Abstract: In our recent study, we have used ZnO nanoparticles assisted with UV light irradiation to investigate the photocatalytic degradation of Phenol Red (PR). The ZnO photocatalyst was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), specific surface area analysis (BET) and UVvisible spectroscopy. X-ray diffractometry result for the ZnO nanoparticles exhibit normal crystalline phase features. All observed peaks can be indexed to the pure hexagonal wurtzite crystal structures, with the space group of P63mc. There are no other impurities in the diffraction peak. In addition, TEM measurement shows that most of the nanoparticles are rod-like and spherical in shape and fairly monodispersed. A significant degradation of the PR was observed when the catalyst was added into the solution even without the UV light exposure. In addition, the photodegradation increases with the photocatalyst loading. The surface area of the ZnO nanomaterials from the BET measurement was 11.9 m2/g. Besides the photocatalyst loading, the effect of some parameters on the photodegradation efficiency such as initial PR concentration and pH were also studied.
Abstract: Wet chemistry methods are used to prepare the
SiO2/Au nanoshells. The purpose of this research was to synthesize
gold coated SiO2 nanoshells for biomedical applications. Tunable
nanoshells were prepared by using different colloidal concentrations.
The nanoshells are characterized by FTIR, XRD, UV-Vis
spectroscopy and atomic force microscopy (AFM). The FTIR results
confirmed the functionalization of the surfaces of silica nanoparticles
with NH2 terminal groups. A tunable absorption was observed
between 470-600 nm with a maximum range of 530-560 nm. Based
on the XRD results three main peaks of Au (111), (200) and (220)
were identified. Also AFM results showed that the silica core
diameter was about 100 nm and the thickness of gold shell about 10
nm.
Abstract: Natural organic matter (NOM) is heterogeneous
mixture of organic compounds that enter the water media from
animal and plant remains, domestic and industrial wastes.
Researches showed that NOM is likely precursor material for
disinfection by products (DBPs). Chlorine very commenly used for
disinfection purposes and NOM and chlorine reacts then
Trihalomethane (THM) and Haloacetic acids (HAAs) which are
cancerogenics for human health are produced. The aim of the study is
to search NOM removal by enhanced coagulation from drinking
water source of Eskisehir which is supplied from Porsuk Dam.
Recently, Porsuk dam water is getting highly polluted and therefore
NOM concentration is increasing. Enhanced coagulation studies were
evaluated by measurement of Dissolved Organic Carbon (DOC), UV
absorbance at 254 nm (UV254), and different trihalomethane
formation potential (THMFP) tests. Results of jar test experiments
showed that NOM can be removed from water about 40-50 % of
efficiency by enhanced coagulation. Optimum coagulant type and
coagulant dosages were determined using FeCl3 and Alum.
Abstract: This paper may be considered as combination of both pervasive computing and Differential GPS (global positioning satellite) which relates to control automatic traffic signals in such a
way as to pre-empt normal signal operation and permit lifesaving vehicles. Before knowing the arrival of the lifesaving vehicles from
the signal there is a chance of clearing the traffic. Traffic signal
preemption system includes a vehicle equipped with onboard computer system capable of capturing diagnostic information and
estimated location of the lifesaving vehicle using the information provided by GPS receiver connected to the onboard computer system
and transmitting the information-s using a wireless transmitter via a
wireless network. The fleet management system connected to a
wireless receiver is capable of receiving the information transmitted
by the lifesaving vehicle .A computer is also located at the
intersection uses corrected vehicle position, speed & direction
measurements, in conjunction with previously recorded data defining
approach routes to the intersection, to determine the optimum time to
switch a traffic light controller to preemption mode so that lifesaving
vehicles can pass safely. In case when the ambulance need to take a
“U" turn in a heavy traffic area we suggest a solution. Now we are
going to make use of computerized median which uses LINKED
BLOCKS (removable) to solve the above problem.
