Abstract: Cadmium oxide (CdO) nanoparticles have been
prepared by chemical coprecipitation method. The synthesized
nanoparticles were characterized by X-ray diffraction analysis
(XRD), scanning electron microscopy (SEM), transmission electron
microscopy (TEM), UV analysis, and dielectric studies. The
crystalline nature and particle size of the CdO nanoparticles were
characterized by Powder X-ray diffraction analysis (XRD). The
morphology of prepared CdO nanoparticles was studied by scanning
electron microscopy. The particle size was studied using the
transmission electron microscopy (TEM).The optical properties were
obtained from UV-Vis absorption spectrum. The dielectric properties
of CdO nanoparticles were studied in the frequency range of 50 Hz–5
MHz at different temperatures. The frequency dependence of the
dielectric constant and dielectric loss is found to decrease with an
increase in the frequency at different temperatures. The ac
conductivity of CdO nanoparticle has been studied.
Abstract: Brushless DC motors (BLDC) are widely used in
industrial areas. The BLDC motors are driven either by indirect ACAC
converters or by direct AC-AC converters. Direct AC-AC
converters i.e. matrix converters are used in this paper to drive the
three phase BLDC motor and it eliminates the bulky DC link energy
storage element. A matrix converter converts the AC power supply to
an AC voltage of variable amplitude and variable frequency. A
control technique is designed to generate the switching pulses for the
three phase matrix converter. For the control of speed of the BLDC
motor a separate PI controller and Fuzzy Logic Controller (FLC) are
designed and a hysteresis current controller is also designed for the
control of motor torque. The control schemes are designed and tested
separately. The simulation results of both the schemes are compared
and contrasted in this paper. The results show that the fuzzy logic
control scheme outperforms the PI control scheme in terms of
dynamic performance of the BLDC motor. Simulation results are
validated with the experimental results.
Abstract: The research investigates the causes of unemployment
in Namibia, Nigeria and South Africa and the role of Capital
Accumulation in reducing the unemployment profile of these
economies as proposed by the post-Keynesian economics. This is
conducted through extensive review of literature on the NAIRU
models and focused on the post-Keynesian view of unemployment
within the NAIRU framework. The NAIRU (non-accelerating
inflation rate of unemployment) model has become a dominant
framework used in macroeconomic analysis of unemployment. The
study views the post-Keynesian economics arguments that capital
accumulation is a major determinant of unemployment.
Unemployment remains the fundamental socio-economic challenge
facing African economies. It has been a burden to citizens of those
economies. Namibia, Nigeria, and South Africa are great African
nations battling with high unemployment rates. The high
unemployment rate in the country led the citizens to chase away
foreigners in the country claiming that they have taken away their
jobs. The study proposes there is a strong relationship between
capital accumulation and unemployment in Namibia, Nigeria, and
South Africa, and capital accumulation is responsible for high
unemployment rates in these countries. For the economies to achieve
steady state level of employment and satisfactory level of economic
growth and development, there is need for capital accumulation to
take place. The countries in the study have been selected after a
critical research and investigations. They are selected based on the
following criteria; African economies with high unemployment rates
above 15% and have about 40% of their workforce unemployed. This
level of unemployment is the critical level of unemployment in
Africa as expressed by International Labour Organization (ILO). And
finally, the African countries experience a slow growth in their Gross
fixed capital formation. Adequate statistical measures have been
employed using a time-series analysis in the study and the results
revealed that capital accumulation is the main driver of
unemployment performance in the chosen African countries. An
increase in the accumulation of capital causes unemployment to
reduce significantly. The results of the research work will be useful
and relevant to federal governments and ministries, departments and
agencies (MDAs) of Namibia, Nigeria and South Africa to resolve
the issue of high and persistent unemployment rates in their
economies which are great burden that slows growth and
development of developing economies. Also, the result can be useful
to World Bank, African Development Bank and International Labour
Organization (ILO) in their further research and studies on how to
tackle unemployment in developing and emerging economies.
