Abstract: This paper presents results of compressive strength,
capillary water absorption, and density tests conducted on concrete
containing recycled aggregate (RCA) which is obtained from
structural waste generated by the construction industry in Turkey. In
the experiments, 0%, 15%, 30%, 45% and 60% of the normal
(natural) coarse aggregate was replaced by the recycled aggregate.
Maximum aggregate particle sizes were selected as 16 mm, 22,4 mm
and 31,5 mm; and 0,06%, 0,13% and 0,20% of air-entraining agent
(AEA) were used in mixtures. Fly ash and superplasticizer were used
as a mineral and chemical admixture, respectively. The same type
(CEM I 42.5) and constant dosage of cement were used in the study.
Water/cement ratio was kept constant as 0.53 for all mixture. It was
concluded that capillary water absorption, compressive strength, and
density of concrete decreased with increasing RCA ratio. Increasing
in maximum aggregate particle size and amount of AEA also affect
the properties of concrete significantly.
Abstract: Elastomeric polymer foam has been used widely in
the automotive industry, especially for isolating unwanted vibrations.
Such material is able to absorb unwanted vibration due to its
combination of elastic and viscous properties. However, the ‘creep
effect’, poor stress distribution and susceptibility to high
temperatures are the main disadvantages of such a system.
In this study, improvements in the performance of elastomeric
foam as a vibration isolator were investigated using the concept of
Foam Filled Fluid (FFFluid). In FFFluid devices, the foam takes the
form of capsule shapes, and is mixed with viscous fluid, while the
mixture is contained in a closed vessel. When the FFFluid isolator is
affected by vibrations, energy is absorbed, due to the elastic strain of
the foam. As the foam is compressed, there is also movement of the
fluid, which contributes to further energy absorption as the fluid
shears. Also, and dependent on the design adopted, the packaging
could also attenuate vibration through energy absorption via friction
and/or elastic strain.
The present study focuses on the advantages of the FFFluid
concept over the dry polymeric foam in the role of vibration isolation.
This comparative study between the performance of dry foam and the
FFFluid was made according to experimental procedures. The paper
concludes by evaluating the performance of the FFFluid isolator in
the suspension system of a light vehicle. One outcome of this
research is that the FFFluid may preferable over elastomer isolators
in certain applications, as it enables a reduction in the effects of high
temperatures and of ‘creep effects’, thereby increasing the reliability
and load distribution. The stiffness coefficient of the system has
increased about 60% by using an FFFluid sample. The technology
represented by the FFFluid is therefore considered by this research
suitable for application in the suspension system of a light vehicle.
Abstract: Ant Colony Optimization (ACO) is a promising
modern approach to the unused combinatorial optimization. Here
ACO is applied to finding the shortest during communication link
failure. In this paper, the performances of the prim’s and ACO
algorithm are made. By comparing the time complexity and program
execution time as set of parameters, we demonstrate the pleasant
performance of ACO in finding excellent solution to finding shortest
path during communication link failure.
Abstract: Food poisoning and infection by bacteria are of public
health significance to both developing and developed countries.
Samples of ogi (akamu) prepared from white and yellow variety of
maize sold in Uturu and Okigwe were analyzed together with the
laboratory prepared ogi for bacterial quality using the standard
microbiological methods. The analyses showed that both white and
yellow variety had total bacterial counts (cfu/g) of 4.0 ×107 and 3.9 x
107 for the laboratory prepared ogi while the commercial ogi had 5.2
x 107 and 4.9 x107, 4.9 x107 and 4.5 x107, 5.4 x107 and 5.0 x107 for
Eke-Okigwe, Up-gate and Nkwo-Achara market respectively. The
Staphylococcal counts ranged from 2.0 x 102 to 5.0 x102 and 1.0 x
102 to 4.0 x102 for the white and yellow variety from the different
markets while Staphylococcal growth was not recorded on the
laboratory prepared ogi. The laboratory prepared ogi had no Coliform
growth while the commercially prepared ogi had counts of 0.5 x103
to 1.6 x 103 for white variety and 0.3 x 103 to 1.1 x103 for yellow
variety respectively. The Lactic acid bacterial count of 3.5x106 and
3.0x106 was recorded for the laboratory ogi while the commercially
prepared ogi ranged from 3.2x106 to 4.2x106 (white variety) and 3.0
x106 to 3.9 x106 (yellow). The presence of bacteria isolates from the
commercial and laboratory fermented ogi showed that Lactobacillus
sp, Leuconostoc sp and Citrobacter sp were present in all the
samples, Micrococcus sp and Klebsiella sp were isolated from Eke-
Okigwe and ABSU-up-gate markets varieties respectively, E. coli
and Staphylococcus sp were present in Eke-Okigwe and Nkwo-
Achara markets while Salmonella sp were isolated from the three
markets. Hence, there are chances of contracting food borne diseases
from commercially prepared ogi. Therefore, there is the need for
sanitary measures in the production of fermented cereals so as to
minimize the rate of food borne pathogens during processing and
storage.
