Abstract: We have aimed to produce a self-cleaning transparent
polymer coating with polyurethane (PU) matrix as the latter is highly
solvent, chemical and weather resistant having good mechanical
properties. Nano-silica modified by 1H, 1H, 2H, 2Hperflurooctyltriethoxysilane
was incorporated into the PU matrix for
attaining self-cleaning ability through hydrophobicity. The
modification was confirmed by particle size analysis and scanning
electron microscopy (SEM). Thermo-gravimetric (TGA) studies were
carried to ascertain the grafting of silane onto the silica. Several
coating formulations were prepared by varying the silica loading
content and compared to a commercial equivalent. The effect of
dispersion and the morphology of the coated films were assessed by
SEM analysis. All coating standardized tests like solvent resistance,
adhesion, flexibility, acid, alkali, gloss etc. have been performed as
per ASTM standards. Water contact angle studies were conducted to
analyze the hydrophobic character of the coating. In addition, the
coatings were also subjected to salt spray and accelerated weather
testing to analyze the durability of the coating.
Abstract: The purpose of the research described in this work is
to answer how to measure the rheologic (viscoelastic) properties
tendo–deformational characteristics of soft tissue. The method would
also resemble muscle palpation examination as it is known in clinical
practice. For this purpose, an instrument with the working name
“myotonometer” has been used. At present, there is lack of objective methods for assessing the
muscle tone by viscous and elastic properties of soft tissue. That is
why we decided to focus on creating or finding quantitative and
qualitative methodology capable to specify muscle tone.
Abstract: The rheological response of blends obtained from
quaternized polysulfone and polyvinyl alcohol in N-methyl-2-
pyrrolidone as against structural peculiarity of polymers from the
blend, composition of polymer mixtures, as well as the types of
interactions were investigated. Results show that the variation of
polyvinyl alcohol composition in the studied system determines
changes of the rheological properties, suggesting that the PVA acts as
a plasticizer. Consequently, rheological behavior of complex system,
described by the nonlinear flow curve, indicates the impact of
polyvinil alcohol content to polysulfone solution, in order to facilitate
the subsequently preparation of bioactive membranes.
Abstract: A 15-storey RC building, studied in this paper, is
representative of modern building type constructed in Madina City in
Saudi Arabia before 10 years ago. These buildings are almost
consisting of reinforced concrete skeleton i.e. columns, beams and
flat slab as well as shear walls in the stairs and elevator areas
arranged in the way to have a resistance system for lateral loads
(wind – earthquake loads). In this study, the dynamic properties of
the 15-storey RC building were identified using ambient motions
recorded at several, spatially-distributed locations within each
building. Three dimensional pushover analysis (Nonlinear static
analysis) was carried out using SAP2000 software incorporating
inelastic material properties for concrete, infill and steel. The effect
of modeling the building with and without infill walls, on the
performance point as well as capacity and demand spectra due to EQ
design spectrum function in Madina area has been investigated. ATC-
40 capacity and demand spectra are utilized to get the modification
factor (R) for the studied building. The purpose of this analysis is to
evaluate the expected performance of structural systems by
estimating, strength and deformation demands in design, and
comparing these demands to available capacities at the performance
levels of interest. The results are summarized and discussed.
Abstract: Electro-osmosis in clayey soils and sediments, for
purposes of clay consolidation, dewatering, or cleanup, and electro
injection in porous media is widespread recent decades. It is
experimentally found that the chemical properties of porous media
especially PH change the characteristics of media. Electro-osmotic
conductivity is a function of soil and grout material chemistry,
altering with time. Many numerical approaches exist to simulate the
of electro kinetic flow rate considering chemical changes. This paper
presents a simplified analytical solution for constant flow rate based
on varying electro osmotic conductivity and time dependent viscosity
for injection of colloidal silica.
Abstract: Energy has a prominent role for development of
nations. Countries which have energy resources also have strategic
power in the international trade of energy since it is essential for all
stages of production in the economy. Thus, it is important for
countries to analyze the weaknesses and strength of the system. On
the other side, international trade is one of the fields that are analyzed
as a complex network via network analysis. Complex network is one
of the tools to analyze complex systems with heterogeneous agents
and interaction between them. A complex network consists of nodes
and the interactions between these nodes. Total properties which
emerge as a result of these interactions are distinct from the sum of
small parts (more or less) in complex systems. Thus, standard
approaches to international trade are superficial to analyze these
systems. Network analysis provides a new approach to analyze
international trade as a network. In this network, countries constitute
nodes and trade relations (export or import) constitute edges. It
becomes possible to analyze international trade network in terms of
high degree indicators which are specific to complex networks such
as connectivity, clustering, assortativity/disassortativity, centrality,
etc. In this analysis, international trade of crude oil and coal which
are types of fossil fuel has been analyzed from 2005 to 2014 via
network analysis. First, it has been analyzed in terms of some
topological parameters such as density, transitivity, clustering etc.
