Abstract: The aim of this paper is to summarize the literature on micromorphology and composition of the enamel of the cat and present an original experiment by SEM on how it responds to the etching with ortophosphoric acid for the time recommended in the veterinary literature (30", 45", 60"), derived from research and experience on human enamel; 21 teeth of cat were randomly divided into three groups of 7 (A, B, C): Group A was subjected to etching for 30 seconds by means of orthophosphoric acid to 40% on a circular area with diameter of about 2mm of the enamel coronal; the Groups B and C had the same treatment but, respectively, for 45 and 60 seconds. The samples obtained were observed by SEM to constant magnification of 1000x framing, in particular, the border area between enamel exposed and not exposed to etching to highlight differences. The images were subjected to the analysis of three blinded experienced operators in electron microscopy. In the enamel of the cat the etching for the times considered is not optimally effective for the purpose adhesives and the presence of a thick prismless layer could explain this situation. To improve this condition may clinically in the likeness of what is proposed for the enamel of human deciduous teeth: a bevel or a chamfer of 1 mm on the contour of the cavity to discover the prismatic enamel and increase the bonding surface.
Abstract: A proton exchange membrane has been developed for
direct methanol fuel cell (DMFC). The nanofiber network composite
membranes were prepared by interconnected network of Nafion
(perfuorosulfonic acid) nanofibers that have been embedded in an
uncharged and inert polymer matrix, by electro-spinning. The
spinning solution of Nafion with a low concentration (1 wt%
compared to Nafion) of high molecular weight poly(ethylene oxide),
as a carrier polymer. The interconnected network of Nafion
nanofibers with average fiber diameter in the range of 160-700nm,
were used to make the membranes, with the nanofiber occupying up
to 85% of the membrane volume. The matrix polymer was
crosslinked with Norland Optical Adhesive 63 under UV. The
resulting membranes showed proton conductivity of 0.10 S/cm at
25°C and 80% RH; and methanol permeability of 3.6 x 10-6 cm2/s.
Abstract: Proximate composition (moisture, protein, total fat, and total ash) and textural characteristics (hardness, adhesiveness, springiness, cohesiveness, chewiness and firmness and work of shear) of cooked sausages formulated from mechanically deboned chicken meat (MDCM) with addition of chicken offal (heart, gizzard or liver) were investigated. Chicken offal replaced equal weight (15 kg) of MDCM in standard sausage formulation. Regarding proximate composition sausage with heart addition was significantly (P
Abstract: An industrial epoxy adhesive used in Carbon Fiber Reinforced Polymer (CFRP) strengthening systems was modified by dispersing multi-walled carbon nanotubes (MWCNTs). Nanocomposites were fabricated using the solvent-assisted dispersion method and ultrasonic mixing. Thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA) and tensile tests were conducted to study the effect of nanotubes dispersion on the thermal and mechanical properties of the epoxy composite. Experimental results showed a substantial enhancement in the decomposition temperature and tensile properties of epoxy composite, while, the glass transition temperature (Tg) was slightly reduced due to the solvent effect. The morphology of the epoxy nanocomposites was investigated by SEM. It was proved that using solvent improves the nanotubes dispersion. However, at contents higher than 2 wt. %, nanotubes started to re-bundle in the epoxy matrix which negatively affected the final properties of epoxy composite.
Abstract: This study is experimentally targeting to develop effective in heat and mass transfer processes for the adsorbate to obtain applicable adsorption capacity data. This is done by using fin and tube heat exchanger core and the adsorbate is adhesive over its surface and located as the core of the adsorber. The pairs are activated carbon powder/R-134a, activated carbon powder/R-407c, activated carbon powder/R-507A, activated carbon granules/R-507A, activated carbon granules/R-407c and activated carbon granules/R-134a, at different adsorption temperatures of 25, 30, 35 and 50°C. The following is results is obtained: at adsorption temperature of 25 °C the maximum adsorption capacity is found to be 0.8352kg/kg for activated carbon powder with R-134a and the minimum adsorption capacity found to be 0.1583kg/kg for activated carbon granules with R-407c. While, at adsorption temperature of 50°C the maximum adsorption capacity is found to be 0.3207kg/kg for activated carbon powder with R-134a and the minimum adsorption capacity found to be 0.0609kg/kg for activated carbon granules with R-407c. Therefore, the activated carbon powder/R-134a pair is highly recommended to be used as adsorption refrigeration working pair because of its higher maximum adsorption capacity than the other tested pairs, to produce a compact, efficient and reliable for long life performance adsorption refrigeration system.
