Abstract: Land degradation is of concern in many countries. People more and more must address the problems associated with the degradation of soil properties due to man. Increasingly, organic soil amendments, such as compost are being examined for their potential use in soil restoration and for preventing soil erosion. In the Czech Republic, compost is the most used to improve soil structure and increase the content of soil organic matter. Land reclamation / restoration is one of the ways to evaluate industrially produced compost because Czech farmers are not willing to use compost as organic fertilizer. The most common use of reclamation substrates in the Czech Republic is for the rehabilitation of landfills and contaminated sites.
This paper deals with the influence of reclamation substrates (RS) with different proportions of compost and sand on selected soil properties–chemical characteristics, nitrogen bioavailability, leaching of mineral nitrogen, respiration activity and plant biomass production. Chemical properties vary proportionally with addition of compost and sand to the control variant (topsoil). The highest differences between the variants were recorded in leaching of mineral nitrogen (varies from 1.36mg dm-3 in C to 9.09mg dm-3). Addition of compost to soil improves conditions for plant growth in comparison with soil alone. However, too high addition of compost may have adverse effects on plant growth. In addition, high proportion of compost increases leaching of mineral N. Therefore, mixture of 70% of soil with 10% of compost and 20% of sand may be recommended as optimal composition of RS.
Abstract: This study aims to identify the current situation and
problems of environmental statement for major four home appliances
(refrigerators, washing machines, air conditioners and television
receivers) sold at online stores in Japan, and then to suggest how to
improve the situation, through a questionnaire survey conducted
among businesses that operate online stores and online malls with
multiple online stores. Results of the study boil down to:
(1) It is found out that environmental statement for the home
appliances at online stores have four problems; (i) less information
on “three Rs" and “chemical substances" than the one on “energy
conservation", (ii) cost for providing environmental statement, (iii)
issues associated with a label and mark placement, and (iv) issues
associated with energy conservation statement.
(2) Improvements are suggested for each of the four problems listed
above, and shown are (i) the effectiveness of, and need to promote, a
label and mark placement, (ii) cost burden on buyers, and (iii) need
of active efforts made by businesses and of dissemination of legal
regulations to businesses.
Abstract: The aim of this study was to investigate the
effectiveness of anaerobic digestion for the treatment of wool
scouring wastes. The experiments design comprised three ratios of
waste (W) to seed(S) (W:S) of 25:75, 50:50 and 75:25, corresponding
to 1.9. 1.7 and 1.5g tCOD/g TS, respectively, with or without
chemicals addition. NH4Cl was added to the reactors as a source for
nitrogen to achieve C:N:P of 420:14:3. A cationic flocculent was
added at 0.5 and 0.75% to enhance flocculation of sludge. The results
showed that the reactors that received W:S at a ratio of 25:75
produced the largest volume of biogas. The final soluble COD
(sCOD) was below the limits for discharge to the sewer system.
Abstract: The aim of this study was to screen for
microorganism that able to utilize 3-N-trimethylamino-1-propanol
(homocholine) as a sole source of carbon and nitrogen. The aerobic
degradation of homocholine has been found by a gram-positive
Rhodococcus sp. bacterium isolated from soil. The isolate was
identified as Rhodococcus sp. strain A4 based on the phenotypic
features, physiologic and biochemical characteristics, and
phylogenetic analysis. The cells of the isolated strain grown on both
basal-TMAP and nutrient agar medium displayed elementary
branching mycelia fragmented into irregular rod and coccoid
elements. Comparative 16S rDNA sequencing studies indicated that
the strain A4 falls into the Rhodococcus erythropolis subclade and
forms a monophyletic group with the type-strains of R. opacus, and
R. wratislaviensis. Metabolites analysis by capillary electrophoresis,
fast atom bombardment-mass spectrometry, and gas
chromatography- mass spectrometry, showed trimethylamine (TMA)
as the major metabolite beside β-alanine betaine and
trimethylaminopropionaldehyde. Therefore, the possible degradation
pathway of trimethylamino propanol in the isolated strain is through
consequence oxidation of alcohol group (-OH) to aldehyde (-CHO)
and acid (-COOH), and thereafter the cleavage of β-alanine betaine
C-N bonds yielded trimethylamine and alkyl chain.
