Abstract: Activated carbon DSAC36-24 iy is adsorbent materials, characterized by a specific surface area of 548.13 m²g⁻¹. Their manufacture uses the natural raw materials like the nucleus of dates. In this study the treatment is done in two stages: A chemical treatment by H3PO4 followed by a physical treatment under nitrogen for 1 hour then under stream of CO2 for 24 hours. A characterization of the various parameters was determined such as the measurement of the specific surface area, determination of pHPZC, bulk density, iodine value. The study of the adsorption of organic molecules (hydroquinone, paranitrophenol, 2,4-dinitrophenol, 2,4,6-trinitrophenol) indicates that the adsorption phenomena are essentially due to the van der Waals interaction. In the case of organic molecules carrying the polar substituents, the existence of hydrogen bonds is also proved by the donor-acceptor forces. The study of the pH effect was done with modeling by different models (Langmuir, Freundlich, Langmuir-Freundlich, Redlich-Peterson), a kinetic treatment is also followed by the application of Lagergren, Weber, Macky.
Abstract: Comparative analysis of the properties of melon seed,
coconut fruit and their oil yield were evaluated in this work using
standard analytical technique AOAC. The results of the analysis
carried out revealed that the moisture contents of the samples studied
are 11.15% (melon) and 7.59% (coconut). The crude lipid content are
46.10% (melon) and 55.15% (coconut).The treatment combinations
used (leaching time, leaching temperature and solute: solvent ratio)
showed significant difference (p < 0.05) in yield between the
samples, with melon oil seed flour having a higher percentage range
of oil yield (41.30 – 52.90%) and coconut (36.25 – 49.83%). The
physical characterization of the extracted oil was also carried out.
The values gotten for refractive index are 1.487 (melon seed oil) and
1.361 (coconut oil) and viscosities are 0.008 (melon seed oil) and
0.002 (coconut oil). The chemical analysis of the extracted oils shows
acid value of 1.00mg NaOH/g oil (melon oil), 10.050mg NaOH/g oil
(coconut oil) and saponification value of 187.00mg/KOH (melon oil)
and 183.26mg/KOH (coconut oil). The iodine value of the melon oil
gave 75.00mg I2/g and 81.00mg I2/g for coconut oil. A standard
statistical package Minitab version 16.0 was used in the regression
analysis and analysis of variance (ANOVA). The statistical software
mentioned above was also used to optimize the leaching process.
Both samples gave high oil yield at the same optimal conditions. The
optimal conditions to obtain highest oil yield ≥ 52% (melon seed)
and ≥ 48% (coconut seed) are solute - solvent ratio of 40g/ml,
leaching time of 2hours and leaching temperature of 50oC. The two
samples studied have potential of yielding oil with melon seed giving
the higher yield.
Abstract: Biodiesel is one of the alternative fuels that promising
for substituting petro diesel as energy source which is advantage on
sustainability and ecofriendly. Due to the raw material that tend to
decompose during storage, biodiesel also have the same characteristic
that tend to decompose and formed higher acid value which is the
result of oxidation to double bond on a chain of ester. Decomposition of biodiesel due to oxidation reaction could
prevent by introduce a small amount of antioxidant. The origin of raw
materials and the process for producing biodiesel will determine the
effectiveness of antioxidant. The quality degradation on biodiesel
could evaluate by measuring iodine value and acid number of
biodiesel. Biodiesel made from high fatty acid Jatropha curcas oil by using
esterification and transesterification process will stand on the quality
by introduce 90 ppm pyrogallol powder on the biodiesel, which could
increase Induction period time from 2 hours to more than 6 hours in
rancimat test evaluation.
Abstract: Several parameters are established in order to measure
biodiesel quality. One of them is the iodine value, which is an
important parameter that measures the total unsaturation within a
mixture of fatty acids. Limitation of unsaturated fatty acids is
necessary since warming of higher quantity of these ones ends in
either formation of deposits inside the motor or damage of lubricant.
Determination of iodine value by official procedure tends to be very
laborious, with high costs and toxicity of the reagents, this study uses
artificial neural network (ANN) in order to predict the iodine value
property as an alternative to these problems. The methodology of
development of networks used 13 esters of fatty acids in the input
with convergence algorithms of back propagation of back
propagation type were optimized in order to get an architecture of
prediction of iodine value. This study allowed us to demonstrate the
neural networks’ ability to learn the correlation between biodiesel
quality properties, in this caseiodine value, and the molecular
structures that make it up. The model developed in the study reached
a correlation coefficient (R) of 0.99 for both network validation and
network simulation, with Levenberg-Maquardt algorithm.
