Abstract: A total of twenty tensile biopsies were collected from
children undergoing tonsillectomy from teaching hospital ENT
department and Kurdistan private hospital in sulaimani city. All
biopsies were homogenized and cultured; the obtained bacterial
isolates were purified and identified by biochemical tests and VITEK
2 compact system. Among the twenty studied samples, only one
Pseudomonas putida with probability of 99% was isolated.
Antimicrobial susceptibility was carried out by disk diffusion
method, Pseudomonas putida showed resistance to all antibiotics
used except vancomycin. The isolate further subjected to PCR and
DNA sequence analysis of blaVIM gene using different set of primers
for different regions of VIM gene. The results were found to be PCR
positive for the blaVIM gene. To determine the sequence of blaVIM
gene, DNA sequencing performed. Sequence alignment of blaVIM
gene with previously recorded blaVIM gene in NCBI- database showed
that P. putida isolate have different blaVIM gene.
Abstract: carrot is one of the important root vegetable crops,
and it is highly nutritious as it contains appreciable amount of
vitamins, minerals and β-carotene. The major objective of current
research was to evaluate the chemical composition of carrot variety
'Nante' hybrids in general and to select the best samples for fresh-cut
salad production. The research was accomplished on fresh in Latvia
cultivated carrots harvested in Zemgale region in the first part of
October, 2011 and immediately used for experiments. Late-bearing
variety 'Nante' hybrid carrots were used for analysis:
'Nante/Berlikum', 'Nante/Maestro', 'Nante/Forto', 'Nante/Bolero'
and 'Nante/Champion'. The quality parameters as moisture, soluble
solid, firmness, b-carotene, carotenoid, color, polyphenols, total
phenolic compounds and total antioxidant capacity were analyzed
using standard methods. For fresh-cut salad production as more
applicable could be recommended hybrids 'Nante/Forto' and
'Nante/Berlikum' - mainly because it-s higher nutritive value, as
higher total phenolic compounds, polyphenols and pronounced
antioxidant capacity.
Abstract: This paper describes the application of a model
predictive controller to the problem of batch reactor temperature
control. Although a great deal of work has been done to improve
reactor throughput using batch sequence control, the control of the
actual reactor temperature remains a difficult problem for many
operators of these processes. Temperature control is important as
many chemical reactions are sensitive to temperature for formation of
desired products. This controller consist of two part (1) a nonlinear
control method GLC (Global Linearizing Control) to create a linear
model of system and (2) a Model predictive controller used to obtain
optimal input control sequence. The temperature of reactor is tuned
to track a predetermined temperature trajectory that applied to the
batch reactor. To do so two input signals, electrical powers and the
flow of coolant in the coil are used. Simulation results show that the
proposed controller has a remarkable performance for tracking
reference trajectory while at the same time it is robust against noise
imposed to system output.
Abstract: Field experiments were carried out at Owo, southwest Nigeria to evaluate the effect of different tillage practices (zero tillage with mulch (ZTM), row tillage (RT) and conventional tillage (CT), and with or without oil palm bunch ash plus poultry manure (OBA+PM) on soil chemical properties, growth and yield of ginger. The experiment was laid out in a randomized complete plot design with three replications. Soil chemical properties, growth and fresh rhizome yield reduced with frequency/intensity of tillage imposed while application of OBA+PM increased them. Among the tillage practices, the highest fresh rhizome yield (15.0t ha-1) was produced by ZTM which was significantly different from other tillage practices. Among the tillage – OBA+PM combinations, the most satisfactorily yield (20.1t ha-1) was produced by ZTM+OBA+PM while the lowest yield (15.7t ha-1) was in CT+OBA+PM.