Abstract: Size based filtration is one of the common methods
employed to isolate circulating tumor cells (CTCs) from whole
blood. It is well known that this method suffers from isolation
efficiency to purity tradeoff. However, this tradeoff is poorly
understood. In this paper, we present the design and manufacturing
of a special rectangular slit filter. The filter was designed to retain
maximal amounts of nucleated cells, while minimizing the pressure
on cells, thereby preserving their morphology. The key parameter,
namely, input pressure, was optimized to retain the maximal number
of tumor cells, whilst maximizing the depletion of normal blood cells
(red and white blood cells and platelets). Our results indicate that for
a slit geometry of 5 × 40 μm on a 13 mm circular membrane with a
fill factor of 21%, a pressure of 6.9 mBar yields the optimum for
maximizing isolation of MCF-7 and depletion of normal blood cells.
Abstract: In this study, oxidative steam reforming of methanol (OSRM) over a Au/CeO2–Fe2O3 catalyst prepared by a depositionprecipitation (DP) method was studied to produce hydrogen in order to feed a Proton Exchange Membrane Fuel Cell (PEMFC). The support (CeO2, Fe2O3, and CeO2–Fe2O3) were prepared by precipitation and co-precipitation methods. The impact of the support composition on the catalytic performance was studied by varying the Ce/(Ce+Fe) atomic ratio, it was found that the 1%Au/CF(0.25) calcined at 300 °C exhibited the highest catalytic activity in the whole temperature studied. In addition, the effect of Au content was investigated and 3%Au/CF(0.25) exhibited the highest activity under the optimum condition in the temperature range of 200 °C to 400 °C. The catalysts were characterized by various techniques: XRD, TPR, XRF, and UV-vis.
Abstract: Structural and UV/Visible optical properties can be
useful to describe a material for the CIGS solar cell active layer,
therefore, this work demonstrates the properties like surface
morphology, X-ray Photoelectron Spectroscopy (XPS) bonding
energy (EB) core level spectra, UV/Visible absorption spectra,
refractive index (n), optical energy band (Eg), reflection spectra for
the Cu25 (In16Ga9) Se40Te10 (CIGST-1) and Cu20 (In14Ga9) Se45Te12
(CIGST-2) chalcogenide compositions. Materials have been
exhibited homogenous surface morphologies, broading /-or diffusion
of bonding energy peaks relative elemental values and a high
UV/Visible absorption tendency in the wave length range 400 nm-
850 nm range with the optical energy band gaps 1.37 and 1.42
respectively. Subsequently, UV/Visible reflectivity property in the
wave length range 250 nm to 320 nm for these materials has also
been discussed.
Abstract: Composite nanostructures of metal
core/semiconductor shell (Au/CdS) configuration were prepared
using organometalic method. UV-Vis spectra for the Au/CdS colloids
show initially two well separated bands, corresponding to surface
plasmon of the Au core, and the exciton of CdS shell. The absorption
of CdS shell is enhanced, while the Au plasmon band is suppressed
as the shell thickness increases. The shell sizes were estimated from
the optical spectra using the effective mass approximation model
(EMA), and compared to the sizes of the Au core and CdS shell
measured by high resolution transmission electron microscope
(HRTEM). The changes in the absorption features are discussed in
terms of gradual increase in the coupling strength of the Au core
surface plasmon and the exciton in the CdS. leading to charge
transfer and modification of electron oscillation in Au core.
Abstract: A sophisticated simulator provides a cost-effective measure to carry out preliminary mission testing and diagnostic while reducing potential failures for real life at sea trials. The presented simulation framework covers three key areas: AUV modeling, sensor modeling, and environment modeling. AUV modeling mainly covers the area of AUV dynamics. Sensor modeling deals with physics and mathematical models that govern each sensor installed onto the AUV. Environment model incorporates the hydrostatic, hydrodynamics, and ocean currents that will affect the AUV in a real-time mission. Based on this designed simulation framework, custom scenarios provided by the user can be modeled and its corresponding behaviors can be observed. This paper focuses on the accuracy of the simulated data from AUV model and environmental model derived from a developed AUV test-bed which was jointly upgraded by DSTO and the University of Adelaide. The main contribution of this paper is to experimentally verify the accuracy of the proposed simulation framework.
