Abstract: Owing to the stringent environmental legislations,
CO2 capture and sequestration is one of the viable solutions to reduce
the CO2 emissions from various sources. In this context, Ionic liquids
(ILs) are being investigated as suitable absorption media for CO2
capture. Due to their non-evaporative, non-toxic, and non-corrosive
nature, these ILs have the potential to replace the existing solvents
like aqueous amine solutions for CO2 separation technologies. Thus,
the present work aims at studying the important aspects such as the
interactions of CO2 molecule with different anions (F-, Br-, Cl-, NO3
-,
BF4
-, PF6
-, Tf2N-, and CF3SO3
-) that are commonly used in ILs
through molecular modeling. In this, the minimum energy structures
have been obtained using Ab initio based calculations at MP2
(Moller-Plesset perturbation) level. Results revealed various degrees
of distortion of CO2 molecule (from its linearity) with the anions
studied, most likely due to the Lewis acid-base interactions between
CO2 and anion. Furthermore, binding energies for the anion-CO2
complexes were also calculated. The implication of anion-CO2
interactions to the solubility of CO2 in ionic liquids is also discussed.
Abstract: There is a general feeling that Internet crime is an
advanced type of crime that has not yet infiltrated developing
countries like Uganda. The carefree nature of the Internet in which
anybody publishes anything at anytime poses a serious security threat
for any nation. Unfortunately, there are no formal records about this
type of crime for Uganda. Could this mean that it does not exist
there? The author conducted an independent research to ascertain
whether cyber crimes have affected people in Uganda and if so, to
discover where they are reported. This paper highlights the findings.
Abstract: The batch nature limits the standard kernel principal component analysis (KPCA) methods in numerous applications, especially for dynamic or large-scale data. In this paper, an efficient adaptive approach is presented for online extraction of the kernel principal components (KPC). The contribution of this paper may be divided into two parts. First, kernel covariance matrix is correctly updated to adapt to the changing characteristics of data. Second, KPC are recursively formulated to overcome the batch nature of standard KPCA.This formulation is derived from the recursive eigen-decomposition of kernel covariance matrix and indicates the KPC variation caused by the new data. The proposed method not only alleviates sub-optimality of the KPCA method for non-stationary data, but also maintains constant update speed and memory usage as the data-size increases. Experiments for simulation data and real applications demonstrate that our approach yields improvements in terms of both computational speed and approximation accuracy.
Abstract: Phylogenetic tree is a graphical representation of the
evolutionary relationship among three or more genes or organisms.
These trees show relatedness of data sets, species or genes
divergence time and nature of their common ancestors. Quality of a
phylogenetic tree requires parsimony criterion. Various approaches
have been proposed for constructing most parsimonious trees. This
paper is concerned about calculating and optimizing the changes of
state that are needed called Small Parsimony Algorithms. This paper
has proposed enhanced small parsimony algorithm to give better
score based on number of evolutionary changes needed to produce
the observed sequence changes tree and also give the ancestor of the
given input.
Abstract: Complexity, as a theoretical background has made it
easier to understand and explain the features and dynamic behavior
of various complex systems. As the common theoretical background
has confirmed, borrowing the terminology for design from the
natural sciences has helped to control and understand urban
complexity. Phenomena like self-organization, evolution and
adaptation are appropriate to describe the formerly inaccessible
characteristics of the complex environment in unpredictable bottomup
systems. Increased computing capacity has been a key element in
capturing the chaotic nature of these systems.
A paradigm shift in urban planning and architectural design has
forced us to give up the illusion of total control in urban
environment, and consequently to seek for novel methods for
steering the development. New methods using dynamic modeling
have offered a real option for more thorough understanding of
complexity and urban processes. At best new approaches may renew
the design processes so that we get a better grip on the complex
world via more flexible processes, support urban environmental
diversity and respond to our needs beyond basic welfare by liberating
ourselves from the standardized minimalism.
A complex system and its features are as such beyond human
ethics. Self-organization or evolution is either good or bad. Their
mechanisms are by nature devoid of reason. They are common in
urban dynamics in both natural processes and gas. They are features
of a complex system, and they cannot be prevented. Yet their
dynamics can be studied and supported.
The paradigm of complexity and new design approaches has been
criticized for a lack of humanity and morality, but the ethical
implications of scientific or computational design processes have not
been much discussed. It is important to distinguish the (unexciting)
ethics of the theory and tools from the ethics of computer aided
processes based on ethical decisions. Urban planning and architecture
cannot be based on the survival of the fittest; however, the natural
dynamics of the system cannot be impeded on grounds of being
“non-human".
