Abstract: Strong anion exchange resins with QN+OH-, have the
potential to be developed and employed as heterogeneous catalyst for
transesterification, as they are chemically stable to leaching of the
functional group. Nine different SIERs (SIER1-9) with QN+OH-were
prepared by suspension polymerization of vinylbenzyl chloridedivinylbenzene
(VBC-DVB) copolymers in the presence of n-heptane
(pore-forming agent). The amine group was successfully grafted into
the polymeric resin beads through functionalization with
trimethylamine. These SIERs are then used as a catalyst for the
transesterification of triacetin with methanol. A set of differential
equations that represents the Langmuir-Hinshelwood-Hougen-
Watson (LHHW) and Eley-Rideal (ER) models for the
transesterification reaction were developed. These kinetic models of
LHHW and ER were fitted to the experimental data. Overall, the
synthesized ion exchange resin-catalyzed reaction were welldescribed
by the Eley-Rideal model compared to LHHW models,
with sum of square error (SSE) of 0.742 and 0.996, respectively.
Abstract: Currently, thorium fuel has been especially noticed
because of its proliferation resistance than long half-life alpha emitter
minor actinides, breeding capability in fast and thermal neutron flux
and mono-isotopic naturally abundant. In recent years, efficiency of
minor actinide burning up in PWRs has been investigated. Hence, a
minor actinide-contained thorium based fuel matrix can confront both
proliferation resistance and nuclear waste depletion aims. In the
present work, minor actinide depletion rate in a CANDU-type nuclear
core modeled using MCNP code has been investigated. The obtained
effects of minor actinide load as mixture of thorium fuel matrix on
the core neutronics has been studied with comparing presence and
non-presence of minor actinide component in the fuel matrix.
Depletion rate of minor actinides in the MA-contained fuel has been
calculated using different power loads. According to the obtained
computational data, minor actinide loading in the modeled core
results in more negative reactivity coefficients. The MA-contained
fuel achieves less radial peaking factor in the modeled core. The
obtained computational results showed 140 kg of 464 kg initial load
of minor actinide has been depleted in during a 6-year burn up in 10
MW power.
Abstract: In this paper, student admission process is studied to
optimize the assignment of vacant seats with three main objectives.
Utilizing all vacant seats, satisfying all programs of study admission
requirements and maintaining fairness among all candidates are the
three main objectives of the optimization model. Seat Assignment
Method (SAM) is used to build the model and solve the optimization
problem with help of Northwest Coroner Method and Least Cost
Method. A closed formula is derived for applying the priority of
assigning seat to candidate based on SAM.
Abstract: Factors affecting construction unit cost vary
depending on a country’s political, economic, social and
technological inclinations. Factors affecting construction costs have
been studied from various perspectives. Analysis of cost factors
requires an appreciation of a country’s practices. Identified cost
factors provide an indication of a country’s construction economic
strata. The purpose of this paper is to identify the essential factors
that affect unit cost estimation and their breakdown using artificial
neural networks. Twenty five (25) identified cost factors in road
construction were subjected to a questionnaire survey and employing
SPSS factor analysis the factors were reduced to eight. The 8 factors
were analysed using neural network (NN) to determine the
proportionate breakdown of the cost factors in a given construction
unit rate. NN predicted that political environment accounted 44% of
the unit rate followed by contractor capacity at 22% and financial
delays, project feasibility and overhead & profit each at 11%. Project
location, material availability and corruption perception index had
minimal impact on the unit cost from the training data provided.
Quantified cost factors can be incorporated in unit cost estimation
models (UCEM) to produce more accurate estimates. This can create
improvements in the cost estimation of infrastructure projects and
establish a benchmark standard to assist the process of alignment of
work practises and training of new staff, permitting the on-going
development of best practises in cost estimation to become more
effective.
Abstract: This paper presents a new structure of microstrip band
pass filter (BPF) based on coupled stepped impedance resonators.
