Abstract: Novel bio-based polymer electrolyte was synthesized
with LiClO4 as the main source of charge carrier. Initially,
polyurethane-LiClO4 polymer electrolytes were synthesized via
prepolymerization method with different NCO/OH ratios and labelled
them as PU1, PU2, PU3 and PU4. Fourier transform infrared (FTIR)
analysis indicates the co-ordination between Li+ ion and polyurethane
in PU1. Differential scanning calorimetry (DSC) analysis indicates
PU1 has the highest glass transition temperature (Tg) corresponds to
the most abundant urethane group which is the hard segment in PU1.
Scanning electron microscopy (SEM) shows the good miscibility
between lithium salt and the polymer. The study found that PU1
possessed the greatest ionic conductivity and the lowest activation
energy, Ea. All the polyurethanes exhibited linear Arrhenius
variations indicating ion transport via simple lithium ion hopping in
polyurethane. This research proves the NCO content in polyurethane
plays an important role in affecting the ionic conductivity of this
polymer electrolyte.
Abstract: The discarded clam shell waste, fossil and edible oil
as biolubricant feedstocks create environmental impacts and food
chain dilemma, thus this work aims to circumvent these issues by
using activated saltwater clam shell waste (SCSW) as solid catalyst
for conversion of Jatropha curcas oil as non-edible sources to ester
biolubricant. The characterization of solid catalyst was done by
Differential Thermal Analysis-Thermo Gravimetric Analysis (DTATGA),
X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD),
Brunauer-Emmett-Teller (BET), Field Emission Scanning Electron
Microscopy (FESEM) and Fourier Transformed Infrared
Spectroscopy (FTIR) analysis. The calcined catalyst was used in the
transesterification of Jatropha oil to methyl ester as the first step, and
the second stage was involved the reaction of Jatropha methyl ester
(JME) with trimethylolpropane (TMP) based on the various process
parameters. The formated biolubricant was analyzed using the
capillary column (DB-5HT) equipped Gas Chromatography (GC).
The conversion results of Jatropha oil to ester biolubricant can be
found nearly 96.66%, and the maximum distribution composition
mainly contains 72.3% of triester (TE).
Abstract: Anultra-low power capacitor less low-dropout voltage
regulator with improved transient response using gain enhanced feed
forward path compensation is presented in this paper. It is based on a
cascade of a voltage amplifier and a transconductor stage in the feed
forward path with regular error amplifier to form a composite gainenhanced
feed forward stage. It broadens the gain bandwidth and thus
improves the transient response without substantial increase in power
consumption. The proposed LDO, designed for a maximum output
current of 100 mA in UMC 180 nm, requires a quiescent current of
69 )A. An undershot of 153.79mV for a load current changes from
0mA to 100mA and an overshoot of 196.24mV for current change of
100mA to 0mA. The settling time is approximately 1.1 )s for the
output voltage undershooting case. The load regulation is of 2.77
)V/mA at load current of 100mA. Reference voltage is generated by
using an accurate band gap reference circuit of 0.8V.The costly
features of SOC such as total chip area and power consumption is
drastically reduced by the use of only a total compensation
capacitance of 6pF while consuming power consumption of 0.096
mW.
Abstract: In this paper, strontium ferrite (SrO.6Fe2O3) was
synthesized by the sol-gel auto-combustion process. The thermal
behavior of powder obtained from self-propagating combustion of
initial gel was evaluated by simultaneous differential thermal analysis
(DTA) and thermo gravimetric (TG), from room temperature to
1200°C. The as-burnt powder was calcined at various temperatures
from 700-900°C to achieve the single-phase Sr-ferrite. Phase
composition, morphology and magnetic properties were investigated
using X-ray diffraction (XRD), transmission electron microscopy
(TEM) and vibrating sample magnetometry (VSM) techniques.
Results showed that the single-phase and nano-sized hexagonal
strontium ferrite particles were formed at calcination temperature of
800°C with crystallite size of 27 nm and coercivity of 6238 Oe.
