Abstract: Noble metal participation in nanostructured
semiconductor catalysts has drawn much interest because of their
improved properties. Recently, it has been discussed by many
researchers that Ag participation in TiO2, CuO, ZnO semiconductors
showed improved photocatalytic and optical properties. In this
research, Ag/ZnO nanocomposite particles were prepared by
Ultrasonic Spray Pyrolysis(USP) Method. 0.1M silver and zinc
nitrate aqueous solutions were used as precursor solutions. The
Ag:Zn atomic ratio of the solution was selected 1:1. Experiments
were taken place under constant air flow of 400 mL/min at 800°C
furnace temperature. Particles were characterized by X-Ray
Diffraction (XRD), Scanning Electron Microscope (SEM) and
Energy Dispersive Spectroscopy (EDS). The crystallite sizes of Ag
and ZnO in composite particles are 24.6 nm, 19.7 nm respectively.
Although, spherical nanocomposite particles are in a range of 300-
800 nm, these particles are formed by the aggregation of primary
particles which are in a range of 20-60 nm.
Abstract: Efficient luminescence is reported for the first time in Eu2+ activated double Chlorides A2BCl4 (A=Alkali metal, B=Alkaline earth element). A simple wet-chemical preparation is described. Emission intensities are comparable to that of the commercial phosphor. Excitation covers near UV region. These phosphors may be useful for applications like solid state lighting, scintillation detectors and X-ray storage using photo-stimulable phosphors.
Abstract: Waste problem is becoming a future problem all over the world. Magnesium wastes which can be used in recycling processes are produced by many industrial activities. Magnesium borates which have useful properties such as; high heat resistance, corrosion resistance, supermechanical strength, superinsulation, light weight, high coefficient of elasticity and so on. Addition, magnesium borates have great potential in the development of ceramic and detergents industry, whisker-reinforced composites, antiwear, and reducing friction additives.
In this study, using the starting materials of waste magnesium and H3BO3 the hydrothermal method was applied at a moderate temperature of 70oC with different reaction times. Several reaction times of waste magnesium to H3BO3 were selected as; 30, 60, 120, 240 minutes. After the synthesis, X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR) techniques were applied to products. As a result, the forms of Admontite [MgO(B2O3)3.7(H2O)] and Mcallisterite [Mg2(B6O7(OH)6)2.9(H2O)] were synthesized.
Abstract: Thermoplastic starch, polylactic acid glycerol and
maleic anhydride (MA) were compounded with natural
montmorillonite (MMT) through a twin screw extruder to investigate
the effects of different loading of MMT on structure, thermal and
absorption behavior of the nanocomposites. X-ray diffraction analysis
(XRD) showed that sample with MMT loading 4phr exhibited
exfoliated structure while sample that contained MMT 8 phr
exhibited intercalated structure. FESEM images showed big lump
when MMT loading was at 8 phr. The thermal properties were
characterized by using differential scanning calorimeter (DSC). The
results showed that MMT increased melting temperature and
crystallization temperature of matrix but reduction in glass transition
temperature was observed Meanwhile the addition of MMT has
improved the water barrier property. The nanosize MMT particle is
also able to block a tortuous pathway for water to enter the starch
chain, thus reducing the water uptake and improved the physical
barrier of nanocomposite.
Abstract: For about two decades scientists have been
developing techniques for enhancing the quality of medical images
using Fourier transform, DWT (Discrete wavelet transform),PDE
model etc., Gabor wavelet on hexagonal sampled grid of the images
is proposed in this work. This method has optimal approximation
theoretic performances, for a good quality image. The computational
cost is considerably low when compared to similar processing in the
rectangular domain. As X-ray images contain light scattered pixels,
instead of unique sigma, the parameter sigma of 0.5 to 3 is found to
satisfy most of the image interpolation requirements in terms of high
Peak Signal-to-Noise Ratio (PSNR) , lower Mean Squared Error
(MSE) and better image quality by adopting windowing technique.
