Abstract: The development, operation and maintenance of
Integrated Waste Management Systems (IWMS) affects essentially
the sustainable concern of every region. The features of such systems
have great influence on all of the components of sustainability. In
order to reach the optimal way of processes, a comprehensive
mapping of the variables affecting the future efficiency of the system
is needed such as analysis of the interconnections among the
components and modeling of their interactions. The planning of a
IWMS is based fundamentally on technical and economical
opportunities and the legal framework. Modeling the sustainability
and operation effectiveness of a certain IWMS is not in the scope of
the present research. The complexity of the systems and the large
number of the variables require the utilization of a complex approach
to model the outcomes and future risks. This complex method should
be able to evaluate the logical framework of the factors composing
the system and the interconnections between them. The authors of
this paper studied the usability of the Fuzzy Cognitive Map (FCM)
approach modeling the future operation of IWMS’s. The approach
requires two input data set. One is the connection matrix containing
all the factors affecting the system in focus with all the
interconnections. The other input data set is the time series, a
retrospective reconstruction of the weights and roles of the factors.
This paper introduces a novel method to develop time series by
content analysis.
Abstract: Member States shall establish zones and
agglomerations throughout their territory to assess and manage air
quality in order to comply with European directives.
In Italy decree 155/2010, transposing Directive 2008/50/EC on
ambient air quality and cleaner air for Europe, merged into a single
act the previous provisions on ambient air quality assessment and
management, including those resulting from the implementation of
Directive 2004/107/EC relating to arsenic, cadmium, nickel, mercury
and polycyclic aromatic hydrocarbons in ambient air.
Decree 155/2010 introduced stricter rules for identifying zones on
the basis of the characteristics of the territory in spite of considering
pollution levels, as it was in the past. The implementation of such
new criteria has reduced the great variability of the previous zoning,
leading to a significant reduction of the total number of zones and to
a complete and uniform ambient air quality assessment and
management throughout the Country.
The present document is related to the new zones definition in
Italy according to Decree 155/2010. In particular the paper contains
the description and the analysis of the outcome of zoning and
classification.
Abstract: The mechanics of rip currents are complex, involving
interactions between waves, currents, water levels and the bathymetry,
that present particular challenges for numerical models. Here,
the effects of a grid-spacing dependent horizontal mixing on the
wave-current interactions are studied. Near the shore, wave rays
diverge from channels towards bar crests because of refraction by
topography and currents, in a way that depends on the rip current
intensity which is itself modulated by the horizontal mixing. At
low resolution with the grid-spacing dependent horizontal mixing,
the wave motion is the same for both coupling modes because the
wave deviation by the currents is weak. In high resolution case,
however, classical results are found with the stabilizing effect of
the flow by feedback of waves on currents. Lastly, wave-current
interactions and the horizontal mixing strongly affect the intensity
of the three-dimensional rip velocity.
Abstract: The adsorption efficiency of fired clayey pellets of 5
and 8 mm diameter size for Cu(II) and Zn(II) ion removal from a
waste printing developer was studied. In order to investigate the
influence of contact time, adsorbent mass and pellet size on the
adsorption efficiency the batch mode was carried out. Faster uptake
of copper ion was obtained with the fired clay pellets of 5 mm
diameter size within 30 minutes. The pellets of 8 mm diameter size
showed the higher equilibrium time (60 to 75 minutes) for copper and
zinc ion. The results pointed out that adsorption efficiency increases
with the increase of adsorbent mass. The maximal efficiency is
different for Cu(II) and Zn(II) ion due to the pellet size. Therefore,
the fired clay pellets of 5 mm diameter size present an effective
adsorbent for Cu(II) ion removal (adsorption efficiency is 63.6%),
whereas the fired clay pellets of 8 mm diameter size are the best
alternative for Zn(II) ion removal (adsorption efficiency is 92.8%)
from a waste printing developer.
Abstract: The increasing demand of gallium, indium and
rare-earth elements for the production of electronics, e.g. solid
state-lighting, photovoltaics, integrated circuits, and liquid crystal
displays, will exceed the world-wide supply according to current
forecasts. Recycling systems to reclaim these materials are not yet in
place, which challenges the sustainability of these technologies. This
paper proposes a multispectral imaging system as a basis for a vision
based recognition system for valuable components of electronics
waste. Multispectral images intend to enhance the contrast of images
of printed circuit boards (single components, as well as labels) for
further analysis, such as optical character recognition and entire
printed circuit board recognition. The results show, that a higher
contrast is achieved in the near infrared compared to ultraviolett and
visible light.
Abstract: The present paper summarizes the analysis of the
request for consultation of information and data on industrial
emissions made publicly available on the web site of the Ministry of
Environment, Land and Sea on integrated pollution prevention and
control from large industrial installations, the so called “AIA Portal”.
