Abstract: The control design for unmanned underwater vehicles (UUVs) is challenging due to the uncertainties in the complex dynamic modeling of the vehicle as well as its unstructured operational environment. To cope with these difficulties, a practical robust control is therefore desirable. The paper deals with the application of coefficient diagram method (CDM) for a robust control design of an autonomous underwater vehicle. The CDM is an algebraic approach in which the characteristic polynomial and the controller are synthesized simultaneously. Particularly, a coefficient diagram (comparable to Bode diagram) is used effectively to convey pertinent design information and as a measure of trade-off between stability, response speed and robustness. In the polynomial ring, Kharitonov polynomials are employed to analyze the robustness of the controller due to parametric uncertainties.
Abstract: The elimimation of mefenamic acid has been carried
out by photolysis, ozonation, adsorption onto activated carbon (AC)
and combinations of the previous single systems (O3+AC and
O3+UV). The results obtained indicate that mefenamic acid is not
photo-reactive, showing a relatively low quantum yield of the order
of 6 x 10-4 mol Einstein-1. Application of ozone to mefenamic
aqueous solutions instantaneously eliminates the pharmaceutical,
achieving simultaneously a 40% of mineralization. Addition of AC to
the ozonation process does not enhance the process, moreover,
mineralization is completely inhibited if compared to results obtained
by single ozonation. The combination of ozone and UV radiation led
to the best results in terms of mineralization (60% after 120 min).
Abstract: The photocatalytic activity efficiency of TiO2 for the degradation of Toluene in photoreactor can be enhanced by nano- TiO2/LDPE composite film. Since the amount of TiO2 affected the efficiency of the photocatalytic activity, this work was mainly concentrated on the effort to embed the high amount of TiO2 in the Polyethylene matrix. The developed photocatalyst was characterized by XRD, UV-Vis spectrophotometer and SEM. The SEM images revealed the high homogeneity of the deposition of TiO2 on the polyethylene matrix. The XRD patterns interpreted that TiO2 embedded in the PE matrix exhibited mainly in anatase form. In addition, the photocatalytic results show that the toluene removal efficiencies of 30±5%, 49±4%, 68±5%, 42±6% and 33±5% were obtained when using the catalyst loading at 0%, 10%, 15%, 25% and 50% (wt. cat./wt. film), respectively.
Abstract: This work relates the development of an optical fiber
(OF) sensor for the detection and quantification of single walled
carbon nanotubes in aqueous solutions. The developed OF displays a
compact design, it requires less expensive materials and equipment
as well as low volume of sample (0.2 mL). This methodology was
also validated by the comparison of its analytical performance with
that of a standard methodology based on ultraviolet-visible
spectroscopy. The developed OF sensor follows the general SDS
calibration proposed for OF sensors as a more suitable calibration
fitting compared with classical calibrations.
Abstract: Excilamps are new UV sources with great potential
for application in wastewater treatment. In the present work, a XeBr
excilamp emitting radiation at 283 nm has been used for the
photodegradation of 4-chlorophenol within a range of concentrations
from 50 to 500 mg L-1. Total removal of 4-chlorophenol was
achieved for all concentrations assayed. The two main photoproduct
intermediates formed along the photodegradation process,
benzoquinone and hydroquinone, although not being completely
removed, remain at very low residual concentrations. Such
concentrations are insignificant compared to the 4-chlorophenol
initial ones and non-toxic. In order to simulate the process and scaleup,
a kinetic model has been developed and validated from the
experimental data.
Abstract: A study concerning the photocatalytic decolourization
of Congo red (CR) dye, over artificial UV irradiation is presented.
Photocatalysts based on a commercial titanium dioxide (TiO2)
modified with transition metals (Ni, Cu and Zn) were used. The
dopage method used was wet impregnation. A TiO2 sample without
salt was subjected to the same hydrothermal treatment to be used as
reference. Congo red solutions to several pH conditions (natural and
basic) were used to evaluate photocatalytic performance of each
doped catalysts. Photodecolourization percentage was measured
spectrofotrometically after 3 h of treatment to 499 nm as response
variable. Kinetics investigations of photodegradation indicated that
reactions obey to Langmuir-Hinshelwood model and pseudo–first
order law. The rate constant studies of photocatalytic decolourization
reactions for Zn–TiO2 and Cu–TiO2 photocatalysts indicated that in
all cases the rate constant of the reaction was higher than that of TiO2
undoped. These results show that nature of the metal modifying the
TiO2 influence on the efficiency of the photocatalyst evaluated in
process. Ni does not present an additional effect compared with TiO2,
while Zn enhances the photoactivity due to its electronic properties.