Abstract: The question of legal liability over injury arising out
of the import and the introduction of GM food emerges as a crucial
issue confronting to promote GM food and its derivatives. There is a
greater possibility of commercialized GM food from the exporting
country to enter importing country where status of approval shall not
be same. This necessitates the importance of fixing a liability
mechanism to discuss the damage, if any, occurs at the level of
transboundary movement or at the market. There was a widespread consensus to develop the Cartagena
Protocol on Biosafety and to give for a dedicated regime on liability
and redress in the form of Nagoya Kuala Lumpur Supplementary
Protocol on the Liability and Redress (‘N-KL Protocol’) at the
international context. The national legal frameworks based on this
protocol are not adequately established in the prevailing food
legislations of the developing countries. The developing economy
like India is willing to import GM food and its derivatives after the
successful commercialization of Bt Cotton in 2002. As a party to the
N-KL Protocol, it is indispensable for India to formulate a legal
framework and to discuss safety, liability, and regulatory issues
surrounding GM foods in conformity to the provisions of the
Protocol. The liability mechanism is also important in the case where
the risk assessment and risk management is still in implementing
stage. Moreover, the country is facing GM infiltration issues with its
neighbors Bangladesh. As a precautionary approach, there is a need
to formulate rules and procedure of legal liability to discuss any kind
of damage occurs at transboundary trade. In this context, the
proposed work will attempt to analyze the liability regime in the
existing Food Safety and Standards Act, 2006 from the applicability
and domestic compliance and to suggest legal and policy options for
regulatory authorities.
Abstract: The strain intensity and redundant strains, dependent
in multistage TRIP wire drawing processes from values used single
partial reductions, should influence on the intensity of transformation
the retained austenite into martensite and thereby on mechanical
properties of drawn wires. The numerical analysis of drawing
processes with use of Drawing 2D programme, for steel wires made
from TRIP steel with 0,29% has been shown in the work. The change
of strain intensity εc and the values of redundant strain εxy, has been
determined for particular draws in dependence of used single partial
reductions.
Abstract: Average temperatures worldwide are expected to
continue to rise. At the same time, major cities in developing
countries are becoming increasingly populated and polluted.
Governments are tasked with the problem of overheating and air
quality in residential buildings. This paper presents the development
of a model, which is able to estimate the occupant exposure
to extreme temperatures and high air pollution within domestic
buildings. Building physics simulations were performed using the
EnergyPlus building physics software. An accurate metamodel is
then formed by randomly sampling building input parameters and
training on the outputs of EnergyPlus simulations. Metamodels are
used to vastly reduce the amount of computation time required when
performing optimisation and sensitivity analyses. Neural Networks
(NNs) have been compared to a Radial Basis Function (RBF)
algorithm when forming a metamodel. These techniques were
implemented using the PyBrain and scikit-learn python libraries,
respectively. NNs are shown to perform around 15% better than RBFs
when estimating overheating and air pollution metrics modelled by
EnergyPlus.
Abstract: The purposes of this study were to: 1) investigate
operation conditions of SME automotive part industry in Bangkok
and vicinity and 2) to compare operation problem levels of SME
automotive part industry in Bangkok and vicinity according to the
sizes of the enterprises. Samples in this study included 196
entrepreneurs of SME automotive part industry in Bangkok and
vicinity derived from simple random sampling and calculation from
R. V. Krejcie and D. W. Morgan’s tables. Research statistics included
frequency, percentage, mean, standard deviation, and T-test. The
results revealed that in general the problem levels of SME automotive
part industry in Bangkok and vicinity were high. When considering
in details, it was found that the problem levels were high at every
aspect, i.e. personal, production, export, finance, and marketing
respectively. The comparison of the problem levels according to the
sizes of the enterprises revealed statistically significant differences at
.05. When considering on each aspect, it was found that the aspect
with the statistical difference at .05 included 5 aspects, i.e.
production, marketing, finance, personal, and export. The findings
also showed that small enterprises faced more severe problems than
those of medium enterprises.
Abstract: The increase in electric power demand in face of
environmental issues has intensified the participation of renewable
energy sources such as photovoltaics, in the energy matrix of various
countries. Due to their operational characteristics, they can generate
time-varying harmonic and inter-harmonic distortions. For this
reason, the application of methods of measurement based on
traditional Fourier analysis, as proposed by IEC 61000-4-7, can
provide inaccurate results. Considering the aspects mentioned herein,
came the idea of the development of this work which aims to present
the results of a comparative evaluation between a methodology
arising from the combination of the Prony method with the Kalman
filter and another method based on the IEC 61000-4-30 and IEC
61000-4-7 standards. Employed in this study were synthetic signals
and data acquired through measurements in a 50kWp photovoltaic
installation.