Abstract: The effect of various humidities on process yields and
degrees of crystallinity for spray-dried powders from spray drying of
lactose with humid air in a straight-through system have been
studied. It has been suggested by Williams–Landel–Ferry kinetics
(WLF) that a higher particle temperature and lower glass-transition
temperature would increase the crystallization rate of the particles
during the spray-drying process. Freshly humidified air produced by
a Buchi-B290 spray dryer as a humidifier attached to the main spray
dryer decreased the particle glass-transition temperature (Tg), while
allowing the particle temperature (Tp) to reach higher values by using
an insulated drying chamber. Differential scanning calorimetry
(DSC) and moisture sorption analysis were used to measure the
degree of crystallinity for the spray-dried lactose powders. The
results showed that higher Tp-Tg, as a result of applying humid air,
improved the process yield from 21 ± 4 to 26 ± 2% and crystallinity
of the particles by decreasing the latent heat of crystallization from
43 ± 1 to 30 ± 11 J/g and the sorption peak height from 7.3 ± 0.7% to
6 ± 0.7%.
Abstract: A theoretical study has been presented to describe the boundary layer flow and heat transfer on an exponentially shrinking sheet with a variable wall temperature and suction, in the presence of magnetic field. The governing nonlinear partial differential equations are converted into ordinary differential equations by similarity transformation, which are then solved numerically using the shooting method. Results for the skin friction coefficient, local Nusselt number, velocity profiles as well as temperature profiles are presented through graphs and tables for several sets of values of the parameters. The effects of the governing parameters on the flow and heat transfer characteristics are thoroughly examined.
Abstract: The mixed convection stagnation point flow toward a vertical plate is investigated. The external flow impinges normal to the heated plate and the surface temperature is assumed to vary linearly with the distance from the stagnation point. The governing partial differential equations are transformed into a set of ordinary differential equations, which are then solved numerically using MATLAB routine boundary value problem solver bvp4c. Numerical results show that dual solutions are possible for a certain range of the mixed convection parameter. A stability analysis is performed to determine which solution is linearly stable and physically realizable.
Abstract: In this paper, we apply the Exp-function method to
Rosenau-Kawahara and Rosenau-KdV equations. Rosenau-Kawahara
equation is the combination of the Rosenau and standard Kawahara
equations and Rosenau-KdV equation is the combination of the
Rosenau and standard KdV equations. These equations are nonlinear
partial differential equations (NPDE) which play an important role
in mathematical physics. Exp-function method is easy, succinct and
powerful to implement to nonlinear partial differential equations
arising in mathematical physics. We mainly try to present an
application of Exp-function method and offer solutions for common
errors wich occur during some of the recent works.
Abstract: A phase diagram of the Ag2SO4 - CaSO4 (Silver sulphate – Calcium Sulphate) binaries system using conductivity, XRD (X-Ray Diffraction Technique) and DTA (Differential Thermal Analysis) data is constructed. The eutectic reaction (liquid -» a-Ag2SO4 + CaSO4) is observed at 10 mole% CaSO4 and 645°C. Room temperature solid solubility limit up to 5.27 mole % of Ca 2+ in Ag2SO4 is set using X-ray powder diffraction and scanning electron microscopy results. All compositions beyond this limit are two-phase mixtures below and above the transition temperature (≈ 416°C). The bulk conductivity, obtained following complex impedance spectroscopy, is found decreasing with increase in CaSO4 content. Amongst other binary compositions, the 80AgSO4-20CaSO4 gave improved sinterability/packing density.
Abstract: The effect of non-homogeneity on the free transverse vibration of thin rectangular plates of bilinearly varying thickness has been analyzed using generalized differential quadrature (GDQ) method. The non-homogeneity of the plate material is assumed to arise due to linear variations in Young’s modulus and density of the plate material with the in-plane coordinates x and y. Numerical results have been computed for fully clamped and fully simply supported boundary conditions. The solution procedure by means of GDQ method has been implemented in a MATLAB code. The effect of various plate parameters has been investigated for the first three modes of vibration. A comparison of results with those available in literature has been presented.
Abstract: A continuous time model of the interaction between
crop insect pests and naturally beneficial pest enemies is created
using a set of simultaneous, non-linear, ordinary differential
equations incorporating natural death rates based on the Weibull
distribution. The crop pest is present in all its life-cycle stages of:
egg, larva, pupa and adult. The beneficial insects, parasitoid wasps,
may be present in either or all parasitized: eggs, larva and pupa.
Population modelling is used to estimate the quantity of the natural
pest enemies that should be introduced into the pest infested
environment to suppress the pest population density to an
economically acceptable level within a prescribed number of days.