Abstract: Considering palm oil as non-drying oil owing to its
low iodine value, an attempt was taken to increase the unsaturation in
the fatty acid chains of palm oil for the preparation of alkyds. To
increase the unsaturation in the palm oil, sulphuric acid (SA) and
para-toluene sulphonic acid (PTSA) was used prior to alcoholysis for
the dehydration process. The iodine number of the oil samples was
checked for the unsaturation measurement by Wijs method. Alkyd
resin was prepared using the dehydrated palm oil by following
alcoholysis and esterification reaction. To improve the film properties
0.5wt.% multi-wall carbon nano tubes (MWCNTs) were used to
manufacture polymeric film. The properties of the resins were
characterized by various physico-chemical properties such as density,
viscosity, iodine value, saponification value, etc. Structural
elucidation was confirmed by Fourier transform of infrared
spectroscopy and proton nuclear magnetic resonance; surfaces of the
films were examined by field-emission scanning electron microscope.
In addition, pencil hardness and chemical resistivity was also
measured by using standard methods. The effect of enhancement of
the unsaturation in the fatty acid chain found significant and
motivational. The resin prepared with dehydrated palm oil showed
improved properties regarding hardness and chemical resistivity
testing. The incorporation of MWCNTs enhanced the thermal
stability and hardness of the films as well.
Abstract: Analysis of the properties of coconut (Cocos nucifera)
and its oil was evaluated in this work using standard analytical
techniques. The analyses carried out include proximate composition
of the fruit, extraction of oil from the fruit using different process
parameters and physicochemical analysis of the extracted oil. The
results showed the percentage (%) moisture, crude lipid, crude
protein, ash and carbohydrate content of the coconut as 7.59, 55.15,
5.65, 7.35 and 19.51 respectively. The oil from the coconut fruit was
odourless and yellowish liquid at room temperature (30oC). The
treatment combinations used (leaching time, leaching temperature
and solute: solvent ratio) showed significant differences (P
Abstract: The aim of the present study is to investigate the
potential use of the selected seed oils. The oil was extracted using
Soxhlet apparatus and the physicochemical characteristics of the oil
determined using standard methods. The following results were
obtained for the physicochemical parameters analysed: for Egusi seed
oil, Oil yield 53.20%, Saponification value 178.03±1.25 mgKOH/g,
Iodine value 49.10±0.32 g I2/100g, Acid value 4.30±0.86 mgKOH/g,
and Peroxide value 5.80±0.27 meq/kg were obtained. For Pawpaw
seed oil, Oil yield 40.10%, Saponification value 24.13±3.93
mgKOH/g, Iodine value 24.87±0.19 g I2/100g, Acid value 9.46±0.40
mgKOH/g, and Peroxide value 3.12±1.22 meq/kg were obtained. For
Sweet orange seed oil, Oil yield 43.10%, Saponification value
106.30±2.37 mgKOH/g, Iodine value 37.08±0.04 g I2/100g, Acid
value 7.59±0.77 mgKOH/g, and Peroxide value 2.21±0.46 meq/kg
were obtained. From the obtained values of the determined
parameters, the oils can be extracted from the three selected seeds in
commercial quantities and that the egusi and sweet orange seed oils
may be utilized in the industrial soap production.
Abstract: A study on the physicochemical properties of Jatropha curcas seed oil for industrial applications were carried out. Physicochemical properties of J. curcas seed oil (59.32% lipids) showed high content of LA (36.70%), iodine value (104.90 mg/g) and saponification value (203.36 mg/g). The present study shows that, J. curcas seed oil is rich in oleic and linoleic acids. The J. curcas seed oil with the highest amount of polyunsaturated fatty acids (linoleic acid) can find an application in surface coating industries and biolubricant base oil applications, whereas the high amount of monounsaturated fatty acid can find an application as a biodiesel feed stock. J. curcas seed oil contains major TAG of monounsaturated OLL, POL, SLL, PLL, OOL, OOO and POP followed by LLL. J. curcas seed oil can be classified as unsaturated oil with an unsaturated fat level of 80.42%. Hence the J. curcas seed oil has great potential for industrial applications such as in paint and surface coatings, production of biodiesel and biolubricant. Therefore, it is crucial to have more research on J. curcas seed oil in the future to explore its potential as a future industrial oilseed crop.
Abstract: Elateriospermum tapos seed (buah perah) is the one
of the rich sources of polyunsaturated fatty acids. It contains high
percentage of oleic acid which is the important component to develop
nervous system and also α-linolenic acid (ALA) which is the
precursor of omega-3 fatty acids series to synthesize
eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA).
However, there is less study about this valuable oilseed and exploit
its potential. Therefore, this paper is to assess the comparison of
physico-chemical properties and fatty composition of perah oil to
palm oil and soybean oil. From the comparison, perah oil shows low
peroxide value means it has good oxidative stability and also high
iodine values shows that it can be used in paint industry. The study
shown that perah oil is comparable to palm oil and soybean oil, so it
has high potential to be exploited in the oleochemical,
pharmaceutical, cosmetics and paint industries.