words are polysemous. When these words are
used to query a search engine, it displays the Search Result Records
(SRRs) with different meanings. The SRRs with similar meanings are
grouped together based on Word Sense Disambiguation (WSD). In
addition to that semantic annotation is also performed to improve the
efficiency of search result records. Semantic Annotation is the
process of adding the semantic metadata to web resources. Thus the
grouped SRRs are annotated and generate a summary which
describes the information in SRRs. But the automatic semantic
annotation is a significant challenge in the semantic web. Here
ontology and knowledge based representation are used to annotate
the web pages.
Abstract: Concerns on corrosion and effective coating
protection of double hull tankers and bulk carriers in service have
been raised especially in water ballast tanks (WBTs). Test
protocols/methodologies specifically that which is incorporated in the
International Maritime Organisation (IMO), Performance Standard
for Protective Coatings for Dedicated Sea Water ballast tanks (PSPC)
are being used to assess and evaluate the performance of the coatings
for type approval prior to their application in WBTs. However, some
of the type approved coatings may be applied as very thick films to
less than ideally prepared steel substrates in the WBT. As such films
experience hygrothermal cycling from operating and environmental
conditions, they become embrittled which may ultimately result in
cracking. This embrittlement of the coatings is identified as an
undesirable feature in the PSPC but is not mentioned in the test
protocols within it. There is therefore renewed industrial research
aimed at understanding this issue in order to eliminate cracking and
achieve the intended coating lifespan of 15 years in good condition.
This paper will critically review test protocols currently used for
assessing and evaluating coating performance, particularly the IMO
PSPC.
Abstract: Roof top rainwater harvesting (RWH) has been
carried out worldwide to provide an inexpensive source of water for
many people. This research aims at evaluating the potential of roof
top rain water harvesting as a resource in Jordan. For the purpose of
this work, two case studies at Al-Jubiha and Shafa-Badran districts in
Amman city were selected. All existing rooftops in both districts
were identified by digitizing 2012 satellite images of the two districts
using Google earth and ArcGIS tools. Rational method was used to
estimate the potential volume of rainwater that can be harvested from
the digitized rooftops. Results indicated that 1.17 and 0.526 MCM/yr
can be harvested in Al-Jubiha and Shafa-Badran districts,
respectively. This study should increase the attention to the
importance of implementing RWH technique in Jordanian residences
as a viable alternative for ensuring a continued source of non-potable
water.
Abstract: This study investigates the effect of moisture
conditioning on the Indirect Tensile Strength (ITS) of asphalt
concrete. As a first step, cylindrical samples of 100 mm diameter and
50 mm thick were prepared using a Superpave gyratory compactor.
Next, the samples were conditioned using Moisture Induced
Susceptibility Test (MIST) device at different numbers of moisture
conditioning cycles. In the MIST device, samples are subjected water
pressure through the sample pores cyclically. The MIST conditioned
samples were tested for ITS. Results show that the ITS does not
change significantly with MIST conditioning at the specific pressure
and cycles adopted in this study.
Abstract: This paper presents the application of finite dynamic
programming, specifically the "Markov Chain" model, as part of the
decision making process of a company in the cosmetics sector located
in the vicinity of Bogota DC. The objective of this process was to
decide whether the company should completely reconstruct its
wastewater treatment plant or instead optimize the plant through the
addition of equipment. The goal of both of these options was to make
the required improvements in order to comply with parameters
established by national legislation regarding the treatment of waste
before it is released into the environment. This technique will allow
the company to select the best option and implement a solution for
the processing of waste to minimize environmental damage and the
acquisition and implementation costs.
Abstract: Because of high thermal efficiency and low CO2
emission, diesel engines are being used widely in many industrial
fields although it makes many PM and NOx which give both human
health and environment a negative effect. NOx regulations for diesel
engines, however, are being strengthened and it is impossible to meet
the emission standard without NOx reduction devices such as SCR
(Selective Catalytic Reduction), LNC (Lean NOx Catalyst), and LNT
(Lean NOx Trap). Among the NOx reduction devices, urea-SCR
system is known as the most stable and efficient method to solve the
problem of NOx emission. But this device has some issues associated
with the ammonia slip phenomenon which is occurred by shortage of
evaporation and thermolysis time, and that makes it difficult to achieve
uniform distribution of the injected urea in front of monolith.
Therefore, this study has focused on the mixing enhancement between
urea and exhaust gases to enhance the efficiency of the SCR catalyst
equipped in catalytic muffler by changing inlet gas temperature and
spray conditions to improve the spray uniformity of the urea water
solution. Finally, it can be found that various parameters such as inlet
gas temperature and injector and injection angles significantly affect
the evaporation and mixing of the urea water solution with exhaust
gases, and therefore, optimization of these parameters are required.
Abstract: A methodology is proposed for estimating the optical
attenuation and proportional depth variation of shallow inland water.
The process is demonstrated with EO-1 Hyperion hyperspectral and
IRS-P6 LISS-3 multispectral images of Kolkata city nearby area
centered around 22º33′ N 88º26′ E. The attenuation coefficient of
water was found to change with fine resolution of wavebands and in
presence of suspended organic matter in water.