Abstract: A sign pattern is a matrix whose entries belong to the set
{+,−, 0}. An n-by-n sign pattern A is said to allow an eventually
positive matrix if there exist some real matrices A with the same
sign pattern as A and a positive integer k0 such that Ak > 0 for all
k ≥ k0. It is well known that identifying and classifying the n-by-n
sign patterns that allow an eventually positive matrix are posed as two
open problems. In this article, the tree sign patterns of small order
that allow an eventually positive matrix are classified completely.
Abstract: The quality of concrete is usually defined by compressive strength, but flexural strength is the most important characteristic of concrete in a pavement which control the mix design of concrete instead of compressive strength. Therefore, the aggregates which are selected for the pavements are affected by higher flexural strength. Roller Compacting Concrete Pavement (RCCP) is not a new construction method. The other characteristic of this method is no bleeding and less shrinkage due to the lower amount of water. For this purpose, a roller is needed for placing and compacting. The surface of RCCP is not smooth; therefore, the most common use of this pavement is in an industrial zone with slower traffic speed which requires durable and tough pavement. For preparing a smoother surface, it can be achieved by asphalt paver. RCCP decrease the finishing cost because there are no bars, formwork, and the lesser labor need for placing the concrete. In this paper, different aspect of RCCP such as mix design, flexural, compressive strength and focus on the different part of RCCP on detail have been investigated.
Abstract: Social networking sites such as Twitter and Facebook
attracts over 500 million users across the world, for those users, their
social life, even their practical life, has become interrelated. Their
interaction with social networking has affected their life forever.
Accordingly, social networking sites have become among the main
channels that are responsible for vast dissemination of different kinds
of information during real time events. This popularity in Social
networking has led to different problems including the possibility of
exposing incorrect information to their users through fake accounts
which results to the spread of malicious content during life events.
This situation can result to a huge damage in the real world to the
society in general including citizens, business entities, and others. In this paper, we present a classification method for detecting the
fake accounts on Twitter. The study determines the minimized set of
the main factors that influence the detection of the fake accounts on
Twitter, and then the determined factors are applied using different
classification techniques. A comparison of the results of these
techniques has been performed and the most accurate algorithm is
selected according to the accuracy of the results. The study has been
compared with different recent researches in the same area; this
comparison has proved the accuracy of the proposed study. We claim
that this study can be continuously applied on Twitter social network
to automatically detect the fake accounts; moreover, the study can be
applied on different social network sites such as Facebook with minor
changes according to the nature of the social network which are
discussed in this paper.
Abstract: Highly stable and homogeneously dispersed amino
acid coated silver nanoparticles (ANP) of ≈ 10 nm diameter, ranging
from 420 to 430 nm are prepared on AgNO3 solution addition to gum
of Azadirachta indica solution at 373.15 K. The amino acids were
selected based on their polarity. The synthesized nanoparticles were
characterized by UV-Vis, FTIR spectroscopy, HR-TEM, XRD, SEM
and 1H-NMR. The coated nanoparticles were used as catalyst for the
reduction of methylene blue dye in presence of Sn(II) in aqueous,
anionic and cationic micellar media. The rate of reduction of dye was
determined by measuring the absorbance at 660 nm,
spectrophotometrically and followed the order: Kcationic > Kanionic >
Kwater. After 12 min and in absence of the ANP, only 2%, 3% and 6%
of the dye reduction was completed in aqueous, anionic and cationic
micellar media respectively while, in presence of ANP coated by
polar neutral amino acid with non-polar -R group, the reduction
completed to 84%, 95% and 98% respectively. The ANP coated with
polar neutral amino acid having non-polar -R group, increased the
rate of reduction of the dye by 94, 3205 and 6370 folds in aqueous,
anionic and cationic micellar media respectively. Also, the rate of
reduction of the dye increased by three folds when the micellar media
was changed from anionic to cationic when the ANP is coated by a
polar neutral amino acid having a non-polar -R group.
Abstract: Carbon dioxide is one of the major greenhouse gas
(GHG) contributors. It is an obligation of the industry to reduce the
amount of carbon dioxide emission to the acceptable limits.