Abstract: A shaft-type activated sludge reactor has been
developed in order to study the feasibility of high-rate wastewater
treatment. The reactor having volume of about 14.5 L was operated
with the acclimated mixed activated sludge under batch and
continuous mode using a synthetic wastewater as feed. The batch
study was performed with varying chemical oxygen demand (COD)
concentrations of 1000–3500 mg·L-1 for a batch period up to 9 h. The
kinetic coefficients: Ks, k, Y and kd were obtained as 2040.2 mg·L-1
and 0.105 h-1, 0.878 and 0.0025 h-1 respectively from Monod-s
approach. The continuous study showed a stable and steady state
operation for a hydraulic retention time (HRT) of 8 h and influent
COD of about 1000 mg·L-1. A maximum COD removal efficiency of
about 80% was attained at a COD loading rate and food-tomicroorganism
(F/M) ratio (COD basis) of 3.42 kg·m-3d-1 and 1.0
kg·kg-1d-1 respectively under a HRT of 8 h. The reactor was also
found to handle COD loading rate and F/M ratio of 10.8 kg·m-3d-1
and 2.20 kg·kg-1d-1 respectively showing a COD removal efficiency
of about 46%.
Abstract: In this project cadmium ions were adsorbed from
aqueous solutions onto either date pits; a cheap agricultural and nontoxic
material, or chemically activated carbon prepared from date pits
using phosphoric acid. A series of experiments were conducted in a
batch adsorption technique to assess the feasibility of using the
prepared adsorbents. The effects of the process variables such as
initial cadmium ions concentration, contact time, solution pH and
adsorbent dose on the adsorption capacity of both adsorbents were
studied. The experimental data were tested using different isotherm
models such as Langmuir, Freundlich, Tempkin and Dubinin-
Radushkevich. The results showed that although the equilibrium data
could be described by all models used, Langmuir model gave slightly
better results when using activated carbon while Freundlich model,
gave better results with date pits.
Abstract: In order to study of The Effect of seed inoculation
with Pseudomonas putida+Bacillus lentus on yield and yield
components of wheat (Triticum aestivum L.) cultivars, an experiment
was carried out as factorial based on Randomized Complete Block
Design (RCBD) in Agricultural Research Station of Shahrood
University of Technology. Results showed that inoculation with
Pseudomonas putida+Bacillus lentus promoted seed germination.
Also, inoculation with Pseudomonas putida+Bacillus lentus
significantly affected grain yield, Number of spikes per m2,
Number of grain per spike and 1000-seed weight and There was not
statistically significant difference between Chamran and Pishtaz
cultivars . Finally, the dosages of chemical fertilizers currently
applied in commercial wheat field in Iran (Shahrood region) could be
reduced through proper combination of Pseudomonas
putida+Bacillus lentus inoculation plus fertilization.
Abstract: Selective oxidation of H2S to elemental sulfur in a
fixed bed reactor over newly synthesized alumina nanocatalysts was
physio-chemically investigated and results compared with a
commercial Claus catalyst. Amongst these new materials, Al2O3-
supported sodium oxide prepared with wet chemical technique and
Al2O3 nanocatalyst prepared with spray pyrolysis method were the
most active catalysts for selective oxidation of H2S to elemental
sulfur. Other prepared nanocatalysts were quickly deactivated,
mainly due to the interaction with H2S and conversion into sulfides.
Abstract: Water 2H NMR signal on the surface of nano-silica material, MCM-41, consists of two overlapping resonances. The 2H water spectrum shows a superposition of a Lorentzian line shape and the familiar NMR powder pattern line shape, indicating the existence of two spin components. Chemical exchange occurs between these two groups. Decomposition of the two signals is a crucial starting point for study the exchange process. In this article we have determined these spin component populations along with other important parameters for the 2H water NMR signal over a temperature range between 223 K and 343 K.
Abstract: In the study the influence of the physical-chemical properties of a liquid, the width of a channel gap and the superficial liquid and gas velocities on the patterns formed during two phase flows in vertical, narrow mini-channels was investigated. The research was performed in the channels of rectangular cross-section and of dimensions: 15 x 0.65 mm and 7.5 x 0.73 mm. The experimental data were compared with the published criteria of the transitions between the patterns of two-phase flows.