Abstract: This paper focuses on a critical component of the
situational awareness (SA), the control of autonomous vertical flight for tactical unmanned aerial vehicle (TUAV). With the SA strategy,
we proposed a two stage flight control procedure using two autonomous control subsystems to address the dynamics variation
and performance requirement difference in initial and final stages of flight trajectory for a nontrivial nonlinear eight-rotor helicopter
model. This control strategy for chosen model of mini-TUAV has been verified by simulation of hovering maneuvers using software
package Simulink and demonstrated good performance for fast
stabilization of engines in hovering, consequently, fast SA with
economy in energy of batteries can be asserted during search-andrescue
operations.
Abstract: Abai Kunanbayev is famous for being enlightener,
composer, interpreter, social agent, philosopher, reformer, who
wanted to enrich Kazakh literature by emergence with Russian and
European culture, and also as a founder of Kazakh written literary
language. Abai Kunanbayev was born in 1845 in East Kazakhstan
area and passed away in 1904 in his hometown. His oeuvre absorbed
and reflected all changes in the life of Kazakh society of the second
half of XIX century. Because ХІХ century, especially its second half,
was an important transition period for Kazakhstan, which radically
changed traditional way of Kazakh society and predetermined further
development in consequence of activation of Russian colonial policy
and approval of commodity-money relations in Steppe Land.Abai
Kunanbayev, besides Arabic and Persian common words and
loanwords from Quran in his words of edification, had used a lot of
words of Arabic, Persian, Latin, Russian, Nogai, Shaghatai, Polish,
Greek, Turkish, which are used in the Kazakh language.
Abstract: A simple method for the simultaneous determination
of hippuric acid and benzoic acid in urine using reversed-phase high
performance liquid chromatography was described. Chromatography
was performed on a Nova-Pak C18 (3.9 x 150 mm) column with a
mobile phase of mixed solution methanol: water: acetic acid
(20:80:0.2) and UV detection at 254 nm. The calibration curve was
linear within concentration range at 0.125 to 6.0 mg/ml of hippuric
acid and benzoic acid. The recovery, accuracy and coefficient
variance of hippuric acid were 104.54%, 0.2% and 0.2% respectively
and for benzoic acid were 98.48%, 1.25% and 0.60% respectively.
The detection limit of this method was 0.01ng/l for hippuric acid and
0.06ng/l for benzoic acid. This method has been applied to the
analysis of urine samples from the suspected of toluene abuser or
glue sniffer among secondary school students at Johor Bahru.
Abstract: The use of magnetic and magnetic/gold core/shell
nanoparticles in biotechnology or medicine has shown good promise
due to their hybrid nature which possesses superior magnetic and
optical properties. Some of these potential applications include
hyperthermia treatment, bio-separations, diagnostics, drug delivery
and toxin removal. Synthesis refinement to control geometric and
magnetic/optical properties, and finding functional surfactants for
biomolecular attachment, are requirements to meet application
specifics.
Various high-temperature preparative methods were used for the
synthesis of iron oxide and gold-coated iron oxide nanoparticles.
Different surface functionalities, such as 11-aminoundecanoic and
11-mercaptoundecanoic acid, were introduced on the surface of the
particles to facilitate further attachment of biomolecular functionality
and drug-like molecules. Nanoparticle thermal stability, composition,
state of aggregation, size and morphology were investigated and the
results from techniques such as Fourier Transform-Infra Red
spectroscopy (FT-IR), Ultraviolet visible spectroscopy (UV-vis),
Transmission Electron Microscopy (TEM) and thermal analysis are
discussed.
Abstract: Nano sized zirconium dioxide in monoclinic phase (m-ZrO2) has been synthesized in pure form through co-precipitation processing at different calcination temperatures and has been characterized by several techniques such as XRD, FT-IR, UV-Vis Spectroscopy and SEM. The dielectric and capacitance values of the pelletized samples have been examined at room temperature as the functions of frequency. The higher dielectric constant value of the sample having larger grain size proves the strong influence of grain size on the dielectric constant.
Abstract: In this work, we solve multipoint boundary value
problems where the boundary value conditions are equations using
the Newton-Broyden Shooting method (NBSM).The proposed
method is tested upon several problems from the literature and the
results are compared with the available exact solution. The
experiments are given to illustrate the efficiency and implementation
of the method.
Abstract: The accelerated sonophotocatalytic degradation of
Reactive Red (RR) 120 dye under visible light using dye sensitized
TiO2 activated by ultrasound has been carried out. The effect of
sonolysis, photocatalysis and sonophotocatalysis under visible light
has been examined to study the influence on the degradation rates by
varying the initial substrate concentration, pH and catalyst loading to
ascertain the synergistic effect on the degradation techniques.
Ultrasonic activation contributes degradation through cavitation
leading to the splitting of H2O2 produced by both photocatalysis and
sonolysis. This results in the formation of oxidative species, such as
singlet oxygen (1O2) and superoxide (O2
-●) radicals in the presence of
oxygen. The increase in the amount of reactive radical species which
induce faster oxidation of the substrate and degradation of
intermediates and also the deaggregation of the photocatalyst are
responsible for the synergy observed under sonication. A
comparative study of photocatalysis and sonophotocatalysis using
TiO2, Hombikat UV 100 and ZnO was also carried out.