Abstract: The main objective of this study is to test the
relationship between numbers of variables representing the firm
characteristics (market-related variables) and the extent of voluntary
disclosure levels (forward-looking disclosure) in the annual reports of
Egyptian firms listed on the Egyptian Stock Exchange. The results
show that audit firm size is significantly positively correlated (in all
the three years) with the level of forward-looking disclosure.
However, industry type variable (which divided to: industries,
cement, construction, petrochemicals and services), is found being
insignificantly association with the level of forward-looking
information disclosed in the annual reports for all the three years.
Abstract: Modeling transfer phenomena in several chemical
engineering operations leads to the resolution of partial differential
equations systems. According to the complexity of the operations
mechanisms, the equations present a nonlinear form and analytical
solution became difficult, we have then to use numerical methods
which are based on approximations in order to transform a
differential system to an algebraic one.Finite element method is one
of numerical methods which can be used to obtain an accurate
solution in many complex cases of chemical engineering.The packed
columns find a large application like contactor for liquid-liquid
systems such solvent extraction. In the literature, the modeling of this
type of equipment received less attention in comparison with the
plate columns.A mathematical bidimensionnal model with radial and
axial dispersion, simulating packed tower extraction behavior was
developed and a partial differential equation was solved using the
finite element method by adopting the Galerkine model. We
developed a Mathcad program, which can be used for a similar
equations and concentration profiles are obtained along the column.
The influence of radial dispersion was prooved and it can-t be
neglected, the results were compared with experimental concentration
at the top of the column in the extraction system:
acetone/toluene/water.
Abstract: The Proton Exchange Membrane Fuel Cell (PEMFC)
control system has an important effect on operation of cell.
Traditional controllers couldn-t lead to acceptable responses because
of time- change, long- hysteresis, uncertainty, strong- coupling and
nonlinear characteristics of PEMFCs, so an intelligent or adaptive
controller is needed. In this paper a neural network predictive
controller have been designed to control the voltage of at the
presence of fluctuations of temperature. The results of
implementation of this designed NN Predictive controller on a
dynamic electrochemical model of a small size 5 KW, PEM fuel cell
have been simulated by MATLAB/SIMULINK.
Abstract: In this study, a 3D combustion chamber was simulated
using FLUENT 6.32. Aims to obtain accurate information about the
profile of the combustion in the furnace and also check the effect of
oxygen enrichment on the combustion process. Oxygen enrichment is
an effective way to reduce combustion pollutant. The flow rate of air
to fuel ratio is varied as 1.3, 3.2 and 5.1 and the oxygen enriched
flow rates are 28, 54 and 68 lit/min. Combustion simulations
typically involve the solution of the turbulent flows with heat
transfer, species transport and chemical reactions. It is common to
use the Reynolds-averaged form of the governing equation in
conjunction with a suitable turbulence model. The 3D Reynolds
Averaged Navier Stokes (RANS) equations with standard k-ε
turbulence model are solved together by Fluent 6.3 software. First
order upwind scheme is used to model governing equations and the
SIMPLE algorithm is used as pressure velocity coupling. Species
mass fractions at the wall are assumed to have zero normal
gradients.Results show that minimum mole fraction of CO2 happens
when the flow rate ratio of air to fuel is 5.1. Additionally, in a fixed
oxygen enrichment condition, increasing the air to fuel ratio will
increase the temperature peak. As a result, oxygen-enrichment can
reduce the CO2 emission at this kind of furnace in high air to fuel
rates.