Abstract: In this paper, a simple microfluidic device for monitoring algal cell behavior is proposed. An array of algal microwells is fabricated by PDMS soft-lithography using X-ray LIGA mold, placed on a glass substrate. Two layers of replicated PDMS and substrate are attached by oxygen plasma bonding, creating a microchannel for the microfluidic system. Algal cell are loaded into the microfluidic device, which provides positive charge on the bottom surface of wells. Algal cells, which are negative charged, can be attracted to the bottom of the wells via electrostatic interaction. By varying the concentration of algal cells in the loading suspension, it is possible to obtain wells with a single cell. Liquid medium for cells monitoring are flown continuously over the wells, providing nutrient and waste exchange between the well and the main flow. This device could lead to the uncovering of the quantitative biology of the algae, which is a key to effective and extensive algal utilizations in the field of biotechnology, food industry and bioenergy research and developments.
Abstract: Artifact is one of the most important factors in
degrading the CT image quality and plays an important role in
diagnostic accuracy. In this paper, some artifacts typically appear in
Spiral CT are introduced. The different factors such as patient,
equipment and interpolation algorithm which cause the artifacts are
discussed and new developments and image processing algorithms to
prevent or reduce them are presented.
Abstract: In order to avoid the potentially devastating
consequences of global warming and climate change, the carbon
dioxide “CO2" emissions caused due to anthropogenic activities must
be reduced considerably. This paper presents the first study
examining the feasibility of carbon sequestration in construction and
demolition “C&D" waste. Experiments were carried out in a self
fabricated Batch Reactor at 40ºC, relative humidity of 50-70%, and
flow rate of CO2 at 10L/min for 1 hour for water-to-solids ratio of 0.2
to 1.2. The effect of surface area was found by comparing the
theoretical extent of carbonation of two different sieve sizes (0.3mm
and 2.36mm) of C&D waste. A 38.44% of the theoretical extent of
carbonation equating to 4% CO2 sequestration extent was obtained
for C&D waste sample for 0.3mm sieve size. Qualitative,
quantitative and morphological analyses were done to validate
carbonate formation using X-ray diffraction “X.R.D.," thermal
gravimetric analysis “T.G.A., “X-Ray Fluorescence Spectroscopy
“X.R.F.," and scanning electron microscopy “S.E.M".
Abstract: Based on the thermodynamic theory, the dependence of
sublimation energy of metal on temperature and pressure is discussed,
and the results indicate that the sublimation energy decreases linearly
with the increase of temperature and pressure. Combined with this
result, the blow-off impulse of aluminum induced by pulsed X-ray is
simulated by smoothed particle hydrodynamics (SPH) method. The
numerical results show that, while the change of sublimation energy
with temperature and pressure is considered, the blow-off impulse of
aluminum is larger than the case that the sublimation energy is
assumed to be a constant.
Abstract: Image registration plays an important role in the
diagnosis of dental pathologies such as dental caries, alveolar bone
loss and periapical lesions etc. This paper presents a new wavelet
based algorithm for registering noisy and poor contrast dental x-rays.
Proposed algorithm has two stages. First stage is a preprocessing
stage, removes the noise from the x-ray images. Gaussian filter has
been used. Second stage is a geometric transformation stage.
Proposed work uses two levels of affine transformation. Wavelet
coefficients are correlated instead of gray values. Algorithm has been
applied on number of pre and post RCT (Root canal treatment)
periapical radiographs. Root Mean Square Error (RMSE) and
Correlation coefficients (CC) are used for quantitative evaluation.
Proposed technique outperforms conventional Multiresolution
strategy based image registration technique and manual registration
technique.
Abstract: The present research focus on the processing of mullite-based ceramics from oil refinery industrial wastes and byproducts of agricultural industry and on the investigating of silane modified surface of ceramics. Two waste products were used as initial material – waste aluminum oxide and waste rice husk. The burning - out additives used were waste rise husk. It is known that the oxide ceramics surface is hydrophilic due to the presence of – OH groups in it. The nature of ceramic surface regarding permeation of water and hydrocarbons can be changed by further treatment with silanes. The samples were studied mainly by X-ray analysis, FT-IR absorbance measurements and microscopic analysis. The X-ray analyses showed the phase composition depends on the firing temperature and on the purity of the starting alumina. Two kind of silanes were used for the transformation of surface from hydrophilic to hydrophobic – trimethoxymethylsilane (TMMS) and trimethylclorsilane (TMCS).