In this paper the ethical challenges of using the dynamic models
are contemplated in light of a few examples of new architecture and
dynamic urban models and literature. It is suggested that ethical
challenges in computational design processes could be reframed
under the concepts of responsibility and transparency.
Abstract: The AL-MAJIRI school system is a variant of private
Arabic and Islamic schools which cater for the religious and moral development of Muslims. In the past, the system produced clerics,
scholars, judges, religious reformers, eminent teachers and great men who are worthy of emulation, particularly in northern Nigeria.
Gradually, the system lost its glory but continued to discharge its
educational responsibilities to a certain extent. This paper takes a
look at the activities of the AL-MAJIRI schools. The introduction
provides background information about Nigeria where the schools
operate. This is followed by an overview of the Nigerian educational system, the nature and the features of the AL-MAJIRI school system,
its weaknesses and the current challenges facing the schools. The paper concludes with emphasis on the urgent need for a comprehensive reform of the curriculum content of the schools. The step by step procedure required for the reform is discussed.
Abstract: Synthesis gas manufacturing by steam reforming of hydrocarbons is an important industrial process. High endothermic nature of the process makes it one of the most cost and heat intensive processes. In the present work, composite effect of different inert gases on synthesis gas yield, feed gas conversion and temperature distribution along the reactor length has been studied using a heterogeneous model. Mathematical model was developed as a first stage and validated against the existing process models. With the addition of inert gases, a higher yield of synthesis gas is observed. Simultaneously the rector outlet temperature drops to as low as 810 K. It was found that Xenon gives the highest yield and conversion while Helium gives the lowest temperature. Using Xenon inert gas 20 percent reduction in outlet temperature was observed compared to traditional case.
Abstract: As a result of urbanization, the unpredictable growth of industry and transport, production of chemicals, military activities, etc. the concentration of anthropogenic toxicants spread in nature exceeds all the permissible standards. Most dangerous among these contaminants are organic compounds having great persistence, bioaccumulation, and toxicity along with our awareness of their prominent occurrence in the environment and food chain. Among natural ecological tools, plants still occupying above 40% of the world land, until recently, were considered as organisms having only a limited ecological potential, accumulating in plant biomass and partially volatilizing contaminants of different structure. However, analysis of experimental data of the last two decades revealed the essential role of plants in environment remediation due to ability to carry out intracellular degradation processes leading to partial or complete decomposition of carbon skeleton of different structure contaminants. Though, phytoremediation technologies still are in research and development, their various applications have been successfully used. The paper aims to analyze mechanisms of organic contaminants uptake and detoxification in plants, being the less studied issue in evaluation and exploration of plants potential for environment remediation.
Abstract: Thanks to the interdisciplinary nature of crises, the
position of researchers in that field is rather difficult. Very often the
traditional methods of research cannot be applied there. The article is
aimed at the changes in crises research. It describes the substance of
individual changes and emphasizes the shift in research approaches
to the crisis.
Abstract: In two studies we tested the hypothesis that the
appropriate linguistic formulation of a deontic rule – i.e. the
formulation which clarifies the monadic nature of deontic operators
- should produce more correct responses than the conditional
formulation in Wason selection task. We tested this assumption by
presenting a prescription rule and a prohibition rule in conditional
vs. proper deontic formulation. We contrasted this hypothesis with
two other hypotheses derived from social contract theory and
relevance theory. According to the first theory, a deontic rule
expressed in terms of cost-benefit should elicit a cheater detection
module, sensible to mental states attributions and thus able to
discriminate intentional rule violations from accidental rule
violations. We tested this prevision by distinguishing the two types
of violations. According to relevance theory, performance in
selection task should improve by increasing cognitive effect and
decreasing cognitive effort. We tested this prevision by focusing
experimental instructions on the rule vs. the action covered by the
rule. In study 1, in which 480 undergraduates participated, we
tested these predictions through a 2 x 2 x 2 x 2 (type of the rule x
rule formulation x type of violation x experimental instructions)
between-subjects design. In study 2 – carried out by means of a 2 x
2 (rule formulation x type of violation) between-subjects design -
we retested the hypothesis of rule formulation vs. the cheaterdetection
hypothesis through a new version of selection task in
which intentional vs. accidental rule violations were better
discriminated. 240 undergraduates participated in this study.
Results corroborate our hypothesis and challenge the contrasting
assumptions. However, they show that the conditional formulation
of deontic rules produces a lower performance than what is
reported in literature.