Abstract: Over last two decades, due to hostilities of environment
over the internet the concerns about confidentiality of information
have increased at phenomenal rate. Therefore to safeguard the information
from attacks, number of data/information hiding methods have
evolved mostly in spatial and transformation domain.In spatial domain
data hiding techniques,the information is embedded directly on
the image plane itself. In transform domain data hiding techniques the
image is first changed from spatial domain to some other domain and
then the secret information is embedded so that the secret information
remains more secure from any attack. Information hiding algorithms
in time domain or spatial domain have high capacity and relatively
lower robustness. In contrast, the algorithms in transform domain,
such as DCT, DWT have certain robustness against some multimedia
processing.In this work the authors propose a novel steganographic
method for hiding information in the transform domain of the gray
scale image.The proposed approach works by converting the gray
level image in transform domain using discrete integer wavelet
technique through lifting scheme.This approach performs a 2-D
lifting wavelet decomposition through Haar lifted wavelet of the cover
image and computes the approximation coefficients matrix CA and
detail coefficients matrices CH, CV, and CD.Next step is to apply the
PMM technique in those coefficients to form the stego image. The
aim of this paper is to propose a high-capacity image steganography
technique that uses pixel mapping method in integer wavelet domain
with acceptable levels of imperceptibility and distortion in the cover
image and high level of overall security. This solution is independent
of the nature of the data to be hidden and produces a stego image
with minimum degradation.
Abstract: ZnO nanocrystals with mean diameter size 14 nm
have been prepared by precipitation method, and examined as
photocatalyst for the UV-induced degradation of insecticide diazinon
as deputy of organic pollutant in aqueous solution. The effects of
various parameters, such as illumination time, the amount of
photocatalyst, initial pH values and initial concentration of
insecticide on the photocatalytic degradation diazinon were
investigated to find desired conditions. In this case, the desired
parameters were also tested for the treatment of real water containing
the insecticide. Photodegradation efficiency of diazinon was
compared between commercial and prepared ZnO nanocrystals. The
results indicated that UV/ZnO process applying prepared
nanocrystalline ZnO offered electrical energy efficiency and
quantum yield better than commercial ZnO. The present study, on the
base of Langmuir-Hinshelwood mechanism, illustrated a pseudo
first-order kinetic model with rate constant of surface reaction equal
to 0.209 mg l-1 min-1 and adsorption equilibrium constant of 0.124 l
mg-1.
Abstract: This paper focuses on a critical component of the situational awareness (SA), the neural control of depth flight of an autonomous underwater vehicle (AUV). Constant depth flight is a challenging but important task for AUVs to achieve high level of autonomy under adverse conditions. With the SA strategy, we proposed a multirate neural control of an AUV trajectory for a nontrivial mid-small size AUV “r2D4" stochastic model. This control system has been demonstrated and evaluated by simulation of diving maneuvers using software package Simulink. From the simulation results it can be seen that the chosen AUV model is stable in the presence of noises, and also can be concluded that the proposed research technique will be useful for fast SA of similar AUV systems in real-time search-and-rescue operations.
Abstract: This paper establishes some closed formulas for
Riemann- Liouville impulsive fractional integral calculus and also
for Riemann- Liouville and Caputo impulsive fractional
derivatives.
Abstract: This paper presents a spectroscopic study on doping
of Vanadyl pathalocyanine (VOPc) by [6,6]-phenyl C61 butyric acid
methyl ester (PCBM). The films are characterized by UV/Vis/NIR
spectroscopy. A drastic increase in the absorption coefficient has
been observed with increasing dopant concentration. Optical
properties of VOPc:PCBM films deposited by spin coating technique
were studied in detail. Optical band gap decreased with the PCBM
incorporation in the VOPc film. Optical band gap calculated from the
absorption spectra decreased from 3.32 eV to 3.26 eV with a
variation of 0–75 % of PCBM concentration in the VOPC films.
Abstract: This paper describes a feasibility study that is
included with the research, development and testing of a micro
communications sonobuoy deployable by Maritime Fixed wing
Unmanned Aerial Vehicles (M-UAV) and rotor wing Quad Copters
which are both currently being developed by the University of
Adelaide. The micro communications sonobuoy is developed to act
as a seamless communication relay between an Autonomous
Underwater Vehicle (AUV) and an above water human operator
some distance away. Development of such a device would eliminate
the requirement of physical communication tethers attached to
submersible vehicles for control and data retrieval.