Each filter consists of two coupled stepped impedance resonators
connected to microstrip feed lines. The coupled junction is utilized to
connect the two BPFs to the antenna. This two band pass filters are
designed and simulated to operate for the digital communication
system (DCS) and Industrial Scientific and Medical (ISM) bands at
1.8 GHz and 2.45 GHz respectively. The proposed circuit presents
good performances with an insertion loss lower than 2.3 dB and
isolation between the two channels greater than 21 dB. The prototype
of the optimized diplexer have been investigated numerically by
using ADS Agilent and verified with CST microwave software.
Abstract: Carbon fiber reinforced polymersarewidely used to strengthen steel structural elements. These structural elements are normally subjected to static, dynamic and fatigue loadings during their life-time. CFRP laminate is commonly used to strengthen these structures under the subjected loads. A number of studies have focused on the characteristics of CFRP sheets bonded to steel members under static, dynamic and fatigue loadings. However, there is a gap in understanding the bonding behavior between CFRP laminates and steel members under impact loading. This paper shows the effect of high load rates on this bond. CFRP laminate CFK 150/2000 was used to strengthen steel joints using Araldite 420 epoxy. The results show that applying a high load rate significantly affects the bond strength but has little influence on the effective bond length.
Abstract: In this study, attempt has been made to investigate the
relationship specifically the causal relation between fund unit prices
of Islamic equity unit trust fund which measure by fund NAV and the
selected macro-economic variables of Malaysian economy by using
VECM causality test and Granger causality test. Monthly data has
been used from Jan, 2006 to Dec, 2012 for all the variables. The
findings of the study showed that industrial production index,
political election and financial crisis are the only variables having
unidirectional causal relationship with fund unit price. However the
global oil price is having bidirectional causality with fund NAV.
Thus, it is concluded that the equity unit trust fund industry in
Malaysia is an inefficient market with respect to the industrial
production index, global oil prices, political election and financial
crisis. However the market is approaching towards informational
efficiency at least with respect to four macroeconomic variables,
treasury bill rate, money supply, foreign exchange rate, and
corruption index.
Abstract: In this study the instability problem of a modified
Taylor-Couette flow between two vertical coaxial cylinders of radius
R1, R2 is considered. The modification is based on the wavy shape of
the inner cylinder surface, where inner cylinders with different
surface amplitude and wavelength are used. The study aims to
discover the effect of the inner surface geometry on the instability
phenomenon that undergoes Taylor-Couette flow. The study reveals
that the transition processes depends strongly on the amplitude and
wavelength of the inner cylinder surface and resulting in flow
instabilities that are strongly different from that encountered in the
case of the classical Taylor-Couette flow.
Abstract: Climate change confronts the built environment with
many new challenges in the form of more severe and frequent hydrometeorological
events. A series of strategies is proposed whereby the
various aspects of buildings and their sites can be made more resilient
to the effects of such events.
Abstract: Artificial Neural Network (ANN) can be trained using
back propagation (BP). It is the most widely used algorithm for
supervised learning with multi-layered feed-forward networks.
Efficient learning by the BP algorithm is required for many practical
applications. The BP algorithm calculates the weight changes of
artificial neural networks, and a common approach is to use a twoterm
algorithm consisting of a learning rate (LR) and a momentum
factor (MF). The major drawbacks of the two-term BP learning
algorithm are the problems of local minima and slow convergence
speeds, which limit the scope for real-time applications. Recently the
addition of an extra term, called a proportional factor (PF), to the
two-term BP algorithm was proposed. The third increases the speed
of the BP algorithm. However, the PF term also reduces the
convergence of the BP algorithm, and criteria for evaluating
convergence are required to facilitate the application of the three
terms BP algorithm. Although these two seem to be closely related,
as described later, we summarize various improvements to overcome
the drawbacks. Here we compare the different methods of
convergence of the new three-term BP algorithm.