Abstract: Data stream analysis is the process of computing
various summaries and derived values from large amounts of data
which are continuously generated at a rapid rate. The nature of a
stream does not allow a revisit on each data element. Furthermore,
data processing must be fast to produce timely analysis results. These
requirements impose constraints on the design of the algorithms to
balance correctness against timely responses. Several techniques
have been proposed over the past few years to address these
challenges. These techniques can be categorized as either dataoriented
or task-oriented. The data-oriented approach analyzes a
subset of data or a smaller transformed representation, whereas taskoriented
scheme solves the problem directly via approximation
techniques. We propose a hybrid approach to tackle the data stream
analysis problem. The data stream has been both statistically
transformed to a smaller size and computationally approximated its
characteristics. We adopt a Monte Carlo method in the approximation
step. The data reduction has been performed horizontally and
vertically through our EMR sampling method. The proposed method
is analyzed by a series of experiments. We apply our algorithm on
clustering and classification tasks to evaluate the utility of our
approach.
Abstract: This paper presents a new spread-spectrum
watermarking algorithm for digital images in discrete wavelet
transform (DWT) domain. The algorithm is applied for embedding
watermarks like patient identification /source identification or
doctors signature in binary image format into host digital
radiological image for potential telemedicine applications.
Performance of the algorithm is analysed by varying the gain factor,
subband decomposition levels, and size of watermark. Simulation
results show that the proposed method achieves higher watermarking
capacity.
Abstract: Proteins levels produced by bacteria may be increased
in stressful surroundings, such as in the presence of antibiotics. It
appears that many antimicrobial agents or antibiotics, when used at
low concentrations, have in common the ability to activate or repress
gene transcription, which is distinct from their inhibitory effect.
There have been comparatively few studies on the potential of
antibiotics or natural compounds in nature as a specific chemical
signal that can trigger a variety of biological functions. Therefore,
this study was focusing on the effect of essential oils from
Cymbopogon flexuosus and C. nardus in regulating proteins
production by Bacillus subtilis ATCC 21332. The Minimum
Inhibition Concentrations (MICs) of both essential oils on B. subtilis
were determined by using microdilution assay, resulting 0.2% and
1.56% for each C. flexuosus and C. nardus subsequently. The
bacteria were further exposed to each essential oils at concentration
of 0.01XMIC for 2 days. The proteins were then isolated and
analyzed by sodium dodecyl sulfate polyacrylamide gel
electrophoresis (SDS-PAGE). Protein profile showed that a band
with approximate size of 250 kD was appeared for the treated
bacteria with essential oils. Thus, Bacillus subtilis ATCC 21332 in
stressful condition with the presence of essential oils at low
concentration could induce the protein production.
Abstract: The Elliptic Curve Digital Signature Algorithm
(ECDSA) is the elliptic curve analogue of DSA, where it is a digital
signature scheme designed to provide a digital signature based on a
secret number known only to the signer and also on the actual
message being signed. These digital signatures are considered the
digital counterparts to handwritten signatures, and are the basis for
validating the authenticity of a connection. The security of these
schemes results from the infeasibility to compute the signature
without the private key. In this paper we introduce a proposed to
development the original ECDSA with more complexity.
Abstract: Recently, a growing interest has emerged on the
development of new and efficient energy sources, due to the inevitable extinction of the nonrenewable energy reserves. One of
these alternative sources which has a great potential and sustainability to meet up the energy demand is biomass energy. This
significant energy source can be utilized with various energy
conversion technologies, one of which is biomass gasification in
supercritical water.
Water, being the most important solvent in nature, has very important characteristics as a reaction solvent under supercritical
circumstances. At temperatures above its critical point (374.8oC and
22.1 MPa), water becomes more acidic and its diffusivity increases.
Working with water at high temperatures increases the thermal
reaction rate, which in consequence leads to a better dissolving of the
organic matters and a fast reaction with oxygen. Hence, supercritical water offers a control mechanism depending on solubility, excellent
transport properties based on its high diffusion ability and new reaction possibilities for hydrolysis or oxidation.
In this study the gasification of a real biomass, namely olive mill
wastewater (OMW), in supercritical water is investigated with the
use of Pt/Al2O3 and Ni/Al2O3 catalysts. OMW is a by-product
obtained during olive oil production, which has a complex nature
characterized by a high content of organic compounds and
polyphenols. These properties impose OMW a significant pollution
potential, but at the same time, the high content of organics makes
OMW a desirable biomass candidate for energy production.