Abstract: Waste Load Allocation (WLA) strategies usually
intend to find economic policies for water resource management.
Water quality trading (WQT) is an approach that uses discharge
permit market to reduce total environmental protection costs. This
primarily requires assigning discharge limits known as total
maximum daily loads (TMDLs). These are determined by monitoring
organizations with respect to the receiving water quality and
remediation capabilities. The purpose of this study is to compare two
approaches of TMDL assignment for WQT policy in small catchment
area of Haraz River, in north of Iran. At first, TMDLs are assigned
uniformly for the whole point sources to keep the concentrations of
BOD and dissolved oxygen (DO) at the standard level at checkpoint
(terminus point). This was simply simulated and controlled by
Qual2kw software. In the second scenario, TMDLs are assigned
using multi objective particle swarm optimization (MOPSO) method
in which the environmental violation at river basin and total treatment
costs are minimized simultaneously. In both scenarios, the equity
index and the WLA based on trading discharge permits (TDP) are
calculated. The comparative results showed that using economically
optimized TMDLs (2nd scenario) has slightly more cost savings rather
than uniform TMDL approach (1st scenario). The former annually
costs about 1 M$ while the latter is 1.15 M$. WQT can decrease
these annual costs to 0.9 and 1.1 M$, respectively. In other word,
these approaches may save 35 and 45% economically in comparison
with command and control policy. It means that using multi objective
decision support systems (DSS) may find more economical WLA,
however its outcome is not necessarily significant in comparison with
uniform TMDLs. This may be due to the similar impact factors of
dischargers in small catchments. Conversely, using uniform TMDLs
for WQT brings more equity that makes stakeholders not feel that
much envious of difference between TMDL and WQT allocation. In
addition, for this case, determination of TMDLs uniformly would be
much easier for monitoring. Consequently, uniform TMDL for TDP
market is recommended as a sustainable approach. However,
economical TMDLs can be used for larger watersheds.
Abstract: Due to the resultant leachate from waste
decomposition in landfills has polluter potential hundred times
greater than domestic sewage, this is considered a problem related to
the depreciation of environment requiring pre-disposal treatment.In
seeking to improve this situation, this project proposes the treatment
of landfill leachate using natural fibers intercropped with advanced
oxidation processes. The selected natural fibers were palm, coconut
and banana fiber.These materials give sustainability to the project
because, besides having adsorbent capacity, are often part of waste
discarded. The study was conducted in laboratory scale.In trials, the
effluents were characterized as Chemical Oxygen Demand (COD),
Turbidity and Color. The results indicate that is technically
promising since that there were extremely oxidative conditions, the
use of certain natural fibers in the reduction of pollutants in leachate
have been obtained results of COD removals between 67.9% and
90.9%, Turbidity between 88.0% and 99.7% and Color between
67.4% and 90.4%.The expectation generated is to continue evaluating
the association of efficiency of other natural fibers with other landfill
leachate treatment processes.
Abstract: Psyllium gum alone and in combination with
sunflower oil was investigated as a possible alternative edible coating
for improvement of quality and shelf life of fresh-cut papaya.
Different concentrations including 0.5, 1 and 1.5 percent of psyllium
gum were used for coating of fresh-cut papaya. In some samples,
refined sunflower oil was used as a lipid component to increase the
effectiveness of coating in terms of water barrier properties. Soya
lecithin was used as an emulsifier in coatings containing oil.