As a matter of fact, a huge amount of information on national
industrial plants is already available on internet, although it is usually
proposed as textual documentation or images.
Thus, it is not possible to access all the relevant information
through interoperability systems and also to retrieval relevant
information for decision making purposes as well as rising of
awareness on environmental issue.
Moreover, since in Italy the number of institutional and private
subjects involved in the management of the public information on
industrial emissions is substantial, the access to the information is
provided on internet web sites according to different criteria; thus, at
present it is not structurally homogeneous and comparable.
To overcome the mentioned difficulties in the case of the
Coordinating Committee for the implementation of the Agreement
for the industrial area in Taranto and Statte, operating before the
IPPC permit granting procedures of the relevant installation located
in the area, a big effort was devoted to elaborate and to validate data
and information on characterization of soil, ground water aquifer and
coastal sea at disposal of different subjects to derive a global
perspective for decision making purposes. Thus, the present paper
also focuses on main outcomes matured during such experience.
Abstract: The aim of this paper is to give an assessment of
environmental effects of IPPC permit conditions of installations that
are in specific territory with high concentration of industrial
activities.
The IPPC permit is the permit that each operator should hold to
operate the installation as stated by the directive 2010/75/UE on
industrial emissions (integrated pollution prevention and control),
known as IED (Industrial Emissions Directive).
The IPPC permit includes all the measures necessary to achieve a
high level of protection of the environment as a whole, also defining
the monitoring requirements as measurement methodology,
frequency and evaluation procedure. The emissions monitoring of a
specific plant may also give indications of the contribution of these
emissions on the air quality of a definite area.
So, it is clear that the IPPC permits are important tools both to
improve the environmental framework and to achieve the air quality
standards, assisting to assess the possible industrial sources
contributions to air pollution.
Abstract: The tombolo of Giens is located in the town of Hyères
(France). We recall the history of coastal erosion, and prominent
factors affecting the evolution of the western tombolo. We then
discuss the possibility of stabilizing the western tombolo. Our
argumentation relies on a coupled model integrating swells, currents,
water levels and sediment transport. We present the conclusions of
the simulations of various scenarios, including pre-existing
propositions from coastal engineering offices. We conclude that
beach replenishment seems to be necessary but not sufficient for the
stabilization of the beach. Breakwaters reveal effective particularly in
the most exposed northern area. Some solutions fulfill conditions so
as to be elected as satisfactory. We give a comparative analysis of the
efficiency of 14 alternatives for the protection of the tombolo.
Abstract: The western Tombolo of the Giens peninsula in
southern France, known as Almanarre beach, is subject to coastal
erosion. We are trying to use computer simulation in order to propose
solutions to stop this erosion. Our aim was first to determine the main
factors for this erosion and successfully apply a coupled hydrosedimentological
numerical model based on observations and
measurements that have been performed on the site for decades.
We have gathered all available information and data about waves,
winds, currents, tides, bathymetry, coastal line, and sediments
concerning the site. These have been divided into two sets: one
devoted to calibrating a numerical model using Mike 21 software, the
other to serve as a reference in order to numerically compare the
present situation to what it could be if we implemented different
types of underwater constructions.
This paper presents the first part of the study: selecting and
melting different sources into a coherent data basis, identifying the
main erosion factors, and calibrating the coupled software model
against the selected reference period.
Our results bring calibration of the numerical model with good
fitting coefficients. They also show that the winter South-Western
storm events conjugated to depressive weather conditions constitute a
major factor of erosion, mainly due to wave impact in the northern
part of the Almanarre beach. Together, current and wind impact is
shown negligible.
Abstract: Interaction between human, location and activity
defines space. In the framework of these relations, space is a
container for current specifications in relations of the 3 mentioned
elements. The change of land utility considered with average
performance range, urban regulations, society requirements etc. will
provide welfare and comfort for citizens. From an engineering view it
is fundamental that choosing a proper location for a specific civil
activity requires evaluation of locations from different perspectives.
The debate of desirable establishment of municipal service elements
in urban regions is one of the most important issues related to urban
planning. In this paper, the research type is applicable based on goal,
and is descriptive and analytical based on nature. Initially existing
terminals in Esfahan are surveyed and then new locations are
presented based on evaluated criteria. In order to evaluate terminals
based on the considered factors, an AHP model is used at first to
estimate weight of different factors and then existing and suggested
locations are evaluated using Arc GIS software and AHP model
results. The results show that existing bus terminals are located in
fairly proper locations. Further results of this study suggest new
locations to establish terminals based on urban criteria.