All of the catalytic gasification experiments were made with five
different reaction temperatures (400, 450, 500, 550 and 600°C),
under a constant pressure of 25 MPa. For the experiments conducted
with Ni/Al2O3 catalyst, the effect of five reaction times (30, 60, 90,
120 and 150 s) was investigated. However, procuring that similar
gasification efficiencies could be obtained at shorter times, the experiments were made by using different reaction times (10, 15, 20,
25 and 30 s) for the case of Pt/Al2O3 catalyst. Through these experiments, the effects of temperature, time and catalyst type on the
gasification yields and treatment efficiencies were investigated.
Abstract: Due to the non- intuitive nature of Quantum
algorithms, it becomes difficult for a classically trained person to
efficiently construct new ones. So rather than designing new
algorithms manually, lately, Genetic algorithms (GA) are being
implemented for this purpose. GA is a technique to automatically
solve a problem using principles of Darwinian evolution. This has
been implemented to explore the possibility of evolving an n-qubit
circuit when the circuit matrix has been provided using a set of
single, two and three qubit gates. Using a variable length population
and universal stochastic selection procedure, a number of possible
solution circuits, with different number of gates can be obtained for
the same input matrix during different runs of GA. The given
algorithm has also been successfully implemented to obtain two and
three qubit Boolean circuits using Quantum gates. The results
demonstrate the effectiveness of the GA procedure even when the
search spaces are large.
Abstract: Nowadays over-consumption of fossil energy in
buildings especially in residential buildings and also considering the
increase in populations, the crisis of energy shortage in a near future
is predictable. The recent performance of developed countries in
construction with the aim of decreasing fossil energies shows that
these countries have understood the incoming crisis and has taken
reasonable and basic actions in this regard. However, Iranian
architecture, with several thousands years of history, has acquired
and executed invaluable experiences in designing, adapting and
coordinating with the nature.
Architectural studies during the recent decades show that imitating
modern western architecture results in high energy wastage beside
the fact that it not reasonably adaptable and corresponded with the
habits and customs of people unlike the architecture in the past which
was compatible and adaptable with the climatic conditions and this
necessitates optimal using of renewable energies more than ever. This
paper studies problems of design, execution and living in today's
houses and reviews the characteristics of climatic elements paying
special attention to the performance of trombe wall and solar
greenhouse in traditional houses and offers some suggestions for
combining these two elements and a climatic strategy.
Abstract: The knowledge of the nature of loading is very
important in order to hold account on the total behavior such as
vibration, shock, fatigue, etc. Fatigue present 90% of failure when
loadings fatigues are very complex. In this paper a study of double
through crack at hole for plate subjected to fatigue loading is
presented. Various modes loading are studied where the applied load
is the same one. The fatigue life is given where the effect of stress
ratio is highlighted. This work is conducted on aluminum alloy 2024
T351 used for much aerospace and aeronautics applications. The
fatigue crack growth behavior with constant amplitude is studied
using the AFGROW code when Forman model is applied. The
fatigue crack growth rate and fatigue life for different loading modes
are compared with variation of others geometrical parameter such as
thickness and dimensions of notch hole.
Abstract: Optical emission based on excitonic scattering processes becomes important in dense exciton systems in which the average distance between excitons is of the order of a few Bohr radii but still below the exciton screening threshold. The phenomena due to interactions among excited states play significant role in the emission near band edge of the material. The theory of two-exciton collisions for GaAs/AlGaAs quantum well systems is a mild attempt to understand the physics associated with the optical spectra due to excitonic scattering processes in these novel systems. The four typical processes considered give different spectral shape, peak position and temperature dependence of the emission spectra. We have used the theory of scattering together with the second order perturbation theory to derive the radiative power spontaneously emitted at an energy ħω by these processes. The results arrived at are purely qualitative in nature. The intensity of emitted light in quantum well systems varies inversely to the square of temperature, whereas in case of bulk materials it simply decreases with the temperature.
Abstract: This research work is concerned with the eigenvalue problem for the integral operators which are obtained by linearization of a nonlocal evolution equation. The purpose of section II.A is to describe the nature of the problem and the objective of the project. The problem is related to the “stable solution" of the evolution equation which is the so-called “instanton" that describe the interface between two stable phases. The analysis of the instanton and its asymptotic behavior are described in section II.C by imposing the Green function and making use of a probability kernel. As a result , a classical Theorem which is important for an instanton is proved. Section III devoted to a study of the integral operators related to interface dynamics which concern the analysis of the Cauchy problem for the evolution equation with initial data close to different phases and different regions of space.