Abstract: This paper presents the experimental results of
leakage current waveforms which appears on porcelain insulator
surface due to existence of artificial pollutants. The tests have been
done using the chemical compounds of NaCl, Na2SiO3, H2SO4, CaO,
Na2SO4, KCl, Al2SO4, MgSO4, FeCl3, and TiO2. The insulator
surface was coated with those compounds and dried. Then, it was
tested in the chamber where the high voltage was applied. Using
correspondence analysis, the result indicated that the fundamental
harmonic of leakage current was very close to the applied voltage
and third harmonic leakage current was close to the yielded leakage
current amplitude. The first harmonic power was correlated to first
harmonic amplitude of leakage current, and third harmonic power
was close to third harmonic one. The chemical compounds of H2SO4
and Na2SiO3 affected to the power factor of around 70%. Both are the
most conductive, due to the power factor drastically increase among
the chemical compounds.
Abstract: Lake Nasser is one of the largest reservoirs in the
world. Over 120 million metric tons of sediments are deposited in its
dead storage zone every year. The main objective of the present work
was to determine the physical and chemical characteristics of Lake
Nasser sediments. The sample had a relatively low surface area of 2.9
m2/g which increased more than 3-fold upon chemical activation. The
main chemical elements of the raw sediments were C, O and Si with
some traces of Al, Fe and Ca. The organic functional groups for the
tested sample included O-H, C=C, C-H and C-O, with indications of
Si-O and other metal-C and/or metal-O bonds normally associated
with clayey materials. Potentiometric titration of the sample in
different ionic strength backgrounds revealed an alkaline material with
very strong positive surface charge at pH values just a little less than
the pH of zero charge which is ~9. Surface interactions of the
sediments with the background electrolyte were significant. An
advanced surface complexation model was able to capture these
effects, employing a single-site approach to represent protolysis
reactions in aqueous solution, and to determine the significant surface
species in the pH range of environmental interest.
Abstract: Carbon nanotubes (CNTs) possess unique structural,
mechanical, thermal and electronic properties, and have been
proposed to be used for applications in many fields. However, to
reach the full potential of the CNTs, many problems still need to be
solved, including the development of an easy and effective
purification procedure, since synthesized CNTs contain impurities,
such as amorphous carbon, carbon nanoparticles and metal particles.
Different purification methods yield different CNT characteristics
and may be suitable for the production of different types of CNTs. In
this study, the effect of different purification chemicals on carbon
nanotube quality was investigated. CNTs were firstly synthesized by
chemical vapor deposition (CVD) of acetylene (C2H2) on a
magnesium oxide (MgO) powder impregnated with an iron nitrate
(Fe(NO3)3·9H2O) solution. The synthesis parameters were selected
as: the synthesis temperature of 800°C, the iron content in the
precursor of 5% and the synthesis time of 30 min. The liquid phase
oxidation method was applied for the purification of the synthesized
CNT materials. Three different acid chemicals (HNO3, H2SO4, and
HCl) were used in the removal of the metal catalysts from the
synthesized CNT material to investigate the possible effects of each
acid solution to the purification step. Purification experiments were
carried out at two different temperatures (75 and 120 °C), two
different acid concentrations (3 and 6 M) and for three different time
intervals (6, 8 and 15 h). A 30% H2O2 : 3M HCl (1:1 v%) solution
was also used in the purification step to remove both the metal
catalysts and the amorphous carbon. The purifications using this
solution were performed at the temperature of 75°C for 8 hours.
Purification efficiencies at different conditions were evaluated by
thermogravimetric analysis. Thermal and electrical properties of
CNTs were also determined. It was found that the obtained electrical
conductivity values for the carbon nanotubes were typical for organic
semiconductor materials and thermal stabilities were changed
depending on the purification chemicals.
Abstract: A group of Stellite alloys are studied in consideration
of temperature effects on their hardness and wear resistance. The
hardness test is conducted on a micro-hardness tester with a hot stage
equipped that allows heating the specimen up to 650°C. The wear
resistance of each alloy is evaluated using a pin-on-disc tribometer
with a heating furnace built-in that provides the temperature capacity
up to 450°C. The experimental results demonstrate that the hardness
and wear resistance of Stellite alloys behave differently at room
temperature and at high temperatures. The wear resistance of Stellite
alloys at room temperature mainly depends on their carbon content and
also influenced by the tungsten content in the alloys. However, at high
temperatures the wear mechanisms of Stellite alloys become more
complex, involving multiple factors. The relationships between
chemical composition, microstructure, hardness and wear resistance of
these alloys are studied, with focus on temperature effect on these
relations.