Abstract: This paper presents an adaptive thermal comfort
model study in the tropical country of Malaysia. A number of
researchers have been interested in applying the adaptive thermal
comfort model to different climates throughout the world, but so far
no study has been performed in Malaysia. For the use as a thermal
comfort model, which better applies to hot and humid climates, the
adaptive thermal comfort model was developed as part of this
research by using the collected results from a large field study in six
lecture halls with 178 students. The relationship between the
operative temperature and behavioral adaptations was determined. In
the developed adaptive model, the acceptable indoor neutral
temperatures lay within the range of 23.9-26.0C, with outdoor
temperatures ranging between 27.0-34.6C. The most comfortable
temperature for students in lecture hall was 25.7C.
Abstract: In this study was monitored the population of the
European Pond Turtle, Emys orbicularis (Linnaeus, 1758) in the area
of Narta Lagoon, Vlora Bay (Albania), from August to October 2014.
A total of 54 individuals of E. orbicularis were studied using
different methodologies. Curved Carapace Length (CCL), Plastron
Length (PL) and Curved Carapace Width (CCW) were measured for
each individual of E. orbicularis and were statistically analyzed. All
captured turtles were separated in seven different size – classes based
on their carapace length (CCL). Each individual of E. orbicularis was
marked by notching the carapace (marginal scutes). Form all
individuals captured resulted that 37 were females (68.5%), 14 males
(25.9%), 3 juveniles (5.5%), while 18 individuals of E. orbicularis
were recaptured for the first and some for the second time.
Abstract: This study was conducted in the area of Vlora Bay,
Albania. Data about Sea Turtles Caretta caretta and Chelonia mydas,
belonging to two periods of time (1984 – 1991; 2008 – 2014) are
given. All data gathered were analyzed using recent methodologies.
For all turtles captured (as by catch), the Curve Carapace Length
(CCL) and Curved Carapace Width (CCW) were measured. These
data were statistically analyzed, where the mean was 67.11 cm for
CCL and 57.57 cm for CCW of all individuals studied (n=13). All
untagged individuals of marine turtles were tagged using metallic
tags (Stockbrand’s titanium tag) with an Albanian address. Sex was
determined and resulted that 45.4% of individuals were females,
27.3% males and 27.3% juveniles. All turtles were studied for the
presence of the epibionts. The area of Vlora Bay is used from marine
turtles (Caretta caretta) as a migratory corridor to pass from
Mediterranean to the northern part of the Adriatic Sea.
Abstract: Modelling of the earth's surface and evaluation of
urban environment, with 3D models, is an important research topic.
New stereo capabilities of high resolution optical satellites images,
such as the tri-stereo mode of Pleiades, combined with new image
matching algorithms, are now available and can be applied in urban
area analysis. In addition, photogrammetry software packages gained
new, more efficient matching algorithms, such as SGM, as well as
improved filters to deal with shadow areas, can achieve more dense
and more precise results.
This paper describes a comparison between 3D data extracted
from tri-stereo and dual stereo satellite images, combined with pixel
based matching and Wallis filter. The aim was to improve the
accuracy of 3D models especially in urban areas, in order to assess if
satellite images are appropriate for a rapid evaluation of urban
environments.
The results showed that 3D models achieved by Pleiades tri-stereo
outperformed, both in terms of accuracy and detail, the result
obtained from a Geo-eye pair. The assessment was made with
reference digital surface models derived from high resolution aerial
photography. This could mean that tri-stereo images can be
successfully used for the proposed urban change analyses.
Abstract: Although, arsenic trioxide has been the subject of
toxicological research, in vitro cytotoxicity and genotoxicity studies
using relevant cell models and uniform methodology are not well
elucidated. Hence, the aim of the present study was to evaluate the
cytotoxicity and genotoxicity induced by arsenic trioxide in human
keratinocytes (HaCaT) using the MTT [3-(4, 5-dimethylthiazol-2-yl)-
2,5-diphenyltetrazolium bromide] and alkaline single cell gel
electrophoresis (Comet) assays, respectively. Human keratinocytes
were treated with different doses of arsenic trioxide for 4 h prior to
cytogenetic assessment. Data obtained from the MTT assay indicated
that arsenic trioxide significantly reduced the viability of HaCaT cells
in a dose-dependent manner, showing an IC50 value of 34.18 ± 0.6
μM. Data generated from the comet assay also indicated a significant
dose-dependent increase in DNA damage in HaCaT cells associated
with arsenic trioxide exposure. We observed a significant increase in
comet tail length and tail moment, showing an evidence of arsenic
trioxide -induced genotoxic damage in HaCaT cells. This study
confirms that the comet assay is a sensitive and effective method to
detect DNA damage caused by arsenic.
Abstract: In this investigation, we have evaluated the effects of
arsenic trioxide on hepatic function in pregnant and lactating Swiss
albino mice and their suckling pups. Experiments were carried out on
female mice given 175 ppm As2O3 in their drinking water from the
14th day of pregnancy until day 14 after delivery. Our results showed
a significant decrease in plasma levels of total protein and albumin,
cholesterol and triglyceride in As2O3 treated mice and their pups. The
hyperbilirubinemia and the increased plasma total alkaline
phosphatase activity suggested the presence of cholestasis.