Afterwards, fitness to Pareto distribution has been analyzed via
Kolmogorov-Smirnov test. Finally, weighted HITS algorithm has
been applied to the data as a centrality measure to determine the real
prominence of countries in these trade networks. Weighted HITS
algorithm is a strong tool to analyze the network by ranking countries
with regards to prominence of their trade partners. We have
calculated both an export centrality and an import centrality by
applying w-HITS algorithm to the data. As a result, impacts of the
trading countries have been presented in terms of high-degree
indicators.
Abstract: The study assessed the effectiveness of Pawpaw
(Carica papaya) wood in reducing the concentrations of heavy
metals in wastewater acting as a bio-sorbent. The following heavy
metals were considered; Zinc, Cadmium, Lead, Copper, Iron,
Selenium, Nickel and Manganese. The physiochemical properties of
Carica papaya stem were studied. The experimental sample was
sourced from the trunk of a felled matured pawpaw tree. Wastewater
for experimental use was prepared by dissolving soil samples
collected from a dump site at Owerri, Imo state of Nigeria in water.
The concentration of each metal remaining in solution as residual
metal after bio-sorption was determined using Atomic absorption
Spectrometer. The effects of pH and initial heavy metal concentration
were studied in a batch reactor. The results of Spectrometer test
showed that there were different functional groups detected in the
Carica papaya stem biomass. There was increase in metal removal as
the pH increased for all the metals considered except for Nickel and
Manganese. Optimum bio-sorption occurred at pH 5.9 with 5g/100ml
solution of bio-sorbent. The results of the study showed that the
treated wastewater is fit for irrigation purpose based on Canada
wastewater quality guideline for the protection of Agricultural
standard. This approach thus provides a cost effective and
environmentally friendly option for treating wastewater.
Abstract: This work aims to investigate the structure–property
relationship in ternary nanocomposites consisting of polypropylene
as the matrix, polyamide 66 as the minor phase and treated nanoclay
DELLITE 67G as the reinforcement. All PP/PA66/Nanoclay systems
with polypropylene grafted maleic anhydride PP-g-MAH as a
compatibilizer were prepared via melt compounding and
characterized in terms of nanoclay content. Morphological structure
was investigated by scanning electron microscopy. The rheological
behavior of the nanocomposites was determined by various methods,
viz melt flow index (MFI) and parallel plate rheological
measurements. The PP/PP-g-MAH/PA66 nanocomposites showed a homogeneous
morphology supporting the compatibility improvement between PP,
PA66, and nanoclay. SEM results revealed the formation of
nanocomposites as the nanoclay was intercalated and exfoliated. In
the ternary nanocomposites, the rheological behavior showed that, the
complex viscosity is increased with increasing the nanoclay. The results showed that the use of nanoclay affects the variations
of storage modulus (G′), loss modulus (G″) and the melt elasticity.
Abstract: This paper presents the effects of mixing procedures
on mechanical properties of flyash-based geopolymer matrices
containing nanosilica (NS) at 0.5%, 1.0%, 2.0%, and 3.0% by weight.
Comparison is made with conventional mechanical dry-mixing of NS
with flyash and wet-mixing of NS in alkaline solutions. Physical and
mechanical properties are investigated using X-Ray Diffraction
(XRD) and Scanning Electron Microscope (SEM). Results show that
generally the addition of NS particles enhanced the microstructure
and improved flexural and compressive strengths of geopolymer
nanocomposites. However, samples, prepared using dry-mixing
approach, demonstrate better physical and mechanical properties
comparing to wet-mixing samples.
Abstract: Low density polyethylene (LDPE) nanocomposites
with 3, 5 and 7 wt. % cobalt ferrite (CoFe2O4) nanopowder fabricated
with extrusion mixing and followed up by hot press to reach compact
samples. The transmission/reflection measurements were carried out
with a network analyzer in the frequency range of 8-12 GHz. By
increasing the percent of CoFe2O4 nanopowder, reflection loss (S11)
increases, while transferring loss (S21) decreases. Reflectivity (R)
calculations made using S11 and S21. Increase in percent of CoFe2O4
nanopowder up to 7 wt. % in composite leaded to higher reflectivity
amount, and revealed that increasing the percent of CoFe2O4
nanopowder up to 7 wt. % leads to further microwave absorption in
8-12 GHz range.