Abstract: A two-dimensional thin-walled capsule of a flexible
semi-permeable membrane is adhered onto a rigid planar substrate
under adhesive forces (derived from a potential function) in the
presence of osmosis across the membrane. The capsule is immersed
in a hypotonic and diluted binary solution of a non-electrolyte
solute. The Stokes flow problem is solved by the immersed interface
method (IIM) with equal viscosities for the enclosed and
surrounding fluid of the capsule. The numerical results obtained are
verified against two simplified theoretical solutions and the
agreements are good. The osmotic inflation of the adhered capsule is
studied as a function of the solute concentration field, hydraulic
conductivity, and the initial capsule shape. Our findings indicate that
the contact length shrinks in dimension as capsule inflates in the
hypotonic medium, and the equilibrium contact length does not
depend on the hydraulic conductivity of the membrane and the
initial shape of the capsule.
Abstract: This study was aimed to study the probability about
the production of fiberboard made of durian rind through latex with
phenolic resin as binding agent. The durian rind underwent the
boiling process with NaOH [7], [8] and then the fiber from durian
rind was formed into fiberboard through heat press. This means that
durian rind could be used as replacement for plywood in plywood
industry by using durian fiber as composite material with adhesive
substance. This research would study the probability about the
production of fiberboard made of durian rind through latex with
phenolic resin as binding agent. At first, durian rind was split,
exposed to light, boiled and steamed in order to gain durian fiber.
Then, fiberboard was tested with the density of 600 Kg/m3 and 800
Kg/m3. in order to find a suitable ratio of durian fiber and latex.
Afterwards, mechanical properties were tested according to the
standards of ASTM and JIS A5905-1994. After the suitable ratio was
known, the test results would be compared with medium density
fiberboard (MDF) and other related research studies. According to
the results, fiberboard made of durian rind through latex with
phenolic resin at the density of 800 Kg/m3 at ratio of 1:1, the
moisture was measured to be 5.05% with specific gravity (ASTM D
2395-07a) of 0.81, density (JIS A 5905-1994) of 0.88 g/m3, tensile
strength, hardness (ASTM D2240), flexibility or elongation at break
yielded similar values as the ones by medium density fiberboard
(MDF).
Abstract: The research study was based on an evaluation of the
ability of glued test samples to pass the criterion of sufficient
bondline adhesion under the exposure conditions defined in EN 302-
1. Additionally, an infrared spectroscopic analysis of the evaluated
adhesives (phenol-resorcinol-formaldehyde PRF and melamine-ureaformaldehyde
MUF) with different mix ratios was carried out to
evaluate the possible effects of a faulty technological process.
Abstract: This paper discusses effects of adhesive thickness,
overlap length and material combinations on the single-lap
joints strength from the point of singular stress fields. A useful
method calculating the ratio of intensity of singular stress is
proposed using FEM for different adhesive thickness and
overlap length. It is found that the intensity of singular stress
increases with increasing adhesive thickness, and decreases
with increasing overlap length. The increment and decrement
are different depending on material combinations between
adhesive and adherent.
Abstract: Axisymmetric vibration of an infinite Pyrocomposite
circular hollow cylinder made of inner and outer pyroelectric layer of
6mm-class bonded together by a Linear Elastic Material with Voids
(LEMV) layer is studied. The exact frequency equation is obtained
for the traction free surfaces with continuity condition at the
interfaces. Numerical results in the form of data and dispersion
curves for the first and second mode of the axisymmetric vibration of
the cylinder BaTio3 / Adhesive / BaTio3 by taking the Adhesive layer
as an existing Carbon Fibre Reinforced Polymer (CFRP) are
compared with a hypothetical LEMV layer with and without voids
and as well with a pyroelectric hollow cylinder. The damping is
analyzed through the imaginary parts of the complex frequencies.