Tremendous research and studies are reported in the past and still the
quest to find the suitable and economical solution of this problem
needed to be explored in order to develop the most plausible absorber
for carbon dioxide removal. Amino acids can be potential alternate
solvents for carbon dioxide capture from gaseous streams. This is due
to its ability to resist oxidative degradation, low volatility and its
ionic structure. In addition, the introduction of promoter-like
piperazine to amino acid helps to further enhance the solubility. In
this work, the effect of piperazine on thermo physical properties and
solubility of β-Alanine aqueous solutions were studied for various
concentrations. The measured physicochemical properties data was
correlated as a function of temperature using least-squares method
and the correlation parameters are reported together with it respective
standard deviations. The effect of activator piperazine on the CO2
loading performance of selected amino acid under high-pressure
conditions (1bar to 10bar) at temperature range of (30 to 60)oC was
also studied. Solubility of CO2 decreases with increasing temperature
and increases with increasing pressure. Quadratic representation of
solubility using Response Surface Methodology (RSM) shows that
the most important parameter to optimize solubility is system
pressure. The addition of promoter increases the solubility effect of
the solvent.
Abstract: Dengue is a mosquito-borne viral disease endemic in
many countries in the tropics and sub-tropics. The state of Punjab in
India shows cyclical and seasonal variation in dengue cases. The
Case Fatality Rate of Dengue has ranged from 0.6 to 1.0 in the past
years. The department has initiated review of the cases that have died
due to dengue in order to know the exact cause of the death in a case
of dengue. The study has been undertaken to know the other
associated co-morbidities and factors causing death in a case of
dengue. The study used the predesigned proforma on which the
records (medical and Lab) were recorded and reviewed by the expert
committee of the doctors. This study has revealed that cases of
dengue having co-morbidities have longer stay in hospital. Fluid
overload and co-morbidities have been found as major factors leading
to death, however, in a confirmed case of dengue hepatorenal
shutdown was found to be major cause of mortality. The data
obtained will help in sensitizing the treating physicians in order to
decrease the mortality due to dengue in future.
Abstract: This paper focuses on the mathematical modeling for
solidification of Al alloy in a cube mold cavity to study the
solidification behavior of casting process. The parametric
investigation of solidification process inside the cavity was
performed by using computational solidification/melting model
coupled with Volume of fluid (VOF) model. The implicit filling
algorithm is used in this study to understand the overall process from
the filling stage to solidification in a model metal casting process.
The model is validated with past studied at same conditions. The
solidification process is analyzed by including the effect of pouring
velocity as well as natural convection from the wall and geometry of
the cavity. These studies show the possibility of various defects
during solidification process.
Abstract: This paper presents the effect of the orbit inclination
on the pointing error of the satellite antenna and consequently on its
footprint on earth for a typical Ku- band payload system. The performance assessment is examined using both analytical
simulations and practical measurements, taking into account all the
additional sources of the pointing errors, such as East-West station
keeping, orbit eccentricity, and actual attitude control performance. An implementation and computation of the sinusoidal biases in
satellite roll and pitch used to compensate the pointing error of the
satellite antenna coverage is studied and evaluated before and after
the pointing corrections performed. A method for evaluation of the performance of the implemented
biases has been introduced through measuring satellite received level
from a mono-pulse tracking 11.1m transmitting antenna before and
after the implementation of the pointing corrections.
Abstract: A myriad of environmental issues face the Nigerian
industrial region, resulting from; oil and gas production, mining,
manufacturing and domestic wastes. Amidst these, much effort has
been directed by stakeholders in the Nigerian oil producing regions,
because of the impacts of the region on the wider Nigerian economy.
Although collaborative environmental management has been noted as
an effective approach in managing environmental issues, little
attention has been given to the roles and practices of stakeholders in
effecting a collaborative environmental management framework for
the Nigerian oil-producing region. This paper produces a framework
to expand and deepen knowledge relating to stakeholders aspects of
collaborative roles in managing environmental issues in the Nigeria
oil-producing region. The knowledge is derived from analysis of
stakeholders’ practices – studied through multiple case studies using
document analysis. Selected documents of key stakeholders –
Nigerian government agencies, multi-national oil companies and host
communities, were analyzed. Open and selective coding was
employed manually during document analysis of data collected from
the offices and websites of the stakeholders. The findings showed
that the stakeholders have a range of roles, practices, interests, drivers
and barriers regarding their collaborative roles in managing
environmental issues. While they have interests for efficient resource
use, compliance to standards, sharing of responsibilities, generating
of new solutions, and shared objectives; there is evidence of major
barriers and these include resource allocation, disjointed policy,
ineffective monitoring, diverse socio- economic interests, lack of
stakeholders’ commitment and limited knowledge sharing. However,
host communities hold deep concerns over the collaborative roles of
stakeholders for economic interests, particularly, where government
agencies and multi-national oil companies are involved. With these
barriers and concerns, a genuine stakeholders’ collaboration is found
to be limited, and as a result, optimal environmental management
practices and policies have not been successfully implemented in the
Nigeria oil-producing region. A framework is produced that describes
practices that characterize collaborative environmental management
might be employed to satisfy the stakeholders’ interests. The
framework recommends critical factors, based on the findings, which
may guide a collaborative environmental management in the oil
producing regions. The recommendations are designed to re-define
the practices of stakeholders in managing environmental issues in the
oil producing regions, not as something wholly new, but as an
approach essential for implementing a sustainable environmental
policy. This research outcome may clarify areas for future research as
well as to contribute to industry guidance in the area of collaborative
environmental management.