Abstract: Developing young people’s employability is a key
policy issue for ensuring their successful transition to the labour
market and their access to career oriented employment. The youths of
today irrespective of their gender need to acquire the knowledge,
skills and attitudes that will enable them to create or find jobs as well
as cope with unpredictable labour market changes throughout their
working lives. In a study carried out to determine the influence of
gender on job-competencies requirements of chemical-based
industries and undergraduate-competencies acquisition by chemists
working in the industries, all chemistry graduates working in twenty
(20) chemical-based industries that were randomly selected from six
sectors of chemical-based industries in Lagos and Ogun States of
Nigeria were administered with Job-competencies required and
undergraduate-competencies acquired assessment questionnaire. The
data were analysed using means and independent sample t-test. The
findings revealed that the population of female chemists working in
chemical-based industries is low compared with the number of male
chemists; furthermore, job-competencies requirements are found not
to be gender biased while there is no significant difference in
undergraduate-competencies acquisition of male and female
chemists. This suggests that females should be given the same
opportunity of employment in chemical-based industries as their male
counterparts. The study also revealed the level of acquisition of
undergraduate competencies as related to the needs of chemicalbased
industries.
Abstract: The purpose of this study was to reduce patient
waiting times, improve system throughput and improve resources
utilization in radiology department. A discrete event simulation
model was developed using Arena simulation software to investigate
different alternatives to improve the overall system delivery based on
adding resource scenarios due to the linkage between patient waiting
times and resource availability. The study revealed that there is no
addition investment need to procure additional scanner but hospital
management deploy managerial tactics to enhance machine
utilization and reduce the long waiting time in the department.
Abstract: In this paper, effect of marginal quality groundwater
on yield of cotton crop and soil salinity was studied. In this
connection, three irrigation treatments each with four replications
were applied. These treatments were i) use of canal water (T1), ii) use
of marginal quality groundwater from tubewell (T2), and iii)
conjunctive use by mixing with the ratio of 1:1 of canal water and
marginal quality tubewell water (T3).
Water was applied to the crop cultivated in Kharif season 2011; its
quantity has been measured using cut-throat flume. Total 11 watering
each of 50 mm depth have been applied from 20th April to 20th July,
2011. Further, irrigations were stopped due to monsoon rainfall up to
crop harvesting.
Maximum crop yield (seed cotton) was observed under T1 which
was 1,517 kg/ha followed by T3 (mixed canal and tubewell water)
having 1009 kg/ha and T2 i.e. marginal quality groundwater having
709 kg/ha. This concludes that crop yield in T2 and T3 in comparison
to T1was reduced by about 53 and 30% respectively.
It has been observed that yield of cotton crop is below potential
limit for three treatments due to unexpected rainfall at the time of full
flowering season; thus the yield was adversely affected.
However, salt deposition in soil profiles was not observed that is
due to leaching effect of heavy rainfall occurred during monsoon
season.
Abstract: In this study which has been conducted in Akçasu
Forest Range District of Devrek Forest Directorate; 3 methods (weed
control with labourer power, cover removal with Hitachi F20
Excavator, and weed control with agricultural equipment mounted on
a Ferguson 240S agriculture tractor) were utilized in weed control
efforts in regeneration of degraded oriental beech forests have been
compared. In this respect, 3 methods have been compared by
determining certain work hours and standard durations of unit areas
(1 hectare). For this purpose, evaluating the tasks made with human
and machine force from the aspects of duration, productivity and
costs, it has been aimed to determine the most productive method in
accordance with the actual ecological conditions of research field.
Within the scope of the study, the time studies have been conducted
for 3 methods used in weed control efforts. While carrying out those
studies, the performed implementations have been evaluated by
dividing them into business stages. Also, the actual data have been
used while calculating the cost accounts. In those calculations, the
latest formulas and equations which are also used in developed
countries have been utilized. The variance of analysis (ANOVA) was
used in order to determine whether there is any statistically
significant difference among obtained results, and the Duncan test
was used for grouping if there is significant difference. According to
the measurements and findings carried out within the scope of this
study, it has been found during living cover removal efforts in
regeneration efforts in demolished oriental beech forests that the
removal of weed layer in 1 hectare of field has taken 920 hours with
labourer force, 15.1 hours with excavator and 60 hours with an
equipment mounted on a tractor. On the other hand, it has been
determined that the cost of removal of living cover in unit area (1
hectare) was 3220.00 TL for labourer power, 1250 TL for excavator
and 1825 TL for equipment mounted on a tractor.