Pretreatment with 1% calcium chloride was given to maintain the
firmness of fresh-cut papaya cubes. 1% psyllium gum coating was
found to yield better results. Further, addition of oil helped to
maintain the quality and acted as a barrier to water vapour, therefore,
minimizing the weight loss.
Abstract: In this study, the feasibility of incorporating ceramic
waste from bricks (perforated brick and double hollow brick) and
extruded polystyrene (XPS) waste, is analysed.
Results show that it is possible to incorporate up to 25% of
ceramic waste and 4% of XPS waste over the weight of gypsum in a
gypsum matrix. Furthermore, with the addition of ceramic waste an
8% of surface hardness increase and a 25% of capillary water
absorption reduction can be obtained. On the other hand, with the
addition of XPS, a 26% reduction of density and a 37% improvement
of thermal conductivity can be obtained.
The obtained results are favorable to use these materials in order to
produce prefabricated gypsum and also as material for interior
cladding walls.
Abstract: Several parameters are established in order to measure
biodiesel quality. One of them is the iodine value, which is an
important parameter that measures the total unsaturation within a
mixture of fatty acids. Limitation of unsaturated fatty acids is
necessary since warming of higher quantity of these ones ends in
either formation of deposits inside the motor or damage of lubricant.
Determination of iodine value by official procedure tends to be very
laborious, with high costs and toxicity of the reagents, this study uses
artificial neural network (ANN) in order to predict the iodine value
property as an alternative to these problems. The methodology of
development of networks used 13 esters of fatty acids in the input
with convergence algorithms of back propagation of back
propagation type were optimized in order to get an architecture of
prediction of iodine value. This study allowed us to demonstrate the
neural networks’ ability to learn the correlation between biodiesel
quality properties, in this caseiodine value, and the molecular
structures that make it up. The model developed in the study reached
a correlation coefficient (R) of 0.99 for both network validation and
network simulation, with Levenberg-Maquardt algorithm.
Abstract: This work studies the effect of chemical composition
on the activity and selectivity of γ–alumina supported CuO/
MnO2/Cr2O3 catalysts toward deep oxidation of CO, dimethyl ether
(DME) and methanol. The catalysts were prepared by impregnation
of the support with an aqueous solution of copper nitrate, manganese
nitrate and CrO3 under different conditions. Thermal, XRD and TPR
analysis were performed. The catalytic measurements of single
compounds oxidation were carried out on continuous flow equipment
with a four-channel isothermal stainless steel reactor. Flow-line
equipment with an adiabatic reactor for simultaneous oxidation of all
compounds under the conditions that mimic closely the industrial
ones was used. The reactant and product gases were analyzed by
means of on-line gas chromatographs.
On the basis of XRD analysis it can be concluded that the active
component of the mixed Cu-Mn-Cr/γ–alumina catalysts consists of at
least six compounds – CuO, Cr2O3, MnO2, Cu1.5Mn1.5O4,
Cu1.5Cr1.5O4 and CuCr2O4, depending on the Cu/Mn/Cr molar ratio.
Chemical composition strongly influences catalytic properties, this
influence being quite variable with regards to the different processes.
The rate of CO oxidation rapidly decrease with increasing of
chromium content in the active component while for the DME was
observed the reverse trend. It was concluded that the best
compromise are the catalysts with Cu/(Mn + Cr) molar ratio 1:5 and
Mn/Cr molar ratio from 1:3 to 1:4.
Abstract: Currently, continuous two-phase decanter process
used for olive oil production is the more internationally widespread.
The wastewaters generated from this industry (OMW) are a real
environmental problem because of its high organic load. Among
proposed treatments for these wastewaters, advanced oxidation
technologies (Fenton, ozone, photoFenton, etc.) are the most
favourable. The direct application of these processes is somewhat
expensive. Therefore, the application of a previous stage based on a
flocculation-sedimentation operation is of high importance. In this
research five commercial flocculants (three cationic, and two anionic)
have been used to achieve the separation of phases (liquid clarifiedsludge).