Abstract: Ranong province has the best kaolin, and it is the most
useful of all the clay types used in ceramic making. Until recently,
there has been only one community business making ceramics in
Ranong province. And this business could not build the mix of body
and glaze from their raw material without assistance. Considering
these problems, this research is aimed to test the composition of
ceramic body and glaze which suit. Kaolin from Ranong is the raw
material which these search focuses on. All other raw materials use in
the investigation will come from southern Thailand, kaolin and
limestone from Ranong province, ball clay from Surat Thani
province, white sand from Songkhla province, and feldspar from
Nakhon Si Thammarat province. Results can be used to develop the
efficiency of industrial production which in return will enhance the
business process.
Abstract: Experiments have been carried out at sub-critical
Reynolds number to investigate free-to-roll motions induced by
forebody and/or wings complex flow on a 30° swept back nonslender
wings-slender body-model for static and dynamic (pitch-up)
cases. For the dynamic (pitch-up) case it has been observed that roll
amplitude decreases and lag increases with increase in pitching
speed. Decrease in roll amplitude with increase in pitch rate is
attributed to low disturbing rolling moment due to weaker interaction
between forebody and wing flow components. Asymmetric forebody
vortices dominate and control the roll motion of the model in
dynamic case when non-dimensional pitch rate ≥ 1x10-2.
Effectiveness of the active control scheme utilizing rotating nose with
artificial tip perturbation is observed to be low in the angle of attack
region where the complex flow over the wings has contributions from
both forebody and wings.
Abstract: This paper proposes a new solution to string matching problem. This solution constructs an inverted list representing a string pattern to be searched for. It then uses a new algorithm to process an input string in a single pass. The preprocessing phase takes 1) time complexity O(m) 2) space complexity O(1) where m is the length of pattern. The searching phase time complexity takes 1) O(m+α ) in average case 2) O(n/m) in the best case and 3) O(n) in the worst case, where α is the number of comparing leading to mismatch and n is the length of input text.
Abstract: Results of Chilean wine classification based on the
information provided by an electronic nose are reported in this paper.
The classification scheme consists of two parts; in the first stage,
Principal Component Analysis is used as feature extraction method to
reduce the dimensionality of the original information. Then, Radial
Basis Functions Neural Networks is used as pattern recognition
technique to perform the classification. The objective of this study is
to classify different Cabernet Sauvignon, Merlot and Carménère wine
samples from different years, valleys and vineyards of Chile.
Abstract: This study describes the preparation of a novel proton
conducting membranes based on bacterial cellulose (BC) modified by
grafting of 2-acrylamido-2-methyl-1 -propanesulfonic acid (AMPS)
through UV-induced graft polymerization. These AMPS-g-BC
membranes have been characterized by various techniques including
FTIR, SEM and TGA, to find their successful grafting of AMPS on
BC, surface morphology and thermal stability, respectively. Physical
properties of AMPS-g-BC membranes have been assessed in terms of
Lamda value( λ ), ion exchange capacity(IEC) and proton
conductivity. The relationship between degree of grafting and AMPS
concentration used for grafting has been determined by weight gain
method. An optimum proton conductivity equal to 2.89x10-2 S cm-1
and IEC value equal to 1.79 mmol g-1 have been obtained when 20
wt% AMPS concentration is used for grafting (i.e. the corresponding
membrane is notated as AMPS20-g-BC).
Abstract: One of the main challenges for one phase anaerobic digestion processes is the high concentration of NH4+ and PO4 3- ions
in the digested sludge supernatant. This project focuses on enhancing the removal of nutrients during the anaerobic digestion process through fixing both NH4+ and PO4 3- ions in the form of struvite (magnesium ammonium phosphate, MAP, MgNH4PO4.6H2O) within the anaerobic sludge. Batch anaerobic digestion tests showed that Mg2+ concentration in the range 279 – 812 mg/L had insignificant effect on CGP but incurred a slight increase in COD removal. The reactor that had soluble Mg2+:NH4+:PO43- at a molar ratio of 1.28:1:00:1:00 achieved the best performance enhancement of 8% increase in COD removal and 32% reduction in NH4+ in the reactor supernatant. Overall, the results show that there is a potential to optimise conventional anaerobic digestion such that supernatant lean in P and N, and sludge rich in nutrients are obtained.
Abstract: Titanium gels doped with water-soluble cationic porphyrin were synthesized by the sol–gel polymerization of Ti (OC4H9)4. In this work we investigate the spectroscopic properties along with SEM images of tetra carboxyl phenyl porphyrin when incorporated into porous matrix produced by the sol–gel technique.