According to the obtained results, it has been found that the
utilization of excavator in weed control effort in regeneration of
degraded oriental beech regions under actual ecological conditions of
research field has been found to be more productive from both of
aspects of duration and costs. These determinations carried out
should be repeated in weed control efforts in degraded forest fields
with different ecological conditions, it is compulsory for finding the
most efficient weed control method. These findings will light the way
of technical staff of forestry directorate in determination of the most
effective and economic weed control method. Thus, the more actual
data will be used while preparing the weed control budgets, and there
will be significant contributions to national economy. Also the results of this and similar studies are very important for developing the policies for our forestry in short and long term.
Abstract: Liposome plays an important role in medical and
pharmaceutical science as e.g. nano scale drug carriers. Liposomes
are vesicles of varying size consisting of a spherical lipid bilayer and
an aqueous inner compartment. Magnet-driven liposome used for the
targeted delivery of drugs to organs and tissues. These liposome
preparations contain encapsulated drug components and finely
dispersed magnetic particles.
Liposomes are vesicles of varying size consisting of a spherical
lipid bilayer and an aqueous inner compartment that are generated in
vitro. These are useful in terms of biocompatibility, biodegradability,
and low toxicity, and can control biodistribution by changing the size,
lipid composition, and physical characteristics. Furthermore,
liposomes can entrap both hydrophobic and hydrophilic drugs and are
able to continuously release the entrapped substrate, thus being useful
drug carriers. Magnetic liposomes (MLs) are phospholipid vesicles
that encapsulate magneticor paramagnetic nanoparticles. They are
applied as contrast agents for magnetic resonance imaging (MRI).
The biological synthesis of nanoparticles using plant extracts plays
an important role in the field of nanotechnology. Green-synthesized
magnetite nanoparticles-protein hybrid has been produced by treating
Iron (III) / Iron (II) chloride with the leaf extract of Datura inoxia.
The phytochemicals present in the leaf extracts act as a reducing as
well stabilizing agents preventing agglomeration, which include
flavonoids, phenolic compounds, cardiac glycosides, proteins and
sugars.
The magnetite nanoparticles-protein hybrid has been trapped
inside the aqueous core of the liposome prepared by reversed phase
evaporation (REV) method using oleic and linoleic acid which has
been shown to be driven under magnetic field confirming the
formation magnetic liposome (ML). Chemical characterization of
stealth magnetic liposome has been performed by breaking the
liposome and release of magnetic nanoparticles. The presence iron
has been confirmed by colour complex formation with KSCN and
UV-Vis study using spectrophotometer Cary 60, Agilent.
This magnet driven liposome using nanoparticles-protein hybrid
can be a smart vesicles for the targeted drug delivery.
Abstract: Over the last few decades, oilfield service rolling
equipment has significantly increased in weight, primarily because of
emissions regulations, which require larger/heavier engines, larger
cooling systems, and emissions after-treatment systems, in some
cases, etc. Larger engines cause more vibration and shock loads,
leading to failure of electronics and control systems.
If the vibrating frequency of the engine matches the system
frequency, high resonance is observed on structural parts and mounts.
One such existing automated control equipment system comprising
wire rope mounts used for mounting computers was designed
approximately 12 years ago. This includes the use of an industrialgrade
computer to control the system operation. The original
computer had a smaller, lighter enclosure. After a few years, a newer
computer version was introduced, which was 10 lbm heavier. Some
failures of internal computer parts have been documented for cases in
which the old mounts were used. Because of the added weight, there
is a possibility of having the two brackets impact each other under
off-road conditions, which causes a high shock input to the computer
parts. This added failure mode requires validating the existing mount
design to suit the new heavy-weight computer.