Abstract: Polymer-like organic thin films were deposited on both
aluminum alloy type 6061 and glass substrates at room temperature by
Plasma Enhanced Chemical Vapor Deposition (PECVD) methodusing
benzene and hexamethyldisiloxane (HMDSO) as precursor materials.
The surface and physical properties of plasma-polymerized organic
thin films were investigated at different r.f. powers. The effects of
benzene/argon ratio on the properties of plasma polymerized benzene
films were also investigated. It is found that using benzene alone
results in a non-coherent and non-adherent powdery deposited
material. The chemical structure and surface properties of the asgrown
plasma polymerized thin films were analyzed on glass
substrates with FTIR and contact angle measurements. FTIR spectra
of benzene deposited film indicated that the benzene rings are
preserved when increasing benzene ratio and/or decreasing r.f.
powers. FTIR spectra of HMDSO deposited films indicated an
increase of the hydrogen concentration and a decrease of the oxygen
concentration with the increase of r.f. power. The contact angle (θ) of
the films prepared from benzene was found to increase by about 43%
as benzene ratio increases from 10% to 20%. θ was then found to
decrease to the original value (51°) when the benzene ratio increases
to 100%. The contact angle, θ, for both benzene and HMDSO
deposited films were found to increase with r.f. power. This signifies
that the plasma polymerized organic films have substantially low
surface energy as the r.f power increases. The corrosion resistance of
aluminum alloy substrate both bare and covered with plasma
polymerized thin films was carried out by potentiodynamic
polarization measurements in standard 3.5 wt. % NaCl solution at
room temperature. The results indicate that the benzene and HMDSO
deposited films are suitable for protection of the aluminum substrate
against corrosion. The changes in the processing parameters seem to
have a strong influence on the film protective ability. Surface
roughness of films deposited on aluminum alloy substrate was
investigated using scanning electron microscopy (SEM). The SEM
images indicate that the surface roughness of benzene deposited films
increase with decreasing the benzene ratio. SEM images of benzene
and HMDSO deposited films indicate that the surface roughness
decreases with increasing r.f. power. Studying the above parameters
indicate that the films produced are suitable for specific practical
applications.
Abstract: The carbon based coils with the nanometer scale have
the 3 dimension helix geometry. We synthesized the carbon nano-coils
by the use of chemical vapor deposition technique with iron and tin as
the catalysts. The fabricated coils have the external diameter of
ranging few hundred nm to few thousand nm. The Scanning
Electro-Microscope (SEM) and Tunneling Electro-Microscope has
shown detail images of the coil-s structure. The fabrication of the
carbon nano-coils can be grown on the metal and non-metal substrates,
such as the stainless steel and silicon substrates. Besides growth on the
flat substrate; they also can be grown on the stainless steel wires. After
the synthesis of the coils, the mechanical and electro-mechanical
property is measured. The experimental results were reported.
Abstract: Soursop (Anona muricata) is one of the underutilized tropical fruits containing nutrients, particularly dietary fibre and antioxidant properties that are beneficial to human health. This objective of this study is to investigate the feasibility of matured soursop pulp flour (SPF) to be substituted with high-protein wheat flour in bread. Bread formulation was substituted with different levels of SPF (0%, 5%, 10% and 15%). The effect on physicochemical properties and sensory attributes were evaluated. Higher substitution level of SPF resulted in significantly higher (p
Abstract: Simulations play a major role in education not only because they provide realistic models with which students can interact to acquire real world experiences, but also because they constitute safe environments in which students can repeat processes without any risk in order to perceive easier concepts and theories. Virtual reality is widely recognized as a significant technological advance that can facilitate learning process through the development of highly realistic 3D simulations supporting immersive and interactive features. The objective of this paper is to analyze the influence of virtual reality-s use in chemistry instruction as well as to present an integrated web-based learning environment for the simulation of chemical experiments. The proposed application constitutes a cost-effective solution for both schools and universities without appropriate infrastructure and a valuable tool for distance learning and life-long education in chemistry. Its educational objectives are the familiarization of students with the equipment of a real chemical laboratory and the execution of virtual volumetric analysis experiments with the active participation of students.