Abstract: The purpose of our study was to compare spontaneous
re-epithelisation characteristics versus assisted re-epithelisation. In
order to assess re-epithelisation of the injured skin, we have imagined
and designed a burn wound model on Wistar rat skin. Our aim was to
create standardised, easy reproducible and quantifiable skin lesions
involving entire epidermis and superficial dermis. We then have
applied the above mentioned therapeutic strategies to compare
regeneration of epidermis and dermis, local and systemic parameter
changes in different conditions. We have enhanced the reepithelisation
process under a moist atmosphere of a polyurethane
wound dress modified with helium non-thermal plasma, and with the
aid of direct cold-plasma treatment respectively. We have followed
systemic parameters change: hematologic and biochemical
parameters, and local features: oxidative stress markers and histology
of skin in the above mentioned conditions. Re-epithelisation is just a
part of the skin regeneration process, which recruits cellular
components, with the aid of epidermal and dermal interaction via
signal molecules.
Abstract: Stochastic models of biological networks are well established in systems biology, where the computational treatment of such models is often focused on the solution of the so-called chemical master equation via stochastic simulation algorithms. In contrast to this, the development of storage-efficient model representations that are directly suitable for computer implementation has received significantly less attention. Instead, a model is usually described in terms of a stochastic process or a "higher-level paradigm" with graphical representation such as e.g. a stochastic Petri net. A serious problem then arises due to the exponential growth of the model-s state space which is in fact a main reason for the popularity of stochastic simulation since simulation suffers less from the state space explosion than non-simulative numerical solution techniques. In this paper we present transition class models for the representation of biological network models, a compact mathematical formalism that circumvents state space explosion. Transition class models can also serve as an interface between different higher level modeling paradigms, stochastic processes and the implementation coded in a programming language. Besides, the compact model representation provides the opportunity to apply non-simulative solution techniques thereby preserving the possible use of stochastic simulation. Illustrative examples of transition class representations are given for an enzyme-catalyzed substrate conversion and a part of the bacteriophage λ lysis/lysogeny pathway.
Abstract: Controlled modification of appropriate sharpness for
nanotips is of paramount importance to develop novel materials and
functional devices at a nanometer resolution. Herein, we present a
reliable and unique strategy of laser irradiation enhanced
physicochemical etching to manufacture super sharp tungsten tips
with reproducible shape and dimension as well as high yields
(~80%). The corresponding morphology structure evolution of
tungsten tips and laser-tip interaction mechanisms were
systematically investigated and discussed using field emission
scanning electron microscope (SEM) and physical optics statistics
method with different fluences under 532 nm laser irradiation. This
work paves the way for exploring more accessible metallic tips
applications with tunable apex diameter and aspect ratio, and,
furthermore, facilitates the potential sharpening enhancement
technique for other materials used in a variety of nanoscale devices.
Abstract: In order to enhance the knowledge of certain
phytochemical Algerian plants that are widely used in traditional
medicine and to exploit their therapeutic potential in modern
medicine, we have done a specific extraction of terpenes and
alkaloids from the leaves of Euphorbia granulata to evaluate the
antioxidant and antibacterial activity of this extracts. After the
extraction it was found that the terpene extract gave the highest yield
59.72% compared with alkaloids extracts.
The disc diffusion method was used to determine the antibacterial
activity against different bacterial strains: Escherichia coli
(ATCC25922), Pseudomonas aeruginosa (ATCC27853) and
Staphylococcus aureus (ATCC25923). All extracts have shown
inhibition of growth bacteria. The different zones of inhibition have
varied from (7 -10 mm) according to the concentrations of extract
used.