For each flocculant, different concentrations (0-1000 mg/L)
have been studied. In these experiments, sludge volume formed and
the final water quality were determined. The final removal
percentages of total phenols (11.3-25.1%), COD (5.6-20.4%), total
carbon (2.3-26.5%), total organic carbon (1.50-23.8%), total nitrogen
(1.45-24.8%), and turbidity (27.9-61.4%) were determined. The
variation on electric conductivity reduction percentage (1-8%) was
also determined. Finally, the best flocculants with highest removal
percentages have been determined (QG2001 and Flocudex CS49).
Abstract: This paper aims to study the effect of cold work
condition on the microstructure of Cu-1.5wt%Ti, and Cu-3.5wt%Ti
and hence mechanical properties. The samples under investigation
were machined, and solution heat treated. X-ray diffraction technique
is used to identify the different phases present after cold deformation
by compression and also different heat treatment and also measuring
the relative quantities of phases present. The metallographic
examination is used to study the microstructure of the samples. The
hardness measurements were used to indicate the change in
mechanical properties. The results are compared with the mechanical
properties obtained by previous workers. Experiments on cold
compression followed by aging of Cu-Ti alloys have indicated that
the most efficient hardening of the material results from continuous
precipitation of very fine particles within the matrix. These particles
were reported to be β`-type, Cu4Ti phase. The β`-β transformation
and particles coarsening within the matrix as well as long grain
boundaries were responsible for the overaging of Cu-1.5wt%Ti and
Cu-3.5wt%Ti alloys. It is well known that plate-like particles are β –
type, Cu3Ti phase. Discontinuous precipitation was found to start at
the grain boundaries and expand into grain interior. At the higher
aging temperature, a classic Widmanstätten morphology forms giving
rise to a coarse microstructure comprised of α and the equilibrium
phase β. Those results were confirmed by X-ray analysis, which
found that a few percent of Cu3Ti, β precipitates are formed during
aging at high temperature for long time for both Cu- Ti alloys (i.e.
Cu-1.5wt%Ti and Cu-3.5wt%Ti).
Abstract: Evidence shows that start-ups success is positively
correlated with the launch of the first product. However, new ventures
are seldom able to acquire abundant resources for new product
development (NPD), which means that entrepreneurs may depend on
personal creativity instead of physical investments to achieve and
accelerate innovation speed. This study accentuates the role of
entrepreneurial bricolage, which defined as making do by applying
combinations of the resources at hand to new problems and
opportunities, in the relations of creative self-efficacy and innovation
speed. This study uses the multiple regression analysis to test the
hypotheses in a sample of 203 start-ups operating in various creative
markets in Taiwan. Results reveal that creative self-efficacy is
positively and directly associated with innovation speed, whereas
entrepreneurial bricolage plays a full mediator. These findings offer
important theoretical and practical implications.
Abstract: Haynes 25 alloy (also known as L-605 alloy) is cobalt
based super alloy which has widely applications such as aerospace
industry, turbine and furnace parts, power generators and heat
exchangers and petroleum refining components due to its excellent
characteristics. However, the workability of this alloy is more
difficult compared to normal steels or even stainless. In present work,
an experimental investigation was performed under cryogenic
cooling to determine cutting tool wear patterns and obtain optimal
cutting parameters in turning of cobalt based superalloy Haynes 25.
In experiments, uncoated carbide tool was used and cutting speed (V)
and feed rate (f) were considered as test parameters. Tool wear
(VBmax) were measured for process performance indicators.
Analysis of variance (ANOVA) was performed to determine the
importance of machining parameters.
Abstract: Current systems complexity has reached a degree that
requires addressing conception and design issues while taking into
account environmental, operational, social, legal and financial
aspects. Therefore, one of the main challenges is the way complex
systems are specified and designed. The exponential growing effort,
cost and time investment of complex systems in modeling phase
emphasize the need for a paradigm, a framework and an environment
to handle the system model complexity. For that, it is necessary to
understand the expectations of the human user of the model and his
limits. This paper presents a generic framework for designing
complex systems, highlights the requirements a system model needs
to fulfill to meet human user expectations, and suggests a graphbased
formalism for modeling complex systems. Finally, a set of
transformations are defined to handle the model complexity.