The results obtained illustrate the effect of different combinations of
parasitoid wasps, using the Pascal distribution to estimate their
success in parasitizing different pest developmental stages, to deliver
pest control to a sustainable level. Effective control, within a
prescribed number of days, is established by the deployment of two
or all three species of wasps, which partially destroy pest: egg, larvae
and pupae stages. The selected scenarios demonstrate effective
sustainable control of the pest in less than thirty days.
Abstract: In this paper, we propose a method that allows faster and more accurate detection of traffic lights by a vision sensor during driving, DGPS is used to obtain physical location of a traffic light, extract from the image information of the vision sensor only the traffic light area at this location and ascertain if the sign is in operation and determine its form. This method can solve the problem in existing research where low visibility at night or reflection under bright light makes it difficult to recognize the form of traffic light, thus making driving unstable. We compared our success rate of traffic light recognition in day and night road environments. Compared to previous researches, it showed similar performance during the day but 50% improvement at night.
Abstract: Solid lipid nanoparticles (SLNs) have gained great attention for the topical treatment of skin associated fungal infection as they facilitate the skin penetration of loaded drugs. Our work deals with the preparation of nystatin loaded solid lipid nanoparticles (NystSLNs) using the hot homogenization and ultrasonication method. The prepared NystSLNs were characterized in terms of entrapment efficiency, particle size, zeta potential, transmission electron microscopy, differential scanning calorimetry, rheological behavior and in vitro drug release. A stability study for 6 months was performed. A microbiological study was conducted in male rats infected with Candida albicans, by counting the colonies and examining the histopathological changes induced on the skin of infected rats. The results showed that SLNs dispersions are spherical in shape with particle size ranging from 83.26±11.33 to 955.04±1.09 nm. The entrapment efficiencies are ranging from 19.73±1.21 to 72.46±0.66% with zeta potential ranging from -18.9 to -38.8 mV and shear-thinning rheological Behavior. The stability studies done for 6 months showed that nystatin (Nyst) is a good candidate for topical SLN formulations. A least number of colony forming unit/ ml (cfu/ml) was recorded for the selected NystSLN compared to the drug solution and the commercial Nystatin® cream present in the market. It can be fulfilled from this work that SLNs provide a good skin targeting effect and may represent promising carrier for topical delivery of Nyst offering the sustained release and maintaining the localized effect, resulting in an effective treatment of cutaneous fungal infection.
Abstract: The coefficient diagram method is primarily an algebraic control design method whose objective is to easily obtain
a good controller with minimum user effort. As a matter of fact, if a
system model, in the form of linear differential equations, is known,
the user only need to define a time-constant and the controller order.
The later can be established regarding the expected disturbance type
via a lookup table first published by Koksal and Hamamci in 2004.
However an inaccuracy in this table was detected and pointed-out in
the present work. Moreover the above mentioned table was expanded
in order to enclose any k order type disturbance.
Abstract: Polymer composite nano-fibers including (1, 3 wt %)
silver nano-particles have been produced by electrospinning method.
Polyacrylonitrile/N,N-dimethylformamide (PAN/DMF) solution have
been prepared and the amount of silver nitrate have been adjusted to
PAN weight. Silver nano-particles were obtained from reduction of
silver ions into silver nano-particles by chemical reduction by
hydrazine hydroxide (N2H5OH). The different amount of silver salt
was loaded into polymer matrix to obtain polyacrylonitrile composite
nano-fiber containing silver nano-particles. The effect of the amount
of silver nano-particles on the properties of composite nano-fiber web
was investigated. Electrical conductivity, mechanical properties,
thermal properties were examined by Microtest LCR Meter 6370
(0.01 mΩ-100 MΩ), Tensile tester, Differential scanning calorimeter
DSC (Q10) and SEM respectively. Also antimicrobial efficiency test
(ASTM E2149-10) was done against to Staphylococcus aureus
bacteria. It has been seen that breaking strength, conductivity,
antimicrobial effect, enthalpy during cyclization increase by use of
silver nano-particles while the diameter of nano-fiber decreases.