This paper discusses the modal finite element method (FEM)
analysis and experimental modal analysis conducted to study the
effects of vibration on the wire rope mounts and the computer. The
existing mount was modelled in ANSYS software, and resultant
mode shapes and frequencies were obtained. The experimental modal
analysis was conducted, and actual frequency responses were
observed and recorded.
Results clearly revealed that at resonance frequency, the brackets
were colliding and potentially causing damage to computer parts. To
solve this issue, spring mounts of different stiffness were modeled in
ANSYS software, and the resonant frequency was determined.
Increasing the stiffness of the system increased the resonant
frequency zone away from the frequency window at which the engine
showed heavy vibrations or resonance. After multiple iterations in
ANSYS software, the stiffness of the spring mount was finalized,
which was again experimentally validated.
Abstract: Many wireless sensor network applications require
K-coverage of the monitored area. In this paper, we propose a
scalable harmony search based algorithm in terms of execution
time, K-Coverage Enhancement Algorithm (KCEA), it attempts to
enhance initial coverage, and achieve the required K-coverage degree
for a specific application efficiently. Simulation results show that
the proposed algorithm achieves coverage improvement of 5.34%
compared to K-Coverage Rate Deployment (K-CRD), which achieves
1.31% when deploying one additional sensor. Moreover, the proposed
algorithm is more time efficient.
Abstract: Nowadays social media information, such as news,
links, images, or VDOs, is shared extensively. However, the
effectiveness of disseminating information through social media
lacks in quality: less fact checking, more biases, and several rumors.
Many researchers have investigated about credibility on Twitter, but
there is no the research report about credibility information on
Facebook. This paper proposes features for measuring credibility on
Facebook information. We developed the system for credibility on
Facebook. First, we have developed FB credibility evaluator for
measuring credibility of each post by manual human’s labelling. We
then collected the training data for creating a model using Support
Vector Machine (SVM). Secondly, we developed a chrome extension
of FB credibility for Facebook users to evaluate the credibility of
each post. Based on the usage analysis of our FB credibility chrome
extension, about 81% of users’ responses agree with suggested
credibility automatically computed by the proposed system.
Abstract: The recommended limit for cadmium concentration in
potable water is less than 0.005 mg/L. A continuous biosorption
process using indigenous red seaweed, Gracilaria corticata, was
performed to remove cadmium from the potable water. The process
was conducted under fixed conditions and the breakthrough curves
were achieved for three consecutive sorption-desorption cycles. A
modeling based on Artificial Neural Network (ANN) was employed
to fit the experimental breakthrough data. In addition, a simplified
semi empirical model, Thomas, was employed for this purpose. It
was found that ANN well described the experimental data (R2>0.99)
while the Thomas prediction were a bit less successful with R2>0.97.
The adjusted design parameters using the nonlinear form of Thomas
model was in a good agreement with the experimentally obtained
ones. The results approve the capability of ANN to predict the
cadmium concentration in potable water.
Abstract: The paper examines the interaction between the
environmental taxation, size of government spending on
environmental protection and greenhouse gas emissions and gross
inland energy consumption. The aim is to analyze the effects of
environmental taxation and government spending on environmental
protection as an environmental policy instruments on greenhouse gas
emissions and gross inland energy consumption in the EU15. The
empirical study is performed using a VAR approach with the
application of aggregated data of EU15 over the period 1995 to 2012.
The results provide the evidence that the reactions of greenhouse gas
emission and gross inland energy consumption to the shocks of
environmental policy instruments are strong, mainly in the short term
and decay to zero after about 8 years. Further, the reactions of the
environmental policy instruments to the shocks of greenhouse gas
emission and gross inland energy consumption are also strong in the
short term, however with the deferred effects. In addition, the results
show that government spending on environmental protection together
with gross inland energy consumption has stronger effect on
greenhouse gas emissions than environmental taxes in EU15 over the
examined period.