Abstract: Platinum oxide nanoparticles were prepared by a
simple hydrothermal route and chemical reduction using
carbohydrates (Fructose and sucrose) as the reducing and
stabilizing agents. The crystallite size of these nanoparticles was
evaluated from X-ray diffraction (XRD), atomic force microscopy
(AFM) and transmission electron microscopy (TEM) and was
found to be 10 nm as shown in figure 1, which is the
demonstration of EM bright field and transmission electron
microscopy. The effect of carbohydrates on the morphology of the
nanoparticles was studied using TEM (Figure 1). The
nanoparticles (100 μg/ml) were administered to the Pseudomonas
Stutzeri and Lactobacillus cultures and the incubation was done at
35 oC for 24 hours. The nanocomposites exhibited interesting
inhibitory as well as bactericidal activity against P. Stutzeri and
and Lactobacillus species. Incorporation of nanoparticles also
increased the thermal stability of the carbohydrates.
Abstract: Bentonitic material from South Aswan, Egypt was evaluated in terms of mineral-ogy and chemical composition as bleaching clay in refining of transformer oil before and after acid activation and thermal treatment followed by acid leaching using HCl and H2SO4 for different contact times. Structural modification and refining power of bento-nite were investigated during modification by means of X-ray diffraction and infrared spectroscopy. The results revealed that the activated bentonite could be used for refining of transformer oil. The oil parameters such as; dielectric strength, viscosity and flash point had been improved. The dielectric breakdown strength of used oil increased from 29 kV for used oil treated with unactivated bentonite to 74 kV after treatment with activated bentonite. Kinematic Viscosity changed from 19 to 11 mm2 /s after treatment with activated bentonite. However, flash point achieved 149 ºC.
Abstract: We demonstrate the synthesis of intermediary views
within a sequence of color encoded, materials discriminating, X-ray
images that exhibit animated depth in a visual display. During the
image acquisition process, the requirement for a linear X-ray detector
array is replaced by synthetic image. Scale Invariant Feature
Transform, SIFT, in combination with material segmented morphing
is employed to produce synthetic imagery. A quantitative analysis of
the feature matching performance of the SIFT is presented along with
a comparative study of the synthetic imagery. We show that the total
number of matches produced by SIFT reduces as the angular
separation between the generating views increases. This effect is
accompanied by an increase in the total number of synthetic pixel
errors. The trends observed are obtained from 15 different luggage
items. This programme of research is in collaboration with the UK
Home Office and the US Dept. of Homeland Security.
Abstract: Medical image modalities such as computed
tomography (CT), magnetic resonance imaging (MRI), ultrasound
(US), X-ray are adapted to diagnose disease. These modalities
provide flexible means of reviewing anatomical cross-sections and
physiological state in different parts of the human body. The raw
medical images have a huge file size and need large storage
requirements. So it should be such a way to reduce the size of those
image files to be valid for telemedicine applications. Thus the image
compression is a key factor to reduce the bit rate for transmission or
storage while maintaining an acceptable reproduction quality, but it is
natural to rise the question of how much an image can be compressed
and still preserve sufficient information for a given clinical
application. Many techniques for achieving data compression have
been introduced. In this study, three different MRI modalities which
are Brain, Spine and Knee have been compressed and reconstructed
using wavelet transform. Subjective and objective evaluation has
been done to investigate the clinical information quality of the
compressed images. For the objective evaluation, the results show
that the PSNR which indicates the quality of the reconstructed image
is ranging from (21.95 dB to 30.80 dB, 27.25 dB to 35.75 dB, and
26.93 dB to 34.93 dB) for Brain, Spine, and Knee respectively. For
the subjective evaluation test, the results show that the compression
ratio of 40:1 was acceptable for brain image, whereas for spine and
knee images 50:1 was acceptable.
Abstract: Low oxygen content vanadium powder was
prepared by hydrogenation dehydrogenization (HDH). The
effect of purification treatment on hydrogen absorption kinetics
of dendritic vanadium was tested, and the effects of milling
technique on powder yield and grain size were studied. The
crystal phase, oxygen and nitrgen content, and grain size of
prepared powder were characterized and analyzed by X-ray
diffraction (XRD), oxygen and nitrogen analyzer and grain size
analyzer. The results show that the alkaline cleaning can
improve the hydrogen absorption of vanadium. The yield of
vanadium hydride powder can reach as high as 90% by 4h
ball-milling, The resultant product also have an oxygen content
less than 600μg/g, and the grain size is smaller than 37μm.