Abstract: This paper study the behavior of the solution at the crack edges for an elliptical crack with developing cusps, Ω in the plane elasticity subjected to shear loading. The problem of finding the resulting shear stress can be formulated as a hypersingular integral equation over Ω and it is then transformed into a similar equation over a circular region, D, using conformal mapping. An appropriate collocation points are chosen on the region D to reduce the hypersingular integral equation into a system of linear equations with (2N+1)(N+1) unknown coefficients, which will later be used in the determination of shear stress intensity factors and maximum shear stress intensity. Numerical solution for the considered problem are compared with the existing asymptotic solution, and displayed graphically. Our results give a very good agreement to the existing asymptotic solutions.
Abstract: This paper focuses on the development of bond graph
dynamic model of the mechanical dynamics of an excavating mechanism
previously designed to be used with small tractors, which are
fabricated in the Engineering Workshops of Jomo Kenyatta University
of Agriculture and Technology. To develop a mechanical dynamics
model of the manipulator, forward recursive equations similar to
those applied in iterative Newton-Euler method were used to obtain
kinematic relationships between the time rates of joint variables
and the generalized cartesian velocities for the centroids of the
links. Representing the obtained kinematic relationships in bondgraphic
form, while considering the link weights and momenta as
the elements led to a detailed bond graph model of the manipulator.
The bond graph method was found to reduce significantly the number
of recursive computations performed on a 3 DOF manipulator for a
mechanical dynamic model to result, hence indicating that bond graph
method is more computationally efficient than the Newton-Euler
method in developing dynamic models of 3 DOF planar manipulators.
The model was verified by comparing the joint torque expressions
of a two link planar manipulator to those obtained using Newton-
Euler and Lagrangian methods as analyzed in robotic textbooks. The
expressions were found to agree indicating that the model captures
the aspects of rigid body dynamics of the manipulator. Based on
the model developed, actuator sizing and valve sizing methodologies
were developed and used to obtain the optimal sizes of the pistons
and spool valve ports respectively. It was found that using the pump
with the sized flow rate capacity, the engine of the tractor is able to
power the excavating mechanism in digging a sandy-loom soil.
Abstract: This paper presents the effect of driving a motor
vehicle on the stress levels of older drivers, indicated by monitoring
their hear rate increase whilst completing various everyday driving
tasks. Results suggest that whilst older female drivers heart rate varied
more significantly than males, the actual age of a participant did not
result in a significant change in heart rate due to stress, within the age
group tested. The analysis of the results indicates the most stressful
manoeuvres undertaken by the older drivers and highlights the tasks
which were found difficult with a view to implementing technologies
to aid the more senior driver in automotive travel.
Abstract: Leptospirosis occurs worldwide (except the
poles of the earth), urban and rural areas, developed and
developing countries, especially in Thailand. It can be
transmitted to the human by rats through direct and indirect
ways. Human can be infected by either touching the infected rats
or contacting with water, soil containing urine from the infected
rats through skin, eyes and nose. The data of the people who
are infected with this disease indicates that most of the
patients are adults. The transmission of this disease is studied
through mathematical model. The population is separated into human
and rat. The human is divided into two classes, namely juvenile
and adult. The model equation is constructed for each class. The
standard dynamical modeling method is then used for
analyzing the behaviours of solutions. In addition, the
conditions of the parameters for the disease free and endemic
states are obtained. Numerical solutions are shown to support the
theoretical predictions. The results of this study guide the way to
decrease the disease outbreak.
Abstract: The photochemical and photo-Fenton oxidation of 1,3-dichloro-2-propanol was performed in a batch reactor, at room temperature, using UV radiation, H2O2 as oxidant, and Fenton-s reagent. The effect of the oxidative agent-s initial concentration was investigated as well as the effect of the initial concentration of Fe(II) by following the target compound degradation, the total organic carbon removal and the chloride ion production. Also, from the kinetic analysis conducted and proposed reaction scheme it was deduced that the addition of Fe(II) significantly increases the production and the further oxidation of the chlorinated intermediates.