Abstract: The paper presents the results of theoretical and
numerical modeling of propagation of shock waves in bubbly liquids
related to nonlinear effects (realistic equation of state, chemical
reactions, two-dimensional effects). On the basis on the Rankine-
Hugoniot equations the problem of determination of parameters of
passing and reflected shock waves in gas-liquid medium for
isothermal, adiabatic and shock compression of the gas component is
solved by using the wide-range equation of state of water in the
analitic form. The phenomenon of shock wave intensification is
investigated in the channel of variable cross section for the
propagation of a shock wave in the liquid filled with bubbles
containing chemically active gases. The results of modeling of the
wave impulse impact on the solid wall covered with bubble layer are
presented.
Abstract: Owing to extensive use of hydrogen in refining or
petrochemical units, it is essential to manage hydrogen network in
order to make the most efficient utilization of hydrogen. On the other
hand, hydrogen is an important byproduct not properly used through
petrochemical complexes and mostly sent to the fuel system. A few
works have been reported in literature to improve hydrogen network
for petrochemical complexes. In this study a comprehensive analysis
is carried out on petrochemical units using a modified automated
targeting technique which is applied to determine the minimum
hydrogen consumption. Having applied the modified targeting
method in two petrochemical cases, the results showed a significant
reduction in required fresh hydrogen.
Abstract: Protein structure determination and prediction has
been a focal research subject in the field of bioinformatics due to the
importance of protein structure in understanding the biological and
chemical activities of organisms. The experimental methods used by
biotechnologists to determine the structures of proteins demand
sophisticated equipment and time. A host of computational methods
are developed to predict the location of secondary structure elements
in proteins for complementing or creating insights into experimental
results. However, prediction accuracies of these methods rarely
exceed 70%.
Abstract: Polystyrene particles of different sizes are optically
trapped with a gaussian beam from a He-Cd laser operating at 442
nm. The particles are observed to exhibit luminescence after a certain
trapping time followed by an escape from the optical trap. The
observed luminescence is explained in terms of the photodegradation
of the polystyrene backbone. It is speculated that these chemical
modifications also play a role for the escape of the particles from the
trap. Variations of the particle size and the laser power show that
these parameters have a great influence on the observed phenomena.
Abstract: This study was conducted to determine effect of water stress on chlorophyll content and chlorophyll fluorescence parameter in young `Dezful- olive trees. Three irrigation regimes (40% ETcrop, 65% ETcrop and 100% ETcrop) were used. After irrigation treatments were applied, some of biochemical parameters including chlorophyll a, b, total chlorophyll, chlorophyll fluorescence and also chlorophyll content index (C.C.I) were measured. Results of Analysis of variance showed that irrigation treatments had significant effect on chlorophylla, total chlorophyll (chl a+b), C.C.I and Fv/Fm ratio. The amount of decreased chlorophyll a and total chlorophyll in plants were received 40% ETcrop were 51.55% and 46.86%, respectively, compared with 100% ETcrop.
Abstract: The sonochemical decolorization and degradation of azo dye Methyl violet using Fenton-s reagent in the presence of a high-frequency acoustic field has been investigated. Dyeing and textile effluents are the major sources of azo dyes, and are most troublesome among industrial wastewaters, causing imbalance in the eco-system. The effect of various operating conditions (initial concentration of dye, liquid-phase temperature, ultrasonic power and frequency and process time) on sonochemical degradation was investigated. Conversion was found to increase with increase in initial concentration, temperature, power level and frequency. Both horntype and tank-type sonicators were used, at various power levels (250W, 400W and 500W) for frequencies ranging from 20 kHz - 1000 kHz. A 'Process Intensification' parameter PI, was defined to quantify the enhancement of the degradation reaction by ultrasound when compared to control (i.e., without ultrasound). The present work clearly demonstrates that a high-frequency ultrasonic bath can be used to achieve higher process throughput and energy efficiency at a larger scale of operation.