Transaminase activities as well as lactate deshydrogenase activity in
plasma, known as biomarkers of hepatocellular injury, were elevated
indicating hepatic cells’ damage after treatment with As2O3.
Exposure to arsenic led to an increase of liver thiobarbituric acid
reactive substances level along with a concomitant decrease in the
activities of superoxide dismutase, catalase and glutathione
peroxidase and in glutathione.
Abstract: Macro invertebrates have been used to monitor
organic pollution in rivers and streams. Several biotic indices based
on macro invertebrates have been developed over the years including
the Biological Monitoring Working Party (BMWP). A new biotic
index, the Gammarus:Asellus ratio has been recently proposed as an
index of organic pollution. This study tested the validity of the
Gammarus:Asellus ratio as an index of organic pollution, by
examining the relationship between the Gammarus:Asellus ratio and
physical chemical parameters, and other biotic indices such as
BMWP and, Average Score Per Taxon (ASPT) from lakes and
streams at Markeaton Park, Allestree Park and Kedleston Hall,
Derbyshire. Macro invertebrates were sampled using the standard
five minute kick sampling techniques physical and chemical
environmental variables were obtained based on standard sampling
techniques. Eighteen sites were sampled, six sites from Markeaton
Park (three sites across the stream and three sites across the lake). Six
sites each were also sampled from Allestree Park and Kedleston Hall
lakes. The Gammarus:Asellus ratio showed an opposite significant
positive correlations with parameters indicative of organic pollution
such as the level of nitrates, phosphates, and calcium and also
revealed a negatively significant correlations with other biotic indices
(BMWP/ASPT). The BMWP score correlated positively significantly
with some water quality parameters such as dissolved oxygen and
flow rate, but revealed no correlations with other chemical
environmental variables. The BMWP score was significantly higher
in the stream than the lake in Markeaton Park, also The ASPT scores
appear to be significantly higher in the upper Lakes than the middle
and lower lakes. This study has further strengthened the use of
BMWP/ASPT score as an index of organic pollution. But additional
application is required to validate the use of Gammarus:Asellus as a
rapid bio monitoring tool.
Abstract: Newly synthesized Polypropylene-g-Polyethylene
glycol polymer was first time used for a compartment-less enzymatic
fuel cell. Working electrodes based on Polypropylene-g-Polyethylene
glycol were operated as unmediated and mediated system (with
ferrocene and gold/cobalt oxide nanoparticles). Glucose oxidase and
bilirubin oxidase was selected as anodic and cathodic enzyme,
respectively. Glucose was used as fuel in a single-compartment and
membrane-less cell. Maximum power density was obtained as 0.65
nW cm-2, 65 nW cm-2 and 23500 nW cm-2 from the unmediated,
ferrocene and gold/cobalt oxide modified polymeric film,
respectively. Power density was calculated to be ~16000 nW cm-2 for
undiluted wastewater sample with gold/cobalt oxide nanoparticles
including system.
Abstract: In this article a comparison was made between Cu and
TiO2 supported catalysts on activated carbon for ozone
decomposition reaction. The activated carbon support in the case of
TiO2/AC sample was prepared by physicochemical pyrolysis and for
Cu/AC samples the supports are chemically modified carbons. The
prepared catalysts were synthesized by impregnation method. The
samples were annealed in two different regimes- in air and under
vacuum. To examine adsorption efficiency of the samples BET
method was used. All investigated catalysts supported on chemically
modified carbons have higher specific surface area compared to the
specific surface area of TiO2 supported catalysts, varying in the range
590÷620 m2/g. The method of synthesis of the precursors had
influenced catalytic activity.
Abstract: Remote sensing plays a vital role in mapping of
resources and monitoring of environments of the earth. In the present
research study, mapping and monitoring of clay siltations occurred in
the Alkhod Dam of Muscat, Sultanate of Oman are carried out using
low-cost multispectral Landsat and ASTER data. The dam is
constructed across the Wadi Samail catchment for ground water
recharge. The occurrence and spatial distribution of siltations in the
dam are studied with five years of interval from the year 1987 of
construction to 2014. The deposits are mainly due to the clay, sand
and silt occurrences derived from the weathering rocks of ophiolite
sequences occurred in the Wadi Samail catchment. The occurrences
of clays are confirmed by minerals identification using ASTER
VNIR-SWIR spectral bands and Spectral Angle Mapper supervised
image processing method. The presence of clays and their spatial
distribution are verified in the field. The study recommends the
technique and the low-cost satellite data to similar region of the
world.