Abstract: In this paper, we present a neural-network (NN) based
approach to represent a nonlinear Tagagi-Sugeno (T-S) system. A
linear differential inclusion (LDI) state-space representation is utilized
to deal with the NN models. Taking advantage of the LDI
representation, the stability conditions and controller design are
derived for a class of nonlinear structural systems. Moreover, the
concept of utilizing the Parallel Particle Swarm Optimization (PPSO)
algorithm to solve the common P matrix under the stability criteria is
given in this paper.
Abstract: In this paper, an analytical study is made for the dynamic behavior of human brain tissue under transient loading. In this analytical model the Mooney-Rivlin constitutive law is coupled with visco-elastic constitutive equations to take into account both the nonlinear and time-dependent mechanical behavior of brain tissue. Five ordinary differential equations representing the relationships of five main parameters (radial stress, circumferential stress, radial strain, circumferential strain, and particle velocity) are obtained by using the characteristic method to transform five partial differential equations (two continuity equations, one motion equation, and two constitutive equations). Analytical expressions of the attenuation properties for spherical wave in brain tissue are analytically derived. Numerical results are obtained based on the five ordinary differential equations. The mechanical responses (particle velocity and stress) of brain are compared at different radii including 5, 6, 10, 15 and 25 mm under four different input conditions. The results illustrate that loading curves types of the particle velocity significantly influences the stress in brain tissue. The understanding of the influence by the input loading cures can be used to reduce the potentially injury to brain under head impact by designing protective structures to control the loading curves types.
Abstract: The design of an optimised horizontal axis 5-meter-long wind turbine rotor blade in according with IEC 61400-2 standard is a research and development project in order to fulfil the requirements of high efficiency of torque from wind production and to optimise the structural components to the lightest and strongest way possible. For this purpose, a research study is presented here by focusing on the structural characteristics of a composite wind turbine blade via finite element modelling and analysis tools. In this work, first, the required data regarding the general geometrical parts are gathered. Then, the airfoil geometries are created at various sections along the span of the blade by using CATIA software to obtain the two surfaces, namely; the suction and the pressure side of the blade in which there is a hat shaped fibre reinforced plastic spar beam, so-called chassis starting at 0.5m from the root of the blade and extends up to 4 m and filled with a foam core. The root part connecting the blade to the main rotor differential metallic hub having twelve hollow threaded studs is then modelled. The materials are assigned as two different types of glass fabrics, polymeric foam core material and the steel-balsa wood combination for the root connection parts. The glass fabrics are applied using hand wet lay-up lamination with epoxy resin as METYX L600E10C-0, is the unidirectional continuous fibres and METYX XL800E10F having a tri-axial architecture with fibres in the 0,+45,-45 degree orientations in a ratio of 2:1:1. Divinycell H45 is used as the polymeric foam. The finite element modelling of the blade is performed via MSC PATRAN software with various meshes created on each structural part considering shell type for all surface geometries, and lumped mass were added to simulate extra adhesive locations. For the static analysis, the boundary conditions are assigned as fixed at the root through aforementioned bolts, where for dynamic analysis both fixed-free and free-free boundary conditions are made. By also taking the mesh independency into account, MSC NASTRAN is used as a solver for both analyses. The static analysis aims the tip deflection of the blade under its own weight and the dynamic analysis comprises normal mode dynamic analysis performed in order to obtain the natural frequencies and corresponding mode shapes focusing the first five in and out-of-plane bending and the torsional modes of the blade. The analyses results of this study are then used as a benchmark prior to modal testing, where the experiments over the produced wind turbine rotor blade has approved the analytical calculations.
Abstract: In this paper, the numerical solution of optimal control problem (OCP) for systems governed by Volterra integro-differential
(VID) equation is considered. The method is developed by means
of the Legendre wavelet approximation and collocation method. The
properties of Legendre wavelet together with Gaussian integration
method are utilized to reduce the problem to the solution of nonlinear
programming one. Some numerical examples are given to confirm the
accuracy and ease of implementation of the method.
Abstract: In this paper, Semi-orthogonal B-spline scaling
functions and wavelets and their dual functions are presented
to approximate the solutions of integro-differential equations.The
B-spline scaling functions and wavelets, their properties and the
operational matrices of derivative for this function are presented to
reduce the solution of integro-differential equations to the solution of
algebraic equations. Here we compute B-spline scaling functions of
degree 4 and their dual, then we will show that by using them we have
better approximation results for the solution of integro-differential
equations in comparison with less degrees of scaling functions