Abstract: The aim of the present study was to evaluate the
mucoadhesion and the release of nicotinamide gel formulations using
in vitro methods. An agar plate technique was used to investigate the
adhesiveness of the gels whereas a diffusion apparatus was employed
to determine the release of nicotinamide from the gels. In this
respect, 10% w/w nicotinamide gels containing bioadhesive
polymers: Carbopol 934P (0.5-2% w/w), hydroxypropylmethyl
cellulose (HPMC) (4-10% w/w), sodium carboxymethyl cellulose
(SCMC) (4-6% w/w) and methylcellulose 4000 (MC) (3-5% w/w)
were prepared. The gel formulations had pH values in the range of
7.14 - 8.17, which were considered appropriate to oral mucosa
application. In general, the rank order of pH values appeared to be
SCMC > MC4000 > HPMC > Carbopol 934P. Types and
concentrations of polymers used somewhat affected the
adhesiveness. It was found that anionic polymers (Carbopol 934 and
SCMC) adhered more firmly to the agar plate than the neutral
polymers (HPMC and MC 4000). The formulation containing 0.5%
Carbopol 934P (F1) showed the highest release rate. With the
exception of the formulation F1, the neutral polymers tended to give
higher relate rates than the anionic polymers. For oral tissue
treatment, the optimum has to be balanced between the residence
time (adhesiveness) of the formulations and the release rate of the
drug. The formulations containing the anionic polymers: Carbopol
934P or SCMC possessed suitable physical properties (appearance,
pH and viscosity). In addition, for anionic polymer formulations,
justifiable mucoadhesive properties and reasonable release rates of
nicotinamide were achieved. Accordingly, these gel formulations
may be applied for the treatment of oral mucosal lesions.
Abstract: The textural parameters, together with appearance and
flavor, are sensory attributes of great importance for the product to be
accepted by the consumer. The objective of the present study was the
evaluation of the textural attributes of Packhams pears in the fresh
state, after drying in a chamber with forced convection at 50ºC,
lyophilized and re-hydrated. In texture analysis it was used the
method of Texture Profile Analysis (TPA). The parameters analyzed
were hardness, cohesiveness, adhesiveness, elasticity and chewiness.
From the results obtained is possible to see that the drying operation
greatly affected some textural properties of the pears, so that the
hardness diminished very much with drying, for both drying
methods.
Abstract: In this paper the strength of adhesive joint under
tension and bending is discussed on the basis of intensity of
singular stress by the application of FEM. A useful method is
presented with focusing on the stress at the edge of interface
between the adhesive and adherent obtained by FEM. After
analyzing the adhesive joint strength with all material
combinations, it is found that to improve the interface strength,
thin adhesive layers are desirable because the intensity of
singular stress decreases with decreasing the thickness.
Abstract: In the present study, development of salbutamol
sulphate nanoparticles that adhere to gastric mucus was investigated.
Salbutamol sulphate has low bioavailability due to short transit time in
gastric. It also has a positive surface charge that provides hurdles to be
encapsulated by the positively strong mucoadhesive polymer of
chitosan. To overcome the difficulties, the surface charge of active
ingredient was modified using several nonionic and anionic
stomach-specific polymers. The nanoparticles were prepared using
ionotropic gelation technique. The evaluation involved determination
of particle size, zeta potential, entrapment efficiency, in vitro drug
release and in vitro mucoadhesion test. Results exhibited that the use
of anionic alginate polymer was more satisfactory than that of
nonionic polymer. Characteristics of the particles was nano-size, high
encapsulation efficiency, fulfilled the drug release requirements and
adhesive towards stomach for around 11 hours. This result shows that
the salbutamol sulphate nanoparticles can be utilized for improvement
its delivery.