Meanwhile, the XRD results show that the phase of hydride
vanadium powder is mainly VH0.81. After a hydrogen
desorption treatment in vacuum at 700Ôäâ, the phase of the
powder converts into V and a little of V2H.
Abstract: A novel physico-chemical route to produce few layer graphene nanoribbons with atomically smooth edges is reported, via acid treatment (H2SO4:HNO3) followed by characteristic thermal shock processes involving extremely cold substances. Samples were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman spectroscopy and X-ray photoelectron spectroscopy. This method demonstrates the importance of having the nanotubes open ended for an efficient uniform unzipping along the nanotube axis. The average dimensions of these nanoribbons are approximately ca. 210 nm wide and consist of few layers, as observed by transmission electron microscopy. The produced nanoribbons exhibit different chiralities, as observed by high resolution transmission electron microscopy. This method is able to provide graphene nanoribbons with atomically smooth edges which could be used in various applications including sensors, gas adsorption materials, composite fillers, among others.
Abstract: The supported Pd catalysts were analyzed by X-ray
diffraction and X-ray absorption spectroscopy in order to determine
their global and local structure. The average particle size of the
supported Pd catalysts was determined by X-ray diffraction method.
One of the main purposes of the present contribution is to focus on
understanding the specific role of the Pd particle size determined by
X-ray diffraction and that of the support oxide. Based on X-ray
absorption fine structure spectroscopy analysis we consider that the
whole local structure of the investigated samples are distorted
concerning the atomic number but the distances between atoms are
almost the same as for standard Pd sample. Due to the strong
modifications of the Pd cluster local structure, the metal-support
interface may influence the electronic properties of metal clusters
and thus their reactivity for absorption of the reactant molecules.
Abstract: The effect of nano Co3O4 addition on the
superconducting properties of (Bi, Pb)-2223 system was studied. The
samples were prepared by the acetate coprecipitation method. The
Co3O4 with different sizes (10-30 nm and 30-50 nm) from x=0.00 to
0.05 was added to Bi1.6Pb0.4Sr2Ca2Cu3Oy(Co3O4)x. Phase analysis by
XRD method, microstructural examination by SEM and dc electrical
resistivity by four point probe method were done to characterize the
samples. The X-ray diffraction patterns of all the samples indicated
the majority Bi-2223 phase along with minor Bi-2212 and Bi-2201
phases. The volume fraction was estimated from the intensities of Bi-
2223, Bi-2212 and Bi-2201 phase. The sample with x=0.01 wt% of
the added Co3O4 (10-30 nm size) showed the highest volume fraction
of Bi-2223 phase (72%) and the highest superconducting transition
temperature, Tc (~102 K). The non-added sample showed the highest
Tc(~103 K) compared to added samples with nano Co3O4 (30-50 nm
size) added samples. Both the onset critical temperature Tc(onset)
and zero electrical resistivity temperature Tc(R=0) were in the range
of 103-115 ±1K and 91-103 ±1K respectively for samples with added
Co3O4 (10-30 nm and 30-50 nm).
Abstract: TiO2 nanoparticles were synthesized by hydrothermal
method at 180°C from TiOSO4 aqueous solution with1m/l
concentration. The obtained products were coated with silica by
means of a seeded polymerization technique for a coating time of
1440 minutes to obtain well defined TiO2@SiO2 core-shell structure.
The uncoated and coated nanoparticles were characterized by using
X-Ray diffraction technique (XRD), Fourier Transform Infrared
Spectroscopy (FT-IR) to study their physico-chemical properties.
Evidence from XRD and FTIR results show that SiO2 is
homogenously coated on the surface of titania particles. FTIR spectra
show that there exists an interaction between TiO2 and SiO2 and
results in the formation of Ti-O-Si chemical bonds at the interface of
TiO2 particles and SiO2 coating layer. The non linear optical limiting
properties of TiO2 and TiO2@SiO2 nanoparticles dispersed in
ethylene glycol were studied at 532nm using 5ns Nd:YAG laser
pulses. Three-photon absorption is responsible for optical limiting
characteristics in these nanoparticles and it is seen that the optical
nonlinearity is enhanced in core-shell structures when compared with
single counterparts. This effective three-photon type absorption at
this wavelength, is of potential application in fabricating optical
limiting devices.