Abstract: Construction projects are information intensive in
nature and involve many activities that are related to each other.
Wireless technologies can be used to improve the accuracy and
timeliness of data collected from construction sites and shares it with
appropriate parties. Nonetheless, the construction industry tends to be
conservative and shows hesitation to adopt new technologies. A main
concern for owners, contractors or any person in charge on a job site
is the cost of the technology in question. Wireless technologies are
not cheap. There are a lot of expenses to be taken into consideration,
and a study should be completed to make sure that the importance
and savings resulting from the usage of this technology is worth the
expenses. This research attempts to assess the effectiveness of using
the appropriate wireless technologies based on criteria such as
performance, reliability, and risk. The assessment is based on a utility
function model that breaks down the selection issue into alternatives
attribute. Then the attributes are assigned weights and single
attributes are measured. Finally, single attribute are combined to
develop one single aggregate utility index for each alternative.
Abstract: We used live E. coli containing synthetic genetic
oscillators to study how the degree of synchrony between the genetic
circuits of sister cells changes with temperature. We found that both
the mean and the variability of the degree of synchrony between the
fluorescence signals from sister cells are affected by temperature.
Also, while most pairs of sister cells were found to be highly
synchronous in each condition, the number of asynchronous pairs
increased with increasing temperature, which was found to be due to
disruptions in the oscillations. Finally we provide evidence that these
disruptions tend to affect multiple generations as opposed to
individual cells. These findings provide insight in how to design
more robust synthetic circuits and in how cell division can affect their
dynamics.
Abstract: In this work new macroporous Ni electrodes modified
with Au nanoparticles for hydrogen production have been developed.
The supporting macroporous Ni electrodes have been obtained by
means of the electrodeposition at high current densities. Then, the Au
nanoparticles were synthesized and added to the electrode surface.
The electrocatalytic behaviour of the developed electrocatalysts was
studied by means of pseudo-steady-state polarization curves,
electrochemical impedance spectroscopy (EIS) and hydrogen
discharge curves. The size of the Au synthetized nanoparticles shows
a monomodal distribution, with a very sharp band between 10 and 50
nm. The characteristic parameters d10, d50 and d90 were 14, 20 and
31 nm respectively. From Tafel polarization data has been concluded
that the Au nanoparticles improve the catalytic activity of the
developed electrodes towards the HER respect to the macroporous Ni
electrodes. EIS permits to obtain the electrochemically active area by
means of the roughness factor value. All the developed electrodes
show roughness factor values in the same order of magnitude. From
the activation energy results it can be concluded that the Au
nanoparticles improve the intrinsic catalytic activity of the
macroporous Ni electrodes.
Abstract: In this paper, the energy saving and human thermal
comfort in a typical office room are investigated. The impact of a
combined system of exhaust inlet air with light slots located at the
ceiling level in a room served by displacement ventilation system is
numerically modelled. Previous experimental data are used to
validate the Computational Fluid Dynamic (CFD) model. A case
study of simulated office room includes two seating occupants, two
computers, two data loggers and four lamps. The combined system is
located at the ceiling level above the heat sources. A new method of
calculation for the cooling coil load in Stratified Air Distribution
(STRAD) system is used in this study. The results show that 47.4%
energy saving of space cooling load can be achieved by combing the
exhaust inlet air with light slots at the ceiling level above the heat
sources.
Abstract: This study aims at developing a novel cold asphalt
concrete binder course mixture by using Ordinary Portland Cement
(OPC) as a replacement for conventional mineral filler (0%-100%)
with new by-product material (LJMU-A2) used as a supplementary
cementitious material. With this purpose, cold asphalt concrete binder
course mixtures with cationic emulsions were studied by means of
stiffness modulus whereas water sensitivity was assessed by
measuring the stiffness modulus ratio before and after sample
conditioning.
The results indicate that a substantial enhancement in the stiffness
modulus and a considerable improvement of water sensitivity
resistance is achieved by adding LJMU-A2 to the cold asphalt
mixtures as a supplementary cementitious material. Moreover, the
addition of LJMU-A2 to those mixtures leads to a stiffness modulus
after 2-day curing compared to that obtained with Portland cement,
which occurs after 7-day curing.