Testing the antiradical activity on DPPH-TLC plates indicated the
presence of substances that have potent anti-free radical. As against,
the BC-TLC revealed that only terpenes extract which was reacted
positively. These results can validate the importance of Euphorbia
granulata in traditional medicine.
Abstract: Elateriospermum tapos seed (buah perah) is the one
of the rich sources of polyunsaturated fatty acids. It contains high
percentage of oleic acid which is the important component to develop
nervous system and also α-linolenic acid (ALA) which is the
precursor of omega-3 fatty acids series to synthesize
eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA).
However, there is less study about this valuable oilseed and exploit
its potential. Therefore, this paper is to assess the comparison of
physico-chemical properties and fatty composition of perah oil to
palm oil and soybean oil. From the comparison, perah oil shows low
peroxide value means it has good oxidative stability and also high
iodine values shows that it can be used in paint industry. The study
shown that perah oil is comparable to palm oil and soybean oil, so it
has high potential to be exploited in the oleochemical,
pharmaceutical, cosmetics and paint industries.
Abstract: Land use change, if not based on proper scientific
investigation affects other physical, chemical, and biological
properties of soil and leading to increased destruction and erosion. It
was imperative to study the effects of changing rangelands to
farmlands on some Soil quality indexes. Undisturbed soil samples
were collected from the depths of 0-10 and 10-30 centimeter in
pasture with good vegetation cover(GP), pasture with medium
vegetation cover(MP), abandoned dry land farming(ADF) and
degraded dry land farming(DDF) land uses in Ghareh Aghaj
watershed of Isfahan province. The results revealed that organic
matter(OM), cation exchange capacity(CEC) and available
potassium(AK) decreasing in the depth of 0-10 centimeter were 66.6,
38.8 and 70 percent and in the depth of 10-30 centimeter were 58,
61.4 and 83.5 percent respectively in DDF comparison with GP.
Concerning to the results, it seems that land use change can decrease
soil quality and increase soil degradation and lead in undesirable
consequences.
Abstract: The aim of the study was to investigate phytochemical
properties, antimicrobial activity and cytotoxicity of Aloe vera. The
phytochemical screening of the extracts of leaves of A. vera revealed
the presence of bioactive compounds such as alkaloids, tannins,
flavonoids phenolic compounds, and etc. with absence of cyanogenic
glycosides. Three different solvents such as methanol, ethanol and
Di-Methyl sulfoxide were used to screen the antimicrobial activity of
A. vera leaves against four human clinical pathogens by agar well
diffusion method. The maximum antibacterial activities were
observed in methanol extract followed by ethanol and Di-Methyl
sulfoxide. It was also found that remarkable antibacterial activities
with methanolic and ethanolic extracts of A. vera compared with the
standard antibiotic, tetracycline that was not active against E. coli
and S. boydii and supported the view that A. vera is a potent
antimicrobial agent compared with the conventional antibiotic.
Moreover, the brine shrimps (Artemia salina) toxicity test exhibited
LC50 value was 569.52 ppm. The resulting data indicated that the A.
vera plant have less toxic effects on brine shrimp. Hence, it is
signified that Aloe vera plant extract is safe to be used as an
antimicrobial agent.
Abstract: The effect of different tempering temperatures and heat treatment times on the corrosion resistance of austenitic stainless steels in oxalic acid was studied in this work using conventional weight loss and electrochemical measurements. Typical 304 and 316 stainless steel samples were tempered at 150oC, 250oC and 350oC after being austenized at 1050oC for 10 minutes. These samples were then immersed in 1.0M oxalic acid and their weight losses were measured at every five days for 30 days. The results show that corrosion of both types of ASS samples increased with an increase in tempering temperature and time and this was due to the precipitation of chromium carbides at the grain boundaries of these metals. Electrochemical results also confirm that the 304 ASS is more susceptible to corrosion than 316 ASS in this medium. This is attributed to the molybdenum in the composition of the latter. The metallographic images of these samples showed non–uniform distribution of precipitated chromium carbides at the grain boundaries of these metals and unevenly distributed carbides and retained austenite phases which cause galvanic effects in the medium.