Abstract: This paper deals with using of prevailing operation
system MS Office (SmartArt...) for mathematical models, using
DYVELOP (Dynamic Vector Logistics of Processes) method. It
serves for crisis situations investigation and modelling within the
organizations of critical infrastructure. In first part of paper, it will be
introduced entities, operators, and actors of DYVELOP method. It
uses just three operators of Boolean algebra and four types of the
entities: the Environments, the Process Systems, the Cases, and the
Controlling. The Process Systems (PrS) have five “brothers”:
Management PrS, Transformation PrS, Logistic PrS, Event PrS and
Operation PrS. The Cases have three “sisters”: Process Cell Case,
Use Case, and Activity Case. They all need for the controlling of
their functions special Ctrl actors, except ENV – it can do without
Ctrl. Model´s maps are named the Blazons and they are able
mathematically - graphically express the relationships among entities,
actors and processes. In second part of this paper, the rich blazons of
DYVELOP method will be used for the discovering and modelling of
the cycling cases and their phases. The blazons need live PowerPoint
presentation for better comprehension of this paper mission. The
crisis management of energetic crisis infrastructure organization is
obliged to use the cycles for successful coping of crisis situations.
Several times cycling of these cases is necessary condition for the
encompassment for both emergency events and the mitigation of
organization´s damages. Uninterrupted and continuous cycling
process brings for crisis management fruitfulness and it is good
indicator and controlling actor of organizational continuity and its
sustainable development advanced possibilities. The research reliable
rules are derived for the safety and reliable continuity of energetic
critical infrastructure organization in the crisis situation.
Abstract: Bezier curves have useful properties for path
generation problem, for instance, it can generate the reference
trajectory for vehicles to satisfy the path constraints. Both algorithms
join cubic Bezier curve segment smoothly to generate the path. Some
of the useful properties of Bezier are curvature. In mathematics,
curvature is the amount by which a geometric object deviates from
being flat, or straight in the case of a line. Another extrinsic example
of curvature is a circle, where the curvature is equal to the reciprocal
of its radius at any point on the circle. The smaller the radius, the
higher the curvature thus the vehicle needs to bend sharply. In this
study, we use Bezier curve to fit highway-like curve. We use
different approach to find the best approximation for the curve so that
it will resembles highway-like curve. We compute curvature value by
analytical differentiation of the Bezier Curve. We will then compute
the maximum speed for driving using the curvature information
obtained. Our research works on some assumptions; first, the Bezier
curve estimates the real shape of the curve which can be verified
visually. Even though, fitting process of Bezier curve does not
interpolate exactly on the curve of interest, we believe that the
estimation of speed are acceptable. We verified our result with the
manual calculation of the curvature from the map.
Abstract: In the present study, feasibility of the selective surface
hydrophilization of polyvinyl chloride (PVC) by microwave treatment
was evaluated to facilitate the separation from automotive shredder
residue (ASR), by the froth flotation. The combination of 60 sec
microwave treatment with PAC, a sharp and significant decrease about
16.5° contact angle of PVC was observed in ASR plastic compared
with other plastics. The microwave treatment with the addition of PAC
resulted in a synergetic effect for the froth flotation, which may be a
result of the 90% selective separation of PVC from ASR plastics, with
82% purity. While, simple mixing with a nanometallic Ca/CaO/PO4
dispersion mixture immobilized 95-100% of heavy metals in ASR
soil/residues. The quantity of heavy metals leached from thermal
residues after treatment by nanometallic Ca/CaO/PO4 was lower than
the Korean standard regulatory limit for hazardous waste landfills.
Microwave treatment can be a simple and effective method for PVC
separation from ASR plastics.