Abstract: Artificial Neural Networks (ANN) trained using backpropagation
(BP) algorithm are commonly used for modeling
material behavior associated with non-linear, complex or unknown
interactions among the material constituents. Despite multidisciplinary
applications of back-propagation neural networks
(BPNN), the BP algorithm possesses the inherent drawback of
getting trapped in local minima and slowly converging to a global
optimum. The paper present a hybrid artificial neural networks and
genetic algorithm approach for modeling slump of ready mix
concrete based on its design mix constituents. Genetic algorithms
(GA) global search is employed for evolving the initial weights and
biases for training of neural networks, which are further fine tuned
using the BP algorithm. The study showed that, hybrid ANN-GA
model provided consistent predictions in comparison to commonly
used BPNN model. In comparison to BPNN model, the hybrid ANNGA
model was able to reach the desired performance goal quickly.
Apart from the modeling slump of ready mix concrete, the synaptic
weights of neural networks were harnessed for analyzing the relative
importance of concrete design mix constituents on the slump value.
The sand and water constituents of the concrete design mix were
found to exhibit maximum importance on the concrete slump value.
Abstract: In the present work, detailed analysis on flow characteristics of a pair of immiscible liquids through horizontal pipeline is simulated by using ANSYS FLUENT 6.2. Moderately viscous oil and water (viscosity ratio = 107, density ratio = 0.89 and interfacial tension = 0.024 N/m) have been taken as system fluids for the study. Volume of Fluid (VOF) method has been employed by assuming unsteady flow, immiscible liquid pair, constant liquid properties, and co-axial flow. Meshing has been done using GAMBIT. Quadrilateral mesh type has been chosen to account for the surface tension effect more accurately. From the grid independent study, we have selected 47037 number of mesh elements for the entire geometry. Simulation successfully predicts slug, stratified wavy, stratified mixed and annular flow, except dispersion of oil in water, and dispersion of water in oil. Simulation results are validated with horizontal literature data and good conformity is observed. Subsequently, we have simulated the hydrodynamics (viz., velocity profile, area average pressure across a cross section and volume fraction profile along the radius) of stratified wavy and annular flow at different phase velocities. The simulation results show that in the annular flow, total pressure of the mixture decreases with increase in oil velocity due to the fact that pipe cross section is completely wetted with water. Simulated oil volume fraction shows maximum at the centre in core annular flow, whereas, in stratified flow, maximum value appears at upper side of the pipeline. These results are in accord with the actual flow configuration. Our findings could be useful in designing pipeline for transportation of crude oil.
Abstract: Turbulent flow in complex geometries receives considerable attention due to its importance in many engineering applications. It has been the subject of interest for many researchers. Some of these interests include the design of storm water channels. The design of these channels requires testing through physical models. The main practical limitation of physical models is the so called “scale effect”, that is, the fact that in many cases only primary physical mechanisms can be correctly represented, while secondary mechanisms are often distorted. These observations form the basis of our study, which centered on problems associated with the design of storm water channels near the Dead Sea, in Israel. To help reach a final design decision we used different physical models. Our research showed good coincidence with the results of laboratory tests and theoretical calculations, and allowed us to study different effects of fluid flow in an open channel. We determined that problems of this nature cannot be solved only by means of theoretical calculation and computer simulation. This study demonstrates the use of physical models to help resolve very complicated problems of fluid flow through baffles and similar structures. The study applies these models and observations to different construction and multiphase water flows, among them, those that include sand and stone particles, a significant attempt to bring to the testing laboratory a closer association with reality.
Abstract: Al-Si-Mg-Ni(-Cu) alloys are widely used in the automotive industry. They have the advantage of low weight associated with low coefficient of thermal expansion and excellent mechanical properties – mainly at high temperatures. The corrosion resistance of these alloys in coastal area, particularly sea water, however is not yet known. In this investigation, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization have been used to evaluate the corrosion resistance of Al-6Si-0.5Mg-2Ni (-2Cu) alloys in simulated sea water environments. The potentiodynamic polarization curves reveal that 2 wt% Cu content alloy (Alloy-2) is more prone to corrosion than the Cu free alloy (Alloy-1). But the EIS test results showed that corrosion resistance or charge transfer resistance (Rct) increases with the addition of Cu. Due to addition of Cu and thermal treatment, the magnitude of open circuit potential (OCP), corrosion potential (Ecorr) and pitting corrosion potential (Epit) of Al-6Si-0.5Mg-2Ni alloy in NaCl solution were shifted to the more noble direction.
Abstract: In the present study, presence of endosulfan, imidacloprid, carbendazim, in the soil /vegetables/cereals and water samples was observed in agriculture fields of Uttarakhand. In view of biodegradation of these pesticides, 9 bacterial isolates were recovered from the soil samples of the fields which tolerated endosulfan, imidacloprid, carbendazim from 100 to 200 µg/ml. Three bacterial consortia used for in vitro bioremediation experiments were consisted of 3 bacterial isolates for carbendazim, imidacloprid and endosulfan, respectively. Maximum degradation (87 and 83%) of α and β endosulfan respectively was observed in soil slurry by consortium. Degradation of Imidacloprid and carbendazim under similar conditions was 88.4 and 77.5% respectively. FT-IR analysis of biodegraded samples of pesticides in liquid media showed stretching of various bonds. GC-MS of biodegraded endosulfan sample in soil slurry showed the presence of nontoxic intermediates. A pot trial with Bacterial treatments lowered down the uptake of pesticides in onion plants.