Abstract: This paper presents a NDT by infrared thermography with excitation CO2 Laser, wavelength of 10.6 μm. This excitation is the controllable heating beam, confirmed by a preliminary test on a wooden plate 1.2 m x 0.9 m x 1 cm. As the first practice, this method is applied to detecting the defect in CFRP heated by the Laser 300 W during 40 s. Two samples 40 cm x 40 cm x 4.5 cm are prepared, one with defect, another one without defect. The laser beam passes through the lens of a deviation device, and heats the samples placed at a determinate position and area. As a result, the absence of adhesive can be detected. This method displays prominently its application as NDT with the composite materials. This work gives a good perspective to characterize the laser beam, which is very useful for the next detection campaigns.
Abstract: The present study focuses on methods allowing a convenient and quick calculation of the SIFs in order to predict the static adhesive strength of bonded joints. A new SIF calculation method is proposed, based on the stresses obtained from a FE model at a reference point located in the adhesive layer at equal distance of the free-edge and of the two interfaces. It is shown that, even limiting ourselves to the two main modes, i.e. the opening and the shearing modes, and using the values of the stresses resulting from a low detailed FE model, an efficient calculation of the peeling stress at adhesive-substrate corners can be obtained by this way. The proposed method is interesting in that it can be the basis of a prediction tool that will allow the designer to quickly evaluate the SIFs characterizing a particular application without developing a detailed analysis.
Abstract: In this paper, the wear of high speed steel hobs during
hobbing has been studied. The wear mechanisms are strongly
influenced by the choice of cutting speed. At moderate and high
cutting speeds three major wear mechanisms were identified:
abrasion, mild adhesive and severe adhesive. The microstructure and
wear behavior of two high speed steel grades (M2 and ASP30) has
been compared. In contrast, a variation in chemical composition or
microstructure of HSS tool material generally did not change the
dominant wear mechanism. However, the tool material properties
determine the resistance against the operating wear mechanism and
consequently the tool life. The metallographic analysis and wear
measurement at the tip of hob teeth included scanning electron
microscopy and stereoscope microscopy. Roughness profilometery is
used for measuring the gear surface roughness.
Abstract: The techniques for estimating the adhesive and cohesive strength in high velocity oxy fuel (HVOF) thermal spray coatings have been discussed and compared. The development trend and the last investigation have been studied. We will focus on benefits and limitations of these methods in different process and materials.
Abstract: New nondestructive technique, namely an inverse technique based on vibration tests, to characterize nonlinear mechanical properties of adhesive layers in sandwich composites is developed. An adhesive layer is described as a viscoelastic isotropic material with storage and loss moduli which are both frequency dependent values in wide frequency range. An optimization based on the planning of experiments and response surface technique to minimize the error functional is applied to decrease considerably the computational expenses. The developed identification technique has been tested on aluminum panels and successfully applied to characterize viscoelastic material properties of 3M damping polymer ISD-112 used as a core material in sandwich panels.
Abstract: In this study the elastic-plastic stress distribution in
weld-bonded joint, fabricated from austenitic stainless steel (AISI
304) sheet of 1.00 mm thickness and Epoxy adhesive Araldite 2011,
subjected to axial loading is investigated. This is needed to improve
design procedures and welding codes, and saving efforts in the
cumbersome experiments and analysis. Therefore, a complete 3-D
finite element modelling and analysis of spot welded, bonded and
weld-bonded joints under axial loading conditions is carried out. A
comprehensive systematic experimental program is conducted to
determine many properties and quantities, of the base metals and the
adhesive, needed for FE modelling, such like the elastic – plastic
properties, modulus of elasticity, fracture limit, the nugget and heat
affected zones (HAZ) properties, etc. Consequently, the finite
element models developed, for each case, are used to evaluate
stresses distributions across the entire joint, in both the elastic and
plastic regions. The stress distribution curves are obtained,
particularly in the elastic regions and found to be consistent and in
excellent agreement with the published data. Furthermore, the
stresses distributions are obtained in the weld-bonded joint and
display the best results with almost uniform smooth distribution
compared to spot and bonded cases. The stress concentration peaks at
the edges of the weld-bonded region, are almost eliminated resulting
in achieving the strongest joint of all processes.