Abstract: Despite the wide spread use of synthetic dyes, natural
dyes are still exploited and used to enhance its inherent aesthetic
qualities as a major material for beautification of the body. Centuries
before the discovery of synthetic dyes, natural dyes were the only
source of dye open to mankind. Dyes are extracted from plant -
leaves, roots and barks, insect secretions, and minerals. However,
research findings have made it clear that of all, plants- leaves, roots,
barks or flowers are the most explored and exploited in which henna
(Lawsonia innermis L.) is one of those plants. Experiment has also
shown that henna is used in body painting in conjunction with an
alkaline (Ammonium Sulphate) as a fixing agent. This of course
gives a clue that if colour derived from henna is properly
investigated, it may not only be used for body decoration but
possibly, may have affinity to fiber substrate. This paper investigates
the dyeing potentials – dye ability and fastness qualities of henna dye
extracts on cotton and linen fibers using mordants like ammonium
sulphate and other alkalis (hydrosulphate and caustic soda, potash,
common salt, potassium alum). Hot and cold water and ethanol
solvent were used in the extraction of the dye to investigate the most
effective method, dye ability, and fastness qualities of these extracts
under room temperature. The results of the experiment show that
cotton have a high rate of dye intake than other fiber. On a similar
note, the colours obtained depend most on the solvent used. In
conclusion, hot water extraction appears more effective. While the
colours obtained from ethanol and both cold hot methods of
extraction range from light to dark yellow, light green to army green
and to some extent shades of brown hues.
Abstract: This research work is an experimental study, through
development of an adhesive from Prosopis africana endosperm. The
prosopis seed for this work were obtained from Enugu State in the
South East part of Nigeria. The seeds were prepared by separating the
endosperm from the seed coat and cotyledon. Three methods were
used to separate them, which are acidic method, roasting method and
boiling method. 20g of seed were treated with different
concentrations (25, 40, 55, 70, and 85% w/w) at 100°C and constant
time (30 minutes), under continuous stirring with magnetic stirrer.
Also 20g of seed were treated with sulphuric acid of concentrations
40% w/w at 100°C with different time (10, 15, 20, 25, 30 minutes),
under continuous stirring with magnetic stirrer. Finally, 20g of seed
were treated with sulphuric acid of concentrations 40% w/w at
different temperature (20°C, 40°C, 60°C, 80°C, and 100°C) with
constant time (30 minutes), under continuous stirring with magnetic
stirrer. The whole endosperm extracted was adhesive. The physical
properties of the adhesive were determined (appearance, odour, taste,
solubility, pH, size, and binding strength). The percentage of the
adhesive yield makes the commercialization of the seed in Nigeria
possible and profitable. The very high viscosity attained at low
concentrations makes prosopis adhesive an excellent thickener in the
food industry.
Abstract: In India, most of the pavement is laid by bituminous
road and the consumption of binder is high for pavement construction
and also modified binders are used to satisfy any specific pavement
requirement. Since the binders are visco-elastic material which is
having the mechanical properties of binder transition from viscoelastic
solid to visco-elastic fluid. In this paper, two different
protocols were used to measure the viscosity property of binder using
a Brookfield Viscometer and there is a need to find the appropriate
mixing and compaction temperatures of various types of binders
which can result in complete aggregate coating and adequate field
density of HMA mixtures. The aim of this work is to find the
transition temperature from Non-Newtonian behavior to Newtonian
behavior of the binder by adopting a steady shear protocol and the
shear rate ramp protocol. The transition from non-Newtonian to
Newtonian can occur through an increase of temperature and shear of
the material. The test has been conducted for unmodified binder VG
30. The transition temperature was found in the unmodified binder
VG is 120oC. Therefore, the application of both modified binder and
unmodified binder in the pavement construction needs to be studied
properly by considering temperature and traffic loading factors of the
respective project site.
Abstract: The statistical study has become indispensable for various fields of knowledge. Not any different, in Geotechnics the study of probabilistic and statistical methods has gained power considering its use in characterizing the uncertainties inherent in soil properties. One of the situations where engineers are constantly faced is the definition of a probability distribution that represents significantly the sampled data. To be able to discard bad distributions, goodness-of-fit tests are necessary. In this paper, three non-parametric goodness-of-fit tests are applied to a data set computationally generated to test the goodness-of-fit of them to a series of known distributions. It is shown that the use of normal distribution does not always provide satisfactory results regarding physical and behavioral representation of the modeled parameters.
Abstract: In this paper, a linear mixed model which has two
random effects is broken up into two models. This thesis gets
the parameter estimation of the original model and an estimation’s
statistical qualities based on these two models. Then many important
properties are given by comparing this estimation with other general
estimations. At the same time, this paper proves the analysis of
variance estimate (ANOVAE) about σ2 of the original model is equal
to the least-squares estimation (LSE) about σ2 of these two models.
Finally, it also proves that this estimation is better than ANOVAE
under Stein function and special condition in some degree.
Abstract: Lightweight and efficient structures have the aim to
enhance the efficiency of the components in various industries.
Toward this end, composites are one of the most widely used
materials because of durability, high strength and modulus, and low
weight. One type of the advanced composites is grid-stiffened
composite (GSC) structures, which have been extensively considered
in aerospace, automotive, and aircraft industries. They are one of the
top candidates for replacing some of the traditional components,
which are used here. Although there are a good number of published
surveys on the design aspects and fabrication of GSC structures, little
systematic work has been reported on their material modification to
improve their properties, to our knowledge. Matrix modification
using nanoparticles is an effective method to enhance the flexural
properties of the fibrous composites. In the present study, a silanecoupling
agent (3-glycidoxypropyltrimethoxysilane/3-GPTS) was
introduced onto the silica (SiO2) nanoparticle surface and its effects
on the three-point flexural response of isogrid E-glass/epoxy
composites were assessed. Based on the Fourier Transform Infrared
Spectrometer (FTIR) spectra, it was inferred that the 3-GPTS
coupling agent was successfully grafted onto the surface of SiO2
nanoparticles after modification. Flexural test revealed an
improvement of 16%, 14%, and 36% in stiffness, maximum load and
energy absorption of the isogrid specimen filled with 3 wt.% 3-
GPTS/SiO2 compared to the neat one. It would be worth mentioning
that in these structures, considerable energy absorption was observed
after the primary failure related to the load peak. In addition, 3-
GPTMS functionalization had a positive effect on the flexural
behavior of the multiscale isogrid composites. In conclusion, this
study suggests that the addition of modified silica nanoparticles is a
promising method to improve the flexural properties of the gridstiffened
fibrous composite structures.
Abstract: Mineral product, waste concrete (fine aggregates),
waste in the optical field, industry, and construction employ separators
to separate solids and classify them according to their size. Various
sorting machines are used in the industrial field such as those operating
under electrical properties, centrifugal force, wind power, vibration,
and magnetic force. Study on separators has been carried out to
contribute to the environmental industry. In this study, we perform
CFD analysis for understanding the basic mechanism of the separation
of waste concrete (fine aggregate) particles from air with a machine
built with a rotor with blades. In CFD, we first performed
two-dimensional particle tracking for various particle sizes for the
model with 1 degree, 1.5 degree, and 2 degree angle between each
blade to verify the boundary conditions and the method of rotating
domain method to be used in 3D. Then we developed 3D numerical
model with ANSYS CFX to calculate the air flow and track the
particles. We judged the capability of particle separation for given size
by counting the number of particles escaping from the domain toward
the exit among 10 particles issued at the inlet. We confirm that
particles experience stagnant behavior near the exit of the rotating
blades where the centrifugal force acting on the particles is in balance
with the air drag force. It was also found that the minimum particle
size that can be separated by the machine with the rotor is determined
by its capability to stay at the outlet of the rotor channels.
Abstract: In this paper, we discuss some properties of left
spectrum and give the representation of linear preserver map the left
spectrum of diagonal quaternionic matrices.
Abstract: This experimental study consists of a characterization
of epoxy grout where an amount of 2% of graphene nanoplatelets
particles were added to commercial epoxy resin to evaluate their
behavior regarding neat epoxy resin. Compressive tests, tensile tests
and flexural tests were conducted to study the effect of graphene
nanoplatelets on neat epoxy resin. By comparing graphene-based and
neat epoxy grout, there is no significant increase of strength due to
weak interface in the graphene nanoplatelets/epoxy composites.
From this experiment, the tension and flexural strength of graphenebased
epoxy grouts is slightly lower than ones of neat epoxy grout.
Nevertheless, the addition of graphene has produced more consistent
results according to a smaller standard deviation of strength.
Furthermore, the graphene has also improved the ductility of the
grout, hence reducing its brittle behaviour. This shows that the
performance of graphene-based grout is reliably predictable and able
to minimise sudden rupture. This is important since repair design of
damaged pipeline is of deterministic nature.
Abstract: Hard coatings are widely used in cutting and forming
tool industries. Titanium Nitride (TiN) possesses good hardness,
strength, and corrosion resistance. The coating properties are
influenced by many process parameters. The coatings were deposited
on steel substrate by changing the process parameters such as
substrate temperature, nitrogen flow rate and target power in a D.C
planer magnetron sputtering. The structure of coatings were analysed
using XRD. The hardness of coatings was found using Micro
hardness tester. From the experimental data, a regression model was
developed and the optimum response was determined using Response